Spelling suggestions: "subject:"metalorganic frameworks"" "subject:"metallorganic frameworks""
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Design and processing of metal-organic frameworks for greenhouse gas capture / Syntes och bearbetning av metall-organiska ramverk med flera ligander för insamling av växthusgaserWiksten, Evelina January 2023 (has links)
Anthropogenic emission of greenhouse gases has long been suspected to contribute to global warming and climate change. Most greenhouse gases are emitted in a mixture, so efficient methods and materials to separate and capture the gases are in demand in order to reduce emissions. A promising material group for this purpose is metal-organic frameworks (MOFs). This class of material have the ability to selectively adsorb green house gases due to its high porosity and high surface area. Zeolitic imidazolate frameworks (ZIFs) are a subclass of MOFs that are topologically similar to zeolites and are known for their good chemical and thermal stability. The aim of this project was to investigate if the greenhouse gas (i.e. CO2 and SF6) capture performance of ZIFs could be improved and tuned using a mixed-linker approach with seven different imidazolate-based organic linkers of different sizes or with various functional groups. As well as to investigate the processability of MOFs using 3D printing. ZIFs composed of different ratios of 2-methylimidazolate as base linker and a second linker of imidazolate, benzimidazolate, 2-aminobenzimidazolate, 5,6-dimethylbenzimidazolate, and 4,5-dichloroimidazolate were succesfully made. The materials were all found to be crystalline, however, mixed-linker ZIFs containing 2-aminobenzimidazole, 5,6-dimethylbenzimidazole and dichloroimidazole were observed to contain more than a single phase. All samples showed to be somewhat porous towards CO2 and SF6, and there seem to be a trend where a low % of a bulkier linker (eg. bIm, ambIm) resulted in a higher uptake of SF6 whereas a high % resulted in a higher uptake of CO2. For dcIm it was the other way around, a low % showed a higher uptake for CO2 whereas a high % showed a higher uptake for SF6. For CO2, the ZIF containing 80% benzimidazolate showed the highest uptake of 9.81 wt%. For SF6, the 25% 4,5-dichloroimidazolate showed the highest uptake of 17.73 wt%. Furthermore, direct ink writing (DIW) 3D printing was also successfully utilized to process and structure a Mn-based MOF using carbopol as binder. The printed structure was found to have similar properties to the pristine MOF in regards to crystallinity and porosity.
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Hydrocarbon Sorption in Flexible MOFs: Part I: Thermodynamic Analysis with the Dubinin-Based Universal Adsorption Theory (D-UAT)Preißler-Kurzhöfer, Hannes, Lange, Marcus, Kolesnikov, Andrei, Möllmer, Jens, Erhart, Oliver, Kobalz, Merten, Krautscheid, Harald, Gläser, Roger 27 October 2023 (has links)
The analysis of empirical sorption equilibrium datasets is still vital to gain insights into
material–property relationships as computational methods remain in development, especially for
complex materials such as flexible MOFs. Therefore, the Dubinin-based universal adsorption theory
(D-UAT) was revisited and evaluated as a simple visualization, analysis, and prediction tool for
sorption equilibrium data. Within the theory, gas properties are normalized into corresponding
states using the critical temperatures of the respective sorptives. The study shows theoretically and
experimentally that the D-UAT is able to condense differences of sorption data visualized in reduced
Dubinin plots to just three governing parameters: (a) the accessible pore volume, (b) the reduced
enthalpy of sorption, and (c) the framework’s reduced free energy differences (in case of flexible
behavior). This makes the theory a fast visualization and analysis tool, the use as a prediction tool
depends on rough assumptions, and thus is not recommended.
