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THE USE OF GASEOUS METAL OXIDE AS AN OXYGEN CARRIER IN COAL CHEMICAL LOOPING COMBUSTIONZhang, Quan 01 May 2018 (has links) (PDF)
Traditional chemical looping technologies utilize solid oxygen carriers and has some disadvantages, especially when solid fuels like coal are used. In this work, a novel chemical looping process using gaseous metal oxide as oxygen carrier was proposed. The reaction of activated charcoal with gas-phase MoO3 was studied for the first time. The experiments were conducted isothermally at different temperatures in a fixed-bed reactor. The apparent activation energy of the reaction was calculated and suitable kinetic models were determined. The results and analysis showed that the proposed concept has potential in both coal chemical looping combustion and gasification process. To further investigate the mechanism of carbon oxidation by gas-phase MoO3, the adsorption of a gaseous (MoO3)3 cluster on a graphene ribbon and subsequent generation of COx was studied by density functional theory (DFT) method and compared with experimental results. The (MoO3)n -graphene complexes show interesting magnetic properties and potentials for nanodevices. A comprehensive analysis of plausible reaction mechanisms of CO and CO2 generation was conducted. Multiple routes to CO and CO2 formation were identified. The (MoO3)3 cluster shows negative catalytic effect for CO formation but does not increase the energy barrier for CO2 formation, indicating CO2 is the primary product. Mechanism of the homogenous MoO3 - CO reaction was studied and showed relatively low energy barriers. The DFT result accounts for key experimental observations of activation energy and product selectivity. The combined theoretical and experimental approach contributes to the understanding of the mechanism of reactions between carbon and metal oxide clusters. To gain a better understanding of the MoO2 oxidation process, the adsorption and dissociation of O2 on MoO2 surface were studied by DFT method. The results show that O2 molecules prefer to be adsorbed on the five-coordinated Mo top sites. Density of states analysis shows strong hybridization of Mo 4d orbitals and O 2p orbitals in the Mo-O bond. Clean MoO2 slab and slabs with O2 adsorption are metallic conductors, while the surface with high O atom coverage is reconstructed and becomes a semiconductor. Surface Mo atoms without adsorbed O or O2 are spin-polarized. The oxygen adsorption shows ability to reduce the spin of surface Mo atoms. The adsorption energy of O2 and O atoms decreases as coverage increases. The transition states of O2 dissociation were located. The energy barriers for O2 dissociation on five-coordinated and four-coordinated Mo top sites are 0.227 eV and 0.281 eV, respectively.
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Chemistry Of Molybdenum Xanthate [Mo02(Et2NCS2)] : Applications In Organic SynthesisMaddani, Mahagundappa R 11 1900 (has links)
The thesis entitled ‘Chemistry of molybdenum xanthate (MoO2[Et2NCS2]2): Applications in organic synthesis’ is presented in 4 chapters. Molybdenum (IV and VI) oxo-complexes are the subject of significant interest due to their functional and structural similarities with several molybdo-enzymes.1 Literature survey suggests that, molybdenum (VI as well as IV) xanthate2 1 resembles the active sites of various molybdo-enzymes. Therefore, in the present thesis, we are presenting our attempts directed towards exploiting molybdenum xanthate 1 in developing various useful methodologies.
Figure 1: Molybdenum xanthate
Chapter 1 discloses the utility of molybdenum xanthate (1) in catalytic, aerobic oxidation of organic azides and alcohols as presented in part A and B.
Part A: A mild molybdenum xanthate catalyzed, chemoselective oxidation of benzylic azides to the corresponding aldehydes3 under aerobic condition is described. This oxidation turned out to be a general method and a variety of benzylic azides were oxidized to the corresponding aldehydes. This oxidation protocol tolerates a variety of functional groups including alcohols, esters, ketones, halides and olefins. More importantly, the oxidation of azides stops at corresponding aldehyde stage without further oxidation to the corresponding carboxylic acids. A few examples are presented in scheme 1.
