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Synthesis of nanocomposites with nano-TiO2 particles and their applications as dental materialsAbdelaaziz, Muftah Ali January 2012 (has links)
Thesis submitted in fulfilment of the requirements for the degree
Magister of Technology: Dental Technology
In the Faculty of Health and Wellness Sciences
At the Cape Peninsula University of Technology, 2012 / A study of the modification of dental nanocomposites with nanosized fillers is presented. The incorporation of TiO2 (titania) nanoparticles, via a silane chemical bond, to a standard dental acrylic resin matrix was explored to determine whether there was an increase in the wear resistance, flexural strength and surface hardness properties of the dental nanocomposites. The principal aim of this study was to synthesize dental nanocomposites with different sizes, treated, nano-TiO2 fillers in urethane dimethacrylate (UDMA) for potential application in posterior restoration and to evaluate their mechanical properties.
Treatment of the nano-TiO2 particles was carried out with a silane coupling agent, 3-(methacryloyloxy)propyltrimethoxysilane (MPTMS), to improve bonding between the nano-TiO2 particles and acrylic matrix (UDMA), and reduce agglomeration of the nano-TiO2. Characterisation of products was carried out using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and fourier transform infrared spectroscopy (FTIR). TEM results were used to compare the particle size distributions of untreated TiO2 and treated TiO2 under various experimental conditions in an ethanol solvent, while SEM images showed the adhesion between the matrix (UDMA) and the nano-TiO2. FTIR was used to show the qualitative composition of untreated TiO2 and treated TiO2.
Eighteen groups of experimental dental nanocomposites were evaluated. Each group contained different average particle sizes of nano-TiO2 (filler): 5 nm, 21 nm and 80 nm. Each particle size category was treated with three different concentrations of the silane, (MPTMS): 2.5, 10 and 30 wt %. Samples were prepared by mixing the monomer resin matrix of UDMA and nano-TiO2 particles. For comparison, a commercially available dental resin was reinforced with untreated and treated nano-TiO2 particle sizes 5, 21 and 80 nm.
Wear resistance, flexural strength and surface hardness of TiO2 nanocomposites treated with 2.5 wt % MPTMS were significantly higher compared to those treated with 10 and 30 wt% MPTMS. The nanocomposites with 5 nm TiO2 had higher wear loss, lower flexural strength and lower surface hardness values compared to those with 21 nm and 80 nm TiO2. Statistical analysis showed that the effect of the concentrations of MPTMS on wear resistance and surface hardness of specimens was significant (p<0.001), which is less than 0.05, while the effect of the concentration of MPTMS on flexural strength was statistically not significant, (p=0.02). Control composites reinforced with treated 80 nm TiO2 particles had much better mechanical properties than any of the other specimens. It was concluded that the most available commercial product for dental restorations could be improved by the addition of nano-TiO2 with relatively large particle size.
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Cobalt-60 radiation beam verification in nasopharyngeal carcinoma: a Kenya experienceKikwai, Richard Malakwen January 2012 (has links)
Thesis (MTech (Radiography))--Cape Peninsula University of Technology, 2012 / Background and purpose The primary aim of this study was to analyse the accuracy and reproducibility of radiation treatment to patients with nasopharyngeal carcinoma at the only tertiary teaching and referral hospital in Kenya. The secondary objective was to review literature on quality assurance procedures that would result to provision of quality radiation treatment to this group of patients. Materials and method During the period May 2011 to March 2012, 35 patients with head and neck cancer comprising of 27 patients with nasopharyngeal carcinoma, 7 with paranasal sinus carcinoma and 1 with lymphoma falling within the enrolment criteria were treated using Equinox cobalt-60 unit with the same beam arrangement and were studied prospectively. Radical radiotherapy was delivered using conventional 2D technique in a routine dose of 60-66Gy to the primary and 50Gy to lymph nodes with additional dose to residual neck nodes. During the period of their treatment, a lateral portal image was taken once weekly. Four film image pairs were obtained per patient with each patient positioned and immobilised in an individualised Orfit thermoplastic mask and a head and neck support. The 4 portal images were compared to a corresponding simulator film taken during simulation planning. Deviations from the varied bony landmarks were measured on the portal images and simulator image from the centre of the radiation beam.
