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English Abstract The Dunkelsteiner Wald granulite massif in Lower Austria belongs to the Gföhl unit of the Moldanubian zone of the Bohemian Massif. Predominant rocks are felsic granulites which in some places contain garnet pyroxenites and peridotites. There are positions of mafic and intermediate granulites on their intersection. Primary mineral association of mafic granulites is garnet, clinopyroxene rich on Jd and Ca-Tschermack component and kyanite. These rocks probably represent Ca-richer variant of pyroxenites. Contemporary mineral association is make by garnet, clinopyroxene, plagioclase and orthopyroxene. Accessory there is amphibole, spinel, rutile and Ilmenite in the rocks. Sapphire inclusion in garnet cores close to kyanite inclusions has been observed in several cases. Decompression of these rocks creates specific symplectite textures in mafic granulites characterized by plagioclase inclusions. These inclusions are partly or fully surrounded by garnet porphyroblasts on their edges and coarse grain symplectics of plagioclase and pyroxene in matrix. A possible explanation of emergence of this specific texture in rocks on intersection with felsic granulite is an infiltration of melt from felsic lithology. Proof can be the enrichment of K component on edges of plagioclase grains. On the other hand,...

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Calcic-iron skarns are one of the characteristic part of the regional metamorphic complexes of the Bohemian Massif. Their mineral assemblages, structures and significant enrichment of Ca, Al and Fe were previously interpreted to be primary (exhalation sediment) or secondary (metasomatic carbonates). In this project, which consists of three sub-studies will focus on the geochemical composition of skarn as the main arguments for the discussion of their origin. Malešov deposit belongs to the typical calcic-iron skarns whose mineral assemblages are not very different from similar skarns associations in the Bohemian massif. It consists of lenticular body that is stored in gneiss and migmatites of the Kutná Hora crystalline complex. On the deposit prevails garnet-pyroxen skarn, less abundantly represented garnet and magnetite skarns and skarns replacement by amphibole or epidote. Fine-grained garnet skarns are formed by isotropic dark red garnet (Adr78-88Prp0-0.3), while in massive garnet rocks garnet grains form the core (Adr13-38Prp2.5), which envelop newly formed garnet (Adr28-66Prp1.6). In association with them is often pyroxene (Hd60-90) which can be replaced by hastingsite amphibole composition. Other minerals present are magnetite, Fe-epidote, calcite and albite. Magnetite and pyroxene skarns are...

Processos de fusão parcial e metassomatismo foram identificados em xenólitos mantélicos da Província Ígnea Alto Paranaíba (PIAP), na região de Coromandel (Minas Gerais), pela combinação de técnicas de análise textural (petrografia, microscopia eletrônica de varredura), análises químicas minerais pontuais de elementos maiores (por Microssonda Eletrônica), traços (por LA-Q-ICPMS) e isótopos (Sr em clinopiroxênio por LA-MC-ICPMS). Os xenólitos, oriundos dos kimberlitos Indaiá 1, Limeira 1 e Forca, foram divididos em três grupos exibindo texturas, mineralogia e química distintas: peridotitos com espinélio ou Cr- espinélio, interpretados como fragmentos de fácies espinélio no manto litosférico raso; xenólitos com flogopita e/ou clinopiroxênio secundário representando porções do manto litosférico que sofreram metassomatismo por interação com fluidos ou magmas; e dunitos e harzburgitos com textura mosaico porfiroclástica a fluidal compatíveis com porções que sofreram efeitos de um fluxo térmico maior, possivelmente associadas a astenosfera ou a zonas de maior permeabilidade na litosfera. De modo geral os xenólitos mantélicos da Província Ígnea do Alto Paranaíba foram afetados por intensa fusão parcial, indicada especialmente pelo alto valor de mg# em olivina e ortopiroxênio, e pelo empobrecimento de Al em clinopiroxênio e minerais do grupo do espinélio. Boa parte desses xenólitos foi modificada por metassomatismo modal e/ou críptico, que atingiu inclusive níveis rasos do manto litosférico (fácies espinélio). Os harzburgitos e dunitos com textura porfiroclástica com mosaico têm baixos valores de mg# em olivina e ortopiroxênio, e altas concentrações de de Ti, Ca e Na em relação aos demais grupos de amostras sugerindo um processo de metassomatismo críptico de alta temperatura (astenosfera, ou zonas permeáveis da litosfera). Estimativas com base em razões \'Y IND.N\' e \'Yb