Les cyanobactéries ont une place très importante dans les écosystèmes aquatiques et un nombre important d’espèces considéré comme nuisible de par leur production de métabolites toxiques. Ces cyanotoxines possèdent des propriétés très variées et ont souvent été associées à des épisodes d’empoisonnement. L’augmentation des épisodes d’efflorescence d’origine cyanobactériennes et le potentiel qu’ils augmentent avec les changements climatiques a renchéri l’intérêt de l’étude des cyanobactéries et de leurs toxines. Considérant la complexité chimique des cyanotoxines, le développement de méthodes de détection simples, sensibles et rapides est toujours considéré comme étant un défi analytique. Considérant ces défis, le développement de nouvelles approches analytiques pour la détection de cyanotoxines dans l’eau et les poissons ayant été contaminés par des efflorescences cyanobactériennes nuisibles a été proposé. Une première approche consiste en l’utilisation d’une extraction sur phase solide en ligne couplée à une chromatographie liquide et à une détection en spectrométrie de masse en tandem (SPE-LC-MS/MS) permettant l’analyse de six analogues de microcystines (MC), de l’anatoxine (ANA-a) et de la cylindrospermopsine (CYN). La méthode permet une analyse simple et rapide et ainsi que la séparation chromatographique d’ANA-a et de son interférence isobare, la phénylalanine. Les limites de détection obtenues se trouvaient entre 0,01 et 0,02 μg L-1 et des concentrations retrouvées dans des eaux de lacs du Québec se trouvaient entre 0,024 et 36 μg L-1. Une deuxième méthode a permis l’analyse du b-N-méthylamino-L-alanine (BMAA), d’ANA-a, de CYN et de la saxitoxine (STX) dans les eaux de lac contaminés. L’analyse de deux isomères de conformation du BMAA a été effectuée afin d’améliorer la sélectivité de la détection. L’utilisation d’une SPE manuelle permet la purification et préconcentration des échantillons et une dérivatisation à base de chlorure de dansyle permet une chromatographie simplifiée. L’analyse effectuée par LC couplée à la spectrométrie de masse à haute résolution (HRMS) et des limites de détections ont été obtenues entre 0,007 et 0,01 µg L-1. Des échantillons réels ont été analysés avec des concentrations entre 0,01 et 0,3 µg L-1 permettant ainsi la confirmation de la présence du BMAA dans les efflorescences de cyanobactéries au Québec. Un deuxième volet du projet consiste en l’utilisation d’une technologie d’introduction d’échantillon permettant des analyses ultra-rapides (< 15 secondes/échantillons) sans étape chromatographique, la désorption thermique à diode laser (LDTD) couplée à l’ionisation chimique à pression atmosphérique (APCI) et à la spectrométrie de masse (MS). Un premier projet consiste en l’analyse des MC totales par l’intermédiaire d’une oxydation de Lemieux permettant un bris de la molécule et obtenant une fraction commune aux multiples congénères existants des MC. Cette fraction, le MMPB, est analysée, après une extraction liquide-liquide, par LDTD-APCI-MS/MS. Une limite de détection de 0,2 µg L-1 a été obtenue et des concentrations entre 1 et 425 µg L-1 ont été trouvées dans des échantillons d’eau de lac contaminés du Québec. De plus, une analyse en parallèle avec des étalons pour divers congénères des MC a permis de suggérer la possible présence de congénères ou d’isomères non détectés. Un deuxième projet consiste en l’analyse directe d’ANA-a par LDTD-APCI-HRMS pour résoudre son interférence isobare, la phénylalanine, grâce à la détection à haute résolution. La LDTD n’offre pas de séparation chromatographique et l’utilisation de la HRMS permet de distinguer les signaux d’ANA-a de ceux de la phénylalanine. Une limite de détection de 0,2 µg L-1 a été obtenue et la méthode a été appliquée sur des échantillons réels d’eau avec un échantillon positif en ANA-a avec une concentration de 0,21 µg L-1. Finalement, à l’aide de la LDTD-APCI-HRMS, l’analyse des MC totales a été adaptée pour la chair de poisson afin de déterminer la fraction libre et liée des MC et comparer les résultats avec des analyses conventionnelles. L’utilisation d’une digestion par hydroxyde de sodium précédant l’oxydation de Lemieux suivi d’une purification par SPE a permis d’obtenir une limite de détection de 2,7 µg kg-1. Des échantillons