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abstract: Uranium Dioxide (UO2) is a significant nuclear fission fuel, which is widely used in nuclear reactors. Understanding the influence of microstructure on thermo-mechanical behavior of UO2 is extremely important to predict its performance. In particular, evaluating mechanical properties, such as elasticity, plasticity and creep at sub-grain length scales is key to developing this understanding as well as building multi-scale models of fuel behavior with predicting capabilities. In this work, modeling techniques were developed to study effects of microstructure on Young’s modulus, which was selected as a key representative property that affects overall mechanical behavior, using experimental data obtained from micro-cantilever bending testing as benchmarks. Beam theory was firstly introduced to calculate Young's modulus of UO2 from the experimental data and then three-dimensional finite element models of the micro-cantilever beams were constructed to simulate bending tests in UO2 at room temperature. The influence of the pore distribution was studied to explain the discrepancy between predicted values and experimental results. Results indicate that results of tests are significantly affected by porosity given that both pore size and spacing in the samples are of the order of the micro-beam dimensions. Microstructure reconstruction was conducted with images collected from three-dimensional serial sectioning using focused ion beam (FIB) and electron backscattering diffraction (EBSD) and pore clusters were placed at different locations along the length of the beam. Results indicate that the presence of pore clusters close to the substrate, i.e., the clamp of the micro-cantilever beam, has the strongest effect on load-deflection behavior, leading to a reduction of stiffness that is the largest for any location of the pore cluster. Furthermore, it was also found from both numerical and i analytical models that pore clusters located towards the middle of the span and close to the end of the beam only have a very small effect on the load-deflection behavior, and it is concluded that better estimates of Young's modulus can be obtained from micro- cantilever experiments by using microstructurally explicit models that account for porosity in about one half of the beam length close to the clamp. This, in turn, provides an avenue to simplify micro-scale experiments and their analysis. / Dissertation/Thesis / Masters Thesis Mechanical Engineering 2015

