The objective of this project is to reconstruct a picture of initial Laurentide Ice Sheet retreat at the end of the Last Glacial Maximum (LGM) using geochemical proxies in Gulf of Mexico sediments, and place the reconstruction into global perspective. The project asks two questions. (1) Can a time frame be established for initial retreat of the Laurentide Ice Sheet? (2) If so, how does the timing compare to that of other large ice sheets and mountain glaciers in both hemispheres? Sediment core MD02-2550 from the anoxic Orca Basin offers excellent preservation and a high sediment accumulation rate. Twelve accelerator mass spectrometry 14C dates provide very good age control from 18.36 - 23.88 ka, the transitional period from glacial to deglacial conditions. Paired Mg/Ca and d18O from the planktonic foraminifera Globigerinoides ruber (pink variety) were combined with a matching record from the upper half of the same core from a previous study (Williams et al., 2010), expanding the record to 10.73 - 23.86 ka. Sea surface temperature (SST) derived from Mg/Ca exhibits a mean value of 23.0 ± 0.8°C through the LGM (18.4-23.9 ka), ~3.9°C below the modern summer mean. At 18.4 ka, mean values drop in an anomalous cold snap, exhibiting a mean of 21.7°C that lasted until 17.8 ka. At 17.8 ka, SST begins a recovery warming toward present day conditions. This warming occurs markedly early relative to the onset of the Bølling-Allerød warm period, known best from Greenland ice core records. The d18O of seawater exhibits no sustained shift toward more depleted values that would be consistent with a single major surge of initial meltwater. Instead, d18Osw appears to have been over 1.5 per mil below the modern mean throughout the LGM, persisting through the early deglacial period, and not shifting toward more positive values until well into the Younger Dryas. The corresponding salinity estimates were likewise ~2 psu lower than modern surface waters. Several negative excursions (~1 per mil) during the LGM and deglaciation coincide with millennial-scale retreats of individual lobes along the southern margin of the Laurentide Ice Sheet. These retreats and re-advances have previously been suggested to mirror small short-term excursions in Greenland ice core d18O, that reflects air temperature changes. The consistently depleted d18Osw-ivc values and corresponding salinity estimates through the LGM require a mechanism to create a steady-state lower salinity environment in the northern Gulf of Mexico during the LGM, which would persist as SST changed.

This thesis explores the natural forces controlling variability of the tropospheric oxidants on interannual to glacial-interglacial time scales. The oxidants (primarily OH and ozone) determine the lifetime of many trace gases of human interest, including air pollutants and long-lived greenhouse gases such as methane. The oxidants respond to meteorological conditions, precursor emissions (natural and anthropogenic), and surface and overhead stratospheric boundary conditions, all of which have changed since the Last Glacial Maximum (LGM; ~21ka). This dissertation first examines in mechanistic detail the effect of variability in the lightning source of nitrogen oxides \((NO_x)\) precursors on interannual variability (IAV) of the oxidants in the recent past. An optimized technique is presented to constrain the lightning \(NO_x\) source in the GEOS-Chem global chemical transport model (CTM) to time-varying satellite data from the Lightning Imaging Sensor. This constraint improves the ability of the CTM to reproduce observed IAV in 9-year (1998-2006) hindcasts of tropical ozone and OH. IAV in ozone and OH is more sensitive to lightning than to biomass burning, despite greater IAV in \(NO_x\) from the latter source. The sensitivity of OH to lightning reflects positive chemical feedbacks on ozone production, \(HO_x\) recycling, and loss frequencies. This dissertation next introduces an offline-coupled climate-biosphere-chemistry framework for determining oxidant levels at and since the LGM. Detailed simulations of tropospheric composition are performed by GEOS-Chem driven by meteorological fields from the GISS ModelE general circulation model, land cover from the BIOME4-TG global terrestrial equilibrium vegetation model, and fire emissions from the LMfire model. Time slice simulations are presented for the present day, preindustrial, and two different possible representations of the LGM climate. Sensitivity of the results to uncertainty in lightning and biomass burning emissions is tested. Though well-buffered, all simulations find net reduced oxidative capacities relative to the present day. The most important parameters for controlling tropospheric oxidants over glacial-interglacial periods are changes in overhead ozone, tropospheric \(H_2O\), and lightning. The results are discussed in the context of the ice-core record, particularly for methane. / Engineering and Applied Sciences

