Aerosols have a significant effect on the global radiation budget through their interactions with radiation and clouds. However, estimates of their effect are the dominant source of uncertainty in current estimates of total anthropogenic effect on climate. A major cause of this uncertainty is the high degree of variability of aerosol properties and processes that affect their lifetime. Prediction of the aerosol effect on climate depends on the ability of three-dimensional numerical models to accurately estimate aerosol properties. However, a limitation of traditional grid-based models is their inability to resolve variability on scales smaller than a grid box. Past research has shown that significant aerosol variability exists on scales smaller than these grid-boxes, which can lead to discrepancies between observations and aerosol models. This thesis uses a synthesis of aerosol observations, global climate model (GCM) data, and a new aerosol modelling technique implemented within a regional-scale model to quantify the important scales of aerosol variability and the extent to which different sub-grid scale processes contribute to discrepancies in aerosol modelling. Analysis of black carbon (BC) plumes from aircraft observations shows that BC plumes represent a large portion of total BC mass and typically exist on scales of 65{ 100 km. Comparison of observed plume scales to those simulated by GCMs at multiple resolutions show that GCMs overestimate the scales of along- ight-track variability by 64% at the highest resolution. Variability is shown to be greater near sources than in remote regions, indicating that models may benefit from higher resolutions in regions of high emissions. Additionally, GCMs at all resolutions show higher variability in the latitudinal direction than the longitudinal direction, suggesting that capturing latitudinal variability may result in greater improvements in aerosol modelling. This work additionally presents a novel technique to allow one to isolate the effect of aerosol variability from other sources of variability within the model. Processes most affected by neglecting aerosol sub-grid variability are gas-phase chemistry and aerosol uptake of water through the aerosol/gas equilibrium reactions. The inherent non-linearities in these processes result in large changes in aerosol parameters when aerosol and gaseous species are artificially mixed over large spatial scales. These changes in aerosol and gas concentrations are exaggerated by convective transport, which transports these altered concentrations to altitudes where their effect is more pronounced. Future aerosol model development should focus on accounting for the effect of sub-grid variability on these processes at global scales in order to improve model predictions of the aerosol effect on climate.

Underwater communication systems are in high demanded for subaquatic environment activities as the sea is an enormous and mostly unexplored place. The ten-meter long and few giga-bit per second range optical communication technique is feasible and has bright future compared to the mature but low data rate (few kilobits per second) acoustic technology and short distance (several meters) radio-frequency signaling schemes. The underwater wireless optical communication (UWOC) technique takes advantage of wide bandwidth, low attenuation effect in the visible range for multiple applications such as seafloor and offshore exploration, oil pipe control and maintenance, and pipeline leak detection. Nowadays, visible light-emitting diode (LED)-based and laser diode (LD)-based UWOC system are attractive and much related research is being conducted in the field. However, the major challenges of developing UWOC systems are the attenuation, scattering and turbulence effects of the underwater environment. The temperature gradient, salinity gradient, and bubbles make underwater optical channel predictable challenging and degrade the optical beam propagating distance and quality. Most studies focus on the statistical distribution of intensity fluctuations in underwater wireless optical channels with random temperature and salinity variations as well as the presence of air bubbles. In this thesis, we experimentally investigate the reciprocity nature of underwater turbulence caused by the turbidity, air bubbles, temperature variations, and salinity. Bit error rate measurement and statistical data analysis reveal the high reciprocal nature of turbulence that can be induced by the presence of bubbles, temperature, and salinity. The mitigation strategies for the different turbulence scenarios are discussed.

