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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
271

Οικονομοτεχνική και περιβαλλοντική αξιολόγηση συστημάτων ανανεώσιμων πηγών ενέργειας για άρδευση γεωργικών εκτάσεων

Βαρούχου, Φωτεινή 12 June 2015 (has links)
Ο αγροτικός τομέας αποτελεί ένα σημαντικό παράγοντα οικονομικής και κοινωνικής συνοχής στην Ελλάδα, τόσο σε εθνικό όσο και σε περιφερειακό επίπεδο. Είναι ένας τομέας με μεγάλα περιθώρια αναπτύξεως, διότι η χώρα μας κατέχει σημαντικά συγκριτικά πλεονεκτήματα για την ανάπτυξή του. Για την ανάπτυξη του αγροτικού τομέα ακρογωνιαίο λίθο αποτελεί η οργανωμένη διαχείριση των καλλιεργειών. Ο κύριος παράγοντας για την ανάπτυξη των καλλιεργειών είναι η άρδευσή τους, και ακόμη περισσότερο ο βέλτιστος τρόπος άρδευσης. Σημαντικό ρόλο παίζει η εκπαίδευση των καλλιεργητών στην εξοικονόμηση νερού, για παράδειγμα σχετικά με τις ανάγκες σε χρόνο άρδευσης, τη ρύθμιση της ποσότητας νερού ανάλογα με το είδος της καλλιέργειας. Στην Ελληνική πραγματικότητα σε πολλές περιοχές δεν υφίσταται υποδομή της ΔΕΗ, και αυτός είναι ένας από τους βασικούς λόγους για τον οποίο οι καλλιεργητές χρησιμοποιούν πατροπαράδοτους τρόπους για την άρδευση, όπως τα αυλάκια, οι λεκάνες και διαδικασίες που στηρίζονται στη χρήση πετρελαίου. Οι συγκεκριμένοι τρόποι έχουν αρνητικές περιβαλλοντικές και οικονομικές επιπτώσεις. Σκοπός αυτής της μεταπτυχιακής διπλωματικής εργασίας είναι οικονομοτεχνικής αξιολόγησης συστημάτων ανανεώσιμων πηγών ενέργειας για την άρδευση γεωργικών εκτάσεων στο Θεσσαλικό κάμπο με τη χρήση φωτοβολταϊκών στοιχείων ή συστήματος Βιομάζας, σε μία περιοχή στην οποία δεν είναι συνδεδεμένη με το δίκτυο της ΔΕΗ. Το πρώτο στάδιο περιλαμβάνει µία γενική αναφορά στις Ανανεώσιμες Πηγές Ενέργειας (ΑΠΕ), στην ανάπτυξή τους και η χρήση τους στον Ευρωπαϊκό Χώρο. Σε δεύτερο στάδιο παρουσιάζονται πληροφορίες για την ηλιακή ενέργεια και τα φωτοβολταϊκά στοιχεία, σχετικά µε την κατασκευή, τη λειτουργία και τις εφαρμογές τους. Το τρίτο στάδιο αναπτύσσεται η έννοια της Βιομάζας, οι επιπτώσεις και οι προοπτικές της. Στο τέταρτο στάδιο γίνεται αναφορά στους τρόπους άρδευσης γεωργικών εκτάσεων και τα πλεονεκτήματα και τα μειονεκτήματα αυτών. Το πέμπτο στάδιο αναφέρεται στη μεθοδολογία αξιολόγησης συστημάτων άρδευσης με την χρήση φωτοβολταϊκών και με τη χρήση συστήματος Βιομάζας. Στη συνέχεια ακολουθεί η παρουσίαση του προβλήματος, η πιλοτική εφαρμογή με τη χρήση διαφόρων παραδοχών και τα αποτελέσματα αυτών. Στο τέλος παραθέτονται τα συμπεράσματα. / The agricultural sector constitute an important factor for the economic and social cohesion of Greece, both at national and regional level. It is a sector, which has great growth margins, because our country holds major comparative advantages for development. The rational crop management is the cornerstone of agricultural sector. The optimal way of irrigation influence the crop growth. Grower have to be educated so as understand the importance to save water in the procedure of irrigation, for example how often they have to irrigate their crops, the amount of water considering the type of crop, et all.. In the Greek reality there are areas that have no electric power supply by the grid system, and this is one of the main reasons why irrigation is achieved using traditional ways such as furrows, basins and by fuel powered individual pumps. These ways have negative environmental and economic consequences. The aim of this graduate diploma thesis is the study of the financial and technical assessment of renewable energy systems for the irrigation of agriculture areas in Thessaly (Greece) using photovoltaic (PV) elements or biomass system, in an area which is not connected to the grid. In the first stage of the dissertation are presented a general introduction to the Renewable Energy Sources (RES), their development and their use in the European Area. In a second stage we proceed with the solar energy systems and the PV elements (construction, operation, applications and cost).. The third stage are mentioned the system of biomass, the impacts and prospects. Following we refer to the ways of farmland irrigation and their advantages/disadvantages. The whole irrigation problem is examined and alternative solutions are proposed. Finally, the results are presented and conclusions are drawn.
272