IND.N\' (normalizadas por Manto PrimitivoPM) em clinopiroxênio, indicam que os peridotitos com Cr-espinélio sofreram uma porcentagem maior de fusão parcial (15-20%), em relação aos peridotitos com espinélio (5-8%), e preferencialmente fracionada. Em algumas amostras nos peridotitos com Crespinélio ainda são encontrados padrões enriquecidos de \'ETRL IND.N\', indicando processos de metassomatismo críptico. Os cristais de clinopiroxênio das amostras de xenólitos metassomatisados têm padrão de distribuição de \'ETR.IND.N\' semelhantes entre si, com padrão de \'ETRL IND.N\' convexo e enriquecido em relação aos \'ETRP IND.N\' (\'La IND.N\' e \'Lu IND.N\', respectivamente 5-14xPM e 0,3-1xPM). Uma amostra de harzburgito com bolsões de clinopiroxênio (In1-12), tem o clinopiroxênio com as maiores razões de \'ETR IND.N\' do conjunto, mantendo o padrão de \'ETRL IND.N\' convexo e enriquecido em relação aos \'ETRP IND.N\' \'(La IND.N\' e \'Lu IND.N\', respectivamente 2543xPM e 1-2,5xPM) dos peridotitos metassomatisados. Razões \'ANTPOT.87 Sr\'/ANTPOT. 86 Sr\' de clinopiroxênio desta última amostra (0,706-0,714) e de flogopita ilmenita wehrlito (0,706-7,10) sugerem que o metassomatismo seria derivado de porção da astenosfera ou litosfera com material proveniente de subducção de crosta. Um valor mais baixo de razão \'ANTPOT. 87 Sr\'/\'ANTPOT.86 Sr\' para clinopiroxênio de peridotito com espinélio (0,703),indica, juntamente com aspectos texturais e de química de maiores e traços, pouca ou nenhuma, influencia do metassomatismo nesta amostra. / Partial melting processes and metasomatism were identified in mantle xenoliths of the Alto Paranaíba Igneous Province (APIP), next Coromandel (Minas Gerais), by combining textural analysis techniques (petrography, scanning electron microscopy) and specific mineral chemical analyzes of major elements (for Electronic Microprobe), trace elements (LA-Q-ICPMS) and isotopes (Sr in clinopyroxene by LA-MC-ICPMS). The xenoliths which are from Indaiá 1, Limeira 1 and Forca kimberlite were divided into three groups displaying different textures, mineralogy and chemistry: peridotites with spinel or Cr-spinel, were interpreted as fragments in the shallow lithospheric mantle; xenoliths with phlogopite and/or secondary clinopyroxene representing the lithospheric mantle portions that suffered metasomatism by interaction with fluids or magmas; and dunites and harzburgites with porphyroclastic texture with mosaic are compatible with portions that have suffered the effects of a higher heat flow, possibly associated with asthenosphere or zones of greater permeability in the lithosphere. Mantle xenoliths from APIP were affected by intense partial melting, suitable for high-value mg# of olivine and orthopyroxene, and the depletion of Al in clinopyroxene and spinel minerals from the group. Many of these xenoliths were modified by modal and/or cryptic metasomatism, which reached even shallow levels of the lithospheric mantle (facies spinel). Harzburgites and dunites with prophyroclastic texture with mosaic have low values of mg# and high concentrations of Ti, Ca and Na in olivine and orthopyroxene compared to other groups of samples suggesting a cryptic metasomatism process of high temperature. \'Y IND.N\' and \'Yb IND.N\' (normalized by Primitive Mantle-PM) ratios in clinopyroxene indicate that the peridotites with Cr-spinel suffered a higher percentage of partial melting (15-20%) compared to the peridotites with spinel (5-8%), and preferably fractional. Some samples in peridotites with Cr-spinel are still found \'LREE IND.N\' enriched ratios patterns, indicating cryptic metasomatism processes. The clinopyroxene crystals of metasomatized xenoliths samples have similar \'REE IND.N\' ratios pattern, with convex \'LREE IND.N\' pattern with higher ratios compared to \'HREE IND.N\' (LaN:5-14xPM and LuN 0,3-1xPM). A harzburgite with insterticial pockted clinopyroxene (In1-12), has the clinopyroxene with the highest \'REE IND.N\' of the set, the convex and enriched \'LREE IND.N\' pattern as well (\'La IND.N\': 25-43xPM and \'Lu IND.N\' 1-2.5XPM) of metasomatized peridotites. Clinopyroxene \'ANTPOT.87 Sr\'/\'ANTPOT.86 Sr\' ratios of the latter sample (0,706 to 0,714) and from phlogopite wehrlite ilmenite sample (0,706 to 0,710) suggest that metassomatism fluids from astenosphere or lithosphere were derivative from crust subduction processes. A lower value ratio \'ANTPOT.87 Sr\'/ANTPOT.86 Sr\' for clinopyroxene in peridotite with spinel (0,703), is in agreement with textural aspects, major and trace elements information, that this group of xenolith little, or no influence of metasomatism.