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Proposed Biomedical Applications of Zirconium-Based Metal-Organic Frameworks as Drug Delivery SystemsPerry-Mills, Ariel Margaret 01 January 2019 (has links)
Metal-organic frameworks (MOFs) are a class of highly crystalline nanoporous materials that self-assemble from inorganic metal oxide clusters and multitopic organic linkers. MOFs can be altered in terms of the types of metals and structures of organic linkers used, allowing for a high degree of customization and manipulation of the synergistic chemical or physical properties that arise from the precise coordination of their molecular components, including exceptionally large surface area and pore size. Zirconium-based MOFs, called UiOs in honor of their conception at the University of Oslo, also show remarkable chemical stability in both acidic and basic environments, making them excellent candidates for biomedical applications as drug delivery systems, where they can either function as molecular cargo ships, with drugs packed into their pores, or as controlled release systems, in which drug molecules are directly attached to their ligands for precise delivery. The objective of this work is to prepare water-stable MOFs whose linkers are decorated with functional groups that have potential compatibility in drug delivery systems and to explore the efficacy of certain synthesis conditions in terms of the crystallinity of the MOF product. Thus, we hope to establish a basis for the ligation of anticancer drugs and fluorescent tags to MOFs for their controlled release at a specified location within the body. These targeted release mechanisms represent new therapeutic possibilities in terms of cancer treatment as their specificity would mitigate damage to healthy tissues, thereby addressing one of the greatest weakness of present treatment options.
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Reticular Chemistry for the Rational Design of Intricate Metal-Organic FrameworksJiang, Hao 11 1900 (has links)
The rational design and construction of Metal-Organic Frameworks (MOFs) with intricate structural complexity are of prime importance in reticular chemistry. However, the design of intricate structures that can practically be synthesized is very difficult, and the suitable targeted intricate nets are still unexplored. Evidently, it is of great value to build the fundamental theory for the design of intricate structures. This dissertation is focused on the exploration of cutting-edge design methodologies in reticular chemistry. This research shows the design and synthesis of several MOF platforms (hex, fcu, gea and the) based on rare earth polynuclear clusters. Furthermore, this research unveils the latest addition, named merged nets approach, to the design toolbox in reticular chemistry for the rational design and construction of intricate mixed-linker MOFs. In essence, a valuable net for design enclosing two edges is rationally generated by merging two edge-transitive nets, spn and hxg. The resultant merged net, named sph net, offers potential for the deliberate design and construction of highly symmetric isoreticular intricate mixed-linker MOFs, sph-MOF-1 to 4, which represent the first examples of MOFs where the underlying net is merged from two 3-periodic edge-transitive nets. Furthermore, the underlying principle of the merged net approach, the fundamental merged net equation, and two key parameters are disclosed. Also, we discovered three analysis methods to check and validate corresponding signature nets in an edge-transitive net. Based on these analysis methods, a signature map of all edge-transitive nets was established. This map showing the systematic relationship among edge-transitive nets will help the material chemist to comprehend more about the underlying nets in reticular chemistry. Based on the revealed map, we systematically described the nine types of merging combination and 140 merged nets based on two edge-transitive nets. Among these enumerated nets, only 18 of them was shown on the RCSR database before. These enumerated merged nets significantly increased the designable targets in reticular chemistry. Using an example of enumerated sub net, we show how this approach can be utilized to design and synthesis mixed-linker porous materials based on the intricate sub-MOF platform, which presents one of the most intricate MOF structures synthesized by design.
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Synthesis of Bimetallic Paddlewheel Complexes and Metal Organic Frameworks for Future Use in CatalysisMattox, Tracy Marie 30 November 2006 (has links)
No description available.
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Binary metal organic framework derived hierarchical hollow Ni3S2/Co9S8/N-doped carbon composite with superior sodium storage performanceLiu, Xinye January 2017 (has links)
No description available.
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A supramolecular approach for engineering functional solid-state chromophore arrays within metal-organic materialsLifshits, Liubov Mikhaylovna 20 April 2016 (has links)
No description available.
