The intersection of decreasing resource size and increasing population and its associated demand creates a pressing need to develop products that act as alternatives to solid sawn lumber. Engineered composite lumber is one such alternative. The product described herein utilizes a modified form of sawn lumber as the raw material. The objective of this research was to manufacture, mechanically test, and evaluate a novel type of engineered lumber. Non destructive evaluation of raw materials and finished beams, and final mechanical testing to determine mean strength and stiffness values as per ASTM 5456 were used. The mechanical property data was converted into design values for fiber stress in bending (Fb) and stiffness (MOE). These design values was compared to those published by the U.S. (NDS) for wood construction. Pine logs were reduced into cants and further processed into matched symmetrical trapezoids. Symmetrical trapezoids were then non-destructively evaluated via E-computer and Director, and sorted by results. Next, the sorted trapezoids were matched into pairs and assembled into bowtie beams. Polyvinyl acetate adhesive was used throughout. Stiffness of the manufactured beams was nondestructively evaluated too. Then the beams were mechanically tested. The information from the E-computer was correlated to the strength and stiffness for each beam. The design strength and stiffness was compared to the values of sections of equivalent depth and maximum width as shown in the NDS. Also, non destructive test values were compared and correlated to those from the destructive tests. Finally, the design strength and stiffness values were respectively multiplied by the sectional area or the moment of inertia. This produced a strength efficiency factor and a stiffness efficiency factor. These factors were compared to factors derived from multiplying the design strength or design stiffness values (from the NDS) times the area or the moment of inertia of a rectangular section of equivalent depth and maximum width. It is found that the mechanically efficient bowtie section produced an increased strength and stiffness efficiency as compared to that of solid sawn material.

The sensitization of stainless steel describes the process by which a high-carbon steel alloy is heated above a certain threshold (either naturally or artificially) followed by a cooling period during which chromium (one of the elements most responsible for providing stainless steel with its corrosion-inhibiting properties) forms new compounds with the carbon present in the steel. With the chromium being taken from the parent material to form these compounds, the corrosion-resistant properties are compromised, which can lead to corrosion, cracking, and broader failure. Currently, the accepted techniques used to test for the presence of sensitization are qualitative and/or destructive in nature. Attempts have been made to non-destructively detect and characterize sensitization through various means, but all with mixed results. With the use of these high-carbon alloys in a range of industries, a comprehensive, in-place process is desirable. This thesis will focus specifically on non-destructive evaluation of sensitization seen as a result of welding steel plates using induction infrared thermography (IIRT). This process uses an induction coil to generate heat within a sample whose resulting heat signature can then be detected with an infrared (IR) camera and analyzed. Previous IIRT experimental results have shown higher levels of heating in the HAZ when sensitization is present as it modifies the original microstructure of the material. New IIRT experiments have been conducted on both welded and unwelded 440C alloy samples to establish quantitative data on the heating profiles. These results (in conjunction with the appropriate experimental parameters) were then used to create a numerical model to replicate them. Despite some limitations in populating the model with accurate parameters, the results obtained were in good agreement with the experiments and provide a foundation for future work. Future work will focus on establishing a predictive tool that can detect and quantify the level of sensitization in an arbitrary steel sample in the field. / Master of Science / The sensitization of stainless steel describes the process by which a high-carbon steel alloy is heated above a certain threshold (either naturally or artificially) followed by a cooling period during which chromium (one of the elements most responsible for providing stainless steel with its corrosion-inhibiting properties) forms new compounds with the carbon present in the steel. With the chromium being taken from the parent material to form these compounds, the corrosion-resistant properties are compromised, which can lead to corrosion, cracking, and broader failure. Currently, the accepted techniques used to test for the presence of sensitization are qualitative and/or destructive in nature. Attempts have been made to non-destructively detect and characterize sensitization through various means, but all with mixed results. With the use of these high-carbon alloys in a range of industries, a comprehensive, in-place process is desirable. This thesis will focus specifically on non-destructive evaluation of sensitization seen as a result of welding steel plates using induction infrared thermography (IIRT). This process uses an induction coil to generate heat within a sample whose resulting heat signature can then be detected with an infrared (IR) camera and analyzed. Previous IIRT experimental results have shown higher levels of heating in the HAZ when sensitization is present as it modifies the original microstructure of the material. New IIRT experiments have been conducted on both welded and unwelded 440C alloy samples to establish quantitative data on the heating profiles. These results (in conjunction with the appropriate experimental parameters) were then used to create a numerical model to replicate them. Despite some limitations in populating the model with accurate parameters, the results obtained were in good agreement with the experiments and provide a foundation for future work. Future work will focus on establishing a predictive tool that can detect and quantify the level of sensitization in an arbitrary steel sample in the field.