Processos de fusão parcial e metassomatismo foram identificados em xenólitos mantélicos da Província Ígnea Alto Paranaíba (PIAP), na região de Coromandel (Minas Gerais), pela combinação de técnicas de análise textural (petrografia, microscopia eletrônica de varredura), análises químicas minerais pontuais de elementos maiores (por Microssonda Eletrônica), traços (por LA-Q-ICPMS) e isótopos (Sr em clinopiroxênio por LA-MC-ICPMS). Os xenólitos, oriundos dos kimberlitos Indaiá 1, Limeira 1 e Forca, foram divididos em três grupos exibindo texturas, mineralogia e química distintas: peridotitos com espinélio ou Cr- espinélio, interpretados como fragmentos de fácies espinélio no manto litosférico raso; xenólitos com flogopita e/ou clinopiroxênio secundário representando porções do manto litosférico que sofreram metassomatismo por interação com fluidos ou magmas; e dunitos e harzburgitos com textura mosaico porfiroclástica a fluidal compatíveis com porções que sofreram efeitos de um fluxo térmico maior, possivelmente associadas a astenosfera ou a zonas de maior permeabilidade na litosfera. De modo geral os xenólitos mantélicos da Província Ígnea do Alto Paranaíba foram afetados por intensa fusão parcial, indicada especialmente pelo alto valor de mg# em olivina e ortopiroxênio, e pelo empobrecimento de Al em clinopiroxênio e minerais do grupo do espinélio. Boa parte desses xenólitos foi modificada por metassomatismo modal e/ou críptico, que atingiu inclusive níveis rasos do manto litosférico (fácies espinélio). Os harzburgitos e dunitos com textura porfiroclástica com mosaico têm baixos valores de mg# em olivina e ortopiroxênio, e altas concentrações de de Ti, Ca e Na em relação aos demais grupos de amostras sugerindo um processo de metassomatismo críptico de alta temperatura (astenosfera, ou zonas permeáveis da litosfera). Estimativas com base em razões \'Y IND.N\' e \'Yb IND.N\' (normalizadas por Manto PrimitivoPM) em clinopiroxênio, indicam que os peridotitos com Cr-espinélio sofreram uma porcentagem maior de fusão parcial (15-20%), em relação aos peridotitos com espinélio (5-8%), e preferencialmente fracionada. Em algumas amostras nos peridotitos com Crespinélio ainda são encontrados padrões enriquecidos de \'ETRL IND.N\', indicando processos de metassomatismo críptico. Os cristais de clinopiroxênio das amostras de xenólitos metassomatisados têm padrão de distribuição de \'ETR.IND.N\' semelhantes entre si, com padrão de \'ETRL IND.N\' convexo e enriquecido em relação aos \'ETRP IND.N\' (\'La IND.N\' e \'Lu IND.N\', respectivamente 5-14xPM e 0,3-1xPM). Uma amostra de harzburgito com bolsões de clinopiroxênio (In1-12), tem o clinopiroxênio com as maiores razões de \'ETR IND.N\' do conjunto, mantendo o padrão de \'ETRL IND.N\' convexo e enriquecido em relação aos \'ETRP IND.N\' \'(La IND.N\' e \'Lu IND.N\', respectivamente 2543xPM e 1-2,5xPM) dos peridotitos metassomatisados. Razões \'ANTPOT.87 Sr\'/ANTPOT. 86 Sr\' de clinopiroxênio desta última amostra (0,706-0,714) e de flogopita ilmenita wehrlito (0,706-7,10) sugerem que o metassomatismo seria derivado de porção da astenosfera ou litosfera com material proveniente de subducção de crosta. Um valor mais baixo de razão \'ANTPOT. 