Engineering the performance of optical devices using plasmonics and nonlinear organic chromophores

Shahin, Shiva January 2014 (has links)
In this work, two optical devices, organic photovoltaics (OPVs) and optical fibers, are introduced. Each of these devices have performance drawbacks. The major drawbacks of organic photovoltaics is their low absorption rate due to bandgap mismatch with the solar spectrum as well as poor charge carrier mobility and short exciton diffusion length. In order to overcome some of these drawbacks and increase the efficiency of OPVs, we use plasmonic gold nanoparticles (AuNPs). We report 30% increase in the efficiency of bulk-heterojunction OPV after incorporation of 50 nm AuNPs. The optical, electrical, and thermal impacts of AuNPs on the performance of PVs have been investigated experimentally and using Lumerical Solutions and COMSOL Multiphysics® simulation packages. The major contributions of AuNPs is causing near field enhancement and increasing the absorption of the structure by 65%, decreasing the extracted carrier density by quenching the excitons, changing the workfunction of the structure, as well as increasing the temperature of their surrounded medium when exited at their plasmon resonance frequency. Furthermore, one of the challenges in devices made from optical fibers such as wavelength division multiplexing systems, is self-phase modulation (SPM) which is a nonlinear phenomenon. We introduce a novel method to remove the SPM in liquid core optical fibers (LCOF) using nonlinear organic chromophores with a negative third-order susceptibility. The idea of this work is to eliminate the effective nonlinear refractive index that the optical pulses are experiencing while propagating through the LCOF. Further, a novel method is introduced to characterize the third-order optical nonlinear susceptibility of organic chromophores in LCOF system. The presented method is simple, and can be extended to the characterization of other nanoscale particles such as quantum dots and plasmonic metal nanoparticles in solutions. Finally, a convenient method is presented that enables researchers to investigate the mechanisms behind photobleaching of various materials. The photostability of materials is of great importance for their acceptance in commercial systems such as organic photovoltaics, electro-optic (EO) modulators and switches, etc. This method is based on the simultaneous detection of different signals such as second-, and third-harmonic generations as well as two-, and three-photon excitation fluorescence using multi-photon microscopy.
273

Development of Low-Temperature Epitaxial Silicon Films and Application to Solar Cells