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Investigating the parameters of metal-organic framework crystal growth control for reverse osmosis membrane nanofillers and direct air capture of CO2Bonnett, Brittany Lauren 02 June 2022 (has links)
Inorganic nano- and micromaterials (NMMs) exhibit unique properties including high surface areas, tunable optical and electronic properties, low densities, thermal and chemical robustness, and catalytic capabilities, among others. One of the more novel subclasses of NMMs, metal-organic frameworks (MOFs), are crystalline porous coordination polymers consisting of metal nodes connected by organic linkers to form one-, two-, or three-dimensional frameworks. While the mechanism of MOF formation is complex, tuning the metal:ligand ratios, reaction temperature and vessel pressure, ligand concentration, modulator concentration, and H+ activity impacts particle size, morphology, dispersity, and isotropy of these materials. MOFs also exhibit post-synthetic modification capabilities, which, along with their tunable synthetic nature, make them promising candidates for composite materials such as functionalized nanofillers for reverse osmosis (RO) desalination. The work described herein investigates synthetic parameters of a zirconium-based porphyrinic MOF, PCN-222, to selectively control its crystal size, aspect ratio, and dispersity. Size-constrained PCN-222 was post-synthetically modified with fatty acids and zwitterions to be used as RO thin-film composite (TFC) membranes with improved membrane flux, salt rejection, and anti-fouling properties. The synthetic parameters of MOFs were also considered for the commercial scale-up of CO2 direct air capture (DAC) solid sorbents, including UiO-66, MIL-101-Cr, and Mg-MOF-74, to preserve CO2 uptake capacities between lab and industrial scales. / Doctor of Philosophy / Metal-organic frameworks (MOFs) are unique, highly porous materials that have garnered attention for their potential in many applications, including catalysis, drug delivery, energy, and gas storage. In this work, MOFs were produced for environmental applications, particularly for the conversion of salt water to drinkable water in a process known as reverse osmosis (RO) desalination. RO uses a thin membrane to separate dissolved salt, as well as organic materials such as decomposed organisms, from water. Though RO membranes are widely used commercially, they suffer from high costs and short lifetimes; however, their performance is improved through the incorporation of extremely small materials known as nanoparticles. MOF nanoparticles were grown small enough to be dispersed in the polymer matrix of the thin membrane, then functionalized to improve salt rejection and flux, or the speed at which clean water is produced from RO processes. They were also modified to improve lifetimes by preventing the build-up of organic materials on the surface. Besides clean water, MOFs were also prepared for capturing the greenhouse gas, CO2, directly from the air. Because MOFs can be made with many different functionalities, they are promising materials for many different research fields.
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Light Harvesting and Energy Transfer in Metal-Organic FrameworksShaikh, Shaunak Mehboob 24 June 2021 (has links)
A key component of natural photosynthesis are the antenna chromophores (chlorophylls and carotenoids) that capture solar energy and direct it towards the reaction centers of photosystems I and II. Highlighted by highly-ordered crystal structures and synthetic tunability via crystal engineering, metal–organic frameworks (MOFs) have the potential to mimic the natural photosynthetic systems in terms of the efficiency and directionality of energy transfer. Owing to their larger surface areas, MOFs have large absorption cross sections, which amplifies the rate of photon collection. Furthermore, MOFs can be constructed using analogues of chlorophyll and carotenoids that can participate in long-range energy transfer. Herein, we aimed to design photoactive MOFs that can execute one of the critical steps involved in photosynthesis - photon collection and subsequent energy transfer.
The influence of spatial arrangement of chromophores on the efficiency and directionality of excitation energy transfer (EET) was investigated in a series of mixed-ligand pyrene- and porphyrin-based MOFs. Due to the significant overlap between the emission spectrum of 1,3,6,8-tetrakis(p-benzoic acid)pyrene (TBAPy) and the absorption spectrum of meso-tetrakis(4-carboxyphenyl)porphyrin (TCPP), the co-assembly of these two ligands in a MOF should enable facile energy transfer. Bearing this in mind, three TBAPy-based MOFs with markedly different network topologies (ROD-7, NU-901, and NU-1000) were chosen and a small number of TCPP units were incorporated in their backbone. To gain insight into the photophysical properties of mixed-ligand MOFs, we conducted time-resolved and steady-state fluorescence measurements on them. Stern-Volmer analysis was performed on the fluorescence lifetime data of mixed-ligand MOFs to determine the quenching constants. The quenching constant values for ROD-7, NU-901, NU-1000, and TBAPy solution were found to be 15.03 ± 0.82 M-1, 10.25 ± 0.99 M-1, 8.16 ± 0.41 M-1, and 3.35 ± 0.30 respectively. In addition, the ratio of the fluorescence intensities of TCPP and TBAPy was used to calculate the EET efficiencies in each of the three MOFs. EET efficiencies were in the following order: ROD-7 > NU-901 > NU-1000 > TBAPy-solution. Based on the trends observed for quenching constants and EET efficiencies, two conclusions were drawn: (1) the ligand-to-ligand energy transfer mechanism in MOFs outperforms the diffusion-controlled mechanism in solution phase, (2) energy transfer in MOFs is influenced by their structural parameters and spectral overlap integrals. The enhanced EET efficiency in ROD-7 is attributed to shorter interchromophoric distance, larger orientation factor, and larger spectral overlap integral. Directionality of energy transfer in these MOFs was assessed by calculating excitonic couplings between neighboring TBAPy linkers using the atomic transition charges approach. Rate constants of EET (kEET) along different directions were determined from the excitonic couplings. Based on the kEET values, ROD-7 is expected to demonstrate highly anisotropic EET along the stacking direction.