The South Westland Continental Margin (SWCM) is incised by two major active canyon channels, the Hokitika and Cook canyons, which export large volumes of terrigenous sediment from the active New Zealand landmass to the deep ocean basins. This thesis examines modern sediment textures and compositions of shelf and canyon heads, to interpret depositional and transport processes in shelf-canyon interactions and the dispersal and provenance of SWCM surface sediments. This is the first detailed study of modern sediments south of the Whataroa River which focuses on both shelf and canyon head sediments. Submarine canyons that incise active continental shelves are major conduits for sediment transfer. The frequency and magnitude of this transfer has important implications for ocean nutrient cycling (i.e. organic carbon), the stratigraphy and morphology of continental shelves, and the development of economic mineral deposits. Grain size analysis, petrology, geochemistry, detrital magnetite analysis (microprobe), swath bathymetry, and wave hindcast data are used to interpret the spatial distribution, dispersal, and provenance of surface grab samples, canyon cores, and beach and river samples on the SWCM. Four main surficial facies are defined from textural and compositional results, primarily reflecting the supply and storm dominated nature of the SWCM. Facies 1 is comprised of inner shelf very fine to medium sand sized quartz, metamorphic lithics, and feldspar. This facies occurs above the mean Hsig wave base (48 m) where silts, clays, and sand sized micas are bypassed further offshore. Facies 2 is a transitional sand to mud facies between 40 -70 m depth where increasing clay, silt, and mica reflect a decrease in the frequency and magnitude of wave orbital remobilisation. Facies 3 is a mud dominated (80-90%), clay rich (7-9%) facies with the highest mica and Al₂O₃ content of all the SWCM facies. The shelves south of the Hokitika canyon are blanketed beyond the inner shelf in facies 3 towards the shelf break. Facies 4 is restricted to the canyon head north rims and is characterised by mixed relict and modern terrigenous sediments and glaucony. Net transport on the SWCM shelf is to the north, particularly during south-westerly storms where wind drift and storm swells may stir and transport the deeper Facies 2 and 3 sediments. The SWCM has an energetic wave climate and numerous high yield mountainous rivers. As a result the shelf has an extensive coverage of silts and clays with sediment transport most likely dominated by nepheloid layers and fluid mud flows during wet storms. North of the Hokitika canyon, shelf width increases as fluvial supply falls, resulting in a more storm dominated shelf as the prevailing hydraulic conditions prevent modern silts and clays from blanketing the outer shelf. Narrower shelf widths and higher fluvial supply between the Hokitika canyon and the Haast region results in more fluvial dominated shelves. Contrasting canyon rim textures and compositions reflect the major influence the Hokitika and Cook canyon heads impose on the SWCM by intercepting modern net northward shelf transport paths. This interception creates a leeward sediment deficit on the canyon north rims where low sedimentation rates prevail and relict sediments are partially exposed. The south and east rims of both canyons are characterised by modern fine grained terrigenous textures and compositions similar to the SWCM middle to outer shelf facies 3. The build-up and storage of these unconsolidated sediments at the south and east rims provides favourable environments for sediment gravity flows that feed into the canyon systems. Wave orbitals can resuspend fine sands up to 50 m below the canyon rims during large storms. This resuspension will be a main driver of canyon head sedimentation in the form of fluid mud flows. Gully networks along the south and east rims of the Hokitika and Cook canyons indicate active submarine erosion, unconfined fluid flow, and sediment gravity flows operate here. ii In contrast, the north canyon rims are characterised by gravels and coarse sands out of equilibrium with the prevailing modern hydraulic regime. Relict gravels are particularly prevalent on the Hokitika canyon north rim between 90 – 150 m depth. A lack of active gully networks and the presence of relict terraces and cuspate channels provide further evidence for a relict origin of HCH north rim sediments and little influx of modern fine sediments. North rim sediments on the Hokitika canyon between 90 – 125 m have features characteristic of relict beach and littoral environments. These features include pebble and coarse sand sized siliciclastics, high heavy mineral percentages (i.e. garnet), high Zr and Y levels, elevated SiO₂/Al₂O₃ ratios, and relict shell fragments. Mature glaucony is common on the north rims of both canyons, especially between 180 -200 m depth providing further evidence for extended periods of little to no modern sediment deposition in the canyon lee. Glaucony grains have experienced limited transport and are probably parautochthonous. The bulk composition of SWCM shelf, canyon, river, and beach sediments is controlled mainly by the hydrodynamic sorting of Alpine Schist derived material. Regional changes in catchment geology are identified in modern SWCM shelf sediments. Ultramafic signals (i.e. enriched trace element patterns and Cr/V and Ni/Y ratios) from the Pounamu Ultramafics and Dun Mountain Ultramafics were identified on the North and Cascade shelves respectively. The contribution of other lithologies to the bulk composition of SWCM sediments is localised due to rapid dilution with Alpine Schist detritus. The low carbonate and skeletal content on the SWCM is due to the energetic wave climate and high fluvial supply on the shelves. A variety of Cr-rich spinels and magnetites are supplied to the SWCM shelves and vary with regional changes in catchment geology. The Cascade shelf is rich in chromites (containing up to 215,000 ppm Cr) and Cr – rich magnetites sourced from the Dun Mountain Ultramafics via the Cascade River. Shelf, beach, and river samples between the Haast River and Waitaha River are dominated by low-Cr magnetite grains which represent the ‘background’ magnetite composition sourced from rivers draining the Alpine Schist dominated catchments. The dispersal of Cr-rich spinels is limited due to the dilution with low Cr-magnetites from rivers and littoral sediments. Glacio-eustatic lowstands such as the Last Glacial Cold Period (LGCP), represented periods of robust connection of local rivers with the Hokitika and Cook canyon heads, increased interception of littoral transport paths, and compartmentalisation of inter-canyon shelves. Hokitika canyon cores reflect these changes with textural and compositional ‘spikes’ indicating higher terrigenous input during the LGCP. The geochemistry of the terrigenous fraction in the Hokitika canyon provides evidence for enrichment in ferromagnesian and Cr-rich minerals during the LGCP. This is due to the increased connectivity of the Cr-spinel bearing Hokitika River to the canyon head. The Cr/V ratio in particular demonstrates its effectiveness as a proxy for interglacial – glacial change in submarine canyon stratigraphy. Increases and decreases in the connectivity of Cr-bearing fluvial systems during lowstands and highstands respectively can be observed with this ratio.