As superligas à base de cobalto são bem conhecidas por sua excelente resistência ao desgaste. Muitas pesquisas reportadas na literatura abordam o comportamento do desgaste destas ligas, seja no desgaste por deslizamento, erosivo ou abrasivo. Não obstante, o desgaste microabrasivo destas ligas não tem sido muito investigado, apesar dos danos causados por este tipo de solicitação. O comportamento do desgaste microabrasivo de três superligas à base de cobalto: a) 48% Co, 29 %Cr, 19 % Fe; b) uma liga com composição química próxima à da liga comercial Tribaloy T400 (Co 56 %, Cr 8.5%, Mo 29% Si 3.3 %) e c) uma liga com composição próxima à da liga comercial Stellite 6 (Co 64%, Cr 24 %, W 4.2 %, C 2,3%) foram investigadas. Os ensaios de microabrasão foram conduzidos com três abrasivos SiO2, Al2O3, e SiC em suspensão em água destilada, com concentração de 0,1 g/cm3. A carga aplicada foi de 0,3 N, a velocidade angular 20 rpm e a distância total de deslizamento, 48 metros. A análise das superfícies desgastadas por microscopia óptica, eletrônica de varredura e por perfilometria de contato mostraram que o tamanho, forma e dureza dos abrasivos podem influenciar significativamente os coeficientes de desgaste. Os ensaios conduzidos com partículas abrasivas de SiC e Al2O3 apresentaram maiores coeficientes de desgaste que os conduzidos com partículas de SiO2. A Liga Co-Cr-Fe mostrou os maiores coeficientes de desgaste quando comparada com as demais ligas, devido à baixa fração volumétrica de partículas de segunda fase, duras, precipitadas em sua microestrutura. Durante os ensaios, as três ligas, ensaiadas com os três diferentes abrasivos, apresentaram coeficientes de desgaste crescentes com o aumento da dureza do abrasivo; observou-se uma variação linear dos coeficientes de desgaste com a razão entre a dureza do abrasivo (Ha) e a dureza composta da liga (Hs), com R2 = 0.74. O micromecanismo dominante em todos os ensaios foi o desgaste abrasivo a dois corpos (grooving wear). A liga com composição próxima à da liga comercial Tribaloy T400, contendo fases de Laves dispersas em sua microestrutura, apresentou uma transição de micromecanismo de desgaste dúctil para frágil, quando submetida a ensaios com partículas abrasivas de Al2O3. Assim sendo, o volume de material removido nesta liga foi ligeiramente maior que o observado no ensaio com partículas de SiC. Na liga contendo baixa fração volumétrica de partículas de segunda fase, com matriz constituída por Co (CFC), observou-se uma camada subsuperficial nanocristalina de aproximadamente 1 µm de espessura, severamente deformada, imediatamente abaixo da superfície desgastada. Concluiu-se que o desgaste microabrasivo induziu a recristalização a frio do material encruado, com formação de grãos equiaxiais de dimensões nanométricas. / Cobalt alloys are well known for their excellent wear resistance. Many investigations are reported in literature related to the behavior of erosive, abrasive or sliding wear of these alloys. Nevertheless, the micro-abrasive wear of these alloys has not been thoroughly investigated, despite the damage caused by this type of wear. The microabrasive wear behavior of three cobalt alloys: a) 48 wt.% Co, 29 wt.% Cr, 19 wt.% Fe; b) an alloy with chemical composition close to Tribaloy T400 (56 wt.% Co, 8.5 wt.% Cr, 29% wt. Mo, 3.3 wt. %Si) and c) an alloy with chemical composition close to Stellite 6 (64wt.% Co 24 wt.% Cr, 4.2 wt.% W, 2,3 wt.% C were investigated. The tests were carried out using three 0,1 g/cm3 slurries composed by SiO2, Al2O3, and SiC particles, in suspension in distilled water. The applied load was 0.3 N, the rotational speed 20 rpm and the total sliding distance 48 m. Analysis of the worn surfaces of the tested alloys by Optical Microscopy, Scanning Electron Microscopy and Contact Stylus Profilometry showed that abrasive size, shape and hardness could significantly influence the wear coefficients. The tests carried out with SiC and Al2O3 slurries resulted in greater wear rates than those carried out in SiO2 slurry. Stellite 250, showed the greatest wear coefficient, compared to the two other experimental alloys, due to a very low volume fraction of hard second phase particles in the microstructure. Wear coefficients decreased with increasing abrasive particles hardness. An approximate linear correlation with the ratio between the hardness of the abrasives (Ha) and the compound hardness of the alloys (Ha) with a correlation factor R2= 0.74. The dominant wear micromechanism observed in all tests was two-body abrasion (grooving wear). The modified T400 alloy, containing Laves phase showed a transition from ductile to brittle wear mechanisms when testing with alumina slurries. The worn volume was slightly greater than the one observed with SiC. A severely deformed nanocrystalline layer was identified, immediately below the worn surface. It was concluded that cold recrystallization of the work-hardened material occurred, with the formation of nano sized equiaxed grains.