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Diagnostic radiography requests in Zimbabwe’s public hospital complex: completeness, accuracy and justtificationSibanda, Lidion January 2012 (has links)
A thesis submitted in fulfilment of the requirements for the degree
Master of Technology: Diagnostic Radiography
in the Faculty of Health and Wellness Sciences
at the Cape Peninsula University of Technology, 2012 / Complete, accurate and justified radiological examination requests are prerequisite to
radiological exposures. However, global research shows evidence of high numbers of
incomplete and inaccurate requests as well as that up to 77% radiological exposures are
unjustified. Plain lumbar spine and plain skull radiology examinations are reported as being
procedures that generate high dose and a low diagnostic yield. This study was designed to
objectively measure the completeness, accuracy and justification of these two examinations
in an effort to make inferences that will contribute to an improved radiology service. This
research could therefore have positive effects on optimisation of radiation protection in
Zimbabwe.
Methodology
A non participatory prospective descriptive analytical document review of quota sampled
radiological request forms for 200 plain skull and 200 plain lumbar spine examinations was
employed. Data was captured using structured data collection instruments designed and
tested by the researcher for this study. The instrument was designed using the IAEA-HHS4
(2010) minimum prescribed request data as a framework and adding additional form fields
found to be relevant through a review of all identified radiological request template forms in
use at the research site. Data analysis involved central tendency measures and inferential
statistics.
Results: The central tendency demonstrated for the two examinations was that generally
referrers for plain lumbar spine and for plain skull radiology would respectively provide 38.9
+/- 0.6% and 40.2+/-0.5% overall examination request information. This information was
significantly below expectation. There was however no significant difference between the
samples’ means for the two examinations. The tendency demonstrated in patient information
for lumbar spine and skull requests was that generally referrers would respectively provide
48.4 +/- 0.8% and 49.5+/- 0.8% patient information. These values were inclusive of each
other and they were significantly (p=0.00 Sig.) below expectation. There was however no
significant difference between the two examinations’ data. The tendency demonstrated for
examination information was that referrers for the research site would generally provide
29.8+/-0.8% (lumbar) and 32.6+/-0.8% (Skull) examination information. These values were
significantly (p=0.000 Sig.) below expectation and demonstrated a significant difference
between the sample means for the two examinations. With respect to referrer information,
the tendency demonstrated was that generally referrers for plain lumbar spine and for plain
skull examinations would respectively provide 38+/- 1% and 38.5 +/- 0.8% referrer
identification information. These were significantly below expectation (p= 0.000 Sig.) but
there was no significant difference between the samples’ means with respect to referrer
information. With respect to accuracy of request data, it was observed that 5% plain lumbar
spine and 3% plain skull requests were specific in so far as information documented on
request forms could unambiguously identify the area to be imaged. It was also observed that
22.5% (lumbar spine) and 12% (skull) examination requests were indicated and therefore
justified. All requests forms were found to be legible.
Conclusions: Generally, referrers to this research site tend to provide incomplete,
inaccurate and unjustified radiological request data. The observed levels of completeness,
accuracy and justification of requests were generally consistent between the two
examinations relative to expectation. These levels had medico-legal implications and
negative effects on optimisation of radiation protection to patients. Further research to
establish causes of this variance in referral behaviour is recommended. The researcher also
recommends further research to establish whether there is an association between
requested examination and completeness, accuracy and justification of diagnostic radiology
examination requests.
Keywords: Radiation protection, radiological request, complete request, accurate request,
justified request, plain skull imaging, plain lumbar spine imaging.
