Solution processed solar cells offer the promise of a low cost solution to global energy concerns. Colloidal quantum dots are one material that can be easily synthesized in and deposited from solution. These nanoparticles also offer the unique ability to select the desired optical and electrical characteristics, all within the same materials system, through small variations in their physical dimensions. These materials, unfortunately, are not without their limitations. To date, films made from colloidal quantum dots exhibit limited mobilities and short minority diffusion lengths. These limitations imply that simple device structures may not be sufficient to make an efficient solar cell. Here we show that through clever manipulation of the geometric and energetic structures, we can utilize the size-tunability of CQDs while masking their poor electrical characteristics. We further outline the physical mechanisms present within these architectures, namely the utilization of a distributed built-in electric field to extract current through drift rather than diffusion. These architectures have consequently exceeded the performance of legacy architectures such as the Schottky cell. Finally, we discuss some of the limiting modes within these architectures and within CQD films in general including the impact of surface traps and polydispersity in CQD populations. Through the development of these novel architectures, the power conversion efficiency of CQD solar cells has increased from ~3.5% to 7.4%; the highest efficiencies yet reported for colloidal quantum dot solar cells.

Projektet omfattade undersökning och framtagande av ett solcellssystem med förmåga att försörja ett FTX-system i ett flerbostadshus från miljonprogrammet med el. För att kunna bedöma storlek och utformning av komponenter har information tagits genom: Informationssökning via databaser, kurslitteratur och intervjuer Simuleringar av solceller i datorprogrammet PVSYST Modulering av ventilationskanaler i datorprogrammet MagiCAD Syftet var främst att undersöka om det gick att få fram ett teoretiskt fungerande system med avseende på både solceller och ventilation. Beroende på vad resultatet blev skulle även ekonomin i projektet undersökas. Undersökningen visade att det teoretiskt ska gå att installera solceller för elframställning som klarar av att täcka FTX-systemets elbehov på årsbasis. Solcellerna bedöms även producera tillräckligt med el för viss övrig elkrävande utrustning under stora delar av året. Det visade sig även att det skulle gå att få solcellerna ekonomiskt lönsamma om en kalkyltid på 14 år används. Metoden som använts för dessa resultat är noga beskriven och är med små förändringar tillämpbar för ett stort antal byggnader i det svenska byggnadsbeståndet. En viktig slutsats är att om fastighetsägarna kan se 15 år fram i tiden för en investering i solenergi, skulle det innebära inte bara miljömässiga utan även ekonomiska vinster. Det finns redan idag kunnande, teknik och produkter för att utvinna en stor del av fastigheternas elbehov genom solens energi. / The project is a feasibility study of including the installation of solar cells and an FTX ventilation system in the renovation of a Swedish million program multi-family ouse. The question concerns whether the energy production of the PV system can match with the energy consumption of the FTX-system. Input data was obtained from: Databases, literature and interviews. Simulations of photovoltaics modules in the computer program PVSYST Modulation of the vents in the computer program MagiCAD The aim was primarily to investigate whether it was possible to get a theoretical working system. The economy of the project should also be investigated depending on the results. The study showed that it should be theoretically possible to install photovoltaics for electricity generation that is able to cover the FTX system's electricity needs on a yearly basis. The photovoltaics are also expected to produce enough electricity for some other equipment that requires electricity for much of the year. It was also found that it should be possible to get the photovoltaics modules economically viable if a pay-back time of 14 years was used. The method used for these results is thoroughly described and with small changes applicable to a large number of buildings in the Swedish building stock. An important conclusion from the project is that if property owner can see 14 years into the future with an investment in solar energy, there is much to be gained. There are already skills, available technologies and products available in order to recover a large portion of the properties' electricity needs through solar energy.