The location of fronts has a direct influence on both the physical and biological processes in the Southern Ocean. However, until recently fronts have been poorly resolved by available data and climate models. In this thesis we utilise a combination of high resolution satellite data, model output and ARGO data to improve our basic understanding of fronts. A method is derived whereby fronts are identified as local maxima in sea surface height gradients. In this way fronts are defined locally as jets, rather than continuous-circumpolar water mass boundaries. A new climatology of Southern Ocean fronts is presented. This climatology reveals a new interpretation of the Subtropical Front. The currents associated with the Subtropical Front correspond to the western boundary current extensions from each basin, and we name these the Dynamical Subtropical Front. Previous studies have instead suggested that the Subtropical Front is a continuous feature across the Southern Ocean associated with the super gyre boundary. A comprehensive assessment of the relationship between front locations and wind stress is conducted. Firstly, the response of fronts to a southward shift in the westerly winds is tested using output from a 100 year climate change simulation on a high resolution coupled model. It is shown that there was no change in the location of fronts within the Antarctic Circumpolar Current as a result of a 1.3° southward shift in the westerly winds. Secondly, it is shown that the climatological position of the Subtropical Front is 5-10° north of the zero wind stress curl line, despite many studies assuming that the location of the Subtropical Front is determined by the zero wind stress curl. Finally, we show that the nutrient supply at ocean fronts is primarily due to horizontal advection and not upwelling. Nutrients from coastal regions are entrained into western boundary currents and advected into the Southern Ocean along the Dynamical Subtropical Front. / <p>At the time of the doctoral defense, the following paper was unpublished and had a status as follows: Paper 4: Submitted.</p>