de poissons contaminés ont été analysés, on a retrouvé des concentrations en MC totales de 2,9 et 13,2 µg kg-1 comparativement aux analyses usuelles qui avaient démontré un seul échantillon positif à 2 µg kg-1, indiquant la possible présence de MC non détectés en utilisant les méthodes conventionnelles. / Cyanobacteria have a very important place in aquatic ecosystems and a significant number of species are considered harmful given their production of toxic metabolites. These cyanotoxins have various chemical proprieties and have often been associated with poisoning episodes. The frequency of cyanobacterial blooms is increasing and the study of cyanobacteria and their toxins is of increasing interest, especially considering the potential increase associated with climate changes. Given the chemical complexity of the cyanotoxins, the development of simple, sensitive and fast detection methods is an analytical challenge. Considering these issues, the development of new analytical approaches for the detection of cyanotoxins in water and fish samples contaminated with harmful cyanobacterial blooms have been proposed. A first approach consists of the use of an on-line solid phase extraction coupled to liquid chromatography and tandem mass spectrometry (SPE-LC-MS/MS) for the analysis of six microcystins (MCs), anatoxin-a (ANA-a) and cylindrospermopsin (CYN). This method allows a simple and rapid analysis and enables the chromatographic separation of ANA-a and its isobaric interference, phenylalanine. The detection limits ranged from 0.01 to 0.02 µg L-1 and concentrations in lake waters were found between 0.024 and 36 µg L-1. A second method consists of using manual solid phase extraction (SPE) coupled to high resolution mass spectrometry (HRMS) for the determination of b-N-methylamino-L-alanine (BMAA), ANA-a, CYN and saxitoxin (STX) in contaminated lake water. The analysis of two conformational isomers of BMAA was done to improve the selectivity. Dansyl chloride-based derivatization allows simplified chromatography. The detection limits were obtained between 0.007 and 0.01 µg L-1. The analysis of bloom water samples detected concentrations of cyanotoxins between 0.01 and 0.3 µg L-1 allowing the confirmation of the presence of BMAA in algal blooms in Québec. A second part of the project consists in the use of an alternative sample introduction technology for MS analysis. It enables ultra-fast analysis (< 15 seconds/sample) without the use of a chromatographic step, and is called laser diode thermal desorption (LDTD) coupled with atmospheric pressure chemical ionization (APCI). The first LDTD project consists of the analysis of total MCs via Lemieux oxidation in order to obtain a common moiety of all MCs existing congeners. This fraction, the MMPB, is analyzed after a liquid-liquid extraction step, with the LDTD-APCI-MS/MS. A value of 0.2 µg L-1 was obtained for detection limit and concentrations between 1 and 425 µg L-1 have been found in contaminated water samples. In addition, a comparison with a parallel analysis using MCs congeners’ standards suggested the possible presence of undetected MCs or isomers. A second project involves the direct analysis of ANA-a using LDTD-APCI-HRMS in order to solve the isobaric interference, phenylalanine, which is possible due to the high resolution detection. The LDTD offers no chromatographic separation and by using HRMS, we can distinguish ANA-a signals from those of phenylalanine. A value of 0.2 µg L-1 was obtained as detection limit and the method has been applied on water bloom samples with a positive concentration of 0.21 µg L-1. Finally, using the LDTD-APCI-HRMS combination, analysis of total MCs has been adapted to fish tissues to determine the unbound and bound MCs and compare the results with standard analysis. The use of digestion with sodium hydroxide prior to Lemieux oxidation followed by SPE purification yielded a detection limit of 2.7 µg kg-1. Total MCs concentrations were found between 2.9 and 13.2 µg kg-1 in real field-collected contaminated fish samples and comparison was made with standard analysis which yield a single positive sample with a concentration of 2 µg kg-1. This indicates the possible presence of undetected MCs using conventional analytical methods.

