A variety of anthropomorphic and environmental stresses are threatening the existence of all seven species of sea turtles. There is growing evidence that alterations in surface waters and sediment temperatures are negatively impacting reproductive success of loggerhead sea turtles (Caretta caretta). Fluctuations in water temperature associated with localized climate oscillations heavily alter the food web dynamics of the ocean. Feeding conditions are expected to be a critical factor in determining body mass and productivity for breeding seasons. An increase in regional temperatures could lead to prolonged reduction in food sources, as well as reduced nesting and recruitment. Loggerhead sea turtle nesting data from 1995-2011 werre compared with the average yearly North Atlantic Oscillation (NAO) and Atlantic Multidecadal Oscillation (AMO) which are important climatic events impacting the SST in the Atlantic Ocean. Because El Niño Southern Oscillation (ENSO) is a global event, it was proposed that turtles in the Atlantic may follow a similar trend. ENSO was quantified using Oceanic Nino Index (ONI). Analysis of loggerhead sea turtle nest frequencies from the years 1995-2011 in comparison to seasonal climate changes showed a significant inverse relationship between the detrended loggerhead nests and average yearly NAO when lagged two years, suggesting loggerheads may spend years prior breeding obtaining optimum body mass to increase successful reproduction. The detrended nesting data showed a tendency toward higher occurrence of nests during La Niña years while nest frequencies decreased during El Niño year; when the yearly detrended loggerhead nesting data was compared with the average yearly ONI; showing a significant inverse relationship without a lag. This may also suggest a relationship between changes of productivity of the ocean influenced by smaller scale climate changes and loggerhead nest frequencies.

A study of the Nova Scotia surface air temperature over the last century (1900 to 2015) shows that internal variability on inter-annual, decadal and multi-decadal time scales can be partly explained by ocean-atmospheric climate modes, external and anthropogenic forcings. The Atlantic Multidecadal Oscillation (AMO) and Arctic Oscillation (AO) are shown to be the dominant climate drivers in Nova Scotia. The El Niño Southern Oscillation (ENSO) is also shown to be a dominant climate driver but only during the summer. Multivariate models were generated over the full time period using only natural ocean-atmospheric modes of variability but could not explain the rapid increase in the recent rate of warming (post-1980). The inclusion of anthropogenic greenhouse gas forcing to the models improved their predictive power annually and seasonally. The modelling results show that 11% of the annual variability in Nova Scotia results from natural forcings along with anthropogenic greenhouse gas forcing while seasonally up to 28% of the temperature variability can be explained by natural plus greenhouse gas forcings. The annual and seasonal low explained variance suggests that Nova Scotia is poorly modulated by climate indices, specifically during the winter, the time when relationships between ocean-atmospheric modes and the regional climate should be the strongest. It leads to believe that Nova Scotia is located in a transition zone where large-scale ocean-atmospheric modes of variability are transitioning from being positively correlated in a region to being negatively correlated in another region. The results of this study help to better understand how large-scale ocean-atmospheric modes of variability, external and anthropogenic greenhouse gas forcings affect Nova Scotia’s surface air temperatures and also provide insight into future potential variability under a changing climate.

Crane motion induces payload oscillation that makes accurate positioning of the payload a challenging task. As the payload size increases, it may be necessary to utilize multiple cranes for better control of the payload position and orientation. However, simultaneously maneuvering multiple cranes to transport a single payload increases the complexity and danger of the operation. This thesis investigates the dynamics and control of dual-hoist bridge cranes transporting distributed payloads. Insights from this dynamic analysis were used to design input shapers that reduce payload oscillation originating from various crane motions. Also, studies were conducted to investigate the effect input shaping has on the performance of human operators using a dual-hoist bridge crane to transport distributed payloads through an obstacle course. In each study, input shaping significantly improved the task completion time. Furthermore, input-shaping control greatly decreased operator effort, as measured by the number of interface button pushes needed to complete a task. These results clearly demonstrate the benefit of input-shaping control on dual-hoist bridge cranes. In addition, a new system identification method that utilizes input shaping for determining the modal frequencies and relative amplitude contributions of individual modes was developed to aid in the dynamic analysis of dual-hoist bridge cranes, as well as other multi-mode systems. This method uses a new type of input shaper to suppress all but one mode to a low level. The shaper can also be used to bring a small-amplitude mode to light by modifying one of the vibration constraints.

