The slotted plate flow meter has been widely tested as an obstruction flow meter during the past several years. It has been tested for both single-phase flows as well as for two-phase flows. Previous studies have revealed that the slotted plate flow meter is always better in performance and accuracy than the standard orifice plate flow meter. This study is primarily based on how a slotted plate responds to horizontal two-phase flow with air and water being used as the working fluids. The plates under consideration are those with beta ratios of 0.43 and 0.467. Experiments have been performed with six different configurations of the slotted plate test sections. The performances of the slotted plate flow meters will be compared to that of a standard orifice plate flow meter and then with a venturi. The effects of varying the upstream quality of the two-phase flow on the differential pressure and the coefficient of discharge of the slotted plates, the standard orifice plate and the venturi will be evaluated. Response characteristics at low differential pressures will be investigated. Tests for repeatability will be performed by studying the effects of the gas Reynolds number and the upstream quality on the differential pressure. The differential pressures across the slotted plates, the standard orifice plate and the venturi will be compared. Reproducibility will be evaluated by comparing the data obtained from all six different configurations. One of the main objectives of this study is to arrive at the best suitable procedure for accurately measuring the flow rate of two-phase flow using the slotted plate flow meter.

The generation and propagation of fluorescence light within biological tissue offers the potential for biomedical diagnostics and analyte sensing. Arising from an exogenous fluorescent dye injected as a contrast agent or immobilized in a polymer implant, the fluorescent decay kinetics can be sensitive to the tissue??s biochemical environment, providing quantitative in vivo information of the confined tissue site. The impact of light propagation and decay kinetics upon the measured signals is important for consideration, simply because tissue scatters light, giving rise to nanosecond photon time-of-flights that are comparable to fluorescence relaxation kinetics. The goal of this study is to develop a time-dependent model describing (i) the generation of fluorescence from dyes exhibiting multi-exponential or more complex kinetics and (ii) its propagation in scattering media. In the preliminary study, fluorescence lifetime spectroscopy is investigated in tissue-like scattering solution. Two fluorescent dyes, 3,3-diethylthiatricarbocyanine iodide (DTTCI) and Indocynanine Green (ICG), which exhibit distinctly different lifetimes and each exhibits single-exponential decay kinetics, were employed. Measurements of phase-modulation as a function of modulation frequency were made at varying concentration ratios of the two dyes to experimentally simulate fluorescence multi-exponential decay kinetics in non-scattering and scattering solutions. The results suggest that frequency-domain measurements of fluorescent decay kinetics along with models of light propagation may be enhanced by scatter in order to probe kinetics more sensitively than in non-scattering solutions. The next study involved fluorescence lifetime sensing in scattering and non-scattering solutions with a pH sensitive dye, Carboxy Seminaphthofluorescein-1 (C-SNAFL-1), which is known to exhibit multi-exponential decay kinetics. The results demonstrate accurate pH sensing in scattering solution via fluorescence kinetics using a simplified propagation model incorporating an average lifetime. Finally, fluorescence lifetime sensing in immobilized systems were investigated. C-SNAFL-1 was immobilized in poly(ethylene glycol) (PEG) microparticles that were immersed in buffered polystyrene solutions. The results demonstrate the ability to perform pH sensing with fluorescence lifetime without the confounding effect of fluorophore loading or the use of 'reference' measurement within multiply scattering systems. In addition, the stability of the immobilized fluorescence sensor and the reliability of fluorescence lifetime measurement verify the prospect of this technology for implantable purposes.

Considered in this thesis is multi-input multi-output (MIMO) systems with non-minimum phase (NMP) zeros and unstable poles where some of the unstable poles are located to the right of the NMP zeros. In the single-input single-output (SISO) case such systems pose serious difficulties in controller synthesis for performance and stability. In spite of the added degrees of freedom the MIMO case also poses difficulties as has been shown in the stabilization of the X-29 aircraft. When using the MIMO QFT technique the synthesis starts by considering a set of equivalent SISO plants derived from the plant transfer function matrix that are used to develop a controller. In effect the design problem is reduced to several MISO designs with the diagonal entries of as the equivalent SISO plants. Developed is a transformation scheme that can be used to condition the resulting equivalent SISO plants so that the difficult problem of NMP zeros lying to the left of unstable poles is avoided. Examples illustrate the use of the proposed transformation.