Part B: As our attempts to oxidize alcohols with molybdenum xanthate 1 were unsuccessful (Chapter 1, Part A), we have attempted supporting the reagent 1 and investigated its utility in the oxidation of alcohols. As a consequence, polyaniline supported molybdenum xanthate (MoO2[Et2NCS2]2) is designed and used in an aerobic and mild chemoselective oxidation of alcohols4 to the corresponding aldehydes and ketones. The scheme to use polyaniline as the support for molybdenum xanthate was derived from the fact that polyaniline is known to increase the redox activity of various metal complexes by coordinating to the metal centre.5 The present oxidation strategy tolerates a variety of functional groups such as olefin, ketones, sulfides, tertiary amines, propargyl group etc. This oxidation strategy also works very well for the oxidation of secondary benzylic alcohols. Interestingly, the supported catalyst can be filtered after the reaction and reused for further oxidation without loss of its activity. Some representative examples are presented in Scheme 2.
Chapter 2 describes the chemoselective and efficient reduction of azides to the corresponding amines. In this chapter, we have shown that a catalytic amount of molybdenum xanthate (1, MoO2[S2CNEt2]2) with PhSiH3 is an effective catalyst for the reduction of azides to the corresponding amines.6 This reduction of azides by 1, was inspired by the reductive silylation of aldehydes through the activation of silanes.7 This reduction tolerates a variety of reducible functional groups such as olefin, aldehydes, ketones, esters, amides and ethers, acetals etc. This strategy was also extended to various aliphatic azides to synthesize amine and their N-Boc derivatives in good yields. Scheme 3 illustrates few examples.
Chapter 3 discloses convenient methods for the synthesis of substituted thiourea derivatives as presented in part A and B.
Part A: A convenient method for the synthesis of tri-substituted thiourea derivatives by the reaction of primary amines with molybdenum dialkyl dithiocarbamates is presented in Part A.8 Primary amines on reaction with molybdenum xanthate produce corresponding thioureas in moderate to good yields. Similar reactions with propargylamine and 2-aminoethanol produce cyclic thiaoxazolidine and oxazolidine derivatives respectively. This methodology has been successfully adopted for the synthesis of amino acids derived chiral thioureas. Some examples are presented in Scheme 4.
Scheme 4: Molybdenum xanthate mediated synthesis of thioureas
Part B: An efficient method for the synthesis of symmetrical and unsymmetrical substituted thiourea9 derivatives by simple condensation of amine and carbon disulfide in aqueous medium is extensively studied. Present method describes the involvement of amino dithiol moiety as an intermediate. Though this method is not successful with secondary amines and aryl amines, it works smoothly with aliphatic primary amines to afford various di- and tri-substituted thiourea derivatives. The present method is also useful in synthesizing various substituted 2-mercapto imidazole heterocycles in moderate yields. A few examples are seen in Scheme 5.
Scheme 5: Synthesis of thiourea derivatives in aqueous medium
Chapter 4 describes a chemoselective deprotection10 of terminal acetonides (isopropylidines) by using aqueous TBHP (70%). A variety of acetonide derivatives on reaction with aq. TBHP in water:t-BuOH (1:1) as solvent mixtures furnish the corresponding acetonide deprotected diol products in good yields. This unprecedented deprotection strategy, tolerates a variety of acid sensitive functional groups such as silyl ether, trityl, olefin, propargyl, methoxymethyl ether, N-Boc, lactones, esters etc. A few examples are documented in Scheme 6.
Scheme 6: Chemoselective deprotection of acetonides
(For structural formula pl see the pdf file)
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Studies On Thermodynamics And Phase Equilibria Of Selected Oxide SystemsShekhar, Chander 18 July 2011 (has links) (PDF)
The availability of high quality thermodynamic data on solid solutions and compounds present in multicomponent systems assists in optimizing processing parameters for synthesis, and in evaluating stability domains and materials compatibility under different conditions. Several oxide systems of technological interest, for which thermodynamic data was either not available or is inconsistent were selected for study. Thermodynamic properties of phases present in the binary systems Nb-O and Ta-O were measured in the temperature range from 1000 to 1300 K using solid state electrochemical cells based on (Y2O3) ThO2 as the electrolyte. Based on these measurements and more recent data on heat capacity and phase transitions reported in the literature, Gibbs energy of formation for NbO, NbO2, NbO2.422, Nb2O5-x and Ta2O5 were reassessed. Significant improvements in the data for NbO2, Nb2O5 and Ta2O5 are suggested. The pseudo binary system MoO2-TiO2 was investigated because of the inconsistency between the phase diagram and thermodynamic properties of the solid solution reported in the literature. Based on new electrochemical measurements, a new improved phase diagram for the system MoO2-TiO2, incorporating recently discovered monoclinic to tetragonal phase transition in MoO2 at 1533 K, is presented. Isothermal section of the phase diagram for the ternary systems Cr-Rh-O and Ta-Rh-O and thermodynamic properties of ternary oxides CrRhO3 and TaRhO4 were measured for the first time in the temperature range from 900 to 1300 K. Phase relations for these systems have been computed as a function of oxygen potential at fixed temperature and as a function of temperature at selected oxygen partial pressures.
