Cette thèse est consacrée au calcul de sections efficaces de réactions impliquant le système à trois corps (e − , e + , p̄) à des énergies représentatives de l’expérience GBAR. Deux approches théoriques ont été utilisées. La première, appelée méthode des canaux couplés, permet de traiter le système dans un cadre théorique plus simple. La deuxième, basée sur le formalisme rigoureux des équations de Faddeev-Merkuriev, a permis le calcul explicite des sections efficaces. Une des difficultés majeures provient de la dégénérescence accidentelle du premier état excité des atomes d’antihydrogène et de positronium. Le traitement de cette dégénérescence a été réalisé dans un premier temps dans le formalisme de canaux couplés avant d’être adapté au code des équations de Faddeev-Merkuriev. Dans ce document, nous discutons les sections efficaces dans le contexte de l’expérience GBAR et interprétons les phénomènes résonnants mis en évidence, les résonances de Feshbach et les oscillations de Gailitis-Damburg. / This thesis is dedicated to cross section calculations involving the three body system (e − , e + , p̄) at representative energies for the GBAR experiment. Two different theoretical formalisms have been used. The first one, the close coupling method, allows to study the system in a more simple and schematic theoretical frame. The second, based on the mathematically rigorous formalism of the Faddeev-Merkuriev equations, is used to compute the explicit cross sections. One of the major difficulties comes from the accidental degeneracy of the antihydrogen and positronium atoms first excited states. The treatment of this degeneracy has been realised, in a first time, with the close-coupling formalism before being adapted to the Faddeev-Merquriev equations code. In this document, we discuss the cross sections in the GBAR experiment frame and we construe the highlighted resonant phenomena, the Feshbach resonances and the Gailitis-Damburg oscillations.

Submitted by Maike Costa (maiksebas@gmail.com) on 2016-03-15T12:16:24Z No. of bitstreams: 1 arquivototal.pdf: 5169144 bytes, checksum: 66d534e3f0c0c59bf5d35a45290fa390 (MD5) / Made available in DSpace on 2016-03-15T12:16:24Z (GMT). No. of bitstreams: 1 arquivototal.pdf: 5169144 bytes, checksum: 66d534e3f0c0c59bf5d35a45290fa390 (MD5) Previous issue date: 2015-02-27 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPES / In this thesis, we propose an experimental setup for the study of Landau quantization and associated effects in a two-dimensional ultracold atomic gas. Gauge fields can emerge in the equation of motion for the optically addressed ultracold atoms. To this end, spatially dependent dark states are necessary for the internal states of the atoms. A tripod level scheme yields two degenerate dark states which can leads to either an Abelian U(1) U(1) gauge field or a non-Abelian SU(2) gauge field. Using a suitable laser configuration, we obtain a uniform U(1) U(1) magnetic field which causes the atoms organize themselves in Landau levels. The strength of the effective magnetic field depends on the relative intensity of the lasers beams at the atomic cloud. We estimate the degeneracy of the energy levels for an atomic gas formed by atoms of 87Rb. In addition, we establish the experimental conditions to reach the lowest Landau level regime. In the zero-temperature limit, we realize the emergence of magnetic oscillations in the atomic energy and its derivative as function of the inverse of the effective magnetic field (de Haas van Alphen effect). The period of the de Haas van Alphen oscillation allow us to determine area of the Fermi circle for the atomic gas via an Onsager-like relation. We also show that detuning the a laser from the two-photon resonance we generate a parabolic scalar potential that laterally confines the atoms. As a consequence, the Landau levels degeneracy is removed, since the energy spectrum depends explicitly on the transverse atomic momentum. We show that the Landau levels presents a reminiscent degeneracy when the boundaries conditions are considered. The residual degeneracy occurs when different energy levels overlap. We map the residual degeneracy points as a function of the effective magnetic field. Finally, we present an experimental scheme for observing the spin Hall effect for ultracold atoms in a tripod configuration. / Nesta tese, propomos um arranjo experimental para o estudo da quantização de Landau e efeitos associados em um gás atômico ultrafrio bidimensional. Campos de calibre podem surgir na equação de movimento para átomos ultrafrios oticamente vestidos. Para que isto ocorra, estados escuros espacialmente dependentes são necessários a partir dos estados internos dos átomos. Átomos numa configuração de níveis de energia do tipo tripod produzem dois estados escuros degenerados, que podem levar a campos de calibre Abelianos U(1) U(1) ou não-Abelianos SU(2). Utilizando uma configuração adequada de lasers, mostramos que é possível se produzir um campo magnético sintético uniforme U(1) U(1) que atua nos átomos neutros fazendo-os se organizarem em níveis de Landau. A intensidade do campo efetivo depende da intensidade relativa dos feixes de luz na nuvem atômica. Estimamos a degenerescência dos níveis de energia para um gás atômico formado por átomos de 87Rb e estabelecemos as condições experimentais para que seja atingido o regime em que todos os átomos populam unicamente o nível de Landau menos energético. Considerando o limite de temperatura nula, verificamos o surgimento de oscilações magnéticas na energia e em sua derivada como uma função do inverso do campo magnético efetivo (efeito de Haas van Alphen). O período da oscilação magnética nos permite determinar a área do círculo de Fermi para o gás atômico através de uma expressão similar a de Onsager para sistemas eletrônicos. Mostramos também que dessintonizando um dos lasers em relação à ressonância de dois fótons geramos um potencial escalar parabólico que faz com os átomos sejam lateralmente confinados. Isto resulta na remoção da degenerescência dos níveis de Landau, uma vez que a energia depende explicitamente do momento atômico transverso. Demonstramos que, aplicando condições periódicas de contorno ao sistema, temos o surgimento de uma degenerescência residual. A degenerescência remanescente ocorre quando diferentes níveis de energia se superpõem. Mapeamos os pontos de degenerescência como uma função do campo magnético efetivo. Por fim, apresentamos um esquema experimental para a observação do efeito spin Hall para átomos ultrafrios em uma configuração tripod.