The Southeast United States during summer and fall is often affected by droughts and tropical cyclones. Both phenomena rank among the most expensive of natural hazards, although droughts are not as feared by the public as hurricanes. When a tropical cyclone causes a pendulum swing from drought to wet conditions, it is known as a “drought-busting tropical cyclone.” The majority of the research related to drought busting tropical cyclones investigates only the storms during their tropical cyclone phase, which covers the southeastern states that have boundaries adjacent to the Atlantic Ocean. An unanswered question from this literature is whether or not these findings apply to the interior southeastern states that have no ocean boundaries, where there is an increase in the probability of a drought-busting tropical cyclone transitioning to an extra-tropical cyclone. This thesis research attempts to determine the impact of drought-busting cyclones on the states of Kentucky and Tennessee. Research findings in this thesis revealed that droughts occur more frequently in the eastern climate divisions of the study area, 2-3 tropical cyclones affect the study area each year, and 6% of warm-season precipitation comes from tropical cyclones or their remnants. Chi-Square analysis and Kruskal-Wallis tests suggest that the Atlantic Multidecadal Oscillation (AMO) has statistically significant relationships with drought frequency, tropical cyclone precipitation, and extra-tropical cyclone precipitation in several climate divisions. While the literature argues that drought-busting tropical cyclones are common in coastal locations, they were found to be rare in Kentucky and Tennessee.

Microfiltration is one of the most important processes in membrane sciences that can be used for separating drops/particles above 1 ??m. Depth microfiltration membranes retain drops/particles inside the surface of the membrane, the process is expensive and membranes quickly become fouled. On the other hand, surface microfiltration membranes stop drops/particles on the surface of the membrane and the process is less fouling. Higher permeate flux and lower trans-membrane pressure is obtained with a shear enhanced microfiltration technique. Production of specific size of drops and stability of the drops are very important in testing the microfiltration of crude oil drops/water emulsions. Oil drops from 1-15 ??m were produced with a food blender, operated at its highest speed for the duration of 12 mins. In addition, vegetable oil drops were stabilised with 1% polyvinyl alcohol (PVA), Tween 20 and gum Arabic, stability was assessed on the basis of consistency in the size distribution and number of drops in each sample analysed at 30 mins interval. A slotted pore Nickel membrane with the slot width and slot length of 4 and 400 ??m respectively has been used in the filtration experiments. The slot width to the slot length ratio (aspect ratio) of the used membrane is 100. Vibrating the membrane at various frequencies created shear rates of different intensities on the surface of the membrane. Membrane with a tubular configuration is preferred over the flat sheet because it is easy to control in-case of membrane oscillations both at lab and industrial scale. Besides this, a tubular membrane configuration provides a smaller footprint as compared to the flat sheet. The influence of applied shear rate on slots/pore blocking has been studied. Applying shear rate to the membrane reduced the blocking of the slots of the membrane; and reduction of slots blocking is a function of the applied shear rate. At higher shear rate, lower blocking of the slots of the membrane was verified by obtaining lower trans-membrane pressure for constant rate filtration. The experiments are in reasonable agreement with the theoretical blocking model. Divergence of the experimental data from the theory may be due to involvement of deforming drops in the process. During microfiltration of oil drops, the drops deform when passing through the slots or pores of the membrane. Different surfactants provided different interfacial tensions between the oil and water interface. The influence of interfacial tension on deformation of drops through the slots was studied. The higher the interfacial tension then the lower would be the deformation of drops through the slots. A mathematical model was developed based on static and drag forces acting on the drops while passing the membrane. The model predicts 100% cut-off of drops through the membrane. Satisfactory agreement of the model with the experiments shows that the concept of static and drag force can be successfully applied to the filtration of deformable drops through the slotted pore membranes. Due to the applied shear rate, inertial lift migration velocities of the drops away from the surface of the membrane were created. Inertial lift velocities are linear functions of the applied shear rate. A mathematical model was modified based on inertial lift migration velocities. The critical radius of the drops is the one above which drops cannot pass through the surface of the membrane into the permeate due to the applied shear rate and back transport. The model is used as a starting point and is an acceptable agreement with the experiment. The model can be used to predict the 100% cut-off value for oil drops filtration and a linear fit between this value and the origin on a graph of grade (or rejection) efficiency and drop size to slot width ratio was used to predict the total concentration of dispersed oil left after filtration. Hence, it is shown how it is possible to predict oil discharge concentrations when using slotted filters.