A mathematical model is developed to describe the micro/nano-scale fluid flow and heat/mass transfer phenomena in an evaporating extended meniscus, focusing on the transition film region under nonisothermal interfacial conditions. The model incorporates thermocapillary stresses at the liquid-vapor interface, a slip boundary condition on the solid wall, polarity contributions to the working fluid field, and binary mixture evaporation. The analytical results show that the adsorbed film thickness and the thin film length decrease with increasing superheat by the thermocapillary stresses, which influences detrimentally the evaporation process by degrading the wettability of the evaporating liquid film. In contrast, the slip effect and the binary mixture enhance the stability of thin film evaporation. The slip effect at the wall makes the liquid in the transition region flow with smaller flow resistance and thus the length of the transition region increases. In addition, the total evaporative heat flow rate increases due to the slip boundary condition. The mixture of pentane and decane increases the length of the thin film by counteracting the thermocapillary stress, which enhances the stability of the thin film evaporation. The polarity effect of water significantly elongates the thin film length due to the strong adhesion force of intermolecular interaction. The strong interaction force restrains the liquid from evaporation for a polar liquid compared to a non-polar liquid. In the experimental part, laser induced fluorescence (LIF) thermometry has been used to measure the microscale temperature field of a heated capillary tube with a 1 mm by 1 mm square cross section. For the temperature measurement, the calibration curve between the temperature and the fluorescent intensity ratio of Rhodamine-B and Rhodamine-110 has been successfully obtained. The fluorescent intensity ratio provides microscale spatial resolution and good temperature dependency without any possible bias error caused by illuminating light and background noise usually encountered in conventional LIF techniques. For the validation of the calibration curve obtained, thermally stratified fields established inside a glass cuvette of 10 mm width were measured. The measurement result showed a good agreement with the linear prediction. The temperature measurement in a 1 mm capillary tube could provide the feasible method of temperature measurement for the thin film region in the future.

A distributed fiber optic intrusion sensor capable of detecting intruders from the pressure of their weight on the earth's surface was investigated in the laboratory and in field tests. The presence of an intruder above or in proximity to the buried sensor induces a phase shift in light propagating along the fiber which allows for the detection and localization of intrusions. Through the use of an ultra-stable erbium-doped fiber laser and phase sensitive optical time domain reflectometry, disturbances were monitored in long (several km) lengths of optical fiber. Narrow linewidth and low frequency drift in the laser were achieved through a combination of optical feedback and insulation of the laser cavity against environmental effects. The frequency drift of the laser, characterized using an all-fiber Mach Zehnder interferometer, was found to be less than 1 MHz/min, as required for operation of the intrusion detection system. Intrusions were simulated in a laboratory setting using a piezoelectric transducer to produce a controllable optical phase shift at the 2 km point of a 12 km path length. Interrogation of the distributed sensor was accomplished by repetitively gating light pulses from the stable laser into the sensing fiber. By monitoring the Rayleigh backscattered light with a photodetector and comparing traces with and without an induced phase shift, the phase disturbances were detected and located. Once the feasibility of such a sensor was proven in the laboratory, the experimental set up was transferred to Texas A&M's Riverside Campus. At the test site, approximately 40 meters of fiber optic cable were buried in a triangle perimeter and then spliced into the 12 km path length which was housed inside the test facility. Field tests were conducted producing results comparable to those found in the laboratory. Intrusions over this buried fiber were detectable on the φ-OTDR trace and could be localized to the intrusion point. This type of sensor has the potential benefits of heightened sensitivity, covertness, and greatly reduced cost over the conventional seismic, acoustic, infrared, magnetic, and fiber optic sensors for monitoring long (multi-km) perimeters.

One experiment was adminstered to address three issues central to identifying the processes that underlie our ability to learn through observation. One objective of the study was to identify the movement features (relative or absolute) extracted by an observer when demonstration acts as the training protocol. A second objective was to investigate how the performance level of the model (trial-to-trial variability in strategy selection) providing the demonstrations influences movement feature extraction. Lastly, a goal was to test whether or not visual perspective of the model by the observer (first-person or third-person) interacts with the aforementioned variables. The goal of the task was to trace two circles templates with a 90 degree relative phase offset between the two hands. Video recordings of two models practicing over three days were used to make three videos for the study; an expert performance, discovery performance, and instruction performance video. The discovery video portrayed a decrease in relative phase error and a transition from high trial-to-trial variability in the strategy selection to use of a single strategy. The instruction video also portrayed a decrease in relative phase error, but with no strategy search throughout practice. The expert video showed no strategy search with trial-to-trial variability within 5% of the goal relative phase of 90 across every trial. Observers watched one of the three video recordings from either a first-person or third-person perspective. In a retention test, the expert observers showed the most consistant capability (learning) in performing the goal phase. The instruction observers also showed learning, but to a lesser degree than the expert observers. The discovery group observers showed the least amount of learning of relative phase. The absolute feature of movement amplitude was not extracted by any observer group, results consistent with postulations by Scully and Newell (1985). Observation from the 1P perspective proved optimal in the expert and instruction observation groups, but the 3P perspective allowed for greater learning of of the goal relative phase (90 degree) in the discovery observation group. Hand lead, a relative feature of motion, was extracted by most obsevers, except those who observed the discovery model from the 3P perspective. It's concluded that the trial-to-trial variabiliy in terms of strategy selection interacted with the process of mental rotation, which prevented the extraction of hand lead in those observers that viewed the discovery model.