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Radiation doses for barium meals and barium enemas in the Western Cape South AfricaNabasenja, Caroline January 2009 (has links)
Thesis submitted in fulfilment of the requirements for the award of the
degree of
Master of Technology Radiography (Diagnostic)
in the Faculty of Health and Wellness Sciences
at the Cape Peninsula University of Technology
2009 / Since their discovery in 1895, the use of x-rays is continuously evolving in medicine
making the diagnosis of injuries and diseases more practicable. It is therefore not
surprising that x-rays contribute 90% of the radiation dose to the population from manmade
sources (DWP, 1992). Moreover, these radiation doses are associated with both
fatal and non-fatal cancer risk that is detrimental to adults between 20 to 60 years (Wall,
1996). Radiation dose to individuals therefore needs to be actively monitored in order to
minimise such risk. Barium contrast examinations were characterised as one of the
radiological examinations that contributed enormously to the collective dose to the
patients in the radiology department (DWP, 1992). Determining the diagnostic reference
levels of such examinations would reduce the over-exposure of individuals to ionising
radiation. Currently in South Africa (SA), there are no diagnostic dose reference levels
for barium meal (BaM) and barium enema (BaE) examinations. This study therefore
investigated the radiation doses delivered to patients referred for BaM and BaE,
obtained potential regional reference doses for these examinations, compared the
radiation doses obtained with those from similar dosimetry studies and investigated
sources of dose variation among the study sites.
A total of 25 BaM and 30 BaE patients in the age range 18 to 85 years, weighing 50 kg
to 90 kg, at 3 hospitals in the Western Cape, SA were investigated. The radiation dose
to the patients was measured using Dose Area Product (DAP) meters that were
permanently fitted onto fixed fluoroscopy units at these 3 hospitals. The third quartile
DAP values were 20.1 Gycm2 and 36.5 Gycm2 for BaM and BaE respectively. The
median DAP values were 13.6 Gycm2 and 27.8 Gycm2 for BaM and BaE respectively.
The median values were recommended as the potential Diagnostic Reference Levels for
BaM and BaE as they are less affected by outlying values of under or over- weight
(Yakoumakis, Tsalafoutas, Sandilos, Koulentianos et al, 1999). The weights of the
patients, fluoroscopy time, the number of images obtained, the use of digital or
conventional fluoroscopy equipment and the level of training of the radiologists were the
factors considered for dose variation among the 3 hospitals.
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Professional communication practices of radiotherapists in the workplace and classroom in higher education in the Western Cape, South AfricaWyrley-Birch, Bridget Diana January 2008 (has links)
Thesis submitted in fulfilment of the requirements for the degree
Master of Technology: Radiography
in the Faculty of Health and Wellness Sciences
at the Cape Peninsula University of Technology
2008 / The focus of this study is the professional communication practices of radiotherapists as clinical
practitioners and as teachers of student/novice radiotherapists. The study was undertaken at a higher
education institution and a radiation oncology department in South Africa and addressed the research
question; what are the communication practices of radiotherapists in their professional practice and as
higher education teachers. This work on professional communication was based on practice and
discourse theory as relating to a local context of professional practice and education. Professional
communication, seen in this sense, is a social practice which needs to be understood as operating
within educational, work and social discursive practices of radiation therapy.
A case study approach was chosen as the most appropriate research strategy for capturing the authentic
communication practices of radiotherapists in clinical and educational practice. The professional
communication practices of ten student and five qualified radiotherapists were investigated through
typical teaching and learning interactions in a work integrated learning curriculum. The learning
interactions were observed and video-taped in the classroom, tutorial, and demonstration room.
Communication interactions were observed and audio taped in the clinical workplace. The research
participants, using the video footage as part of their reflections, were interviewed about their
communication practices. All interviews were audio taped and transcribed. Analysis of the data was
by means of thematic analysis where the data was coded and categorised by means of pattern
matching.
The findings from the study showed that the communication practices of radiotherapists include: an
‘academic language’, through which academic content knowledge is expressed; a ‘professional
language’ for negotiating the complex professional relationships within the clinical environment; and a
language for patient care. Their students (novice radiotherapists) are required to master this professional
language within their own ‘language of learning’ practice which includes the multilingual component of
the workplace. A multilayered model of professional communication evolved and was developed within
the analysis process. This model identifies three genres of professional communication: intra-, inter- and
extraprofessional communication. Each of these genres was shown to have both formal and informal
registers. Technical communication was further identified as a subset of intra- and interprofessional
communication. These were further contextualised within the clinical radiotherapy workplace and the
classroom (pedagogic) communication practice. The findings also identified multilingualism as a
discursive practice within the professional communication of the radiotherapy classroom and workplace.
