Ultrasonic wave field is modeled inside non-planar and inhomogeneous structures using a newly developed mesh-free semi-analytical technique called Distributed Point Source Method (DPSM). Wave field inside a corrugated plate which is a non-planar structure is modeled using DPSM when the structure is excited by a bounded acoustic beam generated by a finite-size transducer. The ultrasonic field is computed both inside the plate and in the surrounding fluid medium. It is observed that the reflected beam strength is weaker for the corrugated plate in comparison to that of the flat plate, as expected. Whereas the backward scattering is found to be stronger for the corrugated plate. DPSM generated results in the surrounding fluid medium are compared with the experimental results.Ultrasonic wave field is also modeled inside inhomogeneous structures. Two types of inhomogeneity are considered - a circular hole and a damaged layered half-space. Elastic wave scattering inside a half-space containing a circular hole is first modeled using DPSM when the structure is excited with a bounded acoustic beam. Then the ultrasonic wave field is computed in presence and absence of a defect in a layered half-space. For the layered problem geometry it is shown how the layer material influences the amount of energy that propagates through the layer and that penetrates into the solid half-space when the solid structure is struck by a bounded acoustic beam. It is also shown how the presence of a crack and the material properties of the layer material affect the ultrasonic fields inside the solid and fluid media.After solving the above problems in the frequency domain the DPSM technique is extended to produce the time domain results by the Fast Fourier Transform technique. Time histories are obtained for a bounded beam striking an elastic half-space. Numerical results are generated for normal and inclined incidences, for defect-free and cracked half-spaces. A number of useful information that is hidden in the steady state response can be obtained from the transient results.

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A series of new planar complexes with the dianion of 2,3-quinoxalinedithiol ligand has been prepared. The complexes have been characterized from the study of their analyses, magnetic moment, conductance, polarograms, electron spin resonance spectra, and electronic spectra, and compared with the available data on the corresponding maleonitriledithiolene and toluene-3,4-dithiolene complexes.

The synthesis and insecticidal activity of certain alcohols (hydroxymethyldibenzofurans, hydroxymethyldibenzothiophenes and some of their ⍺-cyano derivatives), esterified with trans-chrysanthemic acid, were investigated. The preparation of these planar alcohol moieties was undertaken to study conformation-activity effects in insecticides of the pyrethroid type. The synthesis of final ester products employed two methods. One was the direct condensation of the appropriate alcohol with chrysanthemic acid chloride in the presence of pyridine. The other involved the in situ formation of the cyanohydrin from the appropriate aldehyde and subsequent condensation with chrysanthemic acid chloride in the presence of a phase transfer reagent. Insecticidal activity is to be tested at rates of 0.001, 0.01, 0.1, 10, 100, and 1000 ppm. Fenvalerate is used as the standard against Diabrotica undecimpuntata (spotted cucumber beetles).

Thesis advisor: Michael J. Naughton / Geometrically generalized analytical expressions for device transport are derived from first principles for a photovoltaic junction. Subsequently, conventional planar and unconventional coaxial and hemispherical photovoltaic architectures are applied to detail the device physics of the junction based on their respective geometry. For the conventional planar cell, the one-dimensional transport equations governing carrier dynamics are recovered. For the unconventional coaxial and hemispherical junction designs, new multi-dimensional transport equations are revealed. Physical effects such as carrier generation and recombination are compared for each cell architecture, providing insight as to how non-planar junctions may potentially enable greater energy conversion efficiencies. Numerical simulations are performed for arrays of vertically aligned, nanostructured coaxial and hemispherical amorphous silicon solar cells and results are compared to those from simulations performed for the standard planar junction. Results indicate that fundamental physical changes in the spatial dependence of the energy band profile across the intrinsic region of an amorphous silicon p-i-n junction manifest as an increase in recombination current for non-planar photovoltaic architectures. Despite an increase in recombination current, however, the coaxial architecture still appears to be able to surpass the efficiency predicted for the planar geometry, due to the geometry of the junction leading to a decoupling of optics and electronics. / Thesis (PhD) — Boston College, 2012. / Submitted to: Boston College. Graduate School of Arts and Sciences. / Discipline: Physics.

