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An image analysis method has been developed for Sandvik to determine phasecompositions and characteristic length of the binding phase in cubic Boron Nitride(cBN)-composites with low contents of cBN (35-75%).The method consists of taking pictures with a Scanning Electron Microscope,gathering elemental data with X-ray Diffraction (XRD) as well as Energy-dispersiveX-ray Spectroscopy (EDS) and finally using a Matlab program developed for this workto calculate phase compositions and statistical data from the characteristic length ofthe binding phase.Using these methods four different phases were identified in the samples: Blackparticles, most likely made of cBN. A dark gray phase around the black particles, thatconsists of Al-compounds. A light grey binding phase, consisting of TiN or Ti(C,N).Finally there were small traces of white particles which were identified as a product ofabrasive action on cermet milling bodies added during the milling.Mean value, standard deviation and median of the characteristic length of the bindingphase was calculated. For all samples the median value was consistent, sometimeseven being identical for the analyzed sites. This indicates that the binding phase wasevenly distributed across almost all samples.

This thesis deals primarily with the simulation and analysis of shunt active power filters (APF) on a three-phase power distribution system possessing a harmonic generating load. The shunt active power filters are analyzed based on effective total harmonic distortion (THD) levels and response to changing dynamics. These results are derived from the simulation of a pulse-width modulation (PWM) controlled voltage source inverter (VSI) with a capacitor connected to the DC side of the VSI. The primary difference between individual simulations is the particular control law implemented in the shunt APF.

Multiple scattering effects from bubble clouds are investigated in this study. A high performance, general purpose numerical tool for multiple scattering calculations is developed. This numerical tool is applied in three computational scenarios in this study. The total scattering cross section of a bubble cloud is investigated. Numerical results indicate that the resonant frequency of the bubble cloud is much lower than that of a single bubble. The variation of resonant frequency of multiple scattering is also studied. It is found that the resonant frequency decreases as the number of bubbles increases, or as the void fraction of the bubble cloud decreases. Phase distributions of bubble oscillations in various multiple scattering scenarios are presented. It is found that, at resonance, the bubbles synchronize to the same phase, which is indicative of the lowest mode of collective oscillation. At wave localization, half of the bubbles oscillate at phase 0 while the other half oscillate at phase Pi. An intuitive interpretation of this behavior is given.

Distribution load flow and state estimation are two important functions in distribution energy management systems (DEMS) and advanced distribution automation (ADA) systems. Distribution load flow analysis is a tool which helps to analyze the status of a power distribution system under steady-state operating conditions. In this research, an effective and comprehensive load flow algorithm is developed to extensively incorporate the distribution system components. Distribution system state estimation is a mathematical procedure which aims to estimate the operating states of a power distribution system by utilizing the information collected from available measurement devices in real-time. An efficient and computationally effective state estimation algorithm adapting the weighted-least-squares (WLS) method has been developed in this research. Both the developed algorithms are tested on different I testeeders and the results obtained are justified.