In order to explore the mechanistic aspects of EET in porphyrin-based MOFs, we studied the energy transfer characteristics of PCN-223, a zirconium-based MOF containing TCPP ligands. After performing structural characterization, the photophysical properties of PCN-223 and free TCPP were investigated using steady state and time-resolved spectroscopy. pH-dependent fluorescence quenching experiments were performed on both the MOF and ligand. Stern-Volmer analysis of quenching data revealed that the quenching rate constants for PCN-223 and TCPP were 8.06 ± 1011 M-1s-1 and 2.71 ± 1010 M-1s-1 respectively. The quenching rate constant for PCN-223 is, therefore, an order of magnitude larger than that for TCPP. Additionally, PCN-223 demonstrated a substantially higher extent of quenching (q = 93%) as compared to free TCPP solution (q = 51%), at similar concentrations of quencher. The higher extent of quenching in MOF is attributed to energy transfer from neutral TCPP linkers to N-protonated TCPP linkers. Using the Förster energy transfer model, the rate constant of EET in PCN-223 was calculated. The magnitude of rate constant was in good agreement with the kEET values reported for other porphyrin-based MOFs. Nanosecond transient absorption measurements on PCN-223 revealed the presence of a long-lived triplet state (extending beyond 200 μs) that exhibits the characteristic features of a TCPP-based triplet state. The lifetime of MOF is shorter than that of free ligand, which may be attributed to triplet-triplet energy transfer in the MOF. Lastly, femtosecond transient absorption spectroscopy was employed to study the ultrafast photophysical processes taking place in TCPP and PCN-223. Kinetic analysis of the femtosecond transient absorption data of TCPP and PCN-223 showed the presence of three distinct time components that correspond to: (a) solvent-induced vibrational reorganization of excitation energy, (b) vibrational cooling, and (c) fluorescence.
Materials that allow control over the directionality of energy transfer are highly desirable. Core-shell nanocomposites have recently emerged as promising candidates for achieving long-distance, directional energy transfer. For our project, we aim to employ UiO-67-on-PCN‐222 composites as model systems to explore the possibility of achieving directional energy transfer in MOF-based core-shell structures. The core–shell composites were synthesized by following a previously published procedure. Appropriate amounts of Ruthenium(II) tris(5,5′-dicarboxy-2,2′-bipyridine), RuDCBPY, were doped in the shell layer to produce a series of Ru-UiO-67-on-PCN‐222 composites with varying RuDCBPY loadings (CS-1, CS-2, and CS-3). The RuDCBPY-doped core–shell composites were characterized by powder X-ray diffraction (PXRD), scanning electron microscopy (SEM) imaging, Nitrogen adsorption-desorption isotherms, and diffuse reflectance spectroscopy. Efforts are currently underway to quantify RuDCBPY loadings in CS-1, CS-2, and CS-3. After completing structural characterization, the photophysical properties of CS-1, CS-2, and CS-3 will be investigated with the help of time-resolved and steady-state fluorescence spectroscopy. / Doctor of Philosophy / The pigment−protein complexes in natural photosynthetic units (also known as light harvesting antennas) efficiently capture solar energy and transfer this energy to reaction centers that carry out water splitting reactions. The collective chromophoric behavior of antennas can be replicated by metal-organic frameworks (MOFs). MOFs are crystalline, self-assembled materials composed of metal clusters connected by organic molecules. In this dissertation, we study the factors that govern the energy transfer and light harvesting capabilities of MOFs. In chapter 2, we examined the role of 3D structure of MOFs in energy transfer. In chapter 3, we investigated the influence of pH and temperature on the photophysical properties of MOFs. In chapter 4, we explored the possibility of energy transfer in novel MOF-on-MOF composites. This work is intended to pave the way for the construction of highly efficient MOF-based materials that can serve as the light harvesting and energy-transfer components in solar energy conversion devices.