El Gohary, Hassan Gad El Hak Mohamed January 2010 (has links)
Solar photovoltaic has become one of the potential solutions for current energy needs and for combating greenhouse gas emissions. The photovoltaics (PV) industry is booming, with a yearly growth rate well in excess of 30% over the last decade. This explosive growth has been driven by market development programs to accelerate the deployment of sustainable energy options and rapidly increasing fossil fuel prices. Currently, the PV market is based on silicon wafer solar cells (thick cells of around 150–300 μm made of crystalline silicon). This technology, classified as the first-generation of photovoltaic cells. The second generation of photovoltaic materials is based on the introduction of thin film layers of semiconductor materials. Unfortunately, the conversion efficiency of the current PV systems is low despite the lower manufacturing costs. Nevertheless, to achieve highly efficient silicon solar cell devices, the development of new high quality materials in terms of structure and electrical properties is a must to overcome the issues related to amorphous silicon (a -Si:H) degradation. Meanwhile, to remain competitive with the conventional energy sources, cost must be taken into consideration. Moreover, novel approaches combined with conventional mature silicon solar cell technology can boost the conventional efficiency and break its maximum limits. In our approach, we set to achieve efficient, stable and affordable silicon solar cell devices by focusing on the development of a new device made of epitaxial films. This new device is developed using new epitaxial growth phosphorous and/or boron doped layers at low processing temperature using plasma enhanced chemical vapor deposition (PECVD). The junction between the phosphorous or boron-doped epitaxial film of the device is formed between the film and the p or n-type crystalline silicon (c-Si) substrate, giving rise to (n epi-Si/p c-Si device or p epi-Si/n c-Si device), respectively. Different processing conditions have been fully characterized and deployed for the fabrication of different silicon solar cells architectures. The high quality epitaxial film (up to 400 nm) was used as an emitter for an efficient stable homojunction solar cell. Extensive analysis of the developed fine structure material, using high resolution transmission electron microscope (HRTEM), showed that hydrogen played a crucial role in the epitaxial growth of highly phosphorous doped silicon films. The main processing parameters that influenced the quality of the structure were; radio frequency (RF) power density, the processing chamber pressure, the substrate temperature, the gas flow rate used for deposition of silicon films, and hydrogen dilution. The best result, in terms of structure and electrical properties, was achieved at intermediate hydrogen dilution (HD) regime between 91 and 92% under optimized deposition conditions of the rest of the processing parameters. The conductivity and the carrier mobility values are good indicators of the electrical quality of the silicon (Si) film and can be used to investigate the structural quality indirectly. The electrical conductivity analyses using spreading resistance profile (SRP), through the detection of active carriers inside the developed films, are presented in details for the developed epitaxial film under the optimized processing conditions. Measurements of the active phosphorous dopant revealed that, the film has a very high active carrier concentration of an average of 5.0 x1019 cm-3 with a maximum value of 6.9 x 1019 cm-3 at the interface between substrate and the epitaxial film. The observed higher concentration of electrically active P atoms compared to the total phosphorus concentration indicates that more than half of dopants become incorporated into substitutional positions. Highly doping efficiency ηd of more than 50 % was calculated from both secondary ion mass spectroscopy (SIMS) and SRP analysis. A variety of proposed structures were fabricated and characterized on planar, textured, and under different deposition temperatures. Detailed studies of the photovoltaic properties of the fabricated devices were carried out using epitaxial silicon films. The results of these studies confirmed that the measured open circuit voltage (Voc) of the device ranged between 575 and 580 mV with good fill factor (FF) values in the range of 74-76 %. We applied the rapid thermal process (RTP) for a very short time (60 s) at moderate temperature of 750oC to enhance the photovoltaic properties of the fabricated device. The following results were achieved, the values of Voc, and the short circuit current (Isc) were 598 mV and 27.5 mA respectively, with a fill factor value of up to 76 % leading to an efficiency of 12.5 %. Efficiency enhancement by 13.06 % was achieved over the reference cell which was prepared without using RTP. Another way to increase the efficiency of the fabricated device is to reduce the reflections from its polished substrate. This was achieved by utilizing the light trapping technique that transforms the reflective polished surface into a pyramidical texturing using alkaline solutions. Further enhancements of both Voc and Isc were achieved with values of 612 mV and 31mA respectively, and a fill factor of 76 % leading to an increase in the efficiency by up to 13.8 %. A noticeable efficiency enhancement by ~20 % over the reference cell is reported for the developed devices on the textured surfaces. Moreover, the efficiency of the fabricated epitaxial silicon solar cells can be boosted by the deployment of silicon nanocrystals (Si NCs) on the top surface of the fabricated devices. In the course of this PhD research we found a way to achieve this by depositing a thin layer of Si NCs, embedded in amorphous silicon matrix, on top of the epitaxial film. Structural analysis of the deposited Si NCs was performed. It is shown from the HRTEM analysis that the developed Si NCs, are randomly distributed, have a spherical shape with a radius of approximately 2.5 nm, and are 10-20 nm apart in the amorphous silicon matrix. Based on the size of the developed Si NCs, the optical band gap was found to be in the region of 1.8-2.2 eV. Due to the incorporation of Si NCs layer a noticeable enhancement in the Isc was reported.
274

Towards Application of Selectively Transparent and Conducting Photonic Crystal in Silicon-based BIPV and Micromorph Photovoltaics