The shortage of electricity in Nigeria creates a huge gap between demand and supply, making individuals and organizations look for alternatives to obtain regular supply of power. The objective of this study was divided into two parts. First identify the barriers and drivers of the adoption of solar PV systems among home owners and organisations in Rivers State Nigeria. Second, identify the challenges faced by the suppliers of this product for small and large scale suppliers. In order to achieve the objectives of this study, a qualitative research approach was used to carry out the study. A loosely-structured interview and a well-structured interview were used as the method. Findings from this study suggest that the need for a regular power supply was enough to motivate residential adopters to purchase and install solar PVC's and sustainability was a sufficient driver to encourage adoption among organizations interviewed in this study. On the other hand, inadequate policies to encourage subsidies, high cost, difficulty to access finances, high interest rates 20%-22% and short period of payback (3years) for loans involving renewable technology were identified as barriers among residential adopters. Lack of implementation of policies for example, double standard shown by custom officials at ports against the zero tax on importation of renewable energy products set by the government, low level of awareness among the public and lack of organized co-oprative group which provides advisory information to potential adopters were among the barriers identified within this study from interviews conducted with suppliers of solar PV systems.

Solar photovoltaic technology (PV) is a promising clean energy source that assists in climate change mitigation. This is due to solar PV having minimal greenhouse gas emissions when operating compared to burning fossil fuel. Solar PV is also a versatile technology owing to its multiple applications within the built environment. Buildings are responsible for nearly half of the world’s energy consumption; thus, reducing buildings’ energy usage through environmentally-responsive design techniques, in addition to the application of PV products, can not only assist in reducing the energy consumed by buildings, but also contributes to mitigating the adverse effects of climate change. Architects, in particular, play a substantial role in achieving sustainable/environmentally responsive designs; hence, their collaboration is essential. This study investigated American and Canadian architects’ level of awareness and interest in Building Integrated Photovoltaic (BIPV) and Building Applied Photovoltaic (BAPV) products. It also aimed to shed light on the barriers that are responsible for slowing down the adoption process. This study was conducted in two phases: a) a web-based survey questionnaire administered to architects who have an active membership in the Royal Architectural Institute of Canada (RAIC), and the American Institute of Architects (AIA); b) in-depth interviews with architects and key informants in the solar industry. The results indicated that architects are aware of PV benefits and the products available for buildings’ application; however, they lack essential practical knowledge. Furthermore, the results indicated that PV systems’ capital cost is the major perceived barrier to PV adoption in the building industry. Other reported barriers are: the lack of government financial incentives in some jurisdictions, the problematic grid connection process and the lengthy application lead times. Recommendations based on this study’s results include, but are not limited to, providing financial support mechanisms, simplifying the administrative procedures of financial support mechanisms and grid access permits, and offering education and training to architects through architectural associations and academic institutions.

As part of the SUNRISE project (Semiconductors Using Nanostructures for Record Increases in Solar-cell Efficiency), high efficiency, III-V semiconductor, quantum-dot-enhanced, triple-junction solar cells designed and manufactured by Cyrium Technologies Inc. were integrated into OPEL Solar, MK-I, Fresnel-lens-based, 550x concentrating modules carried on a dual axis tracker. Over its first year of operation 1.8 MWh of AC electrical energy was exported to the grid. Measurements of the direct and indirect components of the insolation, as well as the spectral irradiance of light incident on the demonstrator in Ottawa, Canada are presented. The system efficiency is measured and compared to that predicted by a system model to identify loss mechanisms so that they can be minimized in future deployments.

