Marine sedimentary sections across the Paleocene/Eocene (P/E) boundary interval are preserved in the Patala Formation (Upper Indus Basin) and Dungan Formation (Lower Indus Basin), Pakistan. The P/E interval of the Patala Formation is composed of limestone and shale inter-beds indicating deposition on a carbonate platform. The analysis of larger foraminifera across the P/E interval from the Patala Formation (Kala Chitta Ranges), allows the recognition of the Larger Foraminiferal Turnover (LFT). The Larger Foraminiferal Turnover (LFT) observed in the Patala Formation is associated with the PETM (Paleocene Eocene Thermal Maximum) global climatic event and allows the recognition of the P/E boundary in shallow water carbonates of the Indus Basin. This turnover is already reported from other Tethyan sections and from the Salt Range (Upper Indus Basin), Pakistan. The recognition of the LFT allows the inter-basinal and intra-basinal correlation of the P/E interval of the shallow carbonates of the Indus Basin, Pakistan. The available literature on the Paleocene-Eocene Patala and Dungan formations is used to review the planktonic foraminiferal biostratigraphy of the P/E interval. The planktonic foraminiferal zones in the P/E interval of the Indus Basin are identified and reviewed in the light of new international zonations. The planktonic foraminiferal content of the Dungan Formation allows its correlation with the Laki Formation of Rajesthan (India). Four dinoflagellate zones in the P/E interval of the Rakhi Nala section (Lower Indus Basin) are identified and correlated with international and regional zonations. The quantitative analysis of the dinoflagellate cyst assemblages together with geochemical data (i.e., carbon isotopes (organic only), C/N ratio, TOC, carbonate content) is used to reconstruct the palaeoenivronment across the P/E interval. The dinocyst assemblages in general, and the abundance of Apectodinium spp. in particular, indicate the warmer surface water conditions of the global PETM event. The dinocyst assemblages allow the local correlation of the Dungan Formation (part) of the Sulaiman Range with the Patala Formation (part) of the Upper Indus Basin and global correlation of the Zone Pak-DV with the Apectodinium acme Zone of the Northern and Southern hemispheres. The carbon isotopic excursion (CIE) associated with PETM is now globally used to identify the P/E boundary. The CIE in total organic carbon (i.e., δ13CTOC = -28.9‰) and total fine fraction organics (i.e., δ13CFF= 26.4‰) from the Indus Basin is reported for the first time. This CIE record from the Indus Basin is compared with other Tethyan sections from Egypt and Uzbekistan and is also compared with the global sections from USA (Northern hemisphere) and from New Zealand (Southern hemisphere).

A gradual rise in Earth's surface temperature marks a transition from the late Paleocene to the early Eocene ca. 58-51 Ma. Paleocene/Eocene boundary (∼55.5 Ma) sediments deposited in the midst of this slow warming ubiquitously reveal evidence for a massive isotopically light carbon injection and an associated rapid but transient global warming event, or hyperthermal, that has been termed the Paleocene Eocene Thermal Maximum (PETM) and attributed to a carbon injection from multiple potential sources. The PETM has gained importance over the past two decades as a potential geologic analog to the modern anthropogenic carbon injection and climate change. However significant questions surrounding the nature of the carbon injection at the onset of the PETM remain. The Clarence River valley, located in the Marlborough region, South Island, New Zealand, contains a series of outcrops of lithified late Paleocene to early Eocene sediments originally deposited on a paleo-slope margin. Within these sections, the Lower Limestone Member of the Amuri Limestone Formation records the interval of interest. A Lower Limestone prominent recessed unit consisting of multiple marl-rich beds and recording a pronounced negative carbon isotopic excursion (CIE) marks the PETM at sections that have been bisected by tributaries to the Clarence River, including Mead Stream and Dee Stream. Here I detail and discuss Clarence valley Lower Limestone sections and relate these records to global trends with an emphasis on adding constraints to the PETM carbon injection. Specifically, I document the lithologic and carbon isotopic expression of the PETM and two younger paired sets of early Eocene events that, similar to the Mead Stream and Dee Stream PETM sections, reveal negative CIEs and expanded marl-rich units coincident to identical CIEs and condensed carbonate dissolution horizons in deep-sea sections. I further quantify the abundance of bioturbating macrofauna trace fossils through the PETM at both Mead Stream and Dee Stream and argue that New Zealand margin intermediate waters became hypoxic precisely coincident to the PETM carbon injection. In concert, these findings suggest a PETM carbon addition mechanism capable of both diminishing intermediate water dissolved oxygen and of repeated early Eocene injections. / U.S. National Science Foundation (NSF); Joint Oceanographic Institutions (JOI), Inc.