87 Sr\'/\'ANTPOT.86 Sr\' para clinopiroxênio de peridotito com espinélio (0,703),indica, juntamente com aspectos texturais e de química de maiores e traços, pouca ou nenhuma, influencia do metassomatismo nesta amostra. / Partial melting processes and metasomatism were identified in mantle xenoliths of the Alto Paranaíba Igneous Province (APIP), next Coromandel (Minas Gerais), by combining textural analysis techniques (petrography, scanning electron microscopy) and specific mineral chemical analyzes of major elements (for Electronic Microprobe), trace elements (LA-Q-ICPMS) and isotopes (Sr in clinopyroxene by LA-MC-ICPMS). The xenoliths which are from Indaiá 1, Limeira 1 and Forca kimberlite were divided into three groups displaying different textures, mineralogy and chemistry: peridotites with spinel or Cr-spinel, were interpreted as fragments in the shallow lithospheric mantle; xenoliths with phlogopite and/or secondary clinopyroxene representing the lithospheric mantle portions that suffered metasomatism by interaction with fluids or magmas; and dunites and harzburgites with porphyroclastic texture with mosaic are compatible with portions that have suffered the effects of a higher heat flow, possibly associated with asthenosphere or zones of greater permeability in the lithosphere. Mantle xenoliths from APIP were affected by intense partial melting, suitable for high-value mg# of olivine and orthopyroxene, and the depletion of Al in clinopyroxene and spinel minerals from the group. Many of these xenoliths were modified by modal and/or cryptic metasomatism, which reached even shallow levels of the lithospheric mantle (facies spinel). Harzburgites and dunites with prophyroclastic texture with mosaic have low values of mg# and high concentrations of Ti, Ca and Na in olivine and orthopyroxene compared to other groups of samples suggesting a cryptic metasomatism process of high temperature. \'Y IND.N\' and \'Yb IND.N\' (normalized by Primitive Mantle-PM) ratios in clinopyroxene indicate that the peridotites with Cr-spinel suffered a higher percentage of partial melting (15-20%) compared to the peridotites with spinel (5-8%), and preferably fractional. Some samples in peridotites with Cr-spinel are still found \'LREE IND.N\' enriched ratios patterns, indicating cryptic metasomatism processes. The clinopyroxene crystals of metasomatized xenoliths samples have similar \'REE IND.N\' ratios pattern, with convex \'LREE IND.N\' pattern with higher ratios compared to \'HREE IND.N\' (LaN:5-14xPM and LuN 0,3-1xPM). A harzburgite with insterticial pockted clinopyroxene (In1-12), has the clinopyroxene with the highest \'REE IND.N\' of the set, the convex and enriched \'LREE IND.N\' pattern as well (\'La IND.N\': 25-43xPM and \'Lu IND.N\' 1-2.5XPM) of metasomatized peridotites. Clinopyroxene \'ANTPOT.87 Sr\'/\'ANTPOT.86 Sr\' ratios of the latter sample (0,706 to 0,714) and from phlogopite wehrlite ilmenite sample (0,706 to 0,710) suggest that metassomatism fluids from astenosphere or lithosphere were derivative from crust subduction processes. A lower value ratio \'ANTPOT.87 Sr\'/ANTPOT.86 Sr\' for clinopyroxene in peridotite with spinel (0,703), is in agreement with textural aspects, major and trace elements information, that this group of xenolith little, or no influence of metasomatism.