Yang, Yang 11 December 2013 (has links)
Selectively-transparent and conducting photonic crystals (STCPCs) made of alternating layers of sputtered indium-tin oxide (ITO) and spin-coated silica (SiO2) nanoparticle films have potential applications in micromorph solar cells and building integrated photovoltaics (BIPVs). In this work, theoretical calculations have been performed to show performance enhancement of the micromorph solar cell upon integration of the STCPC an intermediate reflector. Thin semi-transparent hydrogenated amorphous silicon (a-Si:H) solar cells with STCPC rear contacts are demonstrated in proof-of-concept devices. A 10% efficiency increase in a 135nm thick a-Si:H cell on an STCPC reflector with Bragg peak at 620nm was observed, while the transmitted solar irradiance and illuminance are determined to be 295W/m2 and 3480 lux, respectively. The STCPC with proper Bragg peak positioning can boost the a-Si:H cell performance while transmitting photons that can be used as heat and lighting sources in building integrated photovoltaic applications.
275

DEVELOPMENT OF CONJUGATED COPOLYMERS FOR CARBON NANOTUBE-BASED SOLAR CELLS

KRAFT, THOMAS M 14 February 2011 (has links)
The investigation carried out in this project allowed for the development of eleven regioregular π-conjugated alternating copolymers and their implementation in organic solar cells. The eleven synthesized polymers, poly[(2,7-(9-(heptadecan-9-yl)-9H-carbazole))-alt-(4,7-dithien-2-yl-2,1,3-benzothiadiazole)] (CB), poly[(2,7-(9,9-dioctyl-9H-fluorene-2,7-diyl))-alt-(1,6-pyrene)] (LP), poly[(2,7-(9-(heptadecan-9-yl)-9H-carbazole))-alt-(5,5’’’-(3,3’’’-dihexyl-2,2':5',2'':5'',2'''-quarterthiophene))] (CT), poly[(2,7-(9-(heptadecan-9-yl)-9H-carbazole))-alt-(2,7-9H-fluoren-9-one)] (CF), poly[(2,7-(9-(heptadecan-9-yl)-9H-carbazole))-alt-(1,6-pyrene)] (CP), poly[(2,7-(9,9-dioctyl-9H-fluorene-2,7-diyl))-alt-(4,7-dithien-2-yl-2,1,3-benzothiadiazole)] (LB), poly[(2,7-(9,9-dioctyl-9H-fluorene-2,7-diyl))-alt-(2,7-9H-fluoren-9-one)] (LF), poly[(5,5’’’-(3,3’’’-dihexyl-2,2':5',2'':5'',2'''-quarterthiophene))-alt-(2,7-9H- fluoren-9-one)] (TF), poly[(2,7-(9,9-dioctyl-9H-fluorene-2,7-diyl))-alt-(4,4'-dioctyl-2,2'-bithiophene)] (oTLT), poly[(2,7-(9-(heptadecan-9-yl)-9H-carbazole))-alt-(4,4'-dioctyl-2,2'-bithiophene)] (oTCT), poly[(2,7-(9-(heptadecan-9-yl)-9H-carbazole))-alt-(4,4'-dihexyl-2,2'-bithiophene)] (TCT), were investigated using theoretical methods that included semi-empirical geometry optimizations, density functional theory (DFT) energy calculations, and time-dependent density functional theory (TD-DFT) optical absorption predictions. The absorption predictions gave credence to our experimental results in which the absorption of the longer polymer chains underwent a redshift from the monomer absorption. With several of the prepared polymers, bulk-heterojunction photovoltaic cells were fabricated and their photovoltaic activity was investigated. Several of the fabricated cells exhibited photovoltaic efficiencies including polymer/PCBM composites with an aluminum back electrode (CF, CT, P3HT, and MEH-PPV), and also inverted cells with a silver back electrode (CT, P3HT, and MEH-PPV). Several polymers (CF, CT, TCT, LP, oTCT, oTLT, P3HT, and MEH-PPV) were used to solubilize single-walled carbon nanotubes (SWNTs). The solubility of the nanotubes occurred by the polymers’ ability to wrap the tubes, disrupt the bundles (ropes of tubes), and allow for the creation of a homogeneous mixture. Polymer:PCBM:SWNT mixtures were prepared and utilized as the active layer in BHJ solar cells. Some of the inverted cells (with a silver back electrode) that incorporated the nanotube composites (CT, oTCT, oTLT, P3HT, and MEH-PPV) displayed photovoltaic activity. These preliminary results illuminate the photovoltaic behavior of the polymer and provide evidence for their future use in polymer solar cells. / Thesis (Master, Chemistry) -- Queen's University, 2011-02-13 22:09:00.464
276