Made available in DSpace on 2014-06-12T17:39:52Z (GMT). No. of bitstreams: 2 arquivo6973_1.pdf: 6103079 bytes, checksum: 7535f9a6f839bc8c1f2bd30a09d8d241 (MD5) license.txt: 1748 bytes, checksum: 8a4605be74aa9ea9d79846c1fba20a33 (MD5) Previous issue date: 2006 / Foram desenvolvidas etapas de processo para fabricação de estruturas resistivas planares e circuitos de condicionamento com conversores e microcontroladores para a construção de sensores inteligentes de temperatura. O objetivo é integrar esse sensor a um sistema capaz de medir pressão para utilizar essas medidas na estimativa da vazão em ambientes agressivos, como em poços de petróleo. Para a medição da temperatura foi escolhida a tecnologia RTD planar, por poder ser fabricada utilizando técnicas de microeletrônica, o que permite projetar sua integração com outras partes do circuito em um mesmo chip ou como circuito híbrido em substrato cerâmico, além de ser de fabricação mais simples e precisa, permitindo fabricação em larga escala, reduzindo custos. O processo de fabricação foi realizado utilizando sistema de litografia óptica e evaporadora disponíveis na sala limpa do Laboratório de Dispositivos e Nanoestruturas. Para esse protótipo foi escolhido o níquel como material transdutor. Para melhorar as características do dispositivo, assim como diminuir a variância, aplicou-se técnicas de otimização estatística de processos. O RTD fabricado foi caracterizado quanto às dimensões, utilizando microscopia óptica e eletrônica e a resistividade foi caracterizada pela técnica das quatro pontas de prova, utilizando um impedancímetro. A avaliação do desempenho do RTD fabricado com relação à variação de temperatura foi realizada através de uma estação de testes com temperatura variável construída, auxiliada por impedancímetro e termopar calibrado. Nessa caracterização observou-se uma variação bastante linear do valor da resistência com a temperatura, próximo de valores obtidos com RTD comerciais, utilizados para comparação. Implementou-se uma configuração de sensor inteligente utilizando-se conversor analógico-digital e o microcontrolador PIC-16F88

Das Signal-zu-Rausch-Verhältnis (SNR) stellt bei modernen Bildgebungstechniken in der Magnetresonanz-Tomographie heutzutage oftmals die entscheidende Limitation dar. Eine Verbesserung durch Modifikation der Hardware ist kostspielig und führt meistens zu einer Verstärkung anderer Probleme, wie zum Beispiel erhöhte Energiedeposition ins Gewebe. Im Gegensatz dazu ist Dichtegewichtung eine Methode, die eine SNR-Erhöhung durch Modifikation der Aufnahmetechnik ermöglicht. In der MR-Bildgebung erfolgt oftmals eine retrospektive Filterung des aufgenommenen Signalverlaufs, beispielsweise zur Artefaktreduktion. Damit einhergehend findet eine Veränderung der Modulationstransferfunktion (MTF) bzw. ihrer Fouriertransformierten, der räumlichen Antwortfunktion (SRF), statt. Optimales SNR wird nach dem Matched Filter-Theorem erzielt, wenn die nachträgliche Filterung dem aufgenommenen Signalverlauf proportional ist. Dies steht dem Ziel der Artefaktreduktion entgegen. Bei Dichtegewichtung steht durch nicht-kartesische Abtastung des k-Raums mit der k-Raum-Dichte ein zusätzlicher Freiheitsgrad zur Verfügung. Dieser ermöglicht es, im Falle eines konstanten Signalverlaufs eine gewünschte MTF ohne Filterung zu erreichen. Bei veränderlichem Signalverlauf kann ein SNR Matched Filter angewendet werden, dessen negative Einflüsse auf die MTF durch Dichtegewichtung kompensiert werden. Somit ermöglicht Dichtegewichtung eine vorgegebene MTF und gleichzeitig ein optimales SNR. In der vorliegenden Arbeit wurde Dichtegewichtung erstmals bei den schnellen Multi-Echo-Sequenzen Turbo-Spin-Echo und Echoplanar-Bildgebung (EPI) angewendet. Im Gegensatz zu bisherigen Implementierungen muss hier der Signalabfall durch T2- bzw. T2*-Relaxation berücksichtigt werden. Dies führt dazu, dass eine prospektiv berechnete dichtegewichtete Verteilung nur bei einer Relaxationszeit optimal ist. Bei Geweben mit abweichenden Relaxationszeiten können sich wie auch bei den kartesischen Varianten dieser Sequenzen Änderungen an SRF und SNR ergeben. Bei dichtegewichteter Turbo-Spin-Echo-Bildgebung des Gehirns konnte mit den gewählten Sequenzparametern ein SNR-Vorteil von 43 % gegenüber der kartesischen Variante erzielt werden. Die Akquisition wurde dabei auf die T2-Relaxationszeit von weißer Substanz optimiert. Da die meisten Gewebe im Gehirn eine ähnliche Relaxationszeit aufweisen, blieb der visuelle Gesamteindruck identisch zur kartesischen Bildgebung. Der SNR-Gewinn konnte in der dichtegewichteten Implementierung zur Messzeithalbierung genutzt werden. Dichtegewichtete EPI weist eine hohe Anfälligkeit für geometrische Verzerrungen, welche durch Inhomogenitäten des Hauptmagnetfeldes verursacht werden, auf. Die Verzerrungen konnten erfolgreich mit einer Conjugate Phase-Methode korrigiert werden. Dazu muss die räumliche Verteilung der Feldinhomogenitäten bekannt sein. Dazu ist zusätzlich zur eigentlichen EPI-Aufnahme die zeitaufwendige Aufnahme einer sogenannten Fieldmap erforderlich. Im Rahmen dieser Arbeit konnte eine Methode entwickelt werden, welche die zur Erlangung einer Fieldmap notwendige Aufnahmedauer auf wenige Sekunden reduziert. Bei dieser Art der Fieldmap-Aufnahme müssen jedoch durch Atmung hervorgerufene Effekte auf die Bildphase berücksichtigt werden. Die Fieldmap-Genauigkeit kann durch Aufnahme unter Atempause, Mittelung oder retrospektiver Phasenkorrektur erhöht werden. Für die gewählten EPI-Sequenzparameter wurde mit Dichtegewichtung gegenüber der kartesischen Variante ein SNR-Gewinn von 14 % erzielt. Anhand einer funktionellen MRT (fMRI)-Fingertapping-Studie konnte demonstriert werden, dass die SNR-Steigerung auch zu einer signifikant erhöhten Aktivierungsdetektion in Teilen der Hirnareale führt, die bei der Fingerbewegung involviert sind. Die Verwendung von zusätzlicher EPI-Phasenkorrektur und iterativer Optimierung der dichtegewichteten k-Raum-Abtastung führt zu weiteren Verbesserungen der dichtegewichteten Bildgebung mit Multi-Echo-Sequenzen. / Magnetic resonance imaging (MRI) is often limited by the signal to noise ratio (SNR). In standard Cartesian acquisition methods, the SNR can be improved by applying a so-called matched filter to the acquired raw data, which correlates with the anticipated signal profile. Unfortunately, this filter changes the spatial response function (SRF), which characterizes the imaging properties of the imaging method, in an undesired way. For example, a matched filter often amplifies undesired image artifacts and is thus normally omitted. In contrast, filters which change the SRF are typically applied, e.g., for artifact reduction. These however do not provide an optimal SNR. Density weighting is a method which allows a desired SRF and an optimal SNR at the same time. This is achieved by introducing a new degree of freedom to the SRF; the density of the acquisition steps in k-space. In this work, density weighting was adapted to turbo spin echo (TSE) and echo planar imaging (EPI). In contrast to earlier implementations of density weighting, signal relaxation has to be taken into consideration with these multi-echo sequences. As a result, the desired SRF and SNR are only obtained for one prospectively determined relaxation time. For deviating relaxation times, changes in SRF and SNR may occur. In density weighted TSE brain imaging, an average SNR gain of 43 % over Cartesian imaging could be achieved for the chosen sequence parameters. The density weighted acquisition was optimized for the T2 relaxation time of white matter. Since the relaxation times of most other tissues in the brain did not significantly differ, the overall visual impression of density weighted and Cartesian images was identical. The achieved SNR gain could be used to halve the acquisition time of the density weighted implementation. Density weighted EPI is especially prone to geometric distortions caused by inhomogeneities of the main magnetic field. The distortions could be successfully corrected with a conjugate phase method. For these methods, a time-consuming acquisition of a so-called field map is typically required. A method could be developed which greatly reduces the field map acquisition time to a few seconds. It was found that phase changes caused by respiration influence the field map accuracy of this and similar methods. A significantly higher accuracy could be achieved by an acquisition under breath-hold or by retrospective phase correction or averaging. It was demonstrated in an fMRI group study that an average SNR gain of 14 % for density weighted EPI resulted in an increased detection power in the activated brain areas. First results involving additional EPI phase correction and iterative k-space sampling optimization demonstrate further improvements of density weighted imaging with multi-echo sequences.