The notion of airplane stability and control being a balancing act between stability and control has been around as long as aeronautics. The Wright brothers’ first successful flights were born of the debate, and were successful at least in part because they spent considerable time teaching themselves how to control their otherwise unstable airplane. This thesis covers four aspects of handling for large transport aircraft: large size and the accompanying low frequency dynamics, the way in which lifting surfaces and control system elements are modelled in flight dynamics analyses, the cockpit feel characteristics and details of how pilots interact with them, and the dynamic instability associated with Pilot Induced Oscillations. The dynamics associated with large transport aircraft are reviewed from the perspective of pilot-in-the-loop handling qualities, including the effects of relaxing static stability in pursuit of performance. Areas in which current design requirements are incomplete are highlighted. Issues with modelling of dynamic elements which are between the pilot’s fingers and the airplane response are illuminated and recommendations are made. Cockpit feel characteristics are examined in detail, in particular, the nonlinear elements of friction and breakout forces. Three piloted simulation experiments are described and the results reviewed. Each was very different in nature, and all were designed to evaluate linear and nonlinear elements of the cockpit feel characteristics from the pilot’s point of view. These included understanding the pilot’s ability to precisely control the manipulator itself, the pilot’s ability to command the flight path, and neuro-muscular modelling to gain a deeper understanding of the range of characteristics pilots can adapt to and why. Based on the data collected and analyzed, conclusions are drawn and recommendations are made. Finally, a novel and unique PIO prediction criterion is developed, which is based on control-theoretic constructs. This criterion identifies unique signatures in the dynamic response of the airplane to predict the onset of instability.

published_or_final_version / Environmental Management / Master / Master of Science in Environmental Management

Based on ethanol fermentation kinetics and bioreactor engineering theory, a system composed of a continuously stirred tank reactor (CSTR) and three tubular bioreactors in series was established for continuous very high gravity (VHG) ethanol fermentation with Saccharomyces cerevisiae. Sustainable oscillations of residual glucose, ethanol, and biomass characterized by long oscillation periods and large oscillation amplitudes were observed when a VHG medium containing 280 g/L glucose was fed into the CSTR at a dilution rate of 0.027 h???1. Mechanistic analysis indicated that the oscillations are due to ethanol inhibition and the lag response of yeast cells to ethanol inhibition. A high gravity (HG) medium containing 200 g/L glucose and a low gravity (LG) medium containing 120 g/L glucose were fed into the CSTR at the same dilution rate as that for the VHG medium, so that the impact of residual glucose and ethanol concentrations on the oscillations could be studied. The oscillations were not significantly affected when the HG medium was used, and residual glucose decreased significantly, but ethanol maintained at the same level, indicating that residual glucose was not the main factor triggering the oscillations. However, the oscillations disappeared after the LG medium was fed and ethanol concentration decreased to 58.2 g/L. Furthermore, when the LG medium was supplemented with 30 g/L ethanol to achieve the same level of ethanol in the fermentation system as that achieved under the HG condition, the steady state observed for the original LG medium was interrupted, and the oscillations observed under the HG condition occurred. The steady state was gradually restored after the original LG medium replaced the modified one. These experimental results confirmed that ethanol, whether produced by yeast cells during fermentation or externally added into a fermentation system, can trigger oscillations once its concentration approaches to a criterion. The impact of dilution rate on oscillations was also studied. It was found that oscillations occurred at certain dilution rate ranges for the two yeast strains. Since ethanol production is tightly coupled with yeast cell growth, it was speculated that the impact of the dilution rate on the oscillations is due to the synchronization of the mother and daughter cell growth rhythms. The difference in the oscillation profiles exhibited by the two yeast strains is due to their difference in ethanol tolerance. For more practical conditions, the behavior of continuous ethanol fermentation was studied using a self-flocculating industrial yeast strain and corn flour hydrolysate medium in a simulated tanks-in-series fermentation system. Amplified oscillations observed at the dilution rate of 0.12 h???1 were postulated to be due to the synchronization of the two yeast cell populations generated by the continuous inoculation from the seed tank upstream of the fermentation system, which was partly validated by oscillation attenuation after the seed tank was removed from the fermentation system. The two populations consisted of the newly inoculated yeast cells and the yeast cells already adapted to the fermentation environment. Oscillations increased residual sugar at the end of the fermentation, and correspondingly, decreased the ethanol yield, indicating the need for attenuation strategies. When the tubular bioreactors were packed with ????? Intalox ceramic saddles, not only was their ethanol fermentation performance improved, but effective oscillation attenuation was also achieved. The oscillation attenuation was postulated to be due to the alleviation of backmixing in the packed tubular bioreactors as well as the yeast cell immobilization role of the packing. The residence time distribution analysis indicated that the mixing performance of the packed tubular bioreactors was close to a CSTR model for both residual glucose and ethanol, and the assumed backmixing alleviation could not be achieved. The impact of yeast cell immobilization was further studied using several different packing materials. Improvement in ethanol fermentation performance as well as oscillation attenuation was achieved for the wood chips, as well as the Intalox ceramic saddles, but not for the porous polyurethane particles, nor the steel Raschig rings. Analysis for the immobilized yeast cells indicated that high viability was the mechanistic reason for the improvement of the ethanol fermentation performance as well as the attenuation of the oscillations. A dynamic model was developed by incorporating the lag response of yeast cells to ethanol inhibition into the pseudo-steady state kinetic model, and dynamic simulation was performed, with good results. This not only provides a basis for developing process intervention strategies to minimize oscillations, but also theoretically support the mechanistic hypothesis for the oscillations.