Cette thèse porte sur la conception, la réalisation et la caractérisation de diodes lasers de puissance, faible bruit à 1.5 µm sur InP pour des applications d’optique hyperfréquence, notamment pour des liaisons optiques analogiques de grande dynamique pour les systèmes radar. La première partie du travail a consisté à modéliser et concevoir des structures laser DFB ayant de faibles pertes internes. Ces structures, appelées lasers à semelle, incorporent une couche épaisse de matériaux entre la zone active et le substrat pour agrandir et délocaliser le mode propre optique des zones dopées p. La complexité de la conception résidait dans le bon compromis à trouver entre les performances statiques et dynamiques. Nous avons réalisé des diodes-lasers DFB avec une puissance > 150 mW, un rendement de 0.4 W/A, un niveau de bruit de 160 dB/Hz et une bande passante de modulation à 3 dB de 7.5 GHz. Les composants ont ensuite été caractérisés puis évalués dans des liaisons analogiques. Nous avons démontré des performances de gain de liaison, de dynamique et de point de compression à l’état de l’art mondial. En bande L (1-2 GHz) par exemple, nous avons montré des liaisons avec 0.5 dB de gain, un point de compression de 21 dBm et une dynamique (SFDR) de 122 dB.Hz2/3.En utilisant la même méthodologie de conception, la dernière partie du travail de thèse a été consacrée à la réalisation et à la caractérisation de lasers de puissance à verrouillage de modes pour la génération de train d’impulsions ultra-courts et la génération de peignes de fréquences. Ces structures présentent de très faibles largeurs de raie RF (550 Hz) et de très fortes puissances optiques (> 18 W en puissance crête). / This work focuses on the design, realization and characterization of high power, low noise 1.5 µm diode lasers for microwave applications and more particularly for high dynamic optical analog link for radar systems. The first part of this study deals with modeling and design of low internal losses DFB laser structures. These specific structures are called slab-coupled optical waveguide lasers, and are composed of a thick layer between the active layer and the substrate. The aim of this waveguide is to enlarge the optical eigenmode and to move the optical mode away from p-doped layers. The main difficulty was to find the good trade-off between laser static performances (optical power, efficiency) and dynamic performances (RIN and modulation bandwidth). We have succeeded in developing high efficiency (0.4 W/A), low noise (RIN ≈ 160 dB/Hz) DFB lasers with more than 150 mW and a 3 dB modulation bandwidth up to 7.5 GHz. We have then characterized our components on wide band and narrow band analog links. We have demonstrated state of the art gain links, dynamic and 1 dB compression power. In the L band (1-2 GHz) for example, we have obtained an optical link with a gain of 0.5 dB, a compression power of 21 dBm and a dynamic (SFDR) of 122 dB.Hz2/3.Finally we have applied the methodology and the design of slab-coupled optical waveguide structures to develop high power mode-locked lasers for ultra-short pulses generation and for optical and electrical comb generation. We have demonstrated narrow RF linewidth (550 Hz) lasers with very high power (continuous power > 400 mW and peak power > 18 W).

The significant advances in fiber-optic technology have broadened the optical network\'s reach into end-user business premises and even homes, allowing new services and technologies to be delivered to the customers. The next wave of innovation will certainly generate numerous opportunities provided by the widespread popularity of emerging solutions and applications such as tactile Internet, telemedicine and real time 3-D content generation, making them part of everyday life. Nevertheless, to support such an unprecedented and insatiable demand of data traffic, higher capacity and security, flexible bandwidth allocation and cost-efficiency have become crucial requirements for technologies candidate for future optical access networks. To this aim, optical code-division multiple-access (OCDMA) technology is considered as a prospective candidate, particularly due to features like asynchronous transmissions, flexible as well as conscious bandwidth resource distribution and support to differentiated services at the physical layer, to name but a few. In this context, this thesis proposes new mathematical formalisms for bit error rate, packet throughput and packet delay to assess the performance of flexible OCDMA networks capable of providing multiservice multirate transmissions according to users\' requirements. The proposed analytical formalisms do not require the knowledge a priori of the users\' code sequences, which means that the network performance can be addressed in a simple and straightforward manner using the code parameters only. In addition, the developed analytical formalisms account for a general number of distinct users\' classes as well as general probability of interference among users. Hence, these formalisms can be successfully applied for performance evaluation of flexible OCDMA networks not only under any number of users\' classes in a network, but also for most spreading codes with good correlation properties. The packet throughput expression is derived assuming Poisson, binomial and Markov chain approaches for the composite packet arrivals with the latter defined as benchmark. Then, it is shown via numerical simulation the Poisson-based expression is not appropriate for a reliable throughput estimate when compared to the benchmark (Markov) results. The binomial-based throughput equation, by its turn, provides results as accurate as the benchmark. In addition, the