在張宜武教授的博士論文中研究到視線表示法和視線數。我們以類似的方法定義有向圖的表示法和有向圖的視線數。 首先，我們定義有向圖的視線數為b(Ｄ) ，Ｄ為有方向性的圖，在論文中可得b(Ｄ)≦┌1/2max｛△﹢(Ｄ),△﹣(Ｄ)｝┐。另一個重要的結論為考慮一個平面有向圖Ｄ，對圖形Ｄ上所有的點v，離開點v的邊（進入的邊）是緊鄰在一起時，則可得有向圖的視線數在這圖形上是１（即 b(Ｄ)=1）。 另外對特殊的圖形也有其不同的視線數，即對有向完全偶圖Ｄm,n ，b(Ｄm,n)≦┌1/2min｛m,n｝┐ ，而對競賽圖Ｄn ，可得b(Ｄn)≦┌n/3┐+1。 / In [2], Chang stuidied the bar visibility representations and defined bar visibility number.We defined analogously the bar visibility representation and the bar visibility number of a directed graph Ｄ. First we show that the bar visibility number, denoted by b(Ｄ),is at most ┌1/2max｛△﹢(Ｄ),△﹣(Ｄ)｝┐ if D is an oriented graph.And we show that b(Ｄ)=1 for the oriented planar graphs in which all outgoing (incoming) edges of any vertex v of Ｄ appear consecutively around v.For any complete bipartite digraph Ｄm,n ，b(Ｄm,n)≦┌1/2min｛m,n｝┐.For any tournament Ｄn,b(Ｄn)≦┌n/3┐+1.