Numerical modeling and fabrication of high efficiency crystalline silicon solar cells

Renshaw, John 20 September 2013 (has links)
Crystalline silicon solar cells translate energy from the sun into electrical energy via the photoelectric effect. This technology has the potential to simultaneously reduce carbon emissions and our dependence on fossil fuels. The cost of photovoltaic energy, however, is still higher than the cost of electricity off of the grid which hampers this technologies adoption. Raising solar cell efficiency without significantly raising the cost is crucial to lowering the cost of photovoltaic produced energy. One technology which holds promise to increase solar cell efficiency is a selective emitter solar cell. In this work the benefit of selective emitter solar cells is quantified through numerical modeling. Further, the use of ultraviolet laser to create a laser doped selective emitter solar cell is explored. Through optimization of the laser doping process to minimize laser induced defects it is shown that this process can increase solar cell efficiency to over 19.1%. Additionally, 2D and 3D numerical modeling are performed to determine the limitations screen printed interdigitated back contact solar cells and the practical efficiency limit for crystalline Si solar cells.
277

Development and characterization of PECVD grown silicon nanowires for thin film photovoltaics

Adachi, Michael Musashi January 2012 (has links)
Nanowires are high aspect ratio nanostructures with structural diameters on the order of nanometers to hundreds of nanometers. In this work, the optical properties of highly crystalline silicon nanowires grown by the Vapor-Liquid-Solid (VLS) method surrounded by a thin silicon shell are investigated for thin film solar cell applications. Crystalline core nanowires were surrounded by a conformal amorphous silicon shell and exhibited extremely high absorption of 95% at short wavelengths (??<550nm) and very low absorption of <2% at long wavelengths (??>780nm). Nanowires were disordered with average lengths ranging from 1.3 to 2.3 ??m. The absorption increased at longer wavelengths as a function of amorphous shell radial thickness, significantly higher than the absorption of a reference planar a-Si thin film. In addition, a new method to grow epitaxial silicon at low growth temperatures on glass substrates is demonstrated. Highly crystalline silicon nanowires with an average length of 800 nm were used as the seed crystal to grow an epitaxial silicon shell around, using a low temperature process. The nanowire core was grown at 400??C, and the shell was grown at about 150??C. Such epitaxial grown nanowire shells could be used as a building block for nanotechnology applications in which epitaxial silicon is required over large-area substrates such as glass. Furthermore, the epitaxial silicon shell nanowires exhibited absorption > 90% up to a wavelength of 600 nm, which was significantly higher than that of a planar 1 ??m nanocrystalline silicon film. The high absorption exhibited by nanowires with both amorphous and crystalline silicon shells makes them promising for use in photovoltaic and photodetector applications. Silicon nanowires were incorporated into thin film silicon n-i-p solar cells in two configurations: as a nanostructured back reflector, and in core-shell nanowire solar cells. First, domed-shaped nanostructures were fabricated by coating an array of silicon nanowires with a thick layer of amorphous silicon. After the nanostructures were coated with Ag and ZnO:Al, they were used as the backreflector in an n-i-p amorphous silicon solar cell. The nanostructured backreflector improved light scattering within the solar cell, leading to a short circuit current of 14.8mA/cm2, a 13% improvement over that of the planar device, which had a Jsc=13.1 mA/cm2. The overall conversion efficiency of nanostructured backreflector device was ?? = 8.87%, a strong improvement over that of the planar device (?? = 7.47%). Silicon nanowires were also incorporated into core-shell nanowire solar cells. The first device architecture investigated consisted of nanowires incorporated as the intrinsic absorption layer between a planar n+ layer and conformal p+ layer. However, the fabricated devices exhibited very low collection efficiencies of < 2% due to the presence of impurities incorporated by the catalyst used during nanowire growth. As a result, the device architecture was modified such that the nanowires provided high aspect ratio structure to enhance absorption in a shell material, but the nanowires themselves were not used as an active device component. Nanowire core-amorphous silicon shell solar cells, on average 525 nm long and about 350nm in total diameter, exhibited an impressive low total reflectance of <3% in the wavelength interval of 410 nm < ?? < 640nm and exceeded 10% only for ??>700 nm. As a result, the core-shell nanowire devices exhibited enhancement in quantum efficiency at low wavelengths, ?? < 500nm and high wavelengths, ?? > 600nm as compared to a planar device. The resulting short circuit current was 14.1 mA/cm2 compared to 12.3 mA/cm2 for the planar device, an improvement of ~15%. Nanowire core- nanocrystalline silicon shell solar cells were also fabricated using the same device architecture. Core-shell nanowires with an average length of 800 nm showed significant enhancement in quantum efficiency over all wavelengths as compared to a 1 ??m thick planar solar cell. The core-shell nanowire device had a short-circuit current of 16.2 mA/cm2 , a ~25% improvement over that of the planar thin film solar cell (Jsc=13.0 mA/cm2). Core-shell nanowire devices did, however, have lower open circuit voltage compared to the planar device. Non-conformal coverage was found to be a limiting factor in device performance, but further improvements can be expected with optimization of the n-i-p deposition conditions and nanowire density.
278