binomial-based throughput is numerically more convenient and computationally more efficient than the Markov chain approach, whereas the Markov-based one is computationally expensive, particularly if the number of users is large. The bit error rate (BER) expressions are derived considering gaussian and binomial distributions for the multiple-access interference and it is shown via numerical simulations that accurate performance of flexible OCDMA networks is only obtained with the binomial-based BER expression. This thesis also proposes and investigates a network architecture for Internet protocol traffic over flexible OCDMA with support to multiservice multirate transmissions, which is independent of the employed spreading code and does not require any new optical processing technology. In addition, the network performance assumes users transmitting asynchronously using receptors based on intensity-modulation direct-detection schemes. Numerical simulations shown that the proposed network performs well when its users are defined with high-weight code or when the channel utilization is low. The BER and packet throughput performance of an OCDMA network that provides multirate transmissions via multicode technique with two codes assigned to each single user is also addressed. Numerical results show that this technique outperforms classical techniques based on multilength code. Finally, this thesis addresses a new breakthrough technology that might lead to higher levels of security at the physical layer of optical networks. This technology consists in the generation of deterministic chaos from a commercial free-running vertical-cavity surface-emitting laser (VCSEL). The chaotic dynamics is generated by means of mechanical strains loaded onto an off-the-shelf quantum-well VCSEL using a simple and easily replicable holder. Deterministic chaos is then achieved, for the first time, without any additional complexity of optical feedback, parameter modulation or optical injection. The simplicity of the proposed system, which is based entirely on low-cost and easily available components, opens the way to the widespread use of commercial and free-running VCSEL devices for chaos-based applications. This off-the-shelf and cost-effective optical chaos generator has the potential for not only paving the way towards new security platforms in optical networks like, for example, successfully hiding the user information in an unpredictable, random-like signal against eventual eavesdroppers, but also for influencing emerging chaos applications initially limited or infeasible due to the lack of low-cost solutions. Furthermore, it leads the way to future realization of emerging applications with high-integrability and -scalability such as two-dimensional arrays of chaotic devices comprising hundreds of individual sources to increase requirements for random bit generation, cryptography or large-scale quantum networks. / Os avanços relacionados a tecnologia fotônica ampliaram o alcance das redes de comunicação óptica tanto em instalações de estabelecimentos comerciais quanto em residências, permitindo que novos serviços e tecnologias fossem entregues aos clientes. A próxima onda de inovação certamente gerará inúmeras oportunidades proporcionadas pela popularidade de soluções emergentes e aplicações como a Internet tátil, a telemedicina e a geração de conteúdo 3-D em tempo real, tornando-os parte da vida cotidiana. No entanto, para suportar a crescente demanda de tráfego atual, uma maior capacidade e segurança, alocação flexível de largura de banda e custo-eficiência tornaram-se requisitos cruciais para as tecnologias candidatas a futuras redes de acesso óptico. Para este fim, a tecnologia de acesso múltiplo por divisão de código óptico (OCDMA) é considerada um candidato em potencial, particularmente devido a características como transmissões assíncronas, distribuição flexível de banda larga e suporte a serviços diferenciados na camada física, para citar apenas alguns. Neste contexto, esta tese propõe novos formalismos matemáticos para a taxa de erro de bits, taxa de transferência de pacotes e atraso de pacotes para avaliar o desempenho de redes OCDMA flexíveis capazes de fornecer transmissões em múltiplas qualidades de serviço (QoS) de acordo com as necessidades dos usuários. Os formalismos analíticos propostos não requerem o conhecimento a priori das sequências de código dos usuários, o que significa que o desempenho da rede pode ser abordado de forma simples e direta usando apenas os parâmetros de código. Além disso, os formalismos analíticos desenvolvidos representam um número geral de classes de usuários distintos, bem como a probabilidade geral de interferência entre os usuários. Portanto, esses formalismos podem ser aplicados com sucesso na avaliação de desempenho de redes OCDMA flexíveis não apenas em qualquer número de classes de usuários em uma rede, mas também para a maioria dos códigos de espalhamento com boas propriedades de correlação. A expressão de taxa de transferência de pacotes é derivada assumindo aproximações de Poisson, binomial e de cadeia de Markov para as chegadas de pacotes compostos, com a última definida como benchmark. Em seguida, é mostrado via simulação numérica que a expressão baseada em Poisson não é apropriada para uma estimativa confiável de taxa de transferência quando comparada aos resultados de benchmark (Markov). A equação de taxa de transferência binomial, por sua vez, fornece resultados tão precisos quanto o benchmark. Além disso, a taxa de transferência binomial é numericamente mais conveniente e computacionalmente eficiente quando comparada com abordagem de Markov, enquanto esta última é computacionalmente