The precise nature of the motion of the lips of the musician is critically important to the sound of the brass wind instrument. The player must match the oscillation of the lips to the acoustical properties of the instrument and it can take many years of practice to master the techniques involved. Visualisation techniques for capturing the motion of the lips during performance are described and the behaviour of the lips quantitatively analysed using digital image analysis. The concept of an artificial mouth for the sounding of brass wind instruments is discussed and the motion of the artificial lips is compared to that of human musicians. When a brass instrument is played loudly the energy of the higher harmonics increases, creating a distinctive ‘brassy’ timbre. It has been suggested that saturation or constraint of the lips of the musician during extremely loud playing is responsible for this change in sound. Measurements of the motion of the lips of a number of different musicians on different instruments suggest that the lips are not significantly constrained at any playing dynamic, and that it is the phenomena of nonlinear propagation and shockwave generation that is responsible for the increase in energy of the higher harmonics. It is widely accepted that the starting transient of a musical instrument is of great importance to both listener and musician. Previous studies of brass instruments have focused on the steady-state behaviour of the lip-instrument interaction. Measurements of the motion of the lips have been synchronised with the pressure in the mouthpiece of the instrument and the sound radiated from the bell in order to investigate the transient behaviour of the system during both the starting transient and slurs between notes. Thiswork has been extended to include measurements of the pressure in the mouth of the player during the starting transient, and this information used to recreate realistic transients using an artificial mouth. The transient behaviour of the system is clearly affected by the time delay between the start of the note and the acoustical feedback from the instrument beginning. The information obtained can be used to aid in the creation of accurate computational and physical models of brass wind instruments.

Waves in the North Atlantic are strongly seasonal, and peak in the winter season. The west coast of Portugal is exposed to winter swell, generated by wind associated with North Atlantic extratropical cyclones. The track of these storms, generated near the North America east coast, is strongly influenced by the North Atlantic Oscillation (NAO). When the NAO is in its positive phase they normally track northeast and reach Western Europe well north of the Iberian Peninsula, in the British Islands or Scandinavia. However, in the negative NAO situation,the track of the storms is more zonal and south than usual, due to a weakened NAO. The characteristics of wave regime in Portugal are shown to be strongly related to the NAO phase and corresponding storm tracking. Positive NAO storms, tracking northeast towards the north of Europe, drive longer period swell from the northwest, whereas negative NAO storms have associated shorter period swell arriving to Portugal from a more westerly direction. The relation between the NAO phase and the storm tracks and the characteristics of the wave regime is investigated with ten year observations from four directional waverider coastal buoys, located off the coast of Portugal.