Large δ13C excursions present at the Permian-Triassic boundary are thought to indicate a considerable release of isotopically light carbon into the atmosphere (Retallack and Jahren, 2008). The largest of these excursions (-22.2 ‰) was measured in organic matter from Antarctica (Retallack and Jahren, 2008). Antarctic coals are known to be heavily intruded by Jurassic dikes and sills, and the δ13C values of the organic matter may have been influenced by later thermal alteration. In order to evaluate the influence of rank and maceral content on isotopic composition, a total of 335 samples described as Permian-age "coal" were obtained primarily from the United States Polar Rock Repository. Most of the organic matter from Permian coal seams in Antarctica has been extensively altered after burial by localized high heat flow and, in some cases, contact metamorphism associated with dikes and sills; this thermal alteration has likely changed the δ13C values of the organic matter. The rank of the samples prior to intrusion is estimated to be medium to high volatile bituminous. The majority of the samples analyzed (96%) have been altered to above low volatile bituminous rank based on vitrinite reflectance, most (83%) are semi- to meta-anthracites, and a few have been altered to anisotropic cokes. The samples do not follow the typical burial maturation geochemical track, as they are higher in volatile matter (%, daf) and O (%, dmmf), and lower in H (%, dmmf) than coals of the same rank that have undergone normal burial maturation. Carbon stable isotopic data indicate a weak correlation with coal rank as well as with the amount of pyrolitic carbon. Although the isotopically lightest samples measured in this study are located within what is interpreted to be the Permian-Triassic boundary, the effects of thermal alteration of organic matter on δ13C values must be considered in any interpretation of Permian-Triassic atmospheric conditions.

No description available.

Call number: LD2668 .T4 1965 L77 / Master of Science

No description available.

The Alleghanian orogeny was a collision between the Gondwanan and Laurentian continents that produced the Pangean supercontinent. Mechanical and kinematic models of collisional orogens are believed to follow a critical taper geometry, where the tectonic imbrication of continental crust begins nearest to the edge of continental plate and advances toward the craton in a break- forward sequence. Studies of shear zones within the Alleghanian collisional orogen, however, suggest that most of the early deformation was translational. Propagation of craton-directed thrusts into the foreland did not occur until the latest Pennsylvanian in the southern Appalachians, and the middle-late Permian in the central Appalachians. Radiometric sedimentary provenance proxies have been applied to the late Mississippian-early Permian strata within the Appalachian foreland basin to determine the crustal composition and structural evolution of the orogen during the continental collision. U-Pb ages of detrital zircons from the early to middle Pennsylvanian sandstones suggest that most of the detritus within the Appalachian basin was recycled from Mesoproterozoic basement and Paleozoic strata of the Laurentian margin. The presence of Archean and late Paleoproterozoic age detrital zircons is cited as evidence of recycling of the Laurentian syn-rift and passive-margin sandstones. Detrital zircon ages from early-middle Permian-age sandstones of the Dunkard Group do not contain any Archean or Paleoproterozoic detrital-zircon ages, implying a source of sediment with a much more restricted age population, possibly the igneous and metamorphic internides or middle Paleozoic sandstones from the Appalachian basin. The persistance of 360-400 Ma K/Ar ages of detrital white mica suggest that the sediment was supplied from a source that was exhumed during the Devonian Acadian orogeny. Detrital-zircon and detrital-white-mica ages from Pennsylvanian-age sandstones indicate that the late Paleozoic orogen did not incorporate any significant synorogenic juvenile crust. The 87Sr/86Sr ratios of middle Pennsylvanian-early Permian lacustrine limestones within the Appalachian basin show a slight enrichment through time, suggesting that labile 87Sr-rich minerals in the Alleghanian hinterland are being exposed. Stable isotopic data from the lacustrine limestones also corroborates that the Appalachian basin became much more arid through time.