dispendiosa, particularmente se o número de usuários é grande. As expressões de taxa de erro de bit (BER) são derivadas considerando distribuições gaussianas e binomiais para a interferência de acesso múltiplo e é mostrado por meio de simulações numéricas que o desempenho exato de redes OCDMA flexíveis é obtido somente com a expressão binomial de BER. Esta tese também propõe e investiga uma arquitetura de rede para o tráfego de protocolo de Internet sobre OCDMA flexível com suporte a transmissões de QoS e de múltiplas taxas, que é independente do código de espalhamento empregado e não requer qualquer nova tecnologia de processamento óptico. Além disso, o desempenho da rede assume que os usuários transmitem de forma assíncrona usando receptores baseados em esquemas de detecção direta de modulação de intensidade. As simulações numéricas mostraram que a rede proposta possui melhor desempenho quando seus usuários são definidos com peso de código alto ou quando a utilização do canal é baixa. O desempenho da BER e da taxa de transferência de pacotes de uma rede OCDMA que fornece transmissões de múltiplas taxas por meio de uma técnica multi-código com dois códigos atribuídos a cada usuário é também abordado. Os resultados numéricos mostram que esta técnica supera as técnicas clássicas baseadas no código de comprimento múltiplo. Finalmente, esta tese aborda uma nova tecnologia que pode levar a níveis mais elevados de segurança na camada física de redes ópticas. Esta tecnologia consiste na geração de caos determinístico a partir de um laser de emissão superficial com cavidade vertical (VCSEL). A dinâmica caótica é gerada através da aplicação de forças mecânicas em um VCSEL comercial usando um suporte simples e facilmente replicável. O caos determinístico é então alcançado, pela primeira vez, sem qualquer complexidade adicional de realimentação óptica, modulação de parâmetros ou injeção óptica. A simplicidade do sistema proposto, o qual se baseia inteiramente em componentes de baixo custo e que são facilmente encontrados, abre o caminho para o uso de dispositivos VCSEL comerciais para aplicações baseadas em caos. Este gerador de caos óptico tem o potencial não só de pavimentar o caminho para novas plataformas de segurança em redes ópticas, como, por exemplo, ocultar com êxito as informações do usuário em um sinal imprevisível e aleatório contra eventuais invasores, como também tem o potencial de influenciar aplicações de caos emergentes inicialmente limitadas ou inviáveis devido à falta de soluções de baixo custo. Além disso, ele conduz o caminho para a realização futura de aplicações emergentes com alta integridade e escalabilidade, tais como matrizes bidimensionais de dispositivos caóticos que compreendem centenas de fontes individuais para aumentar as necessidades de geração de bit aleatória, criptografia ou redes quânticas de grande escala.

The significant advances in fiber-optic technology have broadened the optical network\'s reach into end-user business premises and even homes, allowing new services and technologies to be delivered to the customers. The next wave of innovation will certainly generate numerous opportunities provided by the widespread popularity of emerging solutions and applications such as tactile Internet, telemedicine and real time 3-D content generation, making them part of everyday life. Nevertheless, to support such an unprecedented and insatiable demand of data traffic, higher capacity and security, flexible bandwidth allocation and cost-efficiency have become crucial requirements for technologies candidate for future optical access networks. To this aim, optical code-division multiple-access (OCDMA) technology is considered as a prospective candidate, particularly due to features like asynchronous transmissions, flexible as well as conscious bandwidth resource distribution and support to differentiated services at the physical layer, to name but a few. In this context, this thesis proposes new mathematical formalisms for bit error rate, packet throughput and packet delay to assess the performance of flexible OCDMA networks capable of providing multiservice multirate transmissions according to users\' requirements. The proposed analytical formalisms do not require the knowledge a priori of the users\' code sequences, which means that the network performance can be addressed in a simple and straightforward manner using the code parameters only. In addition, the developed analytical formalisms account for a general number of distinct users\' classes as well as general probability of interference among users. Hence, these formalisms can be successfully applied for performance evaluation of flexible OCDMA networks not only under any number of users\' classes in a network, but also for most spreading codes with good correlation properties. The packet throughput expression is derived assuming Poisson, binomial and Markov chain approaches for the composite packet arrivals with the latter defined as benchmark. Then, it is shown via numerical simulation the Poisson-based expression is not appropriate for a reliable throughput estimate when compared to the benchmark (Markov) results. The binomial-based throughput equation, by its turn, provides results as accurate as the benchmark. In addition, the binomial-based throughput is numerically more convenient and computationally more efficient than the Markov chain approach, whereas the Markov-based one is computationally expensive, particularly if the number of users is large. The bit error rate (BER) expressions are derived considering gaussian and binomial distributions for the multiple-access interference and it is shown via numerical simulations that accurate performance of