The aim of this study is to define mineralogical and geochemical characteristics of phlogopite-pargasite enriched ultramafic-mafic cumulate rocks from Kuran&ccedil / ali (Kirsehir) and their implications for petrology and regional geological setting. The Kuran&ccedil / ali rocks, found within an allochthonous sliver, are representative for the isolated members of the Central Anatolian Ophiolites, derived from closure of Izmir-Ankara-Erzincan branch of Alpine Neotethys. The rocks overthrust the Metamorphic Ophiolitic M&eacute / lange (the uppermost part of the Central Anatolian Metamorphics) and cut by felsic dykes of the Late Cretaceous Central Anatolian Granitoids. The Kuran&ccedil / ali rocks are unusually enriched in phlogopite and pargasite with varying crystal sizes. They are also composed of diopsidic augite, plagioclase, rutile, ilmenite, sphene, apatite and pyrite. The rocks are divided into six types / clinopyroxenite, clinopyroxenite-with-hydrous minerals-plagioclase, phlogopitite, hornblendite, layered gabbro and diorite. Evaluation of detailed EMP data from constituent minerals of different rock types showed that phlogopite with high Fe2+-Fe3+-Al[6]-Ti, diopsidic-augite with high Ca-Al(t)-Ti, Si-undersaturated pargasite with high Al[4]-K-Na-Ti-contents and intercumulus plagioclase with a wide range of composition (an%=40.61-98.58) display unusual compositions. Substitution mechanisms and elemental variations of the minerals suggest crystallization from hydrous metasomatized mantle, high water pressure and oxygen fugacities during formation of the Kuran&ccedil / ali rocks. Major oxide, trace and rare earth element abundances of the rock units were used to evaluate petrological characteristics. Chemical and tectonic discrimination diagrams, and parallel multi-element and REE patterns with highly enriched in LILE and LREE relative to HREE and HFSE show strong calc-alkaline affinity with slight alkaline features. Troughs at Nb-Ta and Ti characterize the rocks but these elements are slightly enriched than N-MORB. The rocks show high LREE/HREE ratios. Both unusual mineralogical and geochemical features of the rocks show that the rocks were generated in an arc environment. Moreover, they require a mantle wedge source strongly influenced by metasomatic components (fluid/melt) derived from subducting slab and/or OIB-like alkaline melt. Comparison of the rocks with tectonically well-defined rocks displays that they are generated in an intra-oceanic arc environment, but owe a comparison with fore-arc back-arc Central Anatolian Ophiolites within supra-subduction zone environment revealed that Kuran&ccedil / ali rocks are different and generated in an arc basement.

Les processus affectant le coin mantellique situé au-dessus d’une zone de subduction (déformation et interaction avec les fluides/liquides magmatiques libérés par la plaque inférieure) ont des implications importantes sur la dynamique de la subduction et le budget géochimique global de la Terre.Afin de mieux contraindre ces processus, ma thèse a porté sur l’étude de l’unité rubanée de l’ophiolite du Semail. Cette unité de 200-500m d’épaisseur s’est (dé)formée, juste au-dessus de l’interface interplaque, pendant l’initiation de la subduction ou du chevauchement intra-océanique (qui a mené, à terme, à l’obduction de l’ophiolite). Elle est en effet située au-dessus de la semelle métamorphique HT (amphibolites à granulites ; 750-850°C et 0.9-1.1GPa) interprétée comme des écailles de la plaque inférieure métamorphisées et sous-plaquées à la plaque supérieure (actuelle ophiolite) lors des premiers stades de la convergence.Après une caractérisation structurale de terrain de cette unité rubanée et la collecte de plus de200 échantillons tout le long de l’ophiolite, j’ai mené une analyse intégrée (Microscopie optique, MEB, microsonde, EBSD, (LA-)ICPMS) sur une sélection d’entre-eux, afin de caractériser l’évolution P-T, pétrologique, géochimique et structurale des péridotites de l’unité rubanée pendant cet épisode de déformation.Les résultats montrent que cette déformation a mené à la formation de zones de cisaillement (proto)mylonitiques (~850-750°C) puis ultramylonitiques (~750-650°C) et