Coal workers’ pneumoconiosis (CWP), commonly referred to as black lung, is a chronic lung disease that results from the inhalation and deposition of coal dust in the lungs. While this disease continues to afflict coal miners, its prevalence has steadily declined over three decades since 1970. Based on a voluntary X-ray surveillance program, conducted by the National Institute for Occupational Safety and Health (NIOSH), this downward trend, however, ended in 2000 and has actually begun to rise. The Mine Safety and Health Administration (MSHA) instituted a Comprehensive Initiative to “End Black Lung” to combat the reported upturn in black lung disease. Rulemaking, with the intent of strengthening respirable dust regulations, is a major part of this initiative. This thesis addresses a controversial aspect of the newly proposed rules – single-shift compliance sampling. Establishing new requirements for respirable dust compliance requires an understanding of both the accuracy and variability of measurements. Measurement variability is especially important in underground mining where the workplace is constantly moving and ventilation controls are continually changing. The results of a ventilation study performed in three underground coal mines are presented in this thesis. A total of 600 dust-concentration measurements were obtained in this study using Continuous Personal Dust Monitors (CPDMs). The data was analyzed to determine the variability associated with taking dust measurements in the mining workplace. The Johnson transformation was found to produce the best-fit distribution model for the data. This thesis summarizes the results of this study and presents a statistical procedure for establishing an exposure limit.

Froth flotation is the most efficient method for phosphate separation, which is a physic-chemical separation process based on the difference of surface properties between the valuable minerals and unwanted gangue minerals. However, the presence of clay slimes in the slurry after grinding consumes a large amount of reagents, decreases the collision probability between bubbles and minerals, prevents phosphate particle attachment to air bubbles, and thus considerably reduces flotation recovery and concentrate grade. Georgia Pacific Chemical, LLC has recently developed novel depressants, i.e., clay binders, which are a series of low molecular weight specialty polymers to help improve phosphate flotation performance by selectively agglomerating and depressing clay particles, thus lowering their surface area and reducing the adsorption of surfactants. This thesis addresses the effects of clay binders on phosphate flotation performance and their adsorption behavior on different minerals in a sedimentary phosphate ore. Quartz Crystal Microbalance with Dissipation technique (QCM-D) was used to study adsorption characteristics of clay binders and batch flotation tests were performed under different conditions to investigate phosphate flotation performance. The experimental results have shown that clay binders significantly improved phosphate flotation selectivity and reduced the dosages of collector and sodium silicate used as dispersant in the industry.

In 2006, Congress passed the MINER Act requiring mine operators to submit an emergency response plan that included post-accident communications and tracking systems to MSHA within three years of the Act. These systems were required to be designed for maximum survivability after a catastrophic event, such as a fire or explosion, and to be permissible (meets MSHA criteria for explosion-proof). At that time, no commercially available systems existed that met these standards. Several companies undertook developing new, or enhancing existing, technologies to meet these requirements. This research presents the results of a study that was conducted to determine the present day types of systems being used, along with their average annual worker hours, coal production, number of mechanized mining units, and type of communications and tracking systems installed. Furthermore, 10 mines were visited to obtain detailed information related to the various technologies. It was found the most influential parameters on system selection include MSHA district, mining method, and number of underground workers.

The research outlined in this thesis is concerned with the environmental aspects of groundwater re-establishment as a consequence of surface mining. No principal effects which have been identified as being detrimental to the restored land area are as follows; i). The vertical and horizontal displacements of backfill materials following restoration, and ii). The pollution of groundwater from contact with weathered rockfill materials. The research into settlement has attempted to classify the types of movement which may occur within a backfill mass, in particular the differential movements which are of great importance to the stability of proposed structures or surface drainage. The field results from 10 opencast mine sites are presented, 3 of which were instrumented for detailed field investigations. It has been shown that backfill movements do not necessarily show similar trends under similar conditions, and reasons for this are proposed. A variety of instrumentation schemes have been devised to examine backfill displacements, both vertically and horizontally. Permeability testing has been conducted at different horizons the backfill mass in order to locate the zones of collapse settlement due to groundwater recovery. A critical review of the instrumentation utilised in the investigations is presented, with suggestions for improvement. Investigations into groundwater pollution have been devoted to examining the qualities of groundwater flowing into British surface mines and evaluating its likely reactions with fill materials. An insight into general groundwater pollution and treatment techniques is presented together with a critical analysis of their applicability, to British conditions. An investigation into water qualities in each of the six geographical regions of the opencast mining industry of Great Britain is detailed. Finally some suggestions for future research areas are indicated.

MgH2 is considered to be one of the most promising options for a solid state hydrogen storage material. For practical use it is still imperative to find a convenient means of overcoming its slow kinetics and high stability. In this investigation, a range of binary and ternary metal oxides of aluminium, silicon, titanium, and zirconium, as well as Pd-modified Ti02 samples, were prepared and characterised. The prepared oxides were ball milled with MgH2, and the hydrogen sorption behaviour of the ball milled mixtures was investigated using DSC-TGA-MSS, Sieverts and IGA. Thermodynamic parameters including enthalpies and entropies of hydrogen desorption were determined from experimental data, and activation energy calculations along with modelling of the kinetics were used to understand the mechanism and rate-limiting step of dehydrogenation. Oxide components, calcination temperature, and surface area were found to have a significant impact on the hydrogen sorption behaviour of MgH2 in the ball milled mixtures. Of the prepared binary and ternary oxides, Ti02 and mixed oxides with a Ti02 component were found to lower the dehydrogenation onset temperature by as much as 100°C, while additions of Pd-modified Ti02 resulted in the lowest dehydrogenation onset temperature of 205°C, compared to 360°C for ball milled MgH2. In addition, rates of hydrogen desorption and absorption were significantly increased as a result of the Ti02 and Ti02 - Pd additives. Dehydrogenation of 90 % of the full H2 capacity took 6 min at 300°C, compared to 230 min for milled MgH2 at 350°C. It was found that a reduction of the Ti02 oxide resulted in the active species responsible for the enhanced dehydrogenation behaviour. Through analysis of the reaction kinetics, the mechanism of dehydrogenation was found to change from a surface controlled, contracting volume model for ball milled MgH2 to one of a Johnson-Mehl-Avrami model of two - dimensional nucleation and growth upon addition of Ti02 and Ti02 - Pd.

The development of electronic surveying instruments, such as electronic theodolites, and concurrent advances in computer technology, has revolutionised engineering surveying; one of the more recent examples being the introduction of Electronic Theodolite Intersection Systems (ETISs). An ETIS consists of two or more electronic theodolites and a computer, with peripheral hardware and suitable software. The theoretical principles on which they are based have been known for a long time, but intersection has seldom been used as a method of measurement. The main reasons for its re-evaluation were the introduction of one-second electronic theodolites and the ability to interface these on-line to a computer. The last decade has seen the development of several commercially available systems and probably even more in-house developed systems. Such systems are capable of performing real-time, non-contact, three-dimensional coordinate determination to a high accuracy, enabling their use in a wide variety of applications. This thesis details all aspects of ETISs. Initially, the theoretical principles on which the systems are based are developed. The components of a system are then detailed and a review of current commercially available systems and their applications is given. The thesis then concentrates on the development of an ETIS by the author and details its' application in both industrial measurement and deformation monitoring. Finally, the thesis concludes with a discussion on the factors affecting the accuracies attainable with ETISs.

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