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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Brillouin Scattering Investigation of Glass-Like Properties in (KBr)1-x(KCN)x Mixed Crystals

Hu, Zhibing 04 1900 (has links)
<p> Brillouin scattering technique is used to investigate the transverse acoustic phonon in (KBr)1-x(KCN)x alloy as a function of temperature for CN- concentration ranging from 0.20 to 0.50. Anomalies in phonon frequency and linewidth are observed and discussed in terms of coupling of the acoustic phonons with orientational motion of CN- ions based on a dynamic microscopic model suggested by Michel et al. The frequency and concentration dependence of the freezing temperature, which marks the formation of an orientational glass state, is examined.</p> <p> A high resolution tandem Fabry-Perot interferometer yields the first evidence of a complex spectrum which consists of the phonon peak and new equal-spaced modes. The Bayesian deconvolution technique is used to extract the spectra. The concentration, time and temperature dependence of these new modes are presented. It is proposed that they arise from the modification of the tunneling levels of the CN, and appear to have the uniform density of states which is the characteristic property of the glass.</p> / Thesis / Master of Science (MSc)
2

Dados cristalográficos de alguns produtos naturais: rubrinolídio, rubrenolídio, cristais mistos de rubrinolídio e rubrenolídio e rubranina / Crystal data for some natural products: rubrinolideo, rubrenolídeo, and mixed crystals of rubrinolideo, rubrenolídeo and rubranina

Pinto, José Pereira 21 February 1975 (has links)
Foram determinados os dados cristalográficos das substâncias denominadas rubrinolídeo, rubrenolídeo, cristais mistos de rubrinolídeo e rubrenolídeo e rubranina. Além disso, foi verificado o isomorfismo entre os cristais mistos de rubrinolídeo, rubrenolídeoe dos cristais mistos do rubrinolídeo e rubrenolídeo. A partir de considerações derivadas do conhecimento das dimensões da cela unitária e da simetria do grupo espacial foi possível sugerir uma possível configuração estereoquímica Para esses compostos. E dada uma introdução geral dos métodos experimentais utilizados e dos fundamentos da teoria da difração dos raios x pelos cristais. Rubrinolídeo: a= (32,95 &#177 0,08)&#197 V = (879 &#177;21)&#1973 b = (5,18 &#177 0,04)&#197 Z=2 molec/cela c= (5,15 &#177 0,07)&#197 massa específica observada &#945 = &#947 = 90&#176 (1,22 &#177 0,16) g/cm3 &#946 = 88&#176 52&#8217 &#177 18&#8217 massa específica calculada 1,13&#177 g/cm3 Rubrenolídeo: &#8204a&#8204 = (34,25 &#177 0,17)&#197 V = (953 &#177 12)&#1973 &#8204b&#8204 = (5,19 &#177 0,03)&#197 Z=2 molec/cela &#8204c&#8204 = (5,36 &#177 0,01)&#197 massa específica observada &#945 = &#947 = 90&#176 (1,24 &#177 0,21) g/cm3 &#946 = 88&#176 52&#8217 &#177 18&#8217 massa específica calculada 1,08&#177 g/cm3 Cristais mistos: &#8204a&#8204 = (33,66 &#177 0,09)&#197 V = (889 &#177 20)&#1973 &#8204b&#8204 = (5,08 &#177 0,01)&#197 z=2 molec/cela &#8204c&#8204 = (5,20 &#177 0,08)&#197 massa específica observada &#945 = &#947 = 90&#176 (1,20 &#177 0,18) g/cm3 &#946 = 88&#176 52&#8217 &#177 18&#8217 massa específica calculada 1,12&#177 g/cm3 Rubranina: &#8204a&#8204 = (15,62 &#177 0,02)&#197 V = (4102 &#177 106)&#1973 &#8204b&#8204 = (11,92 &#177 0,03)&#197 z=2 molec/cela &#8204c&#8204 = (26,84 &#177 0,03)&#197 massa específica observada &#945 = &#947 = 90&#176 (1,24 &#177 0,13) g/cm3 &#946 = 55&#1765 3&#8217 &#177 6&#8217 massa específica calculada 1,27&#177 g/cm3 / The crystal data of the compounds rubrinolideo, rubrenolideo and its mixed crystals ando f rubranine were determined using the Weissenberg equi-inclination and the Buerguer\'s precession methods. The crystal data for these compounds are the following: Rubrinolideo: &#8204a&#8204 = (32,95 &#177 0,08)&#197 V = (879 &#177 21)&#1973 &#8204b&#8204 = (5,18 &#177 0,04)&#197 z=2 molec/cell &#8204c&#8204 = (5,15 &#177 0,07)&#197 dobs=(1,22 &#177 0,16) g/cm3 &#945 = &#947 = 90&#176 dcalc=1,13 &#177 g/cm3 &#946 = 88 &#176 52\' &#8217 18\' Rubrenolideo: &#8204a&#8204 = (34,25 &#177 0,17)&#197 V = (953 &#177 12)&#1973 &#8204b&#8204 = (5,19 &#177 0,03)&#197 z=2 molec/cela &#8204c&#8204 = (5,36 &#177 0,01)&#197 > dobs.=(1,24 &#177 0,21) g/cm3 &#945 = &#947 = 90&#176 dcalc=1,08 &#177 g/cm3 &#946 = 88&#176 52 &#8217 18\' Mixed Crystals: &#8204a&#8204 = (33,66 &#177 0,09)&#197 V = (889 &#177 20)&#1973 &#8204b&#8204 = (5,08 &#177 0,01)&#197 z=2 molec/cell &#8204c&#8204 = (5,20 &#177 0,08)&#197 > dobs=(1,20 &#177 0,18) g/cm3 &#945 = &#947 = 90&#176 dcalc=1,12 &#177 g/cm3 &#946 = 88&#176 52 &#8217 18\' Rubranine: &#8204a&#8204 = (15,62 &#177 0,02)&#197 V = (4102 &#177 106)&#1973 &#8204b&#8204 = (11,92 &#177 0,03)&#197 z=8 molec/cell &#8204c&#8204 = (26,84 &#177 0,03)&#197 > dobs=(1,24 &#177 0,13) g/cm3 &#945 = &#947 = 90&#176 dcalc = 1,27&#177 g/cm3 &#946 = 55&#176 3\' &#8217 6\' There is isomorphism in the crystals of rubrenolideo, rubrinolideo and its mixed crystals. From considerations derived from their cell dimensions and space group symmetry it is proposed a possible estereochemical configuration for these compounds. It is given a general introduction to the used experimental methods and to the fundamental theory of x-rays diffraction by crystals
3