Here we investigate sedimentological responses to past climate change in shallow to deep marine depositional environments. Our primary study spans from the Late Pliocene to the Pleistocene (3.3 to 0.7 Ma), and features results from two International Ocean Discovery Program (IODP) Sites U1525 and U1524. Each of these sites is discussed in separate chapters here (Chapters 1 and 2). This interval experienced the change from the warming of the Late Pliocene, known as the Mid-Piacenzian Warming Period, to the Pleistocene cooling. This shift significantly impacted the expansion of the West Antarctic Ice Sheet, sea ice/polynya formation, and, notably, the genesis of Antarctic Bottom Water (AABW), a crucial component of the global thermohaline circulation. In Chapter 1, we propose that turbidite currents, arising from the formation of dense shelf water (DSW) in the Ross Sea (a precursor to AABW), leave a distinct record in the levees of Hillary Canyon. This canyon acts as a conduit, channeling DSW into the deep ocean and contributing to AABW production. By analyzing turbidite beds based on their frequency, thickness, and grain size, we gain insights into the historical occurrence and magnitude of these currents. Furthermore, we explore the influence of factors such as shelf availability and sea ice/polynya formation within the broader climate context of AABW formation. Chapter 2 shifts its focus to the sedimentological variability from shelf-to-slope along Hillary Canyon. This chapter examines the turbidite record associated with AABW formation within the shared timeframe (2.1 to 0.7 million years ago) between IODP Sites U1524 and U1525, and the impact of along slope currents and other processes in the sedimentary deposition and transport. The second study interval (Chapter 3), focuses on the regional sedimentological response proximal to a hydrothermal vent complex associated with the Paleocene-Eocene Thermal Maximum (PETM; ca. 56 Ma), a global warming event during which thousands of Gt C was released into the ocean-atmosphere on Kyr timescales. IODP Site U1568, strategically located near the hydrothermal vent complex and part of a broader drilling transect in the Modgunn Arch, North Atlantic, is the main study subject. This site's proximity to the vent complex offers a distinctive environment for refining our understanding of stratigraphy and sedimentology within the PETM. We achieve this through a comprehensive analysis of grain size and composition, coupled with a comparison to XRF data. Our findings show that the timing between the onset of the PETM and the response of the sedimentary system to the warming, reflected in the grain size coarsening after the start of the PETM, is not synchronous. Notably, the transition from a marine to a more terrestrial composition predates this shift in grain size, aligning with the PETM onset instead. / Doctor of Philosophy / Deep-marine core records are invaluable sources of sedimentological information that provide insights into the ocean's response to past climates. These cores, extracted from the deep-ocean floor, contain layers of sediment that accumulate over time because of the different processes that occur in the ocean. Analyzing these sediments, by looking at their physical characteristics like how frequently are they deposited, the thickness of the layers, their grain size, and their composition helps to reconstruct past environmental conditions and understand how the oceans have responded to climatic changes. This dissertation focuses on studying the record of two main processes. The first one is the sedimentary record left behind by the formation of Antarctic Bottom Water (AABW), one of the coldest (-1°C), deepest (> 2000 meters below sea level), and densest water masses in the ocean. AABW is a key component of the global ocean circulation system, often referred to as the "global conveyor belt" or the thermohaline circulation. This circulation pattern plays a crucial role in redistributing heat, salt, and nutrients around the world's oceans. AABW is formed near Antarctica through a process that begins with the cooling and sinking of surface waters near the continent. As these waters sink, they become denser and eventually form AABW, filling the deep ocean basins around Antarctica. The dense water flows from the surface to the bottom of the ocean forming turbidity currents. These turbidity currents, dense plumes of water and sediments, flow down submarine conduits, such as Hillary Canyon in the Ross Sea, Antarctica, leaving a sedimentary record in the levees or flanks, called turbidites. The turbidite sequences in sediment cores can reveal information about the frequency and magnitude of these currents, providing insights into the sediment transport processes in deep-marine settings, and for this work, the history of the AABW formation over the last 3.3 Ma. This study will help to understand what are the main controls for AABW formation across different climates in the past, and how we project this into the future climate scenarios. In the second part of the study (Chapter 3), we look at the sedimentary record of a warming event that happened around 56 million years ago. This event, known as the Paleocene-Eocene Thermal Maximum (PETM), involved a significant amount of carbon being released into the air and oceans over thousands of years (150,000 to 200,000). Our focus is IODP Site U1568, located near a submarine hydrothermal vent, and part of a larger drilling transect in the North Atlantic's Modgunn Arch. The vent's unique location provides a crucial perspective for understanding how the system responded to the warming during the Paleocene-Eocene Thermal Maximum (PETM). This warming event was triggered by the release of carbon into the atmosphere, with the vent serving as one of the conduits for this release. To understand this, we studied the grain size and content of the sediment, and compared that with XRF data. Changes in grain size serve as indicators of shifts in the energy of the environment – coarser grains signify a more energetic system. Warmer weather, for instance, can increase precipitation, leading to more erosion and sediment influx into the basin. This influx also brings in more materials from the land, as evidenced by the presence of microfossils and plant fragments. Our discoveries indicate that the sedimentary system responded gradually to the PETM, as reflected in the coarsening of grain size after the PETM's onset. Notably, the transition from a marine to a more terrestrial composition occurred before the change in grain size, aligning more closely with the initiation of the PETM itself.