This experimental research aims at investigating the single-phase flow heat transfer and friction factor, flow boiling heat transfer and pressure drop, and flow visualisation in microchannels using de-ionized water. In the literature, many studies failed to explain the effect of aspect ratio on the single-phase and two-phase flow heat transfer rate and pressure drop. Because the channel aspect ratios and hydraulic diameters were varied together in those studies. Also, there is a discrepancy between past studies and the conventional theory for the flow boiling heat transfer characteristics. Accordingly, the objectives of this research can be listed as follows: (i) modifying the existing experimental facility to perform single-phase and two-phase flow heat transfer and pressure drop and two-phase flow pattern visualization experiments in microchannels, (ii) clarifying the fundamental aspects of flow boiling in micro passages, (iii) investigating the aspect ratio, heat flux, mass flux and vapour quality effects on flow patterns, heat transfer rate and pressure drop in single-phase and two-phase flow, (iv) comparing the obtained results with heat transfer and pressure drop correlations and flow pattern maps available in the literature. Consequently, the pre-existing experimental facility was modified in the current research by changing the pre-heaters, flowmeter and piping in order to achieve the goals of this study. Four copper rectangular microchannels were designed and manufactured. Three microchannel test sections having the same hydraulic diameter and length but different aspect ratios were investigated to reveal the effect of aspect ratio on the single-phase and two-phase flow heat transfer rate and pressure drop. The surface roughness of each microchannel was also examined. It was found that the surface roughnesses of all microchannels are similar. Moreover, an additional microchannel test section was used to examine the effect of heated length on the flow boiling heat transfer coefficient and pressure drop. The single-phase flow results demonstrated that the channel aspect ratio has no influence on the friction factor and heat transfer rate for the tested microchannels and experimental range. In the flow boiling experiments, bubbly, bubbly/slug, slug, churn and annular flow regimes were observed in the tested microchannels. The channel aspect ratio effect was found to be small on the observed flow patterns. The experimental flow patterns were predicted well by the flow pattern map proposed by Galvis and Culham (2012) except for the slug flow regime. The flow pattern maps of Sobierska et al. (2006) and Harirchian and Garimella (2009) reasonably predicted the experimental flow pattern data. The flow boiling heat transfer results showed that the prevailing heat transfer mechanism is nucleate boiling for the low and medium heat flux inputs. On the other hand, the dominant heat transfer mechanism is unclear at the high heat flux inputs while smaller aspect ratio microchannel has better heat transfer performance for low and medium heat flux inputs. However, at high heat flux inputs the channel aspect ratio effect was found to be insignificant on the flow boiling heat transfer coefficient. The experimental flow boiling heat transfer coefficient data were reasonably predicted by the correlations of Sun and Mishima (2009), Li and Wu (2010) and Mahmoud and Karayiannis (2011) from the literature. The flow boiling pressure drop characteristics were also examined in the tested microchannels. Outcome of the experiments consistently indicated a highly linear trend between the increasing flow boiling pressure drop and the heat and mass flux. Also, the flow boiling pressure drop increased with the increase in vapour quality. The effect of channel aspect ratio on the flow boiling pressure drop was also assessed. It was found that when the channel aspect ratio decreased, the flow boiling pressure drop increased. The experimental flow boiling pressure drop data were compared to correlations from the literature. Mishima and Hibiki (1996), Yu et al. (2002) and Zhang et al. (2010) correlations reasonably predicted the experimental flow boiling pressure drop results.

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Sub-Saharan Africa has an underutilised solar resource that is available to provide distributed-scale power to rural communities that are not reached by the current grid systems that are in place. Renewable power generation systems are typically infeasible for this purpose due to their high manufacturing and maintenance costs. This research proposes to address this by experimentally investigating the performance of a micro-scale, solar thermal Rankine cycle with direct steam generation using an affordable solar collector design. The intended power generation range is between 0.1 and 1 kW, which can be used for the direct mechanical pumping of rural irrigation systems or municipal water supplies. The study focuses on the performance of the solar collector (the solar reflector and the solar receiver) under realistic solar thermal conditions in sub-Saharan Africa, as it is considered to be one of the most important components in the solar thermal Rankine cycle. The performance of the solar collector was first characterised in an optical analysis of the new faceted dish reflector design, which comprised six Mylar membranes stretched over the elliptical rims of television satellite dishes. The optical analysis was conducted with the main goal of determining how much concentrated solar radiation would intercept the experimental receiver aperture during solar testing. This was determined by measuring the reflectivity of the reflector facets through ultraviolet and visible light (UV-VIS) spectroscopy and producing an intercept factor trend as a function of receiver aperture size through photographic lunar flux mapping. Based on the spectroscopy analysis, the spectral reflectivity of the clean Mylar facets was determined to be 97% for the visible light spectrum. The intercept factor was determined to be 87% for the designed receiver aperture diameter of 135 mm. The thermal testing took place on a clear, sunny day with low wind velocities. The solar collector followed the arc of the sun throughout the day with a 1° tracking error. During the testing, municipal water was passed through the receiver at 0.284 g/s and the temperature and pressure within the receiver were recorded. A 91-minute testing period occurred, where the inlet and outlet process flows obtained relatively constant operating temperatures with the inlet temperature at 54 °C and the outlet temperature at 343 °C. The total solar irradiance dropped from 801 to 705 W/m2 during this testing period. Using a reflector with a total incident area of 2.73 m2, the total radiation intercepted at the aperture dropped from 1 845 to 1 625 W during this period. The total power capture by the working fluid averaged at approximately 861 W and the total rate of heat loss was determined to be between 1 000 and 750 W. An average collector efficiency of 42% and an average receiver efficiency of 49% were determined for the testing period. An analysis of the heat loss showed that approximately 84% of the heat was lost through the aperture, of which, 31% was from reflected radiation. The second-law analysis showed that most of the irreversibility in the solar collector was caused by absorption of the concentrated radiation at the coil surface. This was because of the large temperature difference between the sun and the receiver coils. The experimental thermal analysis highlighted the design challenges of the micro-scale thermal Rankine cycle. However, the analysis showed that a solar collector can be constructed using locally sourced, affordable materials and can be used to produce power at a micro-scale. With appropriate attention given to optimising the collector design and determining the optimum operating conditions of the solar receiver, the power cycle would be able to compete with current technologies to provide decentralised power to communities in need. / Dissertation (MEng)--University of Pretoria, 2019. / Technology Innovation Agency (TIA); National Research Foundation (NRF); Department of Science and Innovation (DSI) / Mechanical and Aeronautical Engineering / MEng (Mechanical) / Unrestricted