que cette déformation BT s’est faite en décompression (d’~3kbar, i.e. 10km). Les résultats pétrologiques indiquent que des fluides silicatés hydratés ont percolé à travers (et intéragi avec) ces péridotites pendant cette déformation. Ces processus d’interaction ont mené à (1) la précipitation de minéraux métasomatiques (Ol+Opx+Cpx+Spl+Amp±Sulf), et (2) l’enrichissement des phases en éléments mobiles dans les fluides (surtout B, Li et Cs :concentrations de 1 à 40 fois celles du manteau primitif).L’analyse des isotopes du bore (δ11B des péridotites métasomatisées jusqu’à +25‰) démontre que ces fluides ont une signature de subduction et qu’ils sont vraisemblablement issus de la déshydratation de la semelle HT lors de sa formation à 750-850°C.En combinant ces résultats avec une analyse microstructurale, j’ai ensuite étudié les mécanismes et les rétroactions entre la circulation de ces fluides, la déformation des péridotites et la localisation de cette déformation. A l’échelle macroscopique, on observe une focalisation des fluides dans les zones de cisaillement actives, associée à une localisation progressive de la déformation.Nous avons aussi exploré les conséquences rhéologiques de l’hydratation de ce manteau sur le régime, couplé ou découplé, de l’interface. Les lois rhéologiques indiquent que l’affaiblissement des (proto)mylonites de l’unité rubanée, par hydratation, peut expliquer le couplage de l’interface de subduction à 850-750°C et, ainsi, l’accrétion de la semelle HT. Nous interprétons les zones de cisaillement ultramylonitiques ultérieures (~750-650°C) comme étant liées au stade d’exhumation simultanée de l’unité rubanée et de la semelle HT d’environ 10km au-dessus de l’interface, jusqu’à leur position actuelle sous l’ophiolite.Les résultats de cette étude suggèrent donc que l’interface semelle HT/unité rubanée représente une interface de subduction fossilisée et le manteau (proto)mylonitique sus-jacent, un coin mantellique qui s’est (dé)formé et a intéragi avec des fluides de subduction pendant l’initiation de la subduction. L’unité rubanée de l’ophiolite du Semail représente donc un des rares objets géologiques permettant d’étudier les processus à l’oeuvre dans un coin mantellique, et d’en traquer, avant sa fossilisation, les transformations mécaniques et chimiques sur ~1 million d’années. / The processes affecting the mantle wedge atop a subduction zone (deformation and interaction with fluids/melts released by the downgoing plate) play a major role on subduction zones dynamics and the global geochemical budget of the Earth.To better constrain these processes, my Ph.D. research project has focused on studying the basal banded unit of the Semail ophiolite. This 200-500m thick peridotitic basal unit was (de)formed, directly above the interplate interface, during the intra-oceanic subduction (or underthrusting) initiation (that ultimately led to the ophiolite obduction). The banded unit indeed overlies the HT metamorphic sole (amphibolites to granulites ; 750-850°C and 0.9-1.1GPa) interpreted as slices of the downgoing plate underplated to the upper plate (the ophiolite) during early subduction (or subduction "infancy").After a field-based structural characterization of this banded unit and more than 200 samples collected all along the strike of the ophiolite, I carried out an integrated analysis (Optical microscopy, SEM, microprobe, EBSD, (LA-)ICPMS) on selected samples, in order to constrain the P-T, petrological, geochemical and structural evolution of the banded unit peridotites during this deformation event.Our results show that this deformation led to the formation of (proto)mylonitic (at ~850-750°C) then ultramylonitic (at ~750-650°C) shear zones and that this deformation was associated with peridotites decompression (of ~3kbar, i.e. 10km). Petrological results suggest that hydrated silicate fluids have percolated through (and interacted with) these peridotites during their deformation. These interaction processes triggered (1) the precipitation of metasomatic minerals (Ol+Opx+Cpx+Spl+Amp±Sulf), and (2) the enrichment of phases in fluid mobile elements (parti- cularly B, Li and Cs;concentrations from 1 to 40 times higher