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Orientador: Michel Daoud Yacoub / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Eletrica e de Computação / Made available in DSpace on 2018-08-06T02:52:07Z (GMT). No. of bitstreams: 1 Fraidenraich_Gustavo_M.pdf: 1838522 bytes, checksum: 4099008fa7bbc89eb2642a891bd64509 (MD5) Previous issue date: 2006 / Resumo: Neste trabalho, uma nova distribuição de probabilidade amplamente geral, a distribuição a-?-?-µ, é proposta. Esta distribuição contempla como casos particulares várias outras distribuições conhecidas na literatura, tais como Rayleigh, Rice, Nakagami-m, Hoyt, Weibull, a-? (Gamma Generalizada) ?-µ e ?-µ. Por conta de sua generalidade, todos os mais importantes ambientes de desvanecimento de curto prazo são modelados por esta distribuição. Além de prover a função densidade de probabilidade para o modelo a-?-?-µ, os momentos e a função cumulativa de probabilidade também são encontrados. Este modelo geral é então especializado para quatro casos particulares, para os quais distribuições mais simples, mas ainda gerais, são encontradas: a a-?-µ, a-?-µ, ?-? Simétrica e ?-? Assimétrica. Para esses casos, estimadores práticos baseados nos momentos são deduzidos. A aplicabilidade destes estimadores é verificada utilizando medidas de campo realizadas na Unicamp com um equipamento construído no laboratório Wisstek para este ?m. Em seguida, estatísticas de ordem superior, em particular a taxa de cruzamento de nível e a duração média de desvanecimento, são encontradas de forma exata para os ambientes Hoyt e Weibull em sistemas de diversidade com M ramos desbalanceados, não idênticos e independentes utilizando os combinadores por ganho igual e por razão máxima. Neste trabalho, o resultado geral é validado através de simulações e redução das expressões gerais para casos em que os resultados já são conhecidos. Além disso, para alguns destes casos particulares, as expressões gerais são simplificadas e reduzidas a fórmulas fechadas. Estendendo esse último campo de investigação e seguindo um pioneiro trabalho da literatura, o qual abordou o caso Rayleigh, a taxa de cruzamento de nível e a duração média de desvanecimento são obtidas para ambientes Hoyt com dois ramos correlacionados. Nesta investigação, reformula-se a metodologia da literatura e obtém-se um procedimento geral para a análise da taxa de cruzamento de nível e duração média de desvanecimento em ambientes com apenas um cluster, com aplicação direta aos canais Rice, Weibull, ?-? Simétrica e ?-? Assimétrica. Finalmente, este trabalho propõe, de forma precursora, uma distribuição para a fase do canal Nakagami-m. Ao contrário do que, convencionalmente e por simplicidade, se postulava, a distribuição de fase é não uniforme e dependente de m, o que torna o modelo compatível com aqueles aproximados por Nakagami-m, nomeadamente Hoyt e Rice / Abstract: In this work, a new, very general probability density function, the a-?-?-µ distribution, is proposed. This distribution comprises, as particular cases, several other well known distributions such as Rayleigh, Rice, Nakagami-m, Hoyt, Weibull, a-? (Generalized Gamma) ?-µ and ?-µ. Due to its generality, all of the most important short fading environments can be modeled by this distribution. Besides providing the probability density function for the a-?-?-µ model, the moments and the cumulative distribution function are also found. This general model is then specialized into four particular cases, for which new simpler, though still general, distributions, are found: the a-?-µ, a-?-µ, Symmetrical ?-?, and Asymmetrical ?-?. For these cases, practical moment-based estimators are derived. The applicability of these estimators is verified using field measurements obtained through an experiment conducted at the University of Campinas (Unicamp) with an equipment specially built for this end in the Wisstek laboratory. Higher order statistics, more specifically the level crossing rates and average fade durations, are then obtained in an exact form for the Hoyt and Weibull fading environments. The results are applicable to M unbalanced, non-identical, and independent channels using equal gain and maximal ratio combining techniques. The general results are thoroughly validated by means of simulation and also by reducing the general solution to some particular cases for which the solutions are known. Moreover, new closed form expressions are also achieved for some of these particular cases. Extending this field of investigation and following a pioneering work in the literature, which approached the Rayleigh case, the level crossing rate and average fade duration are obtained considering two correlated, unbalanced, and non-identical branches in a Hoyt fading environment. In this investigation, the methodology found in the literature is reformulated and generalized so as to comprise several other cases. The general procedure developed for this analysis can now be applied to other fading environment for which one cluster of mutipaths exists, i.e., Rice, Weibull, Symmetrical ?-?, and Asymmetrical ?-?. Finally, this work proposes, in a pioneering way, the phase distribution for the Nakagami-m channel. Contrary to what conventionally, and for simplicity, was usually postulated, the phase distribution is non-uniform and dependent on m, rendering this model compatible with those approximated by Nakagami-m, namely Hoyt and Rice / Mestrado / Telecomunicações e Telemática / Mestre em Engenharia Elétrica

The potentially most important challenges today are related to energy and the environment. New materials and methods are needed in order to, in a sustainable way, convert and store energy, reduce pollution, and clean the air and water from contaminations. In this, nanomaterials and nanocomposites play a key role, and hence knowledge about the relation between synthesis, structure, and properties of nanosystems is paramount. This thesis demonstrates that solution-chemical synthesis, using amine-modified acetates and nitrates, can be used to prepare widely different nanostructured films. By adjusting the synthesis parameters, metals, oxides, and metal–oxide or oxide–oxide nanocomposites were prepared for two systems based on Co and Zn:Fe, respectively, and the films were characterised using diffraction, spectroscopy, and microscopy techniques, and SQUID magnetometry. A variety of crystalline cobalt films—Co metal, CoO, Co3O4, and composites with different metal:oxide ratios—were synthesised. Heat-treatment parameters and control of the film thickness enabled tuning of the phase ratios. Random and layered Co–CoO composites were prepared by utilising different heating rates and gas flow rates together with a morphology effect associated with the furnace tube. The Co–CoO films exhibited exchange bias due to the ferromagnetic–antiferromagnetic interaction between the Co and CoO, whereas variations in e.g. coercivity and exchange bias field were attributed to differences in the structure and phase distribution. Ordered structures of wurtzite ZnO surrounded by amorphous ZnxFeyO were prepared through controlled phase segregation during the heating, which after multiple coating and heating cycles yielded ZnO–ZnxFeyO superlattices. The amorphous ZnxFeyO was a prerequisite for superlattice formation, and it profoundly affected the ZnO phase, inhibiting grain growth and texture, already from 1% Fe. In addition, ZnO–ZnxFeyO exhibited a photocatalytic activity for the oxidation of water that was higher than results reported for pure ZnO, and comparable to recent results reported for graphene-modified ZnO.

