Les modèles développés afin de prédire le comportement des Alliages à Mémoire de Forme (AMF) sont généralement basés sur une description phénoménologique simplifiée de l’activation des variantes de martensite sous chargement thermomécanique. Cette étude a pour objectif de modéliser et de caractériser par nanoindentation la formation discrète des plaquettes de martensite à l’échelle nanométrique. Un nouveau critère, nommé critère de Patel-Cohen d’indentation, est proposé afin de décrire l’activation de la première variante de martensite sous l’indent et sa transformation inverse. L’évidence de transformation martensitique est observée sur les courbes d’indentation par l’apparition successive d’évènements de type « pop in » et « pop out » lors, respectivement, de la charge et de la décharge. Cela met en évidence la discontinuité spatio-temporelle de l’activation et de la propagation de la transformation martensitique à l’échelle nanométrique. L’émission de dislocations dans le nickel pur a été étudiée en tout premier lieu afin de valider et la procédure de nanoindentation utilisant un indent Berkovich et le calcul des facteurs de Schmid d’indentation décrivant l’activation de « pop ins » correspondant à l’activation et à la propagation de dislocations. Un bon accord est trouvé entre les essais réalisés sur un AMF CuAlBe superélastique et la dépendance théorique à l’orientation cristallographique des charges de « pop-ins » et de « pop outs » prédite par le critère de Patel-Cohen d’indentation introduit dans cette étude / Constitutive models developed to predict Shape Memory Alloys (SMA) behavior are often based on a simplified phenomenological description of martensite variant activation under thermomechanical loading at the micro scale. This study aims at modeling and characterizing by nanoindentation the discrete variant activation events at the nano scale. A new criterion is proposed to describe the first martensite variant activation beneath the indenter. Evidence of discrete martensitic transformation is observed during nanoindentation by the successive occurrences of pop-in and pop-out load events on the force versus displacement curve during respectively loading and unloading. Thus, the spatial-temporal discontinuity of phase transformation activation and propagation is highlighted at the nano scale with the introduction of an indentation Patel-Cohen factor for both forward austenite-martensite and reverse phase transformations. Dislocation emission in pure nickel is first studied to validate both the nanoindentation testing procedure using a Berkovich indenter and the calculations of indentation Schmid factors to describe excursion bursts corresponding to dislocation activation and propagation. Good agreement is found between nanoindentation tests performed on a superelastic CuAlBe SMA and theoretical crystallographic dependence of pop-in and pop-out loads predicted by the new introduced indentation Patel and Cohen factor

CoordenaÃÃo de AperfeiÃoamento de Pessoal de NÃvel Superior / Neste trabalho, um estudo da influencia da seleÃÃo de variantes sobre a cristalografia apÃs a transformaÃÃo martensÃtica no Maraging foi feito. O estudo cobriu a transformaÃÃo sob deformaÃÃo elÃstica e tambÃm sob deformaÃÃo plÃstica. No aÃo Maraging, austenita se transforma em martensita eu uma temperatura em torno de 200ÂC, nÃo importando a velocidade de resfriamento. Para simular a transformaÃÃo durante a deformaÃÃo elÃstica, ensaios de traÃÃo foram feitos em um forno acoplado a uma mÃquina de ensaios universais com uma tensÃo aplicada abaixo do limite de escoamento do material. A amostra foi aquecida atà 850ÂC, o forno foi aberto e a amostra resfriada ao ar sob tensÃo constante. Para estudar a influencia da deformaÃÃo plÃstica antes da deformaÃÃo, amostras foram deformadas plasticamente na temperatura acima da Ms (temperatura de inÃcio da martensita), a forÃa externa atuando sobre a amostra foi removida e o material sofreu a transformaÃÃo martensÃtica por resfriamento ao ar. Figuras de pÃlos foram medidas por EBSD (Electron Back-Scatter Diffraction) em ambas as condiÃÃes e comparadas com as figuras de pÃlos calculadas assumindo os modelos de Patel-Cohen e Taylor-Bishop-Hill. A orientaÃÃo da austenita mÃe foi obtida por envelhecimento na temperatura de 650ÂC e pelo uso de grÃos austenÃticos reconstruÃdos matematicamente. Os resultados mostraram que o modelo de Patel-Cohen foi mais adequado para a deformaÃÃo elÃstica enquanto que Taylor-Bishop-Hill foi melhor para a deformaÃÃo plÃstica. / In this work a study of the influence of variant selection on the crystallography after martensitic transformation in Maraging was studied. The study covered both the transformation under elastic deformation and also during plastic deformation. In Maraging steel, austenite becomes martensite at a temperature around 200oC regardless of the cooling speed. To simulate the transformation during elastic deformation, a tensile test was performed in a furnace attached to a universal testing machine with an applied stress below the yield strength of the material. The specimen was heated to 850o C, the furnace was opened and the sample cooled in air under a constant stress. To study the influence of plastic deformation before transformation, samples were plastically deformed in a temperature above Ms (martensite start temperature), the external force acting on the sample was removed and the material was allowed to transform into martensite by cooling in air. Pole figures were measured by EBSD (Electron Back-Scatter Diffraction) in both conditions and compared with calculated pole figures assuming Patel-Cohen model and Taylor-Bishop-Hill model. The orientation of the parent austenite was obtained either by reversing the austenite by heating at 650  C and by using the mathematically reconstructed austenite grains. Results showed that Patel-Cohen model were more suitable to elastic deformation while Taylor-Bishop-Hill model was more appropriated to plastic deformation.