Metal-spinel-corundum three-phase equilibrium in the Ni-Al-Cr-O system at 1373 K has been explored because of its relevance to high temperature corrosion of super alloys. The Gibbs energy of mixing of spinel solid solution was derived from the tie-line data and is compared with the values calculated from cation distribution models. An oxygen potential diagram is developed for the decomposition of spinel solid solution to nickel and corundum solid solution at 1373 K under reducing conditions.
The high temperature thermodynamic properties of the phases present in quaternary systems Ca-Co-Al-O and Ca-Cu-Ti-O have been measured by solid state electrochemical cells based on stabilized zirconia. Gibbs energies of formation of the quaternary oxides Ca3CoAl4O10 in the temperature range from 1150 to1500 K and CaCu3Ti4O12 in the range from 900 to 1350 K are presented. Chemical potential diagrams have been computed for the system Al2O3-CaO-CoO at 1500 K. The oxygen potential corresponding to the decomposition of the complex perovskite CaCu3Ti4O12 (CCTO) has been calculated as a function of temperature from the emf of the cell. The effect of the oxygen partial pressure on the phase relations in the pseudo-ternary system CaO-(CuO/Cu2O)-TiO2 at 1273 K has been evaluated. The phase diagrams are useful for the control of the secondary phases that form during synthesis of CCTO, a material exhibiting colossal dielectric response.
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Studies On Nanostructured Transition Metal Oxides For Lithium-ion Batteries And SupercapacitorisRagupathy, P 08 1900 (has links)
Rechargeable Li-ion batteries and supercapacitors are the most promising electrochemical energy storage devices in terms of energy density and power density, respectively. Recently, nanostructured materials have gained enormous interest in the field of energy technology as they have special properties compared to the bulk. Commercially available Li-ion batteries, which are the most advanced among the rechargeable batteries, utilize microcrystalline transition metal oxides as cathode materials which act as lithium insertion hosts. To explore better electrochemical performance the use of nanomaterials instead of conventional materials would be an excellent alternative.
High Li-ion insertion at high discharge rates causes slow Li+ transport which in turn results in concentration polarization of lithium ions within the electrode material, causing a drop in cell voltage. This eventually, leads in termination of the discharge process before realizing the maximum capacity of the electrode material being used. This problem can be addressed by decreasing the average particle size which leads to an increase in surface area of the electrode material. Nanostructured materials, because of their high surface area and large surface to volume ratio, to some extent can overcome the problem of slow diffusion of ions.
Supercapacitors are electrical energy storage devices which can deliver large energy in a short time. A supercapacitor can be used as an auxiliary energy device along with a primary source such as a battery or a fuel cell to achieve power enhancement in short pulse applications. Active materials for supercapacitors are classified into three categories: (i) carbonaceous materials, (ii) conducting polymers and (iii) metal oxides. Among the materials studied over the years, metal oxides have been considered as attractive electrode materials for supercapacitors due to the following merits: variable oxidation state, good chemical and electrochemical stability, ease of preparation and handling. The performance of supercapacitors can be enhanced by moving from bulk to nanostructured materials.
The theme of the thesis is to explore novel routes to synthesize nanostructured materials for Li-ion batteries and supercapacitors, and to investigate their physical and electrochemical characteristics.
Chapter I is an introduction of various types of electrochemical energy systems such as battery, fuel cell and supercapacitor. A brief review is made on electrode materials for Li-ion batteries and supercapacitors, and nanostructured materials.
Chapter II deals with the study of nanostrip orthorhombic V2O5 synthesized by a two-step procedure, with the formation of a vanadyl ethylene glycolate precursor and post-calcination treatment. The precursor and the final product are characterized for phase and composition by powder X-ray diffraction (XRD), infrared (IR) spectroscopy, thermal analysis (TGA) and X-ray photoelectron spectroscopy (XPS). The morphological changes are investigated using field emission scanning electron microscopy (FE-SEM) and high resolution transmission electron microscopy (HRTEM). It is found that the individual strips have the following dimensions, length: 1.3 μm, width: 332 nm and thickness: 45 nm. The electrochemical lithium intercalation and de-intercalation of nanostrip V2O5 is investigated by cyclic voltammetry (CV), galvanostatic charge-discharge cycling, galvanostatic intermittent titration technique (GITT) and electrochemical impedance spectroscopy.