flexible OCDMA networks is only obtained with the binomial-based BER expression. This thesis also proposes and investigates a network architecture for Internet protocol traffic over flexible OCDMA with support to multiservice multirate transmissions, which is independent of the employed spreading code and does not require any new optical processing technology. In addition, the network performance assumes users transmitting asynchronously using receptors based on intensity-modulation direct-detection schemes. Numerical simulations shown that the proposed network performs well when its users are defined with high-weight code or when the channel utilization is low. The BER and packet throughput performance of an OCDMA network that provides multirate transmissions via multicode technique with two codes assigned to each single user is also addressed. Numerical results show that this technique outperforms classical techniques based on multilength code. Finally, this thesis addresses a new breakthrough technology that might lead to higher levels of security at the physical layer of optical networks. This technology consists in the generation of deterministic chaos from a commercial free-running vertical-cavity surface-emitting laser (VCSEL). The chaotic dynamics is generated by means of mechanical strains loaded onto an off-the-shelf quantum-well VCSEL using a simple and easily replicable holder. Deterministic chaos is then achieved, for the first time, without any additional complexity of optical feedback, parameter modulation or optical injection. The simplicity of the proposed system, which is based entirely on low-cost and easily available components, opens the way to the widespread use of commercial and free-running VCSEL devices for chaos-based applications. This off-the-shelf and cost-effective optical chaos generator has the potential for not only paving the way towards new security platforms in optical networks like, for example, successfully hiding the user information in an unpredictable, random-like signal against eventual eavesdroppers, but also for influencing emerging chaos applications initially limited or infeasible due to the lack of low-cost solutions. Furthermore, it leads the way to future realization of emerging applications with high-integrability and -scalability such as two-dimensional arrays of chaotic devices comprising hundreds of individual sources to increase requirements for random bit generation, cryptography or large-scale quantum networks. / Os avanços relacionados a tecnologia fotônica ampliaram o alcance das redes de comunicação óptica tanto em instalações de estabelecimentos comerciais quanto em residências, permitindo que novos serviços e tecnologias fossem entregues aos clientes. A próxima onda de inovação certamente gerará inúmeras oportunidades proporcionadas pela popularidade de soluções emergentes e aplicações como a Internet tátil, a telemedicina e a geração de conteúdo 3-D em tempo real, tornando-os parte da vida cotidiana. No entanto, para suportar a crescente demanda de tráfego atual, uma maior capacidade e segurança, alocação flexível de largura de banda e custo-eficiência tornaram-se requisitos cruciais para as tecnologias candidatas a futuras redes de acesso óptico. Para este fim, a tecnologia de acesso múltiplo por divisão de código óptico (OCDMA) é considerada um candidato em potencial, particularmente devido a características como transmissões assíncronas, distribuição flexível de banda larga e suporte a serviços diferenciados na camada física, para citar apenas alguns. Neste contexto, esta tese propõe novos formalismos matemáticos para a taxa de erro de bits, taxa de transferência de pacotes e atraso de pacotes para avaliar o desempenho de redes OCDMA flexíveis capazes de fornecer transmissões em múltiplas qualidades de serviço (QoS) de acordo com as necessidades dos usuários. Os formalismos analíticos propostos não requerem o conhecimento a priori das sequências de código dos usuários, o que significa que o desempenho da rede pode ser abordado de forma simples e direta usando apenas os parâmetros de código. Além disso, os formalismos analíticos desenvolvidos representam um número geral de classes de usuários distintos, bem como a probabilidade geral de interferência entre os usuários. Portanto, esses formalismos podem ser aplicados com sucesso na avaliação de desempenho de redes OCDMA flexíveis não apenas em qualquer número de classes de usuários em uma rede, mas também para a maioria dos códigos de espalhamento com boas propriedades de correlação. A expressão de taxa de transferência de pacotes é derivada assumindo aproximações de Poisson, binomial e de cadeia de Markov para as chegadas de pacotes compostos, com a última definida como benchmark. Em seguida, é mostrado via simulação numérica que a expressão baseada em Poisson não é apropriada para uma estimativa confiável de taxa de transferência quando comparada aos resultados de benchmark (Markov). A equação de taxa de transferência binomial, por sua vez, fornece resultados tão precisos quanto o benchmark. Além disso, a taxa de transferência binomial é numericamente mais conveniente e computacionalmente eficiente quando comparada com abordagem de Markov, enquanto esta última é computacionalmente dispendiosa, particularmente se o número de usuários é grande. As expressões de taxa de erro de bit (BER) são derivadas considerando distribuições gaussianas e binomiais para a interferência de acesso múltiplo e é mostrado por meio de simulações numéricas que o desempenho exato de redes OCDMA flexíveis é obtido somente com a expressão binomial de BER. Esta tese também propõe e investiga uma arquitetura de rede para o tráfego de protocolo de