than those of the primitive mantle).The analysis of boron isotopes (δ11B of metasomatized peridotites up to +25‰) demonstrated that these fluids had a "subduction signature" and that they presumably derived from HT sole dehydration while forming at 850-750°C.By combining these results with microstructural analyses, I then studied the mechanisms and feedbacks between the circulation of these fluids, peridotites ductile deformation and strain localization. At the macroscopic scale, we observe a focusing of fluids in actively deforming peridotites associated to progressive strain localization during peridotites cooling.We also investigated the rheological consequences of banded unit peridotites hydration on the regime (coupled or decoupled) of the interface. Rheological laws indicate that the hydration-related weakening of banded unit (proto)mylonites is able to explain the coupling of the subduction inter- face at 850-750°C and, thereby, HT sole slicing and accretion. We interpret the later development of the ultramylonitic shear zones (at ~750-650°C) as being associated to the subsequent exhumation stage, i.e. the coeval exhumation of the banded unit and the HT metamorphic sole over around10km along the interface, up to their present-day position under the ophiolite.The results of this work suggest that the HT sole/banded unit contact represents a fossilized subduction interface and the overlying (proto)mylonitic mantle, a frozen-in mantle wedge that was (de)formed and interacted with subduction fluids during subduction infancy. The Semail ophiolite banded unit therefore provides a rare glimpse of processes affecting a mantle wedge, and enables tracking its mechanical and geochemical transformations over 1My (prior to its fossilization).The processes highlighted in this Ph.D. research project thus bring new constraints on the (petrological-geochemical-rheological) consequences of mantle wedge peridotites interaction with subduction fluids.

O campo vulcânico Patagônico é composto pelo vulcanismo datado do Quaternário ao Cretáceo e está amplamente distribuído no ambiente geotectônico de extra back-arc continental. Onze vulcões associados à ocorrência de xenólitos mantélicos estão situados dos 36°13’S aos 44°52’S. Estes vulcões são dominantemente compostos por basanitos e a basaltos alcalinos, que são divididos em dois grupos com base em aspectos petrográficos, geoquímicos e isotópicos. (Grupos I e II). Estes Grupos estão relacionados a fontes mantélicas similares, mas foram submetidos a diferentes processos metassomáticos. Os Grupos I e I foram gerados a partir de baixas taxas de fusão a partir de uma fonte mantélica do tipo OIB na zona de estabilidade da granada, mas o Grupo II tem características de manto enriquecido (EMII) possivelmente herdadas de um agente metassomático relacionado à zona de subducção, enquanto que o Grupo I demonstra assinatura geoquímica de magmas tipo OIB relacionados a fontes mantélicas ricas em flogopita. Os basaltos alcalinos do vulcão Agua Poca (37º01’S - 68º07’W) pertencem ao Grupo II e são traquibasaltos. O vulcão Agua Poca é definido é piroclástico monogenético, é composto por intercalações de camadas de spatter e cinder, hospeda xenólitos mantélicos e está localizado a oeste da Província de La Pampa, no extremo norte da Argentina. As amostras de xenólitos mostram textura protogranular, protogranular a porfiroclástica, porfiroclástica e porfiroclástica a equigranular e são compostos por olivina (fosterita), ortopiroxênio (enstatita), clinopiroxênio (diopsídio) e espinélio (sp). Os xenólitos estudados são peridotitos da fácies espinélio e piroxenitos anidros em basaltos alcalinos do Pleistoceno com #Mg em rocha total de 89 a 91. As assinaturas geoquímicas desses xenólitos mostram correlação negativa entre os principais óxidos quando dispostos contra o #Mg e estão empobrecidos em elementos incompatíveis em relação ao manto primitivo (MP). Os xenólitos do vulcão Agua Poca são caracterizados pelo empobrecimento de ETRP e ETRM normalizados para o MP e pelo fracionamento de ETRL em relação aos ETRP (CeN/YbN = 0,15-0,5), com exceção da amostra HAP10 (1,46). Esse comportamento indica que os xenólitos do terreno