Internal waves are generated in a fluid if the density increases continuously with depth. The variation in density with depth, or stratification, defines the natural frequency of the fluid N. Two common examples of stratified fluids are the ocean and atmosphere; internal waves are generated continuously in both mediums. Although there are many internal wave generation mechanisms, one common and frequently studied method is tidal flow over oceanic bathymetry. If the local natural frequency of the water near the topography is greater than the tidal frequencyω, internal waves will be generated by the tidal flow over the topography. If N=ω, only evanescent waves will be formed. Unlike internal waves, evanescent waves decay rapidly as they move vertically away from their generation site. As evanescent waves pass from an evanescent region (N=ω),through a turning depth (N=ω) and into a propagating region (N=ω), they become propagating internal waves. Because internal waves can propagate energy across large distances, they play an important role in oceanic mixing and the overall energy budget of the ocean. Knowing where these waves are formed from evanescent waves and their corresponding energy improves understanding of the impact on their surrounding area.Kinetic energy density of evanescent and internal waves formed from oscillatory flow over topography in evanescent regions is first estimated using synthetic schlieren experiments and a novel linear theory model. Experiments were performed with two Gaussian topographies in an exponential density profile. The linear theory model, which uses a set of equations that links the evanescent and propagating regions with the Airy function to overcome the discontinuity inherent with a turning depth, was compared to the experiments. Both methods showed that increasing Fr1,the strength of the evanescent region relative to the excitation frequency, causes the propagating kinetic energy to decrease. In addition, kinetic energy decreased with increasing distance between the topography and the turning depth. Because the model does not account for non-linearities such as turbulence generation, it regularly overestimates propagating kinetic energy relative to the experiments. After comparing the model with synthetic schlieren experiments, it was used to estimate that 25% of the evanescent wave energy generated by an oceanic topography located at 15◦N, 130◦E can become propagating wave energy.The influence of topography shape and fluid density profile on kinetic energy density was also explored through a combination of experiments, a linear theory model, and numerical simulations. From numerical simulations, kinetic energy can be directly calculated with the velocity pro-file and indirectly with the density perturbation field, in the same manner as the synthetic schlieren experiments. Average propagating internal wave kinetic energy (KE∗ 2) as a function of Fr1D/H,which combines Fr1 with the relative distance between the topography and the turning depth D/H,was compared for all methods. KE∗ 2 decreases with increasing Fr1D/H for all methods. Also, far from the turning depth, the direct and indirect simulations indicate similar kinetic energy when in the propagating region, where a distance from the turning depth can be quantified based on N and ω. This work was expanded to include a medium Gaussian, steep Gaussian, sinusoidal, and complex topography with two layer linear, parabolic, cubic, and exponential density profiles to investigate the validity of assuming an average natural frequency in the evanescent region and the impact of the topographic slope on KE∗ 2. A comparison of the density profiles indicated that using a two layer linear density profile has similar results compared to the other density profiles for estimating KE∗ 2 as a function of Fr1D/H. Also, KE∗ 2 is non-negligible for Fr1D/H<4. Increasing the maximum slope of a topography shape decreases the kinetic energy of the generated internal waves, though it was found that the energy is dependent upon the actual shape of the topography as well.Particle image velocimetry (PIV) experiments were performed and compared to synthetic schlieren (SS). While SS experiments generally resulted in an overestimate of kinetic energy relative to the PIV results, the trends from each experimental method matched well. It is recommended that SS be used in regions away from turning depths, but that either are valid in the evanescent and propagating regions. PIV methods should be used when results near the turning depth or the topography are desired.

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Thesis advisor: Ethan Baxter / Serpentinites assume a critical role in geochemical and geophysical cycles, from recycling fluid into the sub-arc mantle to facilitating exhumation within subduction zones. Rodingite dikes can be used as a lens to investigate the hydration of the oceanic lithosphere as their development is synchronous with serpentinization, and while serpentinites lack sufficient mineral phases for geochronology, rodingite dikes are rich in andradite and grossular garnet which are potentially amenable for geochronology. This research seeks to constrain the timescales and duration of hydration of the oceanic lithosphere within the Alpine Tethys ocean basin, and associated serpentinization, by examining Apennines rodingites from the Internal Ligurides (Italy). These rodingites experienced seafloor hydrothermal alteration and were obducted onto the continental margin during Alpine orogenesis. As a result, they are ideal for studying seafloor metasomatism as they were not affected by prograde subduction zone metamorphism and dehydration. Sr isotopic and trace element profiles were constructed across two rodingite-serpentinite transects, revealing a complex, multi-stage hydration history consisting of 1) Widespread serpentinization, 2) Gabbroic intrusions, 3) Rodingitization, and 4) Localized, late-stage advective fluid flow. Serpentinizing fluids locally display strong continental crustal isotopic signatures, while rodingitization fluids are characterized by seawater-like values. U-Pb geochronology on rodingite garnets produced an age of 96.1 ± 8.9 Ma, which could represent either the main rodingitization phase or the late-stage advective alteration. / Thesis (MS) — Boston College, 2023. / Submitted to: Boston College. Graduate School of Arts and Sciences. / Discipline: Earth and Environmental Sciences.

No / A crystalline solid called a gas hydrate has gas molecules surrounded by water molecules. There are several gases with suitable structures for the production of hydrates, but methane-rich gas hydrates are more common and form in seas and on the ocean. The place of hydrates formation is usually the sediment of the ocean floor and the polar regions, which largely covered with ice. It is also found in large quantities in combination with ambient ice in the ever-frozen polar regions. The importance of gas hydrates is due to the great ability of gas hydrates in natural gas storage, which makes it attractive to use them for the purposes of storing and transporting natural gas and other gases as a competitor to liquefaction and condensing methods. Due to the significance potential of these reserves as the world's future energy supplier and their direct impact on changes in climate conditions due to the greenhouse effect of methane, as well as their geological risks during water hydrocarbon discoveries, marine science researchers have been studying them over the past few years. Acoustic and seismic methods are helpful instruments for measuring subterranean hydrated reserves because there is not the technology to measure hydrated reserves directly.