Dans cette thèse, nous discutons de la dégénérescence et de la construction d’états cohérents généralisés dans les systèmes quantiques en deux dimensions d’espace. Nous développons un schéma pour obtenir des spectres non dégénérés et des combinaisons linéaires appropriées des états propres d’énergie correspondants. Lorsque la dégénérescence dans le spectre d’énergie est linéaire dans les nombres quantiques, nous définissons des opérateurs d’échelle général- isés qui conduisent à une chaîne d’états avec un ensemble naturel de coefficients. De plus, nous récupérons des relations de complétude pour les états généralisés. Lorsque le spectre d’énergie est quadratique dans les nombres quantiques, nous utilisons certains résultats de la théorie des nombres pour catégoriser la dégénérescence et, par conséquent, les combinaisons linéaires appropriées des états propres d’énergie associés. En particulier, nous étudions des oscillateurs harmoniques bidimensionnels isotropes et anisotropes ainsi que le potentiel Morse bidimensionnel et son partenaire supersymétrique non séparable. Dans tous les cas, nous construisons des états cohérents et discutons certains aspects de leur caractère non classique. On retrouve une certaine compression dans les quadratures conjuguées, une dépendance non triviale des variances des quadratures vis-à-vis des paramètres introduits lors de la définition des spectres non dégénérés, et un problème de localisation pour les fonctions d’onde. Comme application, nous étudions le problème de la quantification et de l’analyse semi-classique de l’espace des phases en deux dimensions en exploitant la complétude des familles généralisées d’états cohérents comprimés en deux dimensions. / In this thesis we discuss degeneracy and the construction of generalised coherent states in two-dimensional quantum systems. We develop a scheme for defining non-degenerate spectra and the corresponding averaged energy eigenstates. When the degeneracy in the spectrum is linear in the quantum numbers, we are able to define generalised ladder operators which lead to a chain of states with a natural set of coefficients. Additionally, we are able to recover completeness relations for the generalised states. On the other hand, when the spectrum is quadratic in the quantum numbers, we utilise some results from number theory to categorise the degeneracy and correspondingly the averaged energy eigenstates. In particular we study the two-dimensional isotropic and anisotropic oscillators as well the two-dimensional Morse potential and its non-separable supersymmetric partner. In all cases, we compute the coherent states and discuss certain aspects of their non-classicality. We find squeezing between conjugate quadratures, non-trivial dependence of the quadrature variances on the parameters introduced when defining the non-degenerate spectra, and non-localisation of wavefunctions. As an application, we study the problem of quantisation and semiclassical phase space analysis in two dimensions by exploiting the completeness of generalised families of two-dimensional squeezed coherent states.

To support the growing global demand for energy, new sustainable solutions are needed both economically and environmentally. Thermoelectric waste heat recovery and energy harvesting could contribute by increasing industrial process efficiency, as well as powering stand-alone devices, microgenerators, and small body appliances.The structural complexity of quaternary chalcogenide materials provides an opportunity for engineering defects and disorder, to modify and possibly improve specific properties. Cu2ZnSnS4 (CZTS, often kesterite), valued for the abundance and non-toxicity of the raw materials, seems particularly suited to explore these possibilities, as it presents several structural defects and polymorphic phase transformations. The aim of this doctoral work is to systematically investigate the effects of structural polymorphism, disorder, and defects on the thermoelectric properties of CZTS, with particular emphasis to their physical origin. A remarkable case is the order-disorder transition of tetragonal CZTS, which is found responsible for a sharp enhancement in the Seebeck coefficient due to a flattening and degeneracy of the electronic energy bands. This effect, involving a randomization of Cu and Zn cations in certain crystallographic planes, is verified in bulk and thin film samples, and applications are proposed to exploit the reversible dependence of electronic properties on disorder. Low-temperature mechanical alloying is instead discovered stabilizing a novel polymorph of CZTS, which disordered cubic structure is studied in detail, and proposed deriving from sphalerite-ZnS. The total cation disorder in this compound provides an uncommon occurrence in thermoelectricity: a concurrent optimization of Seebeck coefficient, electrical and thermal conductivity. These findings, besides providing new and general understanding of CZTS, can cast light on profitable mechanisms to enhance the thermoelectric performance of semiconducting chalcogenides, as well as delineate alternative and fruitful applications.