This thesis presents the design and construction of a micro-scale, air powered, impact testing device for use in Virginia Tech's Biological and Bio-inspired Materials Laboratory. A brief overview of current projectile impact testers is presented along with motivation for the fabrication of a new testing system capable of firing a projectile with a maximum diameter of 0.5 mm at velocities ranging from 20 to 50 m/s. Initial design calculations and analysis were performed to optimize barrel length, projectile size, and air pressure for desired velocity ranges. Computer aided design was then utilized to create a digital model of the entire system before production began on the device. Within the scope of this project was the development of a large-scale projectile impact tester as a proof of concept of the system's design that would later be utilized by other researchers as well as the micro-scale tester which carried over the lessons learned and design improvements from the larger device. The culmination of the project was the testing of biological samples (sea urchin spine cross sections) to prove the viability of the device and highlight its research niche. Future use cases and design improvements of the small-scale impact tester were also investigated as part of this thesis work. / Master of Science / This thesis encompasses the design and fabrication of both a large-scale projectile impact tester as a proof of concept design as well as a micro-scale version that carries over many of the design elements of the large version but is designed to fire projectiles for small scale biological material tests. Also included as part of this thesis is a breakdown of the various impact testers currently available within research to show why this project was necessary. The project culminated in simple impact studies of sea urchin spines to showcase the capabilities of the impact tester in its current form as well as to outline some of the expanded properties that could be determined with simple experimental setup changes. From this impact, study it was determined that sea urchin spines are a leading candidate in the formulation of bio-inspired impact resistant ceramic foams as they have excellent energy absorption properties during dynamic loading. The calcite foam structure of the sea urchin spines proved to have better impact absorption capabilities in comparison to many current engineering materials used for impact resistance. The final part of this thesis is a brief overview of the planned future use cases of the device.

京都大学 / 新制・課程博士 / 博士(工学) / 甲第23503号 / 工博第4915号 / 新制||工||1768(附属図書館) / 京都大学大学院工学研究科機械理工学専攻 / (主査)教授 黒瀬 良一, 教授 花崎 秀史, 教授 岩井 裕 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM

Spherical micro- and nano-particles have found widespread use in many various applications from paint to cosmetics to medicine. Due to the multiplicity of desired particle material(s), structure, size range, and functionality, many approaches exist for generating such particles. Bottom-up methods such as chemical synthesis have a high yield and work with a wide range of materials; however, these processes typically lead to large polydispersity and cannot produce structured particles. Top-down approaches such as microfluidics overcome the polydispersity issue and may produce a few different structures in particles, but at lower rates and only at the micro-scale. A method that can efficiently produce uniformly-sized, structured particles out of a variety of materials and at both the micro- and nano-scales does not yet exist. Over the past few years, I have developed an in-fiber particle fabrication method that relies on a surface tension-driven fluid instability, the Plateau-Rayleigh capillary instability (PRI). Thermal treatment of a multimaterial core/cladding fiber induces the PRI, causing the initially intact core to break up into a periodic array of uniformly-sized spherical particles. During this time, I have demonstrated that this method can produce particles from both polymers and glasses, in a multiplicity of structures, and from diameters of over 1 mm down to 20 nm. Furthermore, by using a stack-and-draw method, a high density of cores may be incorporated into a single fiber, making the in-fiber PRI approach a highly scalable process. Finally, I have shown that it is possible to add dopants to the particles to give them functionality. By structuring the particles, it is thus possible to fabricate multi-functional particles whose functionalities may be allocated arbitrarily throughout the volume of the particles.

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