The analysis of ring type seals is of great concern for the designer of high speed and high pressure centrifugal compressors. Computers now play a major role in allowing for a quick evaluation of the floating ring seal. Since the accuracy of the rotor shaft stability evaluation depends on the validity of the dynamic seal characteristics, every step in the evaluation must be carefully scrutinized and updated to include the latest in theory and practical operating experience. This thesis presents the theory and results of one such extension to the current published analysis of oil ring seals. The new analysis includes the influence of the sealing fluid temperature gradients on the leakage flow rate and seal dynamic characteristics for multi-ring and/or multi-land ring configurations. Using classical short bearing theory but allowing for temperature and pressure dependent viscosity variations across the seal, the resulting pressure profiles have been determined numerically utilizing a finite difference solution technique. This thesis discusses the method used to calculate the flow and pressure profiles for oil seals, their influence on the seal dynamic characteristics, and the importance of their consideration on actual turbomachinery stability. / Master of Science

Introduction: At the present time there are, on the market, numerous lubricating aids which are designed to improve the lubricating qualities of the various mineral lubricating oils, especially those intended for automotive use. The manufacturers of some of these make statements concerning them that to any fair-minded individual are startling. With this in mind, it has been the purpose of the author to try to verity these claims or else disprove them. It would be impossible in the time allowed to test allot these aids; so a representative few were chosen which covered the field quite thoroughly. From the results shown by the use of these aids in an internal combustion engine, as well as those shown by the physical property tests in the laboratory, it seems as though their suitability for industrial use would be demonstrated. In other words, the results should show which of the arguments put forth by the manufacturers of the various products are of sound basis and which are stated merely for the sake of advertising and publicity. / Master of Science

by Lam Yip-mou Charles. / Thesis (M.B.A.)--Chinese University of Hong Kong, 1981. / Bibliography: leaves 104-106.

Submitted in partial fulfillment of the academic requirements for the Masters degree in Technology, Chemistry department, Durban University of Technology, Durban, South Africa, 2015. / The focus of most lubricating grease testing has been based on performance and appearance rather than determining the concentration of chemical components. The primary reason being lubricating grease is a difficult matrix to work with from the perspective of the analytical laboratory. The purpose of this study was to develop a simple, reproducible method for elemental determination in lubricating grease and to apply the developed method to work out a flushing procedure for the filling lines in a grease manufacturing plant. The first part of the experimental work focused on developing a suitable and efficient sample preparation technique. Three techniques were explored: direct dilution, microwave assisted acid digestion and emulsification. Direct dilution involved shear mixing the lubricating grease with metal free base oil and diluting it with an organic solvent. Use of these solvents caused plasma destabilization or even plasma extinction and their use posed health risks for laboratory personnel. Microwave digestion involved mineralising the lubricating grease using an optimised microwave assisted acid digestion procedure. In the third sample preparation technique, microemulsions were formed by mixing the lubricating grease with a relatively small volume of a strong mineral acid mixture followed by the surfactant (triton X-100) at room temperature and pressure (RTP). This approach does not require the destruction of the organic matter or the use of large amounts of organic solvents. For all three techniques the sample was subsequently analysed for Al, B, Ba, Ca, Li, Na, S, Mo and Zn. All analysis was performed using an Optima ICP-OES with previously optimised parameters. The direct dilution method gave the most inconsistent results with relative standard deviation (RSD) as high as 56% for calcium, 79% for boron and 66% for lithium. Microwave digestion and emulsification gave comparable results, with the calibration curves of oil emulsions not differing significantly from aqueous ones. For microwave assisted acid digestion the limits of detection ranged from 0.028 mg/L for sodium to 0.255 mg/L for boron. Correlation coefficient values (r2) of all the elements were greater than 0.99. Likewise the limits of detection for emulsification ranged from 0.03 mg/L for aluminium to 0.37 mg/L for sulphur. The correlation coefficients for all the elements were greater than 0.99 and this indicates that the calibration curves were sufficient for analysing the digested grease samples. Five quality assurance samples were analysed using both methods and in addition a t-test performed at the 99.9% confidence level and 4 degrees of freedom showed that the two sample preparation techniques gave similar results. Emulsification has several advantages over microwave digestion technique and superior analytical performance over direct sample dilution using solvents, and hence was chosen as the method of choice for routine analysis of lubricating grease. The second part of the experimental work focused on developing a flushing procedure for filling lines in a lubricating grease plant. A flushing procedure is essential in order to minimise waste, which will in turn minimise production costs and avoids incurring disposal costs. In this series of experiments, the microwave digestion sample preparation technique was utilised for the subsequent determination of the flushing mass required in between product changes. The flushing procedure was implemented and monitored by the use of statistical quality control tools for a specified period of time, and as indicated by Shewart Control charts, the process was in statistical control.

published_or_final_version / Dentistry / Master / Master of Dental Surgery

The present study focuses on the physical and chemical mechanisms of lubricant removal during the first step of the sintering process during powder metallurgy (P/M) processing of ferrous systems. Previous works on the kinetics of delubrication made it possible to develop an empirical model which accounts for the typical weight loss profile observed upon heating of green compacts. It has been established that the rate at which the parts are heated dictates the overall process kinetics, and fitting curve methods yield two parameters which contain the corresponding information: (i) TMAX is the temperature of 50% lubricant removal, and (ii) b is representative of the slope of the curve during weight loss stage. Phase I of this study aims at determining the dependencies of these two parameters with respect to a series of physical variables: green density of the compacts; presence of an alloying element potentially catalytic for the reaction of lubricant pyrolysis; and procedure of compaction and geometry of the compacts. Also, it is suggested that the two parameters obtained from the fitting curve methods can be related to the main two mechanisms of delubrication: evaporation of the lubricant and conversion of the lubricant molecules into smaller hydrocarbons, assuming that these two mechanisms are the kinetically limiting mechanisms. Furthermore, recent studies of the delubrication process have been opening the way to the potential development of gas sensors, which could eventually allow the direct monitoring of the emissions of gaseous species. Several key features have been reported in the literature, including a peak emission of hydrocarbons at the delubrication temperature, as well as strong emissions of CO and CO2 at temperatures above 700°C. The scope of Phase II of this project was thus to verify that these features were retained under various processing conditions, so that the development of a sensor suitable for various sintering environments is viable. Variations in the emission profiles of gaseous species were observed as the processing conditions were changed, and when possible, potential justifications for these changes have been proposed.

Thesis (M.S.)--State University of New York at Binghamton, Thomas J. Watson School of Engineering and Applied Sciences, Systems Science and Industrial Engineering Department, 2006. / Includes bibliographical references.

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