The objective of this dissertation is to apply radiogenic isotopes extracted from marine sediments to investigate aspects of global climate change over the past 25 kyr, especially ocean and atmospheric circulation, continental aridity, and hydrology. By focusing on the geochemical records from marine sediments and authigenic precipitates preserved in these sediments, I aim to better understand climate forcing and feedback mechanisms, which are critical to models of climate change. Firstly, I have investigated the dynamics of the Intertropical Convergence Zone (ITCZ) over the past 25 kyr in the eastern equatorial Pacific by fingerprinting dust provenance using radiogenic isotopes (Nd, Sr, Pb) and trace elements (Fe, Si, Ba) in the detrital fraction of marine sediments along a transect across the equator at 110ºW. Results from this study suggest no glacial-Holocene difference in the mean position of the ITCZ, but a more northerly, possibly stronger, deglacial ITCZ. Secondly, I have applied Nd isotope ratios from authigenic precipitates extracted from marine sediments and those from fish debris to trace past intermediate water circulation changes on glacial-interglacial and millennial timescales. The authigenic Nd isotope record from the Florida Straits suggests a reduced circulation of Antarctic Intermediate Water (AAIW) into the tropical North Atlantic during the Younger Dryas (YD) and Heinrich 1 (H1) events, associated with a significant reduction in AMOC. However, in the Southern Caribbean, apparent deviations in the Nd isotopic compositions between the acid-reductive leachate and the fish debris suggest that the leachate method is not reliable at this location and that it needs to be tested in more detail in various oceanic settings. In the Southern Caribbean, the fish debris Nd isotope results suggest a two-step recovery of the upper North Atlantic Deep Water during the last deglaciation. Comparing our new fish debris Nd isotope data to authigenic Nd isotope data for sediments from the Florida Straits and the Demarara Rise, we propose that glacial and deglacial AAIW does not penetrate beyond the lower depth limit of modern AAIW in the tropical North Atlantic. Both studies suggest a tight connection between Atlantic intermediate water circulation variability and high-latitude North Atlantic climate change.

Sarus cranes (Grus antigone) are the tallest members of the crane family, Gruidae. They are found in four geographically distinct regions: northwest India (Indian Sarus- Grus antigone antigone), southeast Asia (Burmese Sarus- Grus antigone sharpei) and northern Australia (Australian Sarus- Grus antigone gillae). Although the three subspecies are morphologically distinct, their genetic distinctness is unclear. In this study, I focused on control region sequences of mitochondrial DNA (mtDNA) to assess the genetic and phylogeographic distinctness of Sarus subspecies. I used samples from four fragmented populations, seven from India, 16 from southeast Asia, five from Myanmar and eight from Australia. Phylogenetic trees were estimated using two Brolga crane sequences (G. rubicunda) as outgroups. All phylogenetic trees had low resolution, but AMOVA showed that all four Sarus populations are differentiated from each other. Nested clade phylogenetic analysis showed that most of the southeast Asian haplotypes are found at the center, suggesting that the Thai population includes the maximum number of ancestral haplotypes. Sarus cranes probably originated in southeast Asia and migrated both north towards India and south towards Australia during the last glacial maximum.