The association between constructive and destructive conflict and children’s (age three) externalizing behaviors was examined utilizing the Building Strong Families (BSF) data set. The study included 3,328 mothers and 3,148 fathers reporting on conflict behavior, and mother’s reports on children’s externalizing behaviors. My hypotheses indicated that the more constructive conflict, the less externalizing behaviors exhibited while the more destructive conflict, the more externalizing behaviors shown by the children. The majority of the literature demonstrated similar results to my hypotheses, however primarily focusing on mother’s conflict rather than the father’s conflict methods. Similarly, there was little focus on constructive conflict in the literature. Younger children (age three) were of interest for this study due to the lack of research involving these variables and this age group. The specific emotions theory was utilized to shape and inform my hypotheses. The results for this study supported my hypothesis concerning destructive conflict, but rejected the other discussing constructive conflict. Mothers’ correlations of conflict methods with externalizing behaviors were statistically significant while the fathers’ correlations were not. These analyses indicate further research of constructive conflict and its effects on younger children.

Birefringence has been used to study transparent materials since 1815, and is based on the decomposition of a polarized ray of light into two distinct rays when passing through an optically anisotropic material. This thesis uses this phenomenon in a study of phase retardation in crystalline materials. Single and multicrystalline silicon was chosen as the model material. Silicon is an interesting and important material in its own right, and the use of photoelasticity to determine stresses at linear and planar defects can have important consequences in the electrical performance of devices such as electronics and photovoltaic cells. This thesis presents the results of an experimental investigation of residual stresses in multicrystalline silicon wafers using near-infrared (NIR) transmission photoelasticity. NIR transmission through multicrystalline silicon is found to vary with crystallographic orientation and relate to planar atomic density, enabling the assignment of appropriate stress-optic coefficients to different grains. Noise in the data is reduced with the Ramji and Ramesh 10-step phase shifting algorithm when compared to the Patterson and Wang process. Normal stresses at points of zero maximum shear stress can be characterized based on isoclinic behavior around the point. Points at which all normal stresses are zero serve as boundary conditions for shear difference integration and allow for stress separation from a point that is not a free boundary. The second part of this work focuses on residual stresses in silicon wafers subjected to known physical damage such as indentations. Residual stress fields around Vickers indentations in silicon are found to be larger in size than predicted by contact mechanics. Placing Vickers indentations in close proximity creates a secondary stress field surrounding the entire indentation array, and a relationship is developed to explain this behavior. High residual stresses measured at grain boundaries are found to be consistent with models of atomic displacement. Placement of Vickers indentations near grain boundaries results in a change in stress state at the grain boundaries. The results of this study demonstrate the capacity of birefringence as a non-destructive evaluation tool and describe the effects of residual stress concentrations in silicon wafers.

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No description available.

The problem of this study was to develop a curriculum based on present destructive testing procedures used in industry dealing with the mechanical properties of ferrous and non-ferrous metals, and to organize the curriculum at the university level.