In conclusion, it is argued that the professional communication of radiotherapists comprises a
continuum of communication practices that has significance for both professional and pedagogic
radiotherapy practice, and it is shown that communication practices play an important role in the
establishment of professional identity and expertise and enable the novice radiotherapist to find their
‘professional voice’.
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Three-dimensional thinking in radiographyVenter, Dalene January 2008 (has links)
Dissertation submitted in fulfilment of the requirements for the degree Master of Technology: Radiography in the Faculty of Health and Wellness Sciences, 2008 / Introduction
Research to date has not been able to agree whether spatial abilities can be
developed by practice. According to some researchers spatial ability is an inherited
cognitive ability, compared to spatial skills that are task specific and can be acquired
through formal training. It is commonly assumed that radiographers require general
cognitive spatial abilities to interpret complex radiographic images. This research
was conducted to investigate second year radiography students’ three-dimensional
thinking skills pertaining to film-viewing assessments.
Materials and methods
The experimental research strategy was mainly applied together with correlation
research. Two trials were run (in 2005 and 2006). The sample group consisted of
fifteen second year diagnostic radiography students in 2005 and twenty-three second
year diagnostic radiography students, of the same institution, in 2006. Each year
group was randomly divided into a control group and an intervention group. Two
instruments were used, that is a film-viewing assessment and a three-dimensional
test, Academic Aptitude Test (University) (AAT) nr. nine: Spatial Perception (3-D).
The whole class completed this basic spatial aptitude test, as well as a base-line film viewing
assessment, which focused on the evaluation of technique/anatomy of
second year specialised radiographic projections. The marks that the students
achieved in the fore-mentioned tests were compared, to determine if there was any
correlation between their performances in the different tests. A curricular
intervention, which was intended to improve applied three-dimensional skills, was
subsequently applied. The students executed certain modified radiographic
projections on parts of a human skeleton. For each radiographic projection, the
students had to draw the relation of the X-ray beam to the specific anatomical
structures, as well as the relation of these structures to the film. The related images
of these projections were also drawn. With each of the following sessions, films
including images of the previous session were discussed with each student. After the
intervention, the whole class wrote a second film-viewing assessment. The marks
achieved in this assessment were compared to the marks of the initial film-viewing
assessment to determine the influence of the intervention on the performance of the
intervention group. Following this assessment, for ethical reasons, the same
intervention took place with the control group. A third film-viewing assessment was
then written by all the diagnostic second year students to evaluate the overall impact
of the intervention on the applied three-dimensional skills of the class. The marks of
both the 2005 and 2006 classes (intervention classes) were compared to the marks
achieved by former classes from 2000 to 2004 (control classes), in film-viewing
assessments to evaluate the role of the curricular intervention over the years. The
students again completed the three-dimensional test, Spatial Perception (3-D) to
evaluate the impact of the intervention on students’ general three-dimensional
cognitive abilities. These marks were also compared to the marks of the third filmviewing
assessment, to determine if there was any correlation between the students’
performances in the different tests.
Results
The intervention groups did not perform significantly better in film-viewing
assessments after the intervention, compared to the control groups, but reasonable
differences, favouring the intervention group, were achieved. Statistical significance
was achieved in film-viewing assessments with both year groups after the whole
class had the intervention. The intervention year groups also performed significantly
better than the previous year groups (without the intervention) in film-viewing
assessments. The performance in general three-dimensional cognitive abilities of the
group of 2006 improved significantly after the intervention, but on the contrary, the
performance of the group of 2005 declined. There was a small intervention effect on
the performance of the group of 2006. Only a weak to moderate correlation between
the marks of the students achieved in the three-dimensional tests and the marks
achieved in the film-viewing assessments, was found.
Conclusion
The contrasting evidence between the data of the two groups (2005 and 2006) in the
three-dimensional tests and the small intervention effect on the performance of the
group of 2006, makes the intervention not applicable for the increase of general
spatial abilities. The results of this research show that the applied three-dimensional
skills of radiography students in interpreting specialised and modified projections
can be improved by intensive practice, independent of their inherited spatial
abilities.