Student Number : 9902718G - MSc dissertation - School of Geosciences - Faculty of Science / The Late Permian (251.0 ± 0.4 Ma) mass extinction is universally acknowledged as the most consequential of the five major Phanerozoic mass extinctions. More than 90% of marine species, ~70% of terrestrial vertebrates, and ~90% of plant life were lost in a very short interval. The nature of the Permian-Triassic (P-Tr) boundary and the cause of the mass extinction associated with it have been the subject of extensive international debate. Possible causes for the P-Tr extinction include asteroid/comet impact, oceanic anoxia, volcanism, methane clathrate dissociation, or combinations of these causes. Geochemical studies of the P-Tr boundary have traditionally been focused on the marine realm, as the boundary in continental sections is typically difficult to pinpoint. One continental setting of the P-Tr boundary that has, however, received much attention is that in the main Karoo Basin, South Africa. The Karoo Basin is a large retro-arc foreland basin which accumulated sediment from the Carboniferous (300 Ma) through to the Early Jurassic (180 Ma) in southwestern Gondwana. Mineralogical and geochemical investigations across two palaeontologically well-constrained continental P-Tr boundary sections at Commando Drift Dam and Wapadsberg in the southern Karoo Basin of South Africa have been undertaken in order to aid in our understanding of this extinction event. The Commando Drift Dam section is also constrained palaeomagnetically. There is a change in paleosol colour across the P-Tr boundary from green-grey to red-brown, which is believed to reflect a change of oxidizing conditions at the P-Tr boundary. Quartz grains were examined for possibly impact-produced microdeformation features, but these were not found. Iridium concentrations are below the detection limit (by instrumental neutron activation analysis) and the sections could not be evaluated as to whether any significant enrichment has taken place at the P-Tr boundary. Major element chemical profiles are dominated by the signatures of carbonate nodular horizons in both sequences. Iron contents (and accompanying siderophile element abundances) increase across the palaeontologically-defined P-Tr boundary, followed by a decrease thereafter. The major element concentrations, together with the effects of weathering, largely control trace element distribution. Carbon isotopic results from the Commando Drift Dam section show a gradual decrease in values before the P-Tr boundary, with a larger negative excursion at the P-Tr boundary. Above the boundary, gradual recovery to initial ratios is observed, followed by another gradual decrease in values to the palaeomagnetically defined boundary. No evidence supporting an extraterrestrial impact extinction mechanism has been found. Rather, the carbon isotope data from this study support two gradual palaeoclimatic changes separated by a sudden change in the carbon isotopic content of the atmosphere. The size and nature of these excursions support the addition of large amounts of anoxic material into the atmosphere. This is proposed to have been caused by the multiple influx of carbon dioxide, methane and other greenhouse gases at various times and by different mechanisms. Such a release of carbon dioxide, methane and other greenhouse gases could have been caused by the coincident volcanic event (the formation of the Siberian Traps) and the episodic release of methane clathrates.

The end-Permian extinction at 252 Ma is widely regarded as the most severe of the Phanerozoic mass-extinctions and enabled the evolution of the modern carbon cycle and ecosystem structure. The cause of the extinction is still debated but the synergistic pressures of global climate change, such as anoxia and ocean acidification, were clearly important. The extinction occurred in two phases and is marked by a uniquely protracted recovery period of ~ 5 Myrs where diversity fails to reach pre-extinction levels until the Middle Triassic. This period is characterized by an unstable global carbon cycle, secondary extinctions, reef, chert and coal gaps, and changes in the carbonate factory from reef to microbial and abiotic dominated deposition. This thesis focuses on using geochemical data from the Arabian Margin to investigate the carbon cycle record and the links between kill mechanisms and carbon cycle dynamics. A new record of carbon cycling is presented for the Tethys in the form of a carbon isotope record for the entire Early Triassic from the Musandam Peninsula, United Arab Emirates (UAE). The Musandam carbon isotope record can be broadly correlated with global isotopic events but also resolves additional secondary excursions. These new short-lived events are probably related to the occurrence of the more widely recognized Early Triassic excursions, and may represent fluctuations in the driving mechanisms superimposed on the continued instability of the global carbon cycle in the aftermath of the end-Permian extinction. To unravel palaeo-depositional redox conditions this work utilizes geochemical proxies based on Fe systematics (Fe-speciation). To date, however, these proxies have only been calibrated in relation to modern and ancient siliciclastic marine sediments. This clearly limits the use of the Fe-speciation proxy, particularly in relation to carbonate-rich sediments and rocks. This thesis explores the use of Fe-speciation in carbonates using compiled literature and new data from modern oxic and anoxic settings. This new assessment expands the utility of Fe-based redox proxies to also incorporate carbonate-rich rocks that contain significant total Fe (>0.5 wt%), providing care is taken to assess possible impacts of diagenetic processes such as dolomitization. Based on this calibration work Fe-speciation is used to reconstruct the redox structure for the Arabian Margin mixed carbonate and clastic sediments, from the late Permian to the Middle Triassic. Fe-S-C systematics are utilized to identify the spatial and temporal dynamics of anoxia for a Neo-Tethyan shelf-to-basin transect. The unique spatial resolution afforded by this transect allows a direct link to be drawn between biodiversity, carbon cycling and anoxic events. For the first time we can directly observe a switch from deep-ocean dominated anoxia to a dynamic anoxic wedge at the end-Permian extinction. Additionally the data suggest that ferruginous conditions (anoxic non-sulphidic) were dominant in the Tethyan Ocean throughout the Early Triassic, proposing that euxinia was restricted regionally with potential implications for nutrient recycling, carbon cycle models and driving mechanisms. Redox dynamics may have had important implications for the wider carbonate cycle. These two themes are particularly inter-related with regards to oceanic alkalinity and pH. This thesis presents the first shallow water boron isotope record for the Permian Triasssic Boundary, used as a proxy for pH. The record demonstrates some unexpected results; firstly a sudden increase in pH is observed, prior to the first phase of the extinction and interpreted to reflect alkalinity supply from the development of slope anoxia. Secondly there is no evidence for an acidification event at the first phase of the extinction where pH remains stable. A rapid acidification event is, however, seen in the earliest Triassic, contemporary to the second phase of the mass extinction, but delayed compared to the main negative carbon isotope excursion that indicates the main phase of Siberian Trap volcanism. These events may be explained by dramatic changes in ocean the ocean’s buffering capacity linked to changes in alkalinity supply and the carbonate factory.

