In this thesis, a novel electronic ballast that includes a repeatedly resonating ignition circuit is proposed for metal halide lamps. The proposed electronic ballast features a two-stage structure that comprises a power factor corrector and a full-bridge inverter used for current control, filtering and ignition. The full-bridge inverter consists of a leg operating at low-frequency with unidirectional switches and a leg operating at high frequency with bidirectional switches. The low-frequency side performs repetitive resonating on the load circuit with inductors and capacitors to accumulate a high voltage for ignition. Adjusting the duty-ratio of the high-frequency side allows for the regulation of the lamp current. The inductors and capacitors in the load circuit function not only producing the high ignition voltage but also filtering out high-frequency components, so that to drive the lamp with a low-frequency square-wave current. The proposed electronic ballast employing the full-bridge inverter with the specially designed control scheme and circuit parameters allows the metal halide lamp to tackle the demanding starting transient and steady state operation. With a simpler circuit structure and a reduced component count, the product cost will be much lower.

Abstract The metal halide lamp is one of high-intensity discharge lamps. It has many advantages such as good color rendering, high efficacy and a variety of color presentations. However, the problems of acoustic resonance, a long transition period of cold starting, and an extremely high ignition voltage for hot restarting should be overcome. The investigation of the thesis is focused on the electrical characteristics of the metal halide lamp operating at high-frequency. Included are the acoustic resonance, starting transient and steady state operation. Various ballast circuits incorporating with ignitors are designed to drive several 70-W metal halide lamps. The operating frequency ranges with acoustic resonance, the ignition voltages for both cold starting and hot restarting, the transition period, the dimming performance, and the lamp equivalent resistance during the lamp life are measured and analyzed. Based on the investigated results, a useful guideline can be provided for the operation and design of the electronic ballast for metal halide lamps. Key words : Metal halide lamp, electronic ballast, acoustic resonance, hot restarting.

A high-frequency electronic ballast with auto-tracking control was proposed to operate the metal halide lamps at a specific frequency free from acoustic resonance. In case the acoustic resonance should happen, the operating frequency is changed step by step with the auto-tracking control, until the lamp is operated at a frequency with stable operation. The electrical characteristics of the lamps are first investigated. Based on the investigated results, a detection circuit is designed to identify the occurrence of acoustic resonance. With the auto-tracking control, the Class-D half-bridge series-resonant inverter can be adopted for the high-frequency electronic ballast to achieve high efficiency and high power density. The control strategy of auto-tracking is practically realized by a single-chip microprocessor. The proposed approach is implemented on a 70 W test lamp with an operating frequency range from 20 kHz to 30 kHz. To regulate the lamp power at its rated value, a buck-boost converter is used as a pre-regulator, which serves also as a power-factor-corrector to achieve a high power factor at the input line.

This thesis presents a single-stage high-power-factor electronic ballast for metal halide lamps. The proposed ballast integrates a buck-boost converter, a buck converter and a full-bridge inverter into a single power conversion circuit. The buck-boost converter is designed to be operated at the discontinuous conduction mode (DCM) with a constant duty ratio at a fixed switching frequency to provide a constant lamp power and to achieve a high power factor for a given ac input voltage. The full-bridge inverter supplies a square-wave current for the lamp at a low frequency the same as the line frequency to avoid acoustic resonance. For the universal input voltage ranged from 90 V to 264 V, the lamp remains at the rated power by controlling the duty-ratio of the buck converter. The circuit operation is analyzed in detail to derive the design equations. An electronic ballast for 70 W lamps is designed and tested. Computer simulations and experimental measurements are provided to verify that the proposed ballast has the merits of a nearly unity input power factor, a high efficiency greater than 82 % and can drive the lamp at a constant power.

Metal halide perovskites (MHPs) have attracted the attention of researchers particularly in the photo-absorption field. These materials rival traditional semiconductors with their cost-effective ease of synthesis, tunable bandgaps, and excellent photophysical properties. Single-junction MHP solar cells have rivaled current silicon-based photovoltaic devices, boasting a 25.2% light absorption conversion. Recently, MHPs have proven to be effective in x-ray detection. In this paper an investigation of three titanium-based MHPs was conducted. The goal of this research was to characterize the MHPs and determine if they are feasible materials to incorporate in x-ray detectors. After completing the research, two MHP species, FA2TiI6 and MA3TiCl7, were able to be synthesized and characterized. Their crystal systems were determined to be tetragonal with a P4/mmm space group. However, due to equipment limitations, their feasibility in x-ray detectors could not be determined.