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Visitors’ perceptions of the 2010 FIFA world cup: a case study of the host city Nelson Mandela Bay/Port ElizabethNyikana, Siyabulela January 2013 (has links)
Dissertation submitted in fulfilment of the requirements for the degree
Master of Technology: Tourism and Hospitality Management
in the Faculty of Business
at the Cape Peninsula University of Technology
2013 / The continent of Africa hosted the FIFA World Cup™ for the first time in 2010. The historical hosting of Africa‟s first mega-event by South Africa was deemed to be a key opportunity to initiate and promote socio-economic legacies for local South Africans. Therefore, the importance of examining visitor experiences and perceptions of the event cannot be overemphasised. The global struggle for competitive advantage, national reputation or nation branding is in recent times more and more significant as countries compete for attention, respect and trust of investors, tourists, consumers, donors, immigrants and media. Assessing visitors‟ experiences can contribute significantly to knowledge management and inform the planning of future events to leverage positive benefits while minimising the negative impacts. In this study, visitors‟ perceptions of the event are examined using Nelson Mandela Bay / Port Elizabeth (one of the nine [9] host cities for the 2010 event) as a case study. A spatially-based systematic sampling technique was used to interview visitors at fan parks and in the Nelson Mandela Bay Stadium precinct during the 2010 FIFA World Cup™. Face-to-face interviews were conducted and in all, two thousand, two hundred and twenty-five (n=2225) visitors were interviewed.
The key findings reveal that many of the visitors came from the key tourism source markets of South Africa (the United Kingdom [UK], Germany, the Netherlands, the United States of America [USA] and France), were men and had an average age of thirty three (33) years. They generally had positive perceptions about the hosting of the event and the quality of tourism facilities and services on offer during their stay in Nelson Mandela Bay / Port Elizabeth, and South Africa generally. Additionally, many visitors suggested that the hosting of the event in Nelson Mandela Bay / Port Elizabeth offered an opportunity to experience a different tourism destination, with potential for future repeat visitations. However, the city was found to be a poor responsible tourism destination and as not being a good value-for-money destination. During the event, the Nelson Mandela Bay / Port Elizabeth region arguably drew its biggest international crowd as it usually receives fewer international tourists when compared to other regions in South Africa. The study therefore underscores the need for local tourism authorities to devise strategies aimed at capitalising on the exposure garnered through the hosting of the event and at maximising the opportunity to tap into new tourism markets with a view to increasing international visitation in a province that is said to attract only five percent of South Africa‟s international visitors.
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The importance of utilising selection tools in the student selection process in hospitality training institutions in Cape TownLundy, Penelope Rejoice January 2012 (has links)
Thesis submitted in fulfilment of the requirements for the degree
Master of Technology: Tourism and Hospitality Management
in the Faculty of Business
at the Cape Peninsula University of Technology, 2012 / In the light of the growing hospitality industry on one hand, and the limited space available at hospitality training institutions on the other, hotel schools are faced with the challenge of being able to identify students who will most likely be able to complete their courses and thus serve the industry. The practical element of hospitality studies is a defining characteristic that differentiates the subject from other business and management courses. Hotel schools therefore are required to be able to select students that are able to cope with the academic and practical requirements of hospitality courses.
This research focused on analysing the current selection practices used by hospitality training institutions when selecting entry level students. The purpose was to identify success predictors and thus formulate an effective selection programme that incorporates the student‟s academic and vocational skills in order to reduce the student drop-out rate and increase the number of graduates entering the job market.
The target population used for this research was hospitality management students. The criteria used were hospitality management students enrolled for courses with a qualification that is in accordance with NQF level 6 in Cape Town. The two schools that were used as the sample for this study were the IHS (International Hotel School) and the CTHS (Cape Town Hotel School), as they were found to be the only two schools that fit the criteria. The purposive sampling method was used in the form of semi-structured interviews that were conducted with the four academics involved in the student selection process at both institutions. Questionnaires were sent out to students and hospitality industry professionals to be completed. Information was also derived from the IHS and CTHS‟s data-bases to determine what the drop-out rates were at each institution.