Boronsubphthalocyanines (BsubPcs) are a class of organic semiconducting materials which are relatively underdeveloped in their synthetic methods and organic semiconducting applications. A comprehensive investigation of these materials is explored in a rigorous and strategic manner progressing through each stage of the materials development cycle: materials selection from computational screening, organic/organometallic synthesis of target materials using known methods or by the development of new synthetic methods, physical and chemical analysis of new materials, and device implementation in organic light emitting diodes and organic photovoltaic cells. The result is the formation of new compositions of BsubPc specifically engineered for application as organic semiconductors in devices. Specifically, phenoxy-boronsubphthalocyanine derivatives are investigated starting with a computational study of their molecular orbitals – a property that dictates their function (donor or acceptor behaviour) in organic electronic devices. The nature of the axial phenoxylate is found to vary the energy level of the frontier molecular orbitals minimally, by up to ~0.4 eV while the nature of the BsubPc periphery can shift the energy levels of the frontier molecular orbitals by >1 eV. The differential sensitivity of the axial phenoxylate and the BsubPc periphery becomes a key design element allowing controlled adjustments of the frontier molecular orbitals by peripheral modification and isolating the design physical chemical properties essential to device fabrication to the axial phenoxylate. Subsequently, an investigation into the solubility and sublimability of these materials is performed, which leads to their investigation in OLED and OPV devices. The success from the phenoxy-BsubPcs study has led to the exploration of new chemistry to expand the available axial nucleophiles beyond phenoxylates. Previously unattainable sulphur and nitrogen nucleophiles are synthesised using two methods (1) the condensation of Cl-BsubPc with phthalimides and (2) the activation of Cl-BsubPc using aluminum chloride to access thiols and anilines. The phthalimido-BsubPcs synthesized from this method are incorporated in OLEDs.

Boronsubphthalocyanines (BsubPcs) are a class of organic semiconducting materials which are relatively underdeveloped in their synthetic methods and organic semiconducting applications. A comprehensive investigation of these materials is explored in a rigorous and strategic manner progressing through each stage of the materials development cycle: materials selection from computational screening, organic/organometallic synthesis of target materials using known methods or by the development of new synthetic methods, physical and chemical analysis of new materials, and device implementation in organic light emitting diodes and organic photovoltaic cells. The result is the formation of new compositions of BsubPc specifically engineered for application as organic semiconductors in devices. Specifically, phenoxy-boronsubphthalocyanine derivatives are investigated starting with a computational study of their molecular orbitals – a property that dictates their function (donor or acceptor behaviour) in organic electronic devices. The nature of the axial phenoxylate is found to vary the energy level of the frontier molecular orbitals minimally, by up to ~0.4 eV while the nature of the BsubPc periphery can shift the energy levels of the frontier molecular orbitals by >1 eV. The differential sensitivity of the axial phenoxylate and the BsubPc periphery becomes a key design element allowing controlled adjustments of the frontier molecular orbitals by peripheral modification and isolating the design physical chemical properties essential to device fabrication to the axial phenoxylate. Subsequently, an investigation into the solubility and sublimability of these materials is performed, which leads to their investigation in OLED and OPV devices. The success from the phenoxy-BsubPcs study has led to the exploration of new chemistry to expand the available axial nucleophiles beyond phenoxylates. Previously unattainable sulphur and nitrogen nucleophiles are synthesised using two methods (1) the condensation of Cl-BsubPc with phthalimides and (2) the activation of Cl-BsubPc using aluminum chloride to access thiols and anilines. The phthalimido-BsubPcs synthesized from this method are incorporated in OLEDs.

Environmental and economic factors demand radical advances in solar cell technologies. Organic and polymer photovoltaics emerged in the 1990's that have led to low cost per unit area, enabled in significant part by the convenient manufacturing of roll-to-roll-processible solution-cast semiconductors. Colloidal quantum dot solar cells dramatically increase the potential for solar conversion efficiency relative to organics by enabling optimal matching of a photovoltaic device's bandgap to the sun's spectrum. Infrared-absorbing colloidal quantum dot solar cells were first reported in 2005. At the outset of this study in 2007, they had been advanced to the point of achieving 1.8% solar power conversion efficiency. These devices degraded completely within a few hours’ air exposure. The origin of the extremely poor device stability was unknown and unstudied. The efficiency of these devices was speculated to be limited by poor carrier transport and passivation within the quantum dot solid, and by the limitations of the Schottky device architecture. This study sought to tackle three principal challenges facing colloidal quantum dot photovoltaics: stability; understanding; and performance. In the first part of this work, we report the first air-stable infrared colloidal quantum dot photovoltaics. Our devices have a solar power conversion efficiency of 2.1%. These devices, unencapsulated and operating in an air atmosphere, retain 90% of their original performance following 3 days’ continuous solar harvesting. The remarkable improvement in device stability originated from two new insights. First, we showed that inserting a thin LiF layer between PbS film and Al electrode blocks detrimental interfacial reactions. Second, we proposed and validated a model that explains why quantum dots having cation-rich surfaces afford dramatically improved air stability within the quantum dot solid. The success of the cation-enrichment strategy led us to a new concept: what if - rather than rely on organic ligands, as all prior quantum dot photovoltaics work had done - one could instead terminate the surface of quantum dots exclusively using inorganic materials? We termed our new materials strategy ionic passivation. The goal of the approach was to bring our nanoparticles into the closest possible contact while still maintaining quantum confinement; and at the same time achieving a maximum of passivation of the nanoparticles' surfaces. We showcase our ionic passivation strategy by building a photovoltaic device that achieves 5.8% solar power conversion efficiency. This is the highest-ever solar power conversion efficiency reported in a colloidal quantum dot device. More generally, our ionic passivation strategy breaks the past tradeoff between transport and passivation in quantum dot solids. The advance is relevant to electroluminescent and photodetection devices as well as to the record-performing photovoltaic devices reported herein.