Immigration policy and tradition dovetail in their impact on the social organization of immigrant communities, linking the material and non-material aspects of gender. I focus on Asian Indian Patels, who dominate the budget motel business in the United States. I conducted semi-structured interviews with Patel men, women, and teenagers. I stayed overnight in the motels to observe families at work. I was almost always invited to prepare and share a meal, so I observed families at home. My analysis is based on transcribed interviews with participants, fieldnotes, observations, community publications, and information from three key contacts. Most Patels enter the U.S. under family reunification rules in a chain migration. These rules do not recognize families as labor; therefore a majority of documented immigrants are exempt from labor certification. Traditions define Patel women as housewives. The nature of motel work allows women to contribute their labor full-time and still remain housewives: they are not recognized as workers. Community financing and family labor, both escapes from the market economy, allow for the economic success of Patels. When families take on subsequent links in the chain migration, they must meet the costs of migration for new immigrants, and maintain traditional gender hierarchy. When they are the last link in the chain, there is a challenge to this hierarchy. In the second generation, when they remain in the motel business, Patels maintain traditional gender hierarchy. When either partner is linked to the labor market, there is a challenge to traditional gender hierarchy. / Ph. D.

The two-phase MD technique employed in this work determines the liquid and vapor phase densities from a histogram of molecular densities within phase clusters in the simulation cell using a new Monte Carlo (MC) sampling method. These equilibrium densities are then fitted in conjunction with known critical-point scaling laws to obtain the critical temperature, and the critical density. This MC post-processing method was found to be more easily implemented in code, and it is efficient and easily applied to complex, structured molecules. This method has been successfully applied and benchmarked for a simple Lennard-Jones (LJ) fluid and a structured molecule, propane. Various degrees of internal flexibility in the propane models showed little effect on the coexisting densities far from critical point, but internal flexibility (angle bending and bond vibrations) seemed to affect the saturated liquid densities in the near-critical region, changing the critical temperature by approximately 20 K. Shorter cutoffs were also found to affect the phase dome and the location of the critical point. The developed MD+MC method was then used to test the efficacy of two all-atom, site-site pair potential models (with and without point charges) developed solely from the energy landscape obtained from high-level ab initio pair interactions for the first time. Both models produced equivalent phase domes and critical loci. The model's critical temperature for methanol is 77 K too high while that for 1-propanol is 80 K too low, but the critical densities are in good agreement. These differences are likely attributable to the lack of multi-body interactions in the true pair potential models used here. Lastly, the transferability of the ab initio potential model was evaluated by applying it to 1-pentanol. An attempt has been made to separate the errors due to transferability of the potential model from errors due to the use of a true-pair potential. The results suggested a good level of transferability for the site-site model. The lack of multi-body effects appears to be dominant weakness in using the generalized ab initio potential model for determination of the phase dome and critical properties of larger alcohols.