Internet sobre OCDMA flexível com suporte a transmissões de QoS e de múltiplas taxas, que é independente do código de espalhamento empregado e não requer qualquer nova tecnologia de processamento óptico. Além disso, o desempenho da rede assume que os usuários transmitem de forma assíncrona usando receptores baseados em esquemas de detecção direta de modulação de intensidade. As simulações numéricas mostraram que a rede proposta possui melhor desempenho quando seus usuários são definidos com peso de código alto ou quando a utilização do canal é baixa. O desempenho da BER e da taxa de transferência de pacotes de uma rede OCDMA que fornece transmissões de múltiplas taxas por meio de uma técnica multi-código com dois códigos atribuídos a cada usuário é também abordado. Os resultados numéricos mostram que esta técnica supera as técnicas clássicas baseadas no código de comprimento múltiplo. Finalmente, esta tese aborda uma nova tecnologia que pode levar a níveis mais elevados de segurança na camada física de redes ópticas. Esta tecnologia consiste na geração de caos determinístico a partir de um laser de emissão superficial com cavidade vertical (VCSEL). A dinâmica caótica é gerada através da aplicação de forças mecânicas em um VCSEL comercial usando um suporte simples e facilmente replicável. O caos determinístico é então alcançado, pela primeira vez, sem qualquer complexidade adicional de realimentação óptica, modulação de parâmetros ou injeção óptica. A simplicidade do sistema proposto, o qual se baseia inteiramente em componentes de baixo custo e que são facilmente encontrados, abre o caminho para o uso de dispositivos VCSEL comerciais para aplicações baseadas em caos. Este gerador de caos óptico tem o potencial não só de pavimentar o caminho para novas plataformas de segurança em redes ópticas, como, por exemplo, ocultar com êxito as informações do usuário em um sinal imprevisível e aleatório contra eventuais invasores, como também tem o potencial de influenciar aplicações de caos emergentes inicialmente limitadas ou inviáveis devido à falta de soluções de baixo custo. Além disso, ele conduz o caminho para a realização futura de aplicações emergentes com alta integridade e escalabilidade, tais como matrizes bidimensionais de dispositivos caóticos que compreendem centenas de fontes individuais para aumentar as necessidades de geração de bit aleatória, criptografia ou redes quânticas de grande escala.

Je rapporte dans ce manuscrit une étude théorique et expérimentale d’une source compacte, fiable et bas coût d’ondes électromagnétiques continues et cohérentes de 30 Hz de largeur de raie, accordables de 1 GHz à 500 GHz par pas de 1 GHz. Ces ondes sont générées par un photo-mélange de deux diodes lasers DFB (Distributed Feedback) très accordables autour de 1550 nm, stabilisées avec des polarisations orthogonales sur une même cavité Fabry-Perot optique fibrée. J’ai conçue des électroniques de correction très rapides pour chaque laser permettant d’avoir une bande passante d’asservissement de 7 MHz limitée par la longueur de la boucle. Je démontre des suppressions de bruit de phase jusqu’à -60 dBc/ Hz à 1 kHz et de -90 dBc/Hz à 100 kHz d’écart d’une porteuse électrique à 92 GHz. Je mesure aussi une dérive de fréquence de ~170 kHz d’un battement à 10 GHz à long terme sur 7,5 heures de verrouillage continu. Je montre une conception optimisée d’une boucle d’asservissement intégrée de quelques dizaines de cm de longueur qui réduit le bruit de phase de 18 dB à 1 MHz d’écart à la porteuse optique et des couplages phase-amplitude réduits dans la cavité d’un facteur 50 par rapport à ceux estimés expérimentalement. L’ajout d’un troisième laser DFB stabilisé en phase sur un oscillateur local permettrait d’avoir une source continûment accordable sur 1 THz. La source d’ondes continues permettrait également de générer à partir de fibres hautement non linéaires et dispersives des impulsions pico- ou femtosecondes à un taux de répétition fixe en remplacement les lasers DFB par des lasers plus stables. Je calcule par simulation une gigue temporelle de 7,2 fs sur un temps d’intégration de 1 ms à 40 GHz de taux de répétition. / I report in this manuscript a theoretical and experimental study of a compact, reliable and low cost source of 30 Hz linewidth, continuous and coherent electromagnetic waves tunable from 1 GHz to 500 GHz in steps of 1 GHz. These waves are generated by photomixing two distributed feedback (DFB) laser diodes at 1550 nm which are frequency stabilized with orthogonal polarizations on the same optical fibered Fabry-Perot cavity. I have designed very fast electronic control filters for each laser allowing a 7 MHz servo bandwidth limited by the loop length. I demonstrate phase noise suppressions down to -60 dBc/Hz at 1 kHz and -90 dBc/Hz at 100 kHz offset frequencies from a 92 GHz electrical carrier. I also measure a ~170 kHz frequency drift of the beat note at 10 GHz on the long term over a continuous 7.5 hour locking period. I show an optimized design of an integrated servo loop of few tens of cm length which reduces the phase noise by 18 dB at 1 MHz optical carrier offset frequency and the phase-amplitude couplings in the cavity by a factor of 50 compared to the experimental one. The addition of a third DFB laser phase stabilized on a local oscillator allows the possibility to have continuously tunable source over 1 THz. The continuous wave source also makes it possible to generate fixed repetition rate pico- or femtosecond pulses from highly non-linear and dispersive fibers, replacing the DFB lasers by further stable lasers. I have calculated by simulation 7.2 fs temporal jitter at 40 GHz repetition rate over a 1 ms integration time.