In previous studies the slotted orifice plate has demonstrated superior performance characteristics to those of the standard orifice plate. In this study, these comparisons are investigated further. The response characteristics of the slotted orifice plate to the standard orifice plate and V-Cone for two-phase flows of water and air at various qualities, flow rates, and pressures are shown visually. The effect of oil as it flows through a slotted orifice plate and standard orifice plate are visually documented. The effect of manufacturing accuracy on the slotted orifice plates is investigated as to the effect on the coefficient of discharge, percent change in pressure, and Reynolds number. The slotted orifice plate mixes two-phase flow better than the standard orifice plate and V-Cone. There is a manufacturing effect on the slotted orifice plates; the larger the area of the slots, the larger the discharge coefficient.

Due to climatic change, increasing thermal loads inbuildings and rising living standards, comfort cooling inbuildings is becoming increasingly important and the demand forcomfort cooling is expanding very quickly around the world. Theincreased cooling demand results in a peak in electrical powerdemand during the hottest summer hours. This peak presents newchallenges and uncertainties to electricity utilities and theircustomers. Cool thermal storage systems have not only the potential tobecome one of the primary solutions to the electrical powerimbalance between production and demand, but also shift coolingenergy use to off-peak periods and avoid peak demand charges.It increases the possibilities of utilizing renewable energysources and waste heat for cooling generation. In addition, acool storage can actually increase the efficiency of combinedheat and power (CHP) generation provided that heat drivencooling is coupled to CHP. Then, the cool storage may avoidpeaks in the heat demand for cooling generation, and this meansthat the CHP can operate at design conditions in most oftime. Phase Change Materials (PCMs) used for cool storage hasobtained considerable attention, since they can be designed tomelt and freeze at a selected temperature and have shown apromising ability to reduce the size of storage systemscompared with a sensible heat storage system because they usethe latent heat of the storage medium for thermal energystorage. The goal of this thesis is to define suitable PCM candidatesfor comfort cooling storage. The thesis work combines differentmethods to determine the thermophysical properties oftetradecane, hexadecane and their binary mixtures, anddemonstrates the potential of using these materials as PCM forcomfort cooling storage. The phase equilibrium of the binarysystem has been studied theoretically as well asexperimentally, resulting in the derivation of the phasediagram. With knowledge of the liquid-solid phase equilibriumcharacteristics and the phase diagram, an improvedunderstanding is provided for the interrelationships involvedin the phase change of the studied materials. It has beenindicated that except for the minimum-melting point mixture,all mixtures melt and freeze within a temperature range and notat a constant temperature, which is so far often assumed in PCMstorage design. In addition, the enthalpy change during thephase transition (heat of fusion) corresponds to the phasechange temperature range; thus, the storage density obtaineddepends on how large a part of the phase change temperaturerange is valid for a given application. Differential Scanning Calorimetery (DSC) is one frequentlyused method in the development of PCMs. In this thesis, it hasbeen found that varying results are obtained depending on theDSC settings throughout the measurements. When the DSC runs ata high heating/cooling rate it will lead to erroneousinformation. Also, the correct phase transition temperaturerange cannot be obtained simply from DSC measurement. Combiningphase equilibrium considerations with DSC measurements gives areliable design method that incorporates both the heat offusion and the phase change temperature range. The potential of PCM storage for peak shaving in differentcooling systems has been demonstrated. A Computer model hasbeen developed for rapid phase equilibrium calculation. The useof phase equilibrium data in the design of a cool storagesystem is presented as a general methodology. Keywords:Comfort cooling, peak shaving, PCM, coolthermal storage system, DSC, phase change temperature range,the heat of fusion, phase equilibrium, phase diagram. Language:English