Over recent years significant progress has been made in the design and development of late transition metal cationic catalysts for olefin polymerisation. Never-the-less, the activation of catalyst precursors and generation of active species still remains a challenge. In this respect, zwitterionic catalysts could offer a range of advantages over the traditional two component catalytic systems. For example, stable zwitterions are well-defined, single component catalysts which do not require Lewis acid co-catalysts for activation. Therefore, this eliminates the possibility of anions coordinating to the active site and could provide highly active catalysts. Moreover, this could reduce the production costs. In this thesis the 6-aminofulvene-2-aldiminate (AFA) ligand system has been employed to develop zwitterionic, charge-neutral complexes, analogues of Brookhart-type cationic alkene polymerisation catalyst containing 1,2-diimine ligand. Chapter 1 of the thesis provides a comprehensive literature review of the late transition metal (Group 10) α-diimine catalytic systems and the zwitterionic early and late transition metal alkene polymerisation catalysts. Chapter 2 describes the synthesis and characterisation of some novel zwitterionic complexes [(Ph2AFA)Pd(Me)(DMAP)], [(Ph2AFA)(N,N-dimethylbenzylamine-2-C,N)- Pd(II)] and [(Ph2AFA)Ni(η 3-C3H5)] and their possible application as catalyst precursors in alkene polymerisation. In principle, upon activation these complexes should exhibit higher catalytic activity. The ideal catalyst precursor for a highly active palladium based system would be a halide-bridged dimer of the form [(Ph2AFA)Pd(μ-X)]2. Chapter 2 describes several efforts towards the synthesis of such complexes using a range of R2AFA ligands. Even with the introduction of bulky N-substituents such as cyclohexyl or tert-butyl, the halidebridged dimers could not be synthesised. Instead, the reaction between the deprotonated ligand and [PdCl2(NCPh)2] provides bis-chelated complexes [(R2AFA)2Pd]. In order to introduce more steric bulk into the AFAH ligand which might lead to a halide-bridged dimer, two more ligands N,N’-bis(2,6-diisopropyl)phenyl-6-aminofulvene-2-aldimine and N,N’-di-(2,4,6-trimethyl)phenyl-6-aminofulvene-2-aldimine have been synthesised and characterised. It has been found that the presence of the 2,6-diisopropylphenyl substituents in N,N'-bis(2,6-diisopropyl)phenyl-6-aminofulvene-2-aldimine not only prevents the coordination of two ligands to the same metal, but precludes complexation all together. Chapter 2 also describes several efforts to develop a hemi-labile complex for alkene polymerisation. Chapter 3 describes the synthesis of metalloligands of aminofulvene-aldimine (AFA) and corresponding bimetallic complexes. The AFA ligand affords transition metal complexes via both η 5- as well as κ 2-coordination modes. A new synthetic methodology has been developed to synthesise metalloligands [Cp*RuII(Ph2AFA)H][BF4], [Cp*RhIII(Cy2AFA)H][BF4]2 and [Cp*RhIII(Cy2AFA)]- [BF4]. The basicity of the monocationic Rh metalloligand is found to be significantly lower than that of its Ru analogues. This is significant as it opens a potentially easy synthetic route to bimetallic complexes. The bimetallic complex [Cp*RhIII(Cy2AFAPdCl2)][BF4] has been developed for alkene polymerisation in an attempt to investigate the charge effect in alkene polymerisation catalysis. Upon activation this monocationic Rh/Pd bimetallic complex would provide a dicationic active species which would in principle be a more highly active catalyst than the Brookhart mono cationic diimine catalysts. Chapter 4 describes all the experimental procedure and polymerisation tests in this thesis.

Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, 1980. / MICROFICHE COPY AVAILABLE IN ARCHIVES AND SCIENCE. / Vita. / Bibligraphy: leaves 222-228. / by Paul Joseph Lemaire. / Ph.D.