The thesis deals with the application of laser beams for examination of material properties. The properties being examined are quality of surface finish and transmissivity of materials in the optical portion of the electromagnetic spectrum. A measuring device containing laser diodes as a source of laser beam and photodiodes for evaluation of examined phenomena serves for examination of both properties. Conversion of the signal to digital quantity and its further processing take place in a microcontroller. The data is then sent via a serial bus and a converter to a computer, where it may be saved in a user program and where the user can work with them later. The thesis contains results of reflectivity measurement of a set of metal samples with different surface finish. Transmissivity measurement was applied on a set of optical filters.

In dieser Dissertation werden verschiedene Methoden zur Simulation der Dynamik der optischen Moden einer Fabry-Pérot-Laserdiode diskutiert. Experimentell lässt sich hierbei der Effekt des Modenrollens oder Modenhüpfens beobachten. Hier sind zu einem gegebenem Zeitpunkt nur ein oder zwei longitudinale Moden aktiv, dabei wechseln sich die Moden in einem bestimmten Wellenlängenbereich ab. Eine Erklärung für diesen Effekt sind Vibrationen der Ladungsträgerdichten in den aktiven Schichten bzw. den Quantenfilmen. So werden in der ersten betrachteten Methode die Ladungsträgerdichten bzw. die Besetzungsfunktionen zunächst als ortsabhängig betrachtet, um die Ladungsträger-Vibrationen direkt zu bestimmen. Bei diesem Vorgehen wird eine hohe Rechenzeit benötigt, welche bei einer anderen Methode mithilfe eines effektiven Modenwechselwirkungsterms allerdings erheblich reduziert wird. Im ersten Teil dieser Arbeit wird gezeigt, dass diese beiden Methoden sehr ähnliche Ergebnisse liefern, außerdem wird der effektive Modenwechselwirkungsterm unter Berücksichtigung verschiedener Streuprozesse hergeleitet. Bei Strukturen mit mehreren Quantenfilmen oder größeren Stegbreiten spielt der Transport der Ladungsträger von den Kontakten zu den Quantenfilmen eine große Rolle, welcher in dieser Arbeit mithilfe der Drift-Diffusions-Gleichungen untersucht wird. Abschließend wird die Modendynamik mithilfe des Traveling-Wave-Modells simuliert. Im Gegensatz zu den bisher in dieser Arbeit verwendeten Methoden wird das optische Feld hierbei nicht mehr in die einzelnen Moden aufgeschlüsselt, sondern es wird partielle Differentialgleichung gelöst. / In this thesis different methods for the simulation of the mode dynamics in Fabry-Pérot laser diodes are discussed. These laser diodes show the effect of mode rolling, where the currently active longitudinal mode changes over time. This effect can be observed experimentally and can be explained by beating vibrations of the carrier densities in the quantum wells. In the first method used in this work the location dependence of the carrier densities and the distribution functions is considered. This procedure requires a lot of computing time, which is significantly reduced in another method using an effective mode interaction term. In the first part of this thesis it is shown that these two methods give very similar results, and the effective mode interaction term is derived taking into account various scattering processes. For structures with multiple quantum wells or broad ridge widths the transport of the charge carriers from the contacts to the quantum wells is important, which is examined in this work using the Drift-diffusion equations. Finally, the mode dynamics is simulated using the traveling wave model. In contrast to the methods used so far in this work the optical field is no longer broken down into the individual modes, instead a partial differential equation is solved.

This diploma thesis deals with the influence of long fiber optic paths on the polarization state of light and their use for powering polarization sensors. The aim of the diploma thesis was to design the arrangement of optical fiber components so that the polarization properties of light at the end of the path are further usable for sensory purposes. Four partial measurements with a long path (in a laboratory setting, laying in the ground, on a curtain, under the influence of external influence) and one measurement without a path under the influence of external influence were designed. The overall measurement results demonstrate that for the functional power supply of long-distance sensor systems, an existing single-mode fiber can be used (laid by laying in the ground), into which a light source for a given sensor system would be multiplexed. In the discussion, all types of measurements are analyzed and compared with each other. Finally, the overall result is summarized and applications are described in which such a sensor system could be used.