The Late Cretaceous–early Paleogene is the most recent period of Earth history with a dynamic carbon cycle that experienced sustained global greenhouse warmth and can offer a valuable insight into our anthropogenically-warmer future world. Yet, knowledge of ambient climate conditions and evolution of the carbon cycle at this time, along with their relation to forcing mechanisms, are still poorly constrained. In this thesis, I examine marine sediments recovered from the South Atlantic Walvis Ridge (ODP Site 1262) and Indian Ocean Ninetyeast Ridge (IODP Site U1443 and ODP Site 758), to shed new light on the evolution of the climate and carbon cycle from the Late Maastrichtian through to the Early Eocene (~67.10–52.35 Ma). The overarching aims of this thesis are: 1) to identify the long-term trends and principle forcing mechanisms driving the climate and carbon cycle during this time period, through construction of 14.75 million-year-long, orbital-resolution (~1.5–4 kyr), stratigraphically complete, benthic stable carbon (δ13Cbenthic) and oxygen (δ18Obenthic) isotope records; 2) to investigate in more detail the climatic and carbon-cycle perturbations of the Early–Middle Paleocene (e.g., the Dan-C2 event, Latest Danian Event and the Danian/Selandian Transition Event) and place these in their proper (orbital) temporal context; 3) to investigate the Late Maastrichtian warming event and its relationship to the eruption of the Deccan Traps Large Igneous Province, as well as its role (if any) in the subsequent Cretaceous/Paleogene (K/Pg) mass extinction; 4) to provide the first orbital-resolution estimates of temperature and carbonate chemistry variability from the low latitude Indian Ocean spanning the Late Paleocene–Early Eocene, through analysis of trace element and stable isotope data from multiple foraminiferal species. Taken together, the results presented in this thesis provide a critical new insight into the dynamic evolution of the climate and carbon cycle during the greenhouse world of the early Paleogene, and shed light on the potential forcing mechanisms driving the climate and carbon cycle during this time.

The Paleocene-Eocene Thermal Maximum (PETM) (55 million years ago) stands as the largest in a series of extreme warming (hyperthermal) climatic events, which are analogous to the modern day increase in greenhouse gas concentrations. Orbitally triggered (Lourens et al., 2005, Galeotti et al., 2010), the PETM is marked by a large (-3‰) carbon isotope excursion (CIE). Hypothesized to be methane driven, Zeebe et al., (2009) noted that a methane based release would only account for 3.5°C of warming. An isotopically heavier carbon, such as that of soil and C3 plants, has the potential to account for the warming and CIE (Zachos et al., 2005). During the early Eocene, high latitude surface temperatures created favorable conditions for the sequestration of terrestrial carbon. A large untapped terrestrial carbon reservoir, such as that within permafrost regions, contains the potential, if degraded, to account for the CIE as well as the global temperature increase observed during the PETM. Using an fully integrated climate model (GENESIS) with fully coupled vegetation model (BIOME4), we show that adequate conditions for permafrost growth and terrestrial carbon sequestration did exist during the lead up to the PETM. By calculating the flux of net primary production (NPP) and soil respiration (Rs), we demonstrate that the biodegradation of permafrost-based carbon reservoirs had the potential to drive the PETM. Furthermore, we show that the natural planetary response to unbalanced carbon reservoirs resulted in the terrestrial sequestration of atmospheric carbon via permafrost regeneration, yielding a vulnerable carbon reservoir for the subsequent hyperthermal.