The dissertation investigates the starting transient behaviors of metal halide lamps driven by constant currents and constant powers, respectively. Based on the investigation results, three starting scenarios are proposed for shortening the starting time, and an identification strategy is figured out for designing an electronic ballast being capable of driving three small-wattage lamps rated at different powers. A laboratory electronic ballast is designed to drive small-wattage metal halide lamps with a programmable low-frequency square-wave current. Experiments are conducted to examine the effects of the starting current on variations of the light output as well as the lamp voltage and power. From the effects of the applied current on the generated luminance, three starting scenarios are attempted to accelerate the starting transient stage. Experimental evidence shows that the starting time can be effectively shortened by increasing the lamp current during glow-to-arc and warm-up stages. A short interval of over-power operation during the warm-up stage enables the lamp to further enhance the producing of luminance quickly, and hence greatly reduce the starting transient period. According to the starting transient characteristics of metal halide lamps, an identification strategy is figured out to recognize three small-wattage metal halide lamps rated at powers of 20-W, 35-W and 70-W from three world-wide prominent brands, GE, OSRAM and PHILIPS. An electronic ballast is designed to drive the metal halide lamps with the multi-stage constant-power starting scenario. Experimental results evidence that the electronic ballast with the proposed identification strategy can recognize three lamps¡¦ rated powers correctly during the starting transition, and drive the lamp to its rated power before entering the steady-state.

The operating characteristics of metal halide lamps are investigated, including acoustic resonance, spectral energy, and luminous efficacy. To operate metal halide lamps at intended conditions, two test sophisticated ballast circuits are built to drive the lamps with sine-wave current and square-wave current, respectively. One ballast employs the series resonant inverter to output sinusoidal lamp current over a high-frequency range from 20 kHz to 300 kHz. The other makes use of the full-bridge inverter to drive the lamps with square-wave current from 50 Hz up to 300 kHz. For both test circuits, the operating frequency and the magnitude of the lamp current can be controlled independently. On the other hand, the lamp power is adjusted by regulating the DC-link power. Several conclusions are drawn from experimental results: (1) Little difference is found between the lighting spectra of a lamp when driven by sinusoidal current and square-wave current. (2) Luminous efficiency deteriorates as the operating frequency increases. The deterioration is more significant at lower frequencies. (3) Luminous efficiency decreases considerably as the lamp power is reduced. (4) Arc instability from acoustic resonance is highly related to the waveform of the lamp current. The investigated results give better understanding on the steady state operation of metal halide lamps and provide useful information for the design of the electronic ballasts.

The metal halide lamp has become an attractive lighting source because of its compact size, good color rendering, long lamp life, and high luminous efficacy. As a member of high-intensity discharge lamps, it has a negative incremental resistance, which claims the necessity of a ballast circuitry. Similar to other gas discharge lamps, the operating performance can be further improved when driven by a high-frequency electronic ballast. However, there are some obstacles in ballasting the metal halide lamp with the high-frequency inverter. For a cold lamp, an ignition voltage up to several kVs is required for breaking down the electrodes during starting period. The breakdown voltage and the equivalent lamp resistance may vary from time to time and lamp to lamp, and is sensitive to the used time. Furthermore, the ignition voltage for restarting a hot lamp can be ten times that for a cold lamp. On the other hand, the lamp driven by a high-frequency electronic ballast may suffer from acoustic resonance. All these make it difficult in the design of an electronic ballast, especially for the applications with hot restarting. In this dissertation, the operating characteristics for both starting transient and steady-state of the metal halide lamp are first investigated. Then, a simple method by measuring the lamp voltage is proposed to detect the happening of acoustic resonance. Based on the investigated results, several electronic ballasts are designed for driving metal halide lamps with capabilities of wide input voltage range, high input power factor, hot restarting, fast transition. In addition, an inverter circuit is configured for ballasting multiple lamps. A buck-boost power-factor-correction circuit is integrated into the load resonant inverter to achieve a high power factor, fast transition, and constant power operation. The extremely high ignition voltage for hot restarting is generated by an auxiliary ignitor. The electronic ballast is precisely operated at the specific frequency at which acoustic resonance will not occur. In addition to these features, a protection circuit is included to prevent from high voltage and/or current stresses on circuit components in case that the lamp fails to be started up or comes to the end of its life-time. For the ballast with multiple lamps, the load circuits with abnormal lamps can be isolated from the others which are under normal operation. Prototypes of the proposed circuits are built and tested. Experimental results present the satisfactory performances.