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Intrinsic and Extrinsic Catalysis in Zirconium-based Metal-Organic FrameworksGibbons, Bradley James 31 May 2022 (has links)
Metal-organic frameworks (MOFs) are a class of hybrid materials that offer a promising platform for a range of catalytic reactions. Due to their complex structure, MOFs offer unique opportunities to serve as novel catalysts, or as host to improve the properties of previously studied species. However, while other catalytic approaches have been studied for many decades, the recency of their discovery means that significant work is still needed to develop MOFs as a viable option for large scale application. Herein, we aimed to advance the field of MOFs as both novel catalysts, and as host platforms for other catalytic species. To this end, we studied synthetic pathways to produce favorable MOF properties such as higher porosity and active site concentration through introduction of defects and macromorphological control, as well as utilization of molecular catalysts imbedded in the MOF structure for multicomponent, light driven reactivity.
Chapter 1 introduces the history MOFs and the pursuit of the stable structures commonly associated with MOF chemistry. The synthesis process for zirconium-based MOFs will be discussed, with specific attention given to the modulated synthesis process which can harnessed to change MOF properties and improve catalysis. Two specific reactions will be introduced which serve as a basis for study in this work. First, the hydrolysis of organophosphate nerve agents by MOFs acting as novel catalysts will be introduced. The mechanism of reaction, as well as previous work in this field will be discussed. Finally, water oxidation as part of artificial photosynthesis through incorporated molecular catalysts will be introduced.
Chapter 2 presents a modulator screening study on a zirconium-based MOF, UiO-66. One of the most commonly studied MOFs, UiO-66 provides an excellent platform for synthetic modulation. Particle size and defect level were measured of 26 synthetic variations and synthetic conditions were found to isolate changes in defect level and particle size, which typically change coincident with each other. Hydrolysis of the organophosphate compound dimethyl 4-nitrophenylphosphate (DMNP) was used to study the impact of particle size and defect level on reactivity. The reaction was found to be surface limited, even at high levels of missing linker defects.
In Chapter 3, the macromorphology of three zirconium-based MOFs were tuned through synthesis modification. MOF powders and xerogels were prepared and characterized to highlight the desirable properties obtained through the gelation process. The materials were compared in the hydrolysis of DMNP and significant enhancement was observed for UiO-66 and NU-1000 xerogels. This was largely attributed to the introduction of mesoporosity and nanocrystalline particle sizes, which significantly increase the number of reactive sites easily accessible for catalysis.
In Chapter 4 the authors examine MOFs as a host for molecular catalysts for use in photoelectrochemical water oxidation. A ruthenium-based catalyst [Ru(tpy)(dcbpy)]2+ was incorporated into UiO-67 through a mixed linker synthesis and grown on a WO3 substrate (Ru-UiO-67/WO3). Previous work from our group demonstrated Ru-UiO-67 retained the catalytic activity as the molecular species, while improving the recyclability of the material. In this work, addition of WO3 as a light harvester allowed for the reaction to be driven at a photoelectrochemical underpotential, a first for MOF-based water oxidation. Finally, Chapter 5 offers a perspective of the field of MOF-based artificial photosynthesis. Particular attention is given to issues of diffusion, selectivity, stability, and moving towards integration of multiple components rather than the study of half-reactions. / Doctor of Philosophy / Catalysts are a key component of chemistry that has a major impact on everyday life. From biological examples to industrial settings, catalysts are used to facilitate chemical conversions to new products and compounds. Because of the high demand, development of new catalysts with improved reactivity is a significant scientific challenge. A new class of materials known as metal-organic frameworks (MOFs) have been recently shown to acts as new catalysts or improve the properties of existing catalysts. Herein, we discuss the use of MOFs as catalysts for both development of new catalysts and improving known species. MOF-based catalysts have been used in a range of reactions from destruction of toxic chemical weapons to the production of renewable energy through artificial photosynthesis. This work is intended to highlight the potential for MOF-based catalysts and the next steps to further realize their potential.
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