Cuyania são o resultado de 1 a 10% de fusão do DMM (Manto Depletado) ou de 8 a 17% do MP (Manto Primitivo). Em geral, os peridotitos mostram anomalias positivas de Ba, U, Ta, Pb, Zr e Ti; e anomalias negativas de Rb, Th, Nb, La e Y, enquanto que os piroxenitos mostram anomalias positivas de Ba, U, Ta e Pb; e anomalias negativas de Th, Nb, La, Zr, Hf, Ti e Y. Curvas de mistura calculadas para o resíduo de fusão do MP/DMM com a composição de fluídos/sedimentos derivados de ambientes de subducção indicam interação do manto com até 3% de fluídos/sedimentos. As razões 87Sr/86Sr (0,702874 - 0,704999, com média de 0,704035) são muito similares àquelas definidas para peridotitos com fonte tipo OIB. Agua Poca tem razões 87Sr/86Sr, que estão abaixo daquelas definidas para peridotitos metassomatizados (usualmente >0,705). As razões de Nb/Ta sugerem a presença de um reservatório eclogítico refratário subductado fusão parcial gerando líquidos alcalinos com razões Nb/Ta supercondríticas. / The Patagonian Volcanic Field composed of late Cretaceous to Quaternary volcanism is widely distributed in a continental extra back-arc geotectonic environment. Eleven monogenetic volcanoes accompanied with ultramafic xenoliths are situated from 36°13′S to 44°52′S. These volcanoes are dominantly composed of basanite to alkaline basalt, which are divided into two groups, based on mineralogy, geochemical and isotope compositions (Groups I and II). These Groups are originated from the similar subcontinental mantle sources, but were undergone to different metasomatism processes. Groups I and II were generated from low melting degrees of an OIB-like garnet peridotite, but the Group II has enriched mantle (EMII) characteristics possibly inherited from on-going subduction related metasomatism, while Group I demonstrates the OIB-like signature, which might result from phlogopite-bearing in the subcontinental lithosphere. The alkaline basalts from Agua Poca volcano (37º01’S - 68º07’W) belong to the Group II and are trachybasalts. The Agua Poca volcano is a monogenetic pyroclastic volcano composed by intercalation of spatter and cinder layers, host ultramafic mantle xenoliths and is located in the West of the La Pampa Province, Northernmost of Argentine Patagonia. The xenoliths show protogranular, protogranular to porphyroclastic, porphyroclastic and porphyroclastic to equigranular textures, and are composed of olivine (fosterite), orthopyroxene (enstatite), clinopyroxene (diopside) and spinel (sp). The studied xenoliths are anhydrous spinel-bearing peridotite and pyroxenite xenoliths in Pleistocene alkali basalts with whole rock Mg# from 88 to 91. Geochemical signatures of the mantle xenoliths show negative correlation between main oxides against Mg# and depletion in incompatible elements compared to primitive mantle (PM). Agua Poca mantle xenoliths are characterized by flat Sun & McDonough (1989) primitive mantle (PM) normalized HREE and MREE patterns, and depletion of LREE compared to HREE (CeN/YbN = 0.15-0.5), with exception of the HAP10 (1.46) sample. These characteristics suggest that partial melting event is the main process responsible for the generation of these xenoliths. Model calculations suggest that the xenoliths are the result of 1 to 10% of DMM (Depleted Mantle MORB) or 8 to 17% of PM partial melting. Peridotite samples show positive anomalies of Ba, U, Ta, Pb, Zr and Ti; and negative anomalies of Rb, Th, Nb, La and Y, while the pyroxenite samples show positive anomalies of Ba, U, Ta and Pb; and negative anomalies of Th, Nb, La, Zr, Hf, Ti and Y. Mixing curves calculated to mixtures of melting residue of PM/DMM and fluid or sediment compositions related to subduction tectonic setting end members suggest up to 3% of interaction of the fluid sediment on the depleted mantle residue. 87Sr/86Sr ratios (0.702874 - 0.704999, with average of 0.704035) are similar to those defined to peridotites with OIB source (87Sr/86Sr = 0.70244 to 0.70502), being close to Depleted Mantle (DM; 87Sr/86Sr = 0.7023 to 0.7032) values. Nb/Ta ratios suggest that Agua Poca xenoliths were undergone to partial melting processes that generated alkaline magmas with superchondritic Nb/Ta ratios.