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Efeito da adi??o de feldspato e/ou res?duo de caulin em formula??es ? base de argila il?ticaCastro, Raimundo Jos? de Sousa 16 November 2010 (has links)
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Previous issue date: 2010-11-16 / The red pottery industry in Piau? state is well developed and stands out at the
national context for the technical quality of its products. The floor and wall tile
industry, however, is little developed since the state has only one company that
produces red clay-based ceramic tiles. This thesis aims at using the predominantly
illitic basic mass of the above mentioned industry, with the addition of feldspar and/or
kaolin residue in order to obtain products of higher technical quality. Kaolin residue
consists basically of kaolinite, muscovite mica and quartz; the feldspar used was
potassic. In this experiment, basic mass (MB) was used for experimental control and
fifteen formulations codified as follows: F2, F4, F8, F16, F32, FR2, FR4, FR8, FR16,
FR32, R2, R4, R8, R16 and R32. All raw materials were dry-milled, classified,
formulated and then humidified to 10% water. Thereafter, test samples were
produced by unixial pressing process in a rectangular steel matrix (60.0 x 20.0 x 5.0)
mm3 at (25 MPa). They were fired at four temperatures: 1080?C, 1120?C, 1160?C,
with a heating rate of 10?C/min during up to 10 min in an electric oven, and the last
one in an industrial oven with a peak of 1140?C, aim ing to confirm the results found
in laboratory and, finally, technological tests were performed: MEA, RL, AA, PA, TRF
and PF. The results revealed that the residue under study can be considered a raw
material with large potential in the industry of red clay-based ceramic tiles, since the
results found both in laboratory and in the industry have shown that the test samples
produced from the formulations with up to 4% feldspar and those produced with up to
8% feldspar and residue permitted a reduction in the water absorption rate and an
increase in the mechanical resistance while those samples produced with up to 4%
residue had an increase in the mechanical resistance when compared to those
produced from the basic mass and that the formulation with 2% feldspar and residue
presented the best technological properties, lowering the sintering temperature down
to 1120?C / A ind?stria de cer?mica vermelha do Piau? ? bem desenvolvida e se destaca no
contexto nacional pela qualidade t?cnica de seus produtos. J? a ind?stria de
revestimento pouco se desenvolveu, visto que o estado possui uma ?nica empresa
que produz revestimento de base argilosa vermelha. Esta tese tem por objetivo
utilizar a massa b?sica predominantemente il?tica da ind?stria citada, adicionando ?
mesma feldspato e/ou res?duo de caulim com o prop?sito de obter produtos de
melhores qualidades t?cnicas. O res?duo caulim ? constitu?do basicamente de
caulinita, mica moscovita e quartzo; o feldspato utilizado foi o pot?ssico. Para este
experimento, utilizou-se a massa b?sica (MB) para controle experimental e quinze
formula??es assim codificadas: F2, F4, F8, F16, F32, FR2, FR4, FR8, FR16, FR32,
R2, R4, R8, R16 e R32. Todas as mat?rias-primas foram mo?das a seco,
caracterizadas, formuladas, depois umidificadas a 10% com ?gua. Em seguida,
foram confeccionados corpos-de-prova por prensagem uniaxial em matriz retangular
de a?o (60,0 x 20,0 x 5,0) mm? a (24 MPa), os quais foram queimados em quatro
temperaturas: 1080?C, 1120?C, 1160?C, com taxa de aqu ecimento de 10?C/min e
patamar de 10 min em forno el?trico, e a ?ltima em forno a rolo industrial e pico de
1140?C com o objetivo de validar os resultados encontra dos em laborat?rio; por
?ltimo, foram realizados ensaios tecnol?gicos: MEA, RL, AA, PA, TRF e PF. Os
mesmos mostraram que o res?duo estudado pode ser considerado como mat?riaprima
de grande potencial para a ind?stria de pisos e revestimentos cer?micos de
base argilosa vermelha, j? que tanto os resultados encontrados em laborat?rio como
na ind?stria mostram que os corpos-de-prova produzidos a partir das formula??es
com feldspato at? 4% e os produzidos com feldspato e res?duo at? 8% permitiram
uma redu??o da absor??o de ?gua e aumento da resist?ncia mec?nica, sendo que
os corpos-de-prova produzidos com at? 4% de res?duo tiveram aumento da
resist?ncia mec?nica, quando comparados aos corpos-de-prova produzidos a partir
da massa b?sica e que a formula??o com 2% de feldspato e res?duo apresentou
melhores propriedades tecnol?gicas, reduzindo a temperatura de sinteriza??o para
1120?C
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