Sobre a natureza dos ácidos coleicos / About the nature of choleic acids

Senise, Paschoal Ernesto Américo 17 April 1942 (has links)
Não consta resumo na publicação. / Abstract not available.
4

Dados cristalográficos de alguns produtos naturais: rubrinolídio, rubrenolídio, cristais mistos de rubrinolídio e rubrenolídio e rubranina / Crystal data for some natural products: rubrinolideo, rubrenolídeo, and mixed crystals of rubrinolideo, rubrenolídeo and rubranina

José Pereira Pinto 21 February 1975 (has links)
Foram determinados os dados cristalográficos das substâncias denominadas rubrinolídeo, rubrenolídeo, cristais mistos de rubrinolídeo e rubrenolídeo e rubranina. Além disso, foi verificado o isomorfismo entre os cristais mistos de rubrinolídeo, rubrenolídeoe dos cristais mistos do rubrinolídeo e rubrenolídeo. A partir de considerações derivadas do conhecimento das dimensões da cela unitária e da simetria do grupo espacial foi possível sugerir uma possível configuração estereoquímica Para esses compostos. E dada uma introdução geral dos métodos experimentais utilizados e dos fundamentos da teoria da difração dos raios x pelos cristais. Rubrinolídeo: a= (32,95 &#177 0,08)&#197 V = (879 &#177;21)&#1973 b = (5,18 &#177 0,04)&#197 Z=2 molec/cela c= (5,15 &#177 0,07)&#197 massa específica observada &#945 = &#947 = 90&#176 (1,22 &#177 0,16) g/cm3 &#946 = 88&#176 52&#8217 &#177 18&#8217 massa específica calculada 1,13&#177 g/cm3 Rubrenolídeo: &#8204a&#8204 = (34,25 &#177 0,17)&#197 V = (953 &#177 12)&#1973 &#8204b&#8204 = (5,19 &#177 0,03)&#197 Z=2 molec/cela &#8204c&#8204 = (5,36 &#177 0,01)&#197 massa específica observada &#945 = &#947 = 90&#176 (1,24 &#177 0,21) g/cm3 &#946 = 88&#176 52&#8217 &#177 18&#8217 massa específica calculada 1,08&#177 g/cm3 Cristais mistos: &#8204a&#8204 = (33,66 &#177 0,09)&#197 V = (889 &#177 20)&#1973 &#8204b&#8204 = (5,08 &#177 0,01)&#197 z=2 molec/cela &#8204c&#8204 = (5,20 &#177 0,08)&#197 massa específica observada &#945 = &#947 = 90&#176 (1,20 &#177 0,18) g/cm3 &#946 = 88&#176 52&#8217 &#177 18&#8217 massa específica calculada 1,12&#177 g/cm3 Rubranina: &#8204a&#8204 = (15,62 &#177 0,02)&#197 V = (4102 &#177 106)&#1973 &#8204b&#8204 = (11,92 &#177 0,03)&#197 z=2 molec/cela &#8204c&#8204 = (26,84 &#177 0,03)&#197 massa específica observada &#945 = &#947 = 90&#176 (1,24 &#177 0,13) g/cm3 &#946 = 55&#1765 3&#8217 &#177 6&#8217 massa específica calculada 1,27&#177 g/cm3 / The crystal data of the compounds rubrinolideo, rubrenolideo and its mixed crystals ando f rubranine were determined using the Weissenberg equi-inclination and the Buerguer\'s precession methods. The crystal data for these compounds are the following: Rubrinolideo: &#8204a&#8204 = (32,95 &#177 0,08)&#197 V = (879 &#177 21)&#1973 &#8204b&#8204 = (5,18 &#177 0,04)&#197 z=2 molec/cell &#8204c&#8204 = (5,15 &#177 0,07)&#197 dobs=(1,22 &#177 0,16) g/cm3 &#945 = &#947 = 90&#176 dcalc=1,13 &#177 g/cm3 &#946 = 88 &#176 52\' &#8217 18\' Rubrenolideo: &#8204a&#8204 = (34,25 &#177 0,17)&#197 V = (953 &#177 12)&#1973 &#8204b&#8204 = (5,19 &#177 0,03)&#197 z=2 molec/cela &#8204c&#8204 = (5,36 &#177 0,01)&#197 > dobs.=(1,24 &#177 0,21) g/cm3 &#945 = &#947 = 90&#176 dcalc=1,08 &#177 g/cm3 &#946 = 88&#176 52 &#8217 18\' Mixed Crystals: &#8204a&#8204 = (33,66 &#177 0,09)&#197 V = (889 &#177 20)&#1973 &#8204b&#8204 = (5,08 &#177 0,01)&#197 z=2 molec/cell &#8204c&#8204 = (5,20 &#177 0,08)&#197 > dobs=(1,20 &#177 0,18) g/cm3 &#945 = &#947 = 90&#176 dcalc=1,12 &#177 g/cm3 &#946 = 88&#176 52 &#8217 18\' Rubranine: &#8204a&#8204 = (15,62 &#177 0,02)&#197 V = (4102 &#177 106)&#1973 &#8204b&#8204 = (11,92 &#177 0,03)&#197 z=8 molec/cell &#8204c&#8204 = (26,84 &#177 0,03)&#197 > dobs=(1,24 &#177 0,13) g/cm3 &#945 = &#947 = 90&#176 dcalc = 1,27&#177 g/cm3 &#946 = 55&#176 3\' &#8217 6\' There is isomorphism in the crystals of rubrenolideo, rubrinolideo and its mixed crystals. From considerations derived from their cell dimensions and space group symmetry it is proposed a possible estereochemical configuration for these compounds. It is given a general introduction to the used experimental methods and to the fundamental theory of x-rays diffraction by crystals
5

Sobre a natureza dos ácidos coleicos / About the nature of choleic acids

Paschoal Ernesto Américo Senise 17 April 1942 (has links)
Não consta resumo na publicação. / Abstract not available.
6

Zeitaufgelöste inelastische Neutronenstreuung an entmischenden Silber-Natriumchlorid-Einkristallen / Time-resolved inelastic neutron scattering from demixing silver-sodium-chloride single crystals

Caspary, Dirk 31 October 2002 (has links)
No description available.

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