The hydrodynamics of an agitated tank have been studied byphase-Doppler anemometry. The focus is on the impeller anddischarge region of a 45o pitched blade turbine (PBT). Thestudy includes agitation of pure water as well as of a dilutesuspension of process particles. A three-dimensionalphase-Doppler anemometer is used to measure local,instantaneous, three-dimensional velocities of the fluid and ofthe suspended particles. A shaft encoding technique is used toresolve the turbulent fluctuations from the periodic velocityfluctuation due to the impeller blades, and to provide moredetailed information about the variations relative to theimpeller blade. Velocity bias is corrected for by the total3-dimensional velocity. The mean flow field, the fluctuating velocities, and thecomplete Reynolds stress tensor, are reported for the liquidphase flow. The periodic fluctuations in the flow that aregenerated by the impeller blades are eliminated in theexamination of the turbulence. The anisotropy of the turbulenceis assessed by the invariants of the anisotropy tensor. Thetrailing vortex structure is demonstrated to be associated withhigh kinetic energy and strong anisotropy of the turbulence.The vortex is still observable 130-140 degrees behind theblade. It gradually moves down from the impeller blade but thelocation in radial direction remains essentially unchanged. Theinfluence of the periodic fluctuations is examined and it isshown that the turbulence appears more isotropic when theperiodic fluctuations are not eliminated. The solid particle concentration is low below the impellerand is high above the impeller tip. The particles diverge fromthe liquid flow mean direction, especially below the agitatorclose to the tip where the strongest turbulence is found.Periodic fluctuations in the particle concentration relate tothe variations found in the angle-resolved mean velocity andfluctuating velocity. The ratio of the maximum to the minimumconcentration is about 2.0 in the present study. The baffles influence on the conditions in the impellerregion, and this influence can be observed on the fluid meanvelocity field, the angle-resolved velocities, the kineticenergy, and on the behavior of larger process particles. In theimpeller region the highest kinetic energies are about 15%higher upstream of the baffle than at the middle plane betweenthe baffles. The highest energy level in the middle plane isactually the lowest value and is therefore not representativewhen rotation symmetry is assumed. Local energy dissipation rates have been investigated, andthe integration of the local energy dissipation rates overdifferent control volumes has been compared with macroscopicenergy balance calculations. The discrepancy is significant.Different reasons have been analyzed and recommendations forfurther investigation are given. I n the outflow region there is a significant variation alsoin the direction of the instantaneous velocity, which may leadto direction bias in the case of non-spherical measurementvolume. In order to account for this direction bias, amathematical model is developed to estimate the projected areaof the measurement volume in LDA or PDA. It is shown that theprojected area variation can lead to a significant directionbias in determination of time averaged values and localparticle concentration in a highly turbulent stirred tank flow.This bias is however negligible for an orthogonal optical setup, as is used in the present study. <b>Keywords:</b>Hydrodynamics, phase-Doppler anemometer,suspension, pitched-blade turbine, anisotropy, turbulence,Reynolds stresses, trailing vortex, kinetic energy, stirredtank

This thesis focuses on femtosecond studies of relaxation and photo-induced dissociation processes in the liquid environment. Measurements are performed using both polarization sensitive and magic angle transient absorption spectroscopy with excitation wavelengths of 387 nm and 258 nm and a white light continuum probe. In the first three papers the photodissociation of the trihalides I3- in acetonitrile and methanol as well as I2Br- in acetonitrile solution is investigated. These studies address such issues as the time scale for the production of the main photoproduct I2-, rotational dynamics of the formed diatomic anions, the subsequent wavepacket dynamics of the coherently excited diiodide anion and vibrational relaxation in, and the geminate recombination of, the I2- fragment. A nearly equal, bent geometry for the parent anion at the moment of bond breakage is proposed in all three solutions. However, the rotational temperature of the diiodide anion produced in the various solutions, reveals that motion along the bending coordinate of the dissociating triatomic anions plays an important role. The first signs of I2- fragments can already be observed at delays of approximately 130 – 190 fs which indicates a faster dissociation than suggested in earlier publications. The production of I2- seems fastest for I3- in methanol, followed by I2Br- in acetonitrile and is slowest for I3- in acetonitrile. It appears that vibrational relaxation of newly formed I2- fragments happens on a short time scale of a few hundred femtoseconds from initially excited vibrational states centered around v = 60 to v = 20. This fast relaxation was never directly observed before in solution. After that it relaxes with a slower time constant of approximately 2 ps which is shorter than most former reported values. This biexponential behavior agrees well with earlier molecular dynamics simulations. The dependence of the dissociation product formation on excitation energy, parent anion and solvent is found to be relatively strong. These findings lead us to believe that the photo-induced dissociation of the triatomic anions I3- and I2Br- in solution may very well resemble the gas phase process more than previously thought. In paper IV electronic and vibrational relaxation rates of the cyanine dye Methyl-DOTCI are determined after excitation to high lying electronic states. The measurements are performed with two different excitation wavelengths and in various solvents. They reveal a fast electronic relaxation to the second excited electronic state which subsequently relaxes to the first excited electronic state with a time constant of about 10 ps. This relatively long relaxation time may partly be explained by the badly overlapping electronic wavefunctions obtained from theoretical calculations. Vibrational relaxation proceeds with a similar time constant of 10 ps but shows a marked solvent dependence with faster relaxation rates in alcohol solutions.