Understanding oxygenation throughout Earth history, particularly intervals where marine deoxygenation occurred, are crucial to investigating the changes in habitability on Earth. Marine deoxygenation events, in particular, can result in changes in the carbon, sulfur, and iron cycles on our planet. Changes in these elemental cycles lead to distinctive variation in the chemical composition of seawater that is recorded in marine sediments that are preserved into the sedimentary record. Our modern ocean is experiencing rapid deoxygenation, thus understanding the duration and extent of ancient deoxygenation events is vital to predicting future climate scenarios. Here I investigated the record of environmental change during the Early Jurassic Toarcian Oceanic Anoxic Event or T-OAE (~183 Ma). The first chapter of this dissertation investigates the record of marine anoxia across the Pliensbachian to Toarcian transition. Specifically, I investigate the temporal and geographic development of anoxia across three basins from the European Epicontinental Seaway. Through utilization of iron speciation, a local redox proxy, I identify anoxia developing before and persisting well after the negative carbon isotope excursion (NCIE) conventionally used to define the T-OAE. These data indicate an increase in the occurrence of anoxia at the Pliensbachian – Toarcian boundary, coincident with the initial phase of volcanism associated with the Karoo-Ferrar Large Igneous Province and an interval of heightened marine invertebrate extinction. Ultimately, our data support a greater temporal extent of anoxic conditions around the T-OAE, which support the greater sensitivity of marine oxygen levels to climatic change outside of the NCIE interval. The second chapter of this dissertation assesses the occurrence and extent of organic matter sulfurization (OMS), a biogeochemical feedback known to enhance the preservation and burial of OM. Because this process is accelerated when euxinic conditions develop in the water column, I investigated it as a mechanism promoting OM burial across two oceanic anoxic events of the Mesozoic. Importantly, I find that sulfurization does not occur uniformly across both events and propose a conceptual model of the depositional settings most favorable for sulfurization to occur and when throughout geologic time OMS is most likely to influence the global cycles of carbon and sulfur. / Doctor of Philosophy / Understanding past time intervals where there was widespread loss of oxygen in the oceans is crucial to understanding habitability on Earth. Since our modern oceans are experiencing a rapid loss of oxygen, understanding the duration and extent of ancient marine oxygen loss events is vital to predicting future habitability of the oceans. These ancient events can result in distinctive changes in the carbon, sulfur, and iron cycles on our planet. Variation in these elemental cycles lead to distinctive shifts in the chemical composition of seawater that is recorded in marine sediments that get preserved as rocks in the geologic record. Here, I investigated the record of environmental change during the Early Jurassic Toarcian Oceanic Anoxic Event or T-OAE (~183 Ma). The first chapter of this dissertation investigates the record of marine oxygen loss across the T-OAE. Specifically, I investigate the temporal and geographic development of oxygen loss across three ancient marine basins. Through utilization of a local tracer of water column oxygen loss (e.g. iron speciation) I identify oxygen loss developing before and persisting well after the conventional timeframe associated with the event. These data indicate oxygen loss first occurred before the T-OAE, coincident with the initial phase of volcanic eruptions from the Karoo-Ferrar Large Igneous Province and an interval of heightened marine extinction. Ultimately, these data support a longer time interval of oxygen loss around the T-OAE and the greater sensitivity of marine oxygen levels to climatic change. The second chapter of this dissertation assesses the occurrence and extent of organic matter sulfurization (OMS), a feedback known to enhance the preservation and burial of organic matter (OM). Because this process is accelerated when oxygen is lost and free sulfur builds up in the water column, I investigated its occurrence across two oceanic oxygen loss events of the Mesozoic Era. Importantly, I find that sulfurization does not occur uniformly across both events and propose a conceptual model of the settings most favorable for sulfurization to occur and also when in geologic time it is most likely to influence the global cycling of carbon and sulfur.

Approximately, two-thirds of earth's surface is covered by water. There is a growing interest from the military and commercial communities in having, an efficient, secure and high bandwidth underwater wireless communication (UWC) system for tactical underwater applications such as oceanography studies and offshore oil exploration. The existing acoustic and radio frequency (RF) technologies are severely limited in bandwidth because of the strong frequency dependent attenuation of sound in seawater and the high conductivity of seawater at radio frequencies, respectively. Recently, underwater wireless optical communication (UWOC) has been proposed as the best alternative or complementary solution to meet this challenge. Taking advantage of the low absorption window of seawater in blue-green (400-550 nm) regime of the electromagnetic spectrum, UWOC is expected to establish secure, efficient and high data rate communication links over short and moderate distances (< 100 m) for versatile applications such as underwater oil pipe inspection, remotely operated vehicle (ROV) and sensor networks. UWOC uses the latest gallium nitrite (GaN) visible light-emitting diode (LED) and laser diode (LD) transmitters. Although some research on LED lased UWOC is being conducted, both the military and academic 5 research communities are favoring the use of laser beams, which potentially could enhance the available bandwidth by up to three orders of magnitude. However, the underwater wireless channel is optically very challenging and difficult to predict. The propagation of laser beams in seawater is significantly affected by the harsh marine environments and suffers from severe attenuation which is a combined effect of absorption and scattering, optical turbulence, and multipath effects at high transmission rates. These limitations distort the intensity and phase structure of the optical beam leading to a decrease in signal-to-noise ratio (SNR) which ultimately degrades the performance of UWOC links by increasing the probability of error. In this dissertation, we seek to experimentally demonstrate the feasibility of short range (≤ 20 m) UWOC systems over various underwater channel water types using different modulation schemes as well as to model and describe the statistical properties of turbulence-induced fading in underwater wireless optical channels using laser beam intensity fluctuations measurements.