The findings revealed that the student drop-out rate was up to a significant 30%. A number of students were not well informed of the nature of the hospitality industry and the career path to which it lead when applying to study courses in hospitality. The findings also revealed that each school used different assessment criteria during the selection process. The selection process ranged from being a purely academic exercise to being a very extensive interview and assessment programme that tested both academic and vocational skills. Realising that it is vital to determine industry fit, the researcher made recommendations on tools that could be used during the selection process that would allow access to as many students as possible without resulting in a high drop-out rate. Utilising effective selection tools in the student selection process not only ensures a steady flow of suitable candidates, but also will ensure efficient hospitality professionals in the future to continuously supply the growing hospitality and tourism industry.
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The development and promotion of heritage tourism in RwandaGitera, Valence January 2008 (has links)
Thesis submitted in fulfilment of the requirements for the degree Master of
Technology: Tourism and Hospitality Management in the Faculty of
Business at the Cape Peninsula University of Technology, 2008 / Taping into a growing global tourism market, the government of Rwanda has
been marketing and promoting tourism as being considered as one of the sectors
that will help the country achieve its economic targets through revenue gains and
job creation. However, Rwanda’s tourism product has understandably, been
aimed largely at gorilla tourism so as to raise much needed foreign currency.
While this has been proving positive as regards achieving industry targets,
dependence on an exclusive product could be detrimental to the industry in the
future.
This research that was carried out in Rwanda’s Museums focused on a
significant form of tourism in Africa, namely heritage tourism with specific
reference to its development and promotion in Rwanda. The results reveal that
heritage tourism, and domestic heritage tourism in particular, is experiencing
growth with genocide museums playing a large part in this growth. The findings
further suggest that the heritage management, especially marketing of heritage
tourism can be improved. The research provides several procedures for
improvement in management of heritage destination that include the assessment
of heritage resources, the role of tourism managers, and different marketing
strategies for heritage sites.
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The communication processes applied during the implementation of the Balance Scorecard performance management system within a Metropolitan Police Department located in the Western CapePhillips, Shaun Peter January 2013 (has links)
Mini-thesis submitted in partial fulfilment of the requirements for the degree
Master of Technology: Public Management
in the
Faculty of Business
at the
CAPE PENINSULA UNIVERSITY OF TECHNOLOGY
2013 / Gillis (2004:1) stated in her publication in Communication World that “employees are the lifeblood of an organisation.”
Local governments, both in South Africa and abroad, are increasingly faced with the need to change for a number of reasons, one of which is to change so as to become more responsive and improve performance. As local government devises means to attain the objectives of performance management, how does it ensure that performance management objectives are mainstreamed within the organisation? Academic writers agree that staff resistances are counterproductive to the efforts made by any municipality to introduce performance management systems with the aim of bringing about effective and efficient service to its constituents. The key to avoiding staff resistances, which all organisations have to take account of, is communicating with employees. The writer suggests that this process is necessary and unavoidable, yet it is almost always ignored.
The main aim of this study was to review the communication practices underpinning the Balance Scorecard (BSC) performance management system within the Cape Town Metropolitan Police Department (CTMPD). Tentative discussions with the metropolitan police department’s middle and low level managers indicated little understanding of how the BSC fits into the CTMPD’s accountability measures. At regular senior management meetings, called the Operational Management Forum (OMF), in 2011, the researcher learnt from operational directors and managers that they were not properly consulted with regard to the BSC system and that the implementation of the system was not adequately communicated. Managers claimed that only a short presentation was given in 2009 and it was then expected that middle managers would achieve the desired results and attain objectives towards which they had very little input. They have since become disillusioned and have resorted to focussing solely on ensuring that they spend their budgets with little understanding that there is more to the BSC than financial measurements. Thus the research questions were posed: why was performance management introduced within the CTMPD and what guidelines can be provided to improve how performance management is communicated to managers? A questionnaire was used to gain insight into this; it was administered to middle management within the CTMPD. The main findings of the research were that the respondents have an understanding of
performance management. Another finding was that the majority of the respondents were not trained in the BSC performance management system. The researcher thus recommended that the safety and security training college be tasked to develop a training workshop, with the help of the support services manager. In addition, the researcher also recommended that the support services division ensures that candidates eligible for middle management positions be tested on their core communication skills and understanding of performance management principles prior to appointment.
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