Solution processed solar cells offer the promise of a low cost solution to global energy concerns. Colloidal quantum dots are one material that can be easily synthesized in and deposited from solution. These nanoparticles also offer the unique ability to select the desired optical and electrical characteristics, all within the same materials system, through small variations in their physical dimensions. These materials, unfortunately, are not without their limitations. To date, films made from colloidal quantum dots exhibit limited mobilities and short minority diffusion lengths. These limitations imply that simple device structures may not be sufficient to make an efficient solar cell. Here we show that through clever manipulation of the geometric and energetic structures, we can utilize the size-tunability of CQDs while masking their poor electrical characteristics. We further outline the physical mechanisms present within these architectures, namely the utilization of a distributed built-in electric field to extract current through drift rather than diffusion. These architectures have consequently exceeded the performance of legacy architectures such as the Schottky cell. Finally, we discuss some of the limiting modes within these architectures and within CQD films in general including the impact of surface traps and polydispersity in CQD populations. Through the development of these novel architectures, the power conversion efficiency of CQD solar cells has increased from ~3.5% to 7.4%; the highest efficiencies yet reported for colloidal quantum dot solar cells.

In designing any power generation system that incorporates photovoltaics (PV) there is a basic requirement to accurately estimate the output from the proposed PV array under operating conditions. PV modules are given a power rating at standard test conditions(STC) of 1000Wm-2, AM1.5 and a module temperature of 25 °C, but these conditions do not represent what is typically experienced under outdoor operation. It is well known that different PV technologies have different seasonal patterns of behaviour. These differences are due to the variations in spectral response, the different temperature coefficients of voltage and current and, in the case of amorphous silicon (a-Si) modules, the extra effect of photo-degradation and thermal annealing. In this study a novel method has been used to obtain highly accurate energy output data from six different PV modules representing five different technologies: Single crystal silicon (c-Si). Poly-crystalline silicon (p-Si) (2 modules). Triple junction amorphous silicon (3j, a-Si). Copper indium diselenide (CIS). Laser grooved buried contact (LGBC, c-Si) crystalline silicon. This data set includes all the associated meteorological parameters and back-of-module temperatures. The monitoring system allows the simultaneous measurement of six different modules under long-term outdoor operation, which in turn allows a direct comparison of the performance of the modules. Each of the modules has been deployed for at least one year, which provides useful information about the seasonal behaviour of each technology. This data set ultimately provides system designers and consumers with valuable information on the expected output of these different module types in climates like that of Perth, Western Australia. The second part of the study uses the output data collected to assess and compare output predictions made by some currently available photovoltaic performance prediction tools or methods. These range from a generalised approach, as used in the Australian Standards, to the commercially available software packages that employ radiation, thermal and PV models of varying complexities. The results of these evaluations provide very valuable information, to PV consumers, about how complex PV output prediction tools need to be to give acceptable results.