Chapter III describes the synthesis of nanoparticels of LiMn2O4 by microwave assisted hydrothermal method. The phase and purity of spinel LiMn2O4 are confirmed by powder XRD analysis. The morphological studies are carried out using FE-SEM and HRTEM. The electrochemical performance of spinel LiMn2O4 is studied by using CV and galvanostatic charge-discharge cycling. The initial discharge capacity is found to be about 89 mAh g-1 at a current density of 21 mA g-1 with reasonably good cyclability.
Chapter IV deals with synthesis of MoO2 nanoparticles through ethylene glycol medium and its electrochemical characterization. XRD data confirms the formation MoO2 on monoclinic phase, space group P21/c. Polygon shape of MoO2 is observed in HRTEM. MoO2 facilitates reversible insertion-extraction of Li+ ions between 0.25 to 3.0 V vs. Li/Li+. CV and galvanostatic charge-discharge cycling are conducted on this anode material to complement the electrochemical data.
Chapter V reports the synthesis of nanostructured MnO2 at ambient conditions by reduction of potassium permanganate with aniline. Physical characterization is carried out to identify the phase and morphology. The as prepared MnO2 is amorphous and it contains particles of 5 to 10 nm in diameter. On annealing at a temperature > 400 °C, the amorphous MnO2 attains crystalline α-phase with a concomitant change in morphology. A gradual conversion of nanoparticles to nanorods (length 500-750 nm and diameter 50-100 nm) is evident from SEM and TEM studies. High resolution TEM images suggest that nanoparticles and nanorods grow in different crystallographic planes. The electrochemical lithium intercalation and de-intercalation of nanorods was performed by (CV) and galvanostatic charge-discharge cycling. The initial discharge capacity of nanorod α-MnO2 is found to be about 197 mAh g-1 at a current density of 13.0 mA g-1. Capacitance behavior of amorphous MnO2 is studied by CV and galvanostatic charge-discharge cycling in a potential range from -0.2 to 1.0 V vs. SCE in 0.1 M sodium sulphate solution. The effect of annealing on specific capacitance is also investigated. Specific capacitance of about 250 F g-1 is obtained for as prepared MnO2 at a current density of 0.5 mA cm-2 (0.8 A g-1).
Chapter VI pertains to electrochemical supercapacitor studies on nanostructured MnO2 synthesized by polyol method. Although X-ray diffraction (XRD) pattern of the as synthesized nano-MnO2 shows poor crystallinity, it is found that it is locally arranged in δ-MnO2 type layered structure composed of edge-shared network of MnO6 octahedra by Mn K-edge X-ray Absorption Near Edge Structure (XANES) measurement. Annealed MnO2 shows high crystalline tunneled based α-MnO2 as confirmed by powder XRD pattern and XANES. As synthesized MnO2 exhibits good cyclability as an electrode material for supercapacitor.
In Chapter VII, capacitance behavior of nanostrip V2O5, TiO2 coated V2O5 and nanocomposites of PEDOT/V2O5 are presented. Structural and morphological studies are carried out by powder XRD, IR, TGA, SEM and TEM. Cyclic voltammogram of pristine V2O5 shows the regular rectangular shape indicating the ideal capacitance behavior in aqueous 0.1 M K2SO4. The SC value of pristine V2O5 is found to be about 100 F g-1. Nanostrip V2O5 is modified with TiO2 using titanium isobutoxide to enhance the capacitance retention upon cycling. Only 48 % of the initial capacitance remains in the case of pristine V2O5 after 100 cycles, while TiO2 coated V2O5 exhibits better cyclability with capacitance of 70 % of the initial capacitance. The capacitance retention is attributed to the presence of TiO2 on the surface of V2O5 which prevents the vanadium dissolution into the electrolyte. Microwave assisted hydrothermally synthesized PEDOT/V2O5 nanocomposites are utilized as capacitor materials. The initial SC of PEDOT/V2O5 (237 F g-1) is higher than that of either pristine V2O5 or PEDOT. The enhanced electrochemical performance is attributed to synergic effect and an enhanced bi-dimensionality.
Details of the above studies are described in the thesis with a conclusion at the end of each Chapter.
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