This work deals with the underlying physical mechanisms and processes that dominate the fracture of cement based materials and their electrical properties. Electric current emissions were recorded when hardened cement pastes and cement mortars suffered mechanical loading in various modes. Such electric current emissions are known as Pressure Stimulated Currents (PSC) when the applied loading is compressional while they are mentioned as Bending Stimulated Currents (BSC) when the material suffers bending loadings. The physical mechanism responsible for the PSC and BSC emissions can be interpreted in terms of the Moving Charged Dislocations model that correlates mechanical deformation and electric charge distortions in the sample bulk. Laboratory experiments were designed based on the mechanical and physical properties of cement. To conduct the experiments all the background material concerning cement fracture mechanics, the microstructure of the hardened cement paste and the Interfacial Transition Zone of cement mortar were taken into consideration. Additionally, the experience of the PSC technique when it was applied on marble samples was used to guide the experimental procedures and compare qualitatively and quantitatively the experimental results. The relationship between the emitted PSC and the strain was established for the very first time for cement based materials in the present work. When the material was stressed within the range where stress and strain are linearly related a linear relation between PSC and stress rate (d/dt) was observed. Deviation from this linearity appeared when the applied stress was in the range where the applied stress and the yielded strain were not linearly related. Slightly before fracture, intense, non-linear PSC emissions were detected. The damage of the sample structure due to excessive loading in the plastic region significantly affected the recorded phenomena. Bending tests proved that similar electric current emissions are detected when a sample beam suffers 3 Point Bending Tests. The dependence of the emitted electric current on the way of fracture (i.e. compressional or tensional) was proved. It was also shown that the magnitude of the emitted electric current is directly related to the magnitude of damage due to the external loading. Thus, as it was expected, the electric current emitted from the tensed zone is significantly greater than the corresponding emitted from the compressed zone.

There is an increasing need of automation for routine tasks like sorting agricultural produce in large scale post-harvest processing. Among different kinds of sensors used for such automation tasks, near-infrared (NIR) technology provides a rapid and effective solution for quantitative analysis of quality indices in food products. As industries and farms are adopting modern data-driven technologies, there is a need for evaluation of the modelling tools to find the optimal solutions for problem solving. This study aims to understand the process of evaluation of the modelling tools, in view of near-infrared data obtained from green leafy vegetables. The first part of this study deals with prediction of the type of leafy green vegetable from the near-infrared reflectance spectra non-destructively taken from the leaf surface. Supervised classification methods used for the classification task were k-nearest neighbors (KNN), support vector machines (SVM), linear discriminant analysis (LDA) classifier, regularized discriminant analysis (RDA) classifier, naïve Bayes classifier, bagged trees, random forests, and ensemble discriminant subspace classifier. The second part of this study deals with prediction of total glucosinolate and total polyphenol contents in leaves using Partial Least Squares Regression (PLSR) and Principal Component Regression (PCR). Optimal combination of predictors were chosen by using recursive feature elimination. NIR spectra taken from 283 different samples were used for classification task. Accuracy rates of tuned classifiers were compared for a standard test set. The ensemble discriminant subspace classifier was found to yield the highest accuracy rates (89.41%) for the standard test set. Classifiers were also compared in terms of accuracy rates and F1 scores. Learning rates of classifiers were compared with cross-validation accuracy rates for different proportions of dataset. Ensemble subspace discriminants, SVM, LDA and KNN were found to be similar in their cross-validation accuracy rates for different proportions of data. NIR spectra as well as reference values for total polyphenol content and total glucosinolate contents were taken from 40 samples for each analyses. PLSR model for total glucosinolate prediction built with spectra treated with Savitzky-Golay second derivative yielded a RMSECV of 0.67 μmol/g of fresh weight and cross-validation R2 value of 0.63. Similarly, PLSR model built with spectra treated with Savitzky-Golay first derivative yielded a RMSECV of 6.56 Gallic Acid Equivalent (GAE) mg/100g of fresh weight and cross-validation R-squared value of 0.74. Feature selection for total polyphenol prediction suggested that the region of NIR between 1300 - 1600 nm might contain important information about total polyphenol content in the green leaves.