A significant amount of palynological work has been done on southern African coal seams in the Ecca Group, but as yet there is little consensus on how these areas relate to each other. This study investigated the palynology of a coal seam from Mmamantswe (Mmamabula area), Botswana, approximately 70 km north-east of Gaborone. A total of 124 samples were taken from two borehole cores and subjected to acid preparation, oxidation and acetolysis. Coal samples were found to be barren of palynomorphs. Fifty carbonaceous mudstones and siltstone samples yielded twenty-two productive samples. A thermal alteration index of 3.0-3.5 was assigned for the sediments. Palynomorph diversity was high, with 64 genera and 90 species present, dominated by trilete and alete spores. This indicates a parent flora of mostly lower order lycopods, sphenophytes and ferns. Non-taeniate bisaccate and monosaccate pollens were scarce, and striates extremely rare (only two species), suggesting an autochthonous origin for the coal swamp. The Mmamantswe core was sub-divided into five microfloral assemblage zones. A transition from monosaccate dominance in the lower part of the core, to equal numbers of monosaccates and non-taeniate bisaccates in the upper part of the core, was seen. As the Mmamantswe palynoflora possesses elements of both the Late Carboniferous glacial floras and the mid-Permian coal floras, it is thought to represent a cross-over assemblage dating to soon after the Permo-Carboniferous boundary (Sakmarian and Early Artinskian). The Mmamantswe assemblage can be correlated with Assemblage Zones II and III of Falcon (1975a); Biozones B and C of MacRae (1988); and Zones 1, 2 and 3 of Anderson (1977) but does not fit well into any existing biozonation. The Mmamantswe palynoflora was most similar to that of Milorgfjella, Dronning Maud Land, Antarctica (Larrson et al. 1990) and the No. 2 Seam, Witbank, South Africa (Falcon 1989). Taphonomic controls on palynomorph preservation suggest that future studies should also attempt to focus on Permian sediments not containing coal, as microfloral assemblages from coal seams tend to be autochthonous, and subject to local climatic influences. Accordingly they are not as useful for inter-basinal correlation across Gondwana.

No description available.

The Shattuck Sandstone Member of the Guadalupian age Queen Formation was deposited in back-reef environments on a carbonate platform of the Northwest Shelf (Permian Basin, New Mexico, USA) during a lowstand of sea level. At Mesa Queen Field, the Shattuck Sandstone is a sheet-like sand body that averages 30 ft (9.1 m) in thickness. The Shattuck Sandstone includes deposits of four major siliciclastic environments: (1) fluvial sandflats, (2) eolian sand sheets, (3) inland sabkhas, and (4) marine-reworked eolian sands. Fluvial sandflat deposits are further subdivided into sheetflood, wadi plain, and river-mouth deposits. Dolomites, evaporites, and siliciclastics that formed in adjacent coastal sabkha and lagoonal environments bound the Shattuck Sandstone from above and below. The Shattuck Sandstone is moderately- to well-sorted, very fine-grained subarkose, with a mean grain size of 98 μm (3.55φ). Eolian sand sheet, wadi plain, and marine-reworked eolian facies comprise the productive reservoir intervals. Reservoir quality reflects intragranular and intergranular secondary porosity formed by partial dissolution of labile feldspar grains, and pore-filling anhydrite and dolomite cements. Vertical successions and regional facies patterns support previous interpretations that these deposits formed during a sea-level lowstand and early stages of the subsequent transgression. Facies patterns across the shelf indicate fluvial sandflats prograded over coastal and continental sabkhas, and eolian sand deposition became more common during sea-level fall and lowstand. During subsequent transgression, eolian sediments in the upper portion of the Shattuck Sandstone were reworked as coastal and lagoon environments became reestablished on the inner carbonate platform.