Orientador: Michel Daoud Yacoub / Tese (doutorado) - Universidade Estadual de Campinas, Faculdade de Engenharia Eletrica e de Computação / Made available in DSpace on 2018-08-15T14:34:24Z (GMT). No. of bitstreams: 1 Dias_UgoSilva_D.pdf: 7207559 bytes, checksum: 799e62195e2d2cf1cf1a42599b611bf6 (MD5) Previous issue date: 2010 / Resumo: Esta tese propõe, investiga e valida estatísticas de primeira e segunda ordens para canais com desvanecimento em ambientes sem fio. A caracterização estatística contempla tanto a obtenção de modelos teóricos quanto investigações práticas através de campanhas de medições de campo. Os modelos probabilísticos analisados aqui, chamados ?-µ e a-µ, foram recentemente propostos com o intuito de prover uma análise mais realista do canal rádio-móvel. Por apresentarem um grau de liberdade a mais do que as distribuições tradicionais, uma maior flexibilidade é alcançada. Mais especificamente, as contribuições desta tese são: a obtenção da distribuição conjunta da envoltória e da fase para canais em desvanecimento ?-µ e a validação do seu modelo de fase. Além disso, e sem menos importância, a distribuição a-µ é validada amplamente. Suas funções de distribuição cumulativa, correlação cruzada, autocorrelação e espectro de potência da envoltória, estas últimas encontradas em formulações fechadas, bem como a taxa de cruzamento de nível, são investigadas na prática através do uso de um sistema de medição de campo construído especialmente para este fim. Comparações entre o modelo de canal a-µ e os modelos tradicionais da literatura são realizadas e um excelente ajuste entre os dados teóricos e experimentais é encontrado / Abstract: This thesis proposes, investigates and validates first and second order statistics of fading channels in wireless environments. The statistical characterization includes both theoretical models and practical investigations through field measurements. The investigated channel models, namely ?-µ and a-µ, have recently been proposed in order to provide a more realistic analysis of the propagated signal. Because these fading models have one more degree of freedom than the traditional distributions, a greater flexibility is achieved. More specifically, the contributions of this thesis are: the ?-µ phase-envelope joint distribution derivation and its phase model validation. Furthermore, the distribution a-µ is fully validated. Its cumulative distribution, cross-correlation, autocorrelation and power spectrum functions of the envelope, these latter obtained in closed-form expressions, and the level crossing rate, are investigated in practice by using a field measurement system, specifically built for this purpose. Comparisons between the a-µ channel model and the traditional distributions are performed and excellent fits between the theoretical and experimental data are found / Doutorado / Telecomunicações e Telemática / Doutor em Engenharia Elétrica

Gas chromatography (GC) is an analytical chemistry tool used to determine the chemical composition of a gas sample by separating sample analytes as they travel through a GC column. Recent efforts have been made to understand and control gas chromatography separations with a negative thermal gradient on the column. The present work presents results from thermal gradient GC separations on two GC columns in different configurations (serpentine and radial) in a stainless-steel plate. Methods to fabricate the GC systems capable of isothermal, temperature programmed and thermal gradient separations are presented. Isothermal experimental data from the serpentine column were used to fit retention and dispersion parameters in a transport model that simulates GC separation for hydrocarbons C12-C14. Transport model simulated retention times and peak widths matched experimental values well for isothermal, temperature programmed and thermal gradient separations. The validated transport model was used to study the effect of static (not varying temporally) thermal gradients on GC separations with varying injection widths, injection band shapes and stationary phase thickness. Resolution results from different heating conditions were considered comparable if retention times for each analyte were within 5%. An optimal, static thermal gradient is shown to reduce analyte band spreading from axially-varying velocity gradients with resolution improvements over isothermal separations of up to 8% for analytes with similar retention factors. Static thermal gradients have a larger effect on fronting peak shape than tailing peak shape. Stationary phase distribution acts similar to a velocity gradient and can be corrected by a thermal gradient. Another transport model was created from isothermal experimental data on a commercial column for hydrocarbons C12-C20. An optimal, static thermal gradient does not improve resolution for all analyte pairs. An optimal, dynamic (varying tempo-rally) thermal gradient is created by uniformly increasing the temperature on an optimal, static thermal gradient. Improvements in resolution of up to 20% are achievable over temperature programmed GC separation. A dynamic thermal gradient can also correct for a poor sample injection by creating a temperature trap at the beginning of the column.