With increasing miniaturization in industry and medical technology, non-destructive testing techniques are an area of everincreasing importance. In this framework, X-ray microscopy offers an efficient tool for the analysis, understanding and quality assurance of microscopic species, in particular as it allows reconstructing three-dimensional data sets of the whole sample’s volumevia computed tomography (CT). The following thesis describes the conceptualization, design, construction and characterization of a compact laboratory-based X-ray microscope in the hard X-ray regime around 9 keV, corresponding to a wavelength of 0.134 nm. Hereby, the main focus is on the optimization of resolution and contrast at relatively short exposure times. For this, a novel liquid-metal-jet anode source is the basis. Such only recently commercially available X-ray source reaches a higher brightness than other conventional laboratory sources, i.e. the number of emitted photons (X-ray quanta) per area and solid angle is exceptionally high. This is important in order to reach low exposure times. The reason for such high brightness is the usage of the rapidly renewing anode out of liquid metal which enables an effective dissipation of heat, normally limiting the creation of high intensities on a small area. In order to cover a broad range of different samples, the microscope can be operated in two modes. In the “micro-CT mode”, small pixels are realized with a crystal-scintillator and an optical microscope via shadow projection geometry. Therefore, the resolution is limited by the emitted wavelength of the scintillator, as well as the blurring of the screen. However, samples in the millimeter range can be scanned routinely with low exposure times. Additionally, this mode is optimized with respect to in-line phase contrast, where edges of an object are enhanced and thus better visible. In the second “nano-CT mode”, a higher resolution can be reached via X-ray lenses. However, their production process is due to the physical properties of the hard X-ray range - namely high absorption and low diffraction - extremely difficult, leading typically to low performances. In combination with a low brightness, this leads to long exposure times and high requirements in terms of stability, which is one of the key problems of laboratory-based X-ray microscopy. With the here-developed setup and the high brightness of its source, structures down to 150 nm are resolved at moderate exposure times (several minutes per image) and nano-CTs can be obtained. / Mit zunehmender Miniaturisierung in Industrie und Medizintechnik werden zerstörungsfreie Prüfverfahren immer wichtiger. In diesem Umfeld bietet Röntgenmikroskopie ein effizientes Instrument zu Analyse, Verständnis und Qualitätssicherung mikroskopischer Proben, insbesondere da sie im Rahmen der Computer-Tomografie (CT) die Aufnahme dreidimensionaler Datensätze des gesamten Probenvolumens ermöglicht. Die vorliegende Arbeit befasst sich mit Konzeption, Design, Aufbau und Charakterisierung eines kompakten Labor-Röntgenmikroskops im harten Röntgenbereich bei 9 keV, bzw. einer Wellenlänge von 0.134 nm. Im Fokus liegt dabei die Optimierung von Auflösung und Kontrast bei möglichst kurzen Belichtungszeiten. Hier für bildet die Basis eine neuartige Flüssig-Metall- Anoden Röntgenquelle. Solche erst seit kurzem kommerziell verfügbare Quellen erreichen eine höhere Brillianz als konventionelle Laborquellen, d.h. dass die Anzahl der emittierten Photonen (Röntgenquanten) pro Fläche und Raumwinkel außergewöhnlich hoch ist. Dies ist ein entscheidender Faktor, um nötige Belichtungszeiten zu verringern. Der Grund für die hohe Brillianz ist die Verwendung einer sich sehr schnell erneuernden Anode aus flüssigem Metall. Diese ermöglicht die effektive Abfuhr von Wärme, welche normalerweise die Erzeugung von höheren Intensitäten auf kleinerer Fläche limitiert. Um ein möglichst großes Spektrum an Proben abzubilden, kann das Mikroskop in zwei Modi betrieben werden. Im ”Mikro-CT Modus“ werden kleine Pixel mit Hilfe eines Kristall-Leuchtschirms und einem Lichtmikroskop über das Schattenwurfprinzip erreicht, weswegen dessen Auflösung durch die Wellenlänge des emittierten Lichts und die Unschärfe des Schirms beschränkt ist. Dafür können Proben im Millimeterbereich bei geringen Belichtungszeiten standardmäßig aufgenommen werden. Zudem wurde dieser Modus auf inline Phasen-Kontrast optimiert, bei welchem die Kanten eines Objekts durch Interferenz überhöht dargestellt werden und somit besser sichtbar sind. Im zweiten ”Nano-CT Modus“ kann eine erhöhte Auflösung mit Hilfe von Röntgenlinsen erreicht werden. Deren Herstellung ist aber aufgrund der physikalische Eigenschaften im harten Röntgenbereichs - nämlich starke Absorption und schwache Brechung - technisch extrem schwierig und meist mit einer sehr geringe optischen “Leistung” verbunden. Dies führt in Kombination mit einer geringen Brillianz zu sehr langen Belichtungszeiten und hohen Anforderungen an die Stabilität, was ein Kernproblem der auf Laborquellen basierenden Röntgenmikroskope darstellt. Mit der hier entwickelten Anlage können durch die hohe Brillianz der verwendeten Quelle bei moderaten Belichtungszeiten (wenige Minuten pro Bild) Strukturen der Größe 150 nm voneinander getrennt, sowie Nano-CTs aufgenommen werden.