A regiäo de Monte Verde (Camanducaia, MG) está sìtuada a 1500 m de altitude, na porção sul da serra da Mantiqueira. Alvéolos do relevo serrano, como o entroncamento dos córregos do cadete e da Minhoca com o rio Jaguari, junto à sua área urbana, propìciaram o acúmulo de sucessões métricas de sedimentos argilo-arenosos em condiçöes favoráveis à formação de material turfoso e à preservação de palinomorfos. Nesta área, o presente estudo reconstitui, a partir da integração dos registros palinológico, sedimentológico (granulometria e minerais pesados) e geoquímico/isotópico (C e N) de três testemunhos rasos (até 230 cm), a evoluçäo e os possíveis controles sedimentares e paleoclimáticos do cenário paleoflorístico no Quaternário tardio, com especial atençäo para a Floresta de Araucária. O contexto geral registrado nos testemunhos é de planície de inundação fluvial, com cobertura arbórea próxima, e influência varìável de fluxos de encosta. Na parte montante do vale do cadete, obtiveram-se idades compreendidas entre 38695 - 40522 anos cal A.P., em 220 cm de profundidade, e 2060 - 1880 anos cal 4.P., em 5 cm. Na parte inferior da coluna, até cerca de 16000 anos A.P., há indícios de aumento de distalidade para cima. Entre cerca de 16000 e 3500 anos A.P., evidencia-se redução da influência da matéria orgânica de plantas terrestres, em detrimento de algas, possivelmente em momento de abeÍura relativa da cobertura florestal. Os últimos 3500 anos seriam de restabelecimento da cobeÍura florestal, possivelmente já nos moldes da existente hoje, com redução gradual do aporte de areia. Mais a jusante do mesmo vale, as idades ficaram compreendidas entre 26764-26023 anos cal 4.P., em 210 cm de profundidade, e 2350 - 2150 anos cal A.P., em 10 cm, A parte inferior do intervalo, mais antiga que 20830-20370 anos cal A.P., é dominada por influência de áreas fontes locais, graníticas. Em 20000 anos A.P., fontes distais, metamórficas, passam a atuar, com aumento da influência de algas. Nos últimos 5000 a 6000 anos A.P., tem-se o readensamento da Floresta de Araucária, com manutenção de brejos, sob condiçöes climáticas frias e úmidas. Os resultados sugerem que as mudanças climáticas nos últimos 40 mil anos em Monte Verde não foram acentuadas a ponto de exercer grande impacto florístico e que houve predomínio de Araucaria e elementos associados a essa floresta durante todo intervalo estudado, sob condições climáticas frias e úmidas. / he Monte Verde region (Camanducaia, MG) is located in the southern portion of the Mantiqueira Range, with 1500 m of elevation. Relief alveoli, as the junction of cadete and Minhoca creeks with Jaguari River, sited close to the urban area, propitiated the accumulation of metric sucessions of sandy-mud sediments, under cond itions favorable to the formation of peat material and preservation of paìynomorphs. ln this area, the present study integrates palynological, sedimentological (grain size and heavy minerals) and geochemical/isotopic (C and N) records of three shallow cores (up to 230 cm deep) to reconstruct the evolution and possible sedtmentary and paleoclimatic controls of the Laie Quaternary paleofloristic scenario, with special emphasìs in the Araucaria Forest. The general sedimentary context recorded in the cores is a river floodplain close to tree cover areas, and with variable influence of slope flows. On the upstream Cadete valley, were obtained ages of 38695-40522 cal years BP, at the deep of 220 cm, and 2060-1880 cal years BP, at 5 cm. From the bottom of the column until about 16000 BP, there is evidence of increased distality upwards The time interval between about 16000 and 3500 yr BP shows a reduction in the influence of organic matter derived from terrestrial plants, to the detriment of algae, possibly in a moment of relative opening of the forest cover. The last 3500 years would be characterized by the restoration of forest cover, possibly similar to the existing today, with gradual reduction of the sand supply ln the downstream of the same valley, the ages vary from 26,764 fo 26,023 cal years BP, at 210 cm deep, to 2350 to 2150 cal years BP, at 10 cm. The lower part of the sedimentary column, older than 20830-20370 AP\' is dominated by the influence of local granitìc sources areas. ln 20000 years BP, distal metamorphic sources begin to act paralel with a increased influence of algae. over the last 5000-6000 years, a increase of Araucaria Forest is recorded, with maintenance of weflands under cold and wet climatic conditions. This results suggest that climate changes during the last 40 k years in Monte Verde region were not sufficient to exert great floristic impact. Araucaria and associated forest elements predominated during the whole studied interval, under cold and wet weather conditions.

Few studies utilise modern species distribution data and modeling to make predictions for examining potential fossil localities. Instead, species distribution modeling is often used for palaeoenvironmental interpretations. Using palaeoclimate data to model potential past distributions for a species provides a prediction showing areas where its fossil remains may be found. In this study, the current, Last Glacial Maximum, and Last Interglacial potential distributions of the arid steppe-obligate saiga antelope (Artiodactyla: Bovidae, Saiga tatarica) were modeled using the species distribution model Maxent. Few fossil records exist, but available fossil locality records were used to validate both palaeo models, resulting in speculative predictions about where the saiga may have lived. Known fossil localities of saiga from the Last Glacial Maximum time period were located within predicted moderately suitable environments, while four of seven Last Interglacial fossil localities were located within predicted moderately suitable environments, suggesting that models can accurately identify areas where fossils for the saiga can be found. Specifically, these models suggest saiga fossils may be located in northwestern and northeastern China, the western and central regions of the Middle East, and southern Alaska. The predicted areas in northeastern China are of particular interest because saiga fossils have not been identified in this region, but some palaeontologists theorize that northeast China may have been suitable for saiga in the past. The models lend credence to this argument.

No description available.

No description available.