Dark Ages Interferometer (DALI) Deployment Rover: Energy System

Andersson, Gustav, Ericsson, Emil January 2014 (has links)
The cosmic “Dark Ages” is the cosmic era between the epochs of recombination of cosmic microwave background and the formation of the first stars. The only signal from this epoch is from neutral hydrogen, which could represent one of the richest data sets in cosmology. In order to extract this data, NASA/JPL has proposed a rover mission to the farside of the moon to deploy several radio arrays. Here the arrays would gather data undisturbed by human interference. This thesis examines the possibility of using photovoltaic and electric batteries as an energy solution for a rover on the moon. The requirement for such a system to survive on the moon is discussed in a literature study. A proof of concept simulation using a Simulink model has also been done. The thesis concludes that a rover can deploy the radio array using solar energy. It would be able to hibernate through the night using radioisotope heating. It would need to wait for its batteries to charge before each night. / I kosmologi kallas epoken mellan “rekombinationen till väte” och bildandet av de första stjärnorna för “den mörka tidsåldern”. Från denna tid finns endast spår i form av strålning från neutralt väte. Denna strålning kan enligt astronomer vara en viktigare källa till data om universums uppkomst än den kosmiska mikrovågsstrålningen. Därför arbetar NASA/JPL med att hitta metoder att observera denna rika källa till data. Den mest använda metoden är att använda lågfrekventa radioteleskop för att observera strålning med våglängder mellan 3-30 m och frekvenser mellan 10-100 Mhz. Ett stort problem med så kort strålning är den lätt störs ut av mänsklig påverkan och andra radiokällor, tillexempel solen. Ett sätt att undvika antropogen störning är att bygga ett radioteleskop på månens baksida. Eftersom månen är i en låst bana runt jorden vänder den alltid samma sida bort från planeten. Därför är platsen alltid i radioskugga från jorden ochstörs inte av mänsklighetens radiotrafik. JPL har lång erfarenhet av användandet av robotfarkoster för att utforska himlakroppar. År 2030 vill de sända en så kallad rover för att upprätta en grupp radioteleskop på månen med syftet att införskaffa data om “den mörka tidsåldern.” Högskolan i Halmstad erbjuder sedan 2013 studenter möjligheten att skriva sitt examensarbete i samarbete med NASA/JPL om konstruktionen av denna rover. Detta arbete har ämnat finna en lösning på rovens energiförsörjning genom att använda solceller och batterier. Slutsatsen har varit att det är möjligt att driva en rover på månen med solceller samt batterier. Ett krav är att rovern värms med radioisotoperunder natten för att minska energianvändningen.
279

Molecular Engineering of D-π-A Dyes for Dye-Sensitized Solar Cells

Gabrielsson, Erik January 2014 (has links)
Dye-sensitized solar cells (DSSCs) present an interesting method for the conversion of sunlight into electricity. Unlike in other photovoltaic technologies, the difficult tasks of light absorption and charge transport are handled by two different materials in DSSCs. At the heart of the DSSC, molecular light absorbers (dyes) are responsible for converting light into current. In this thesis the design, synthesis and properties of new metal-free D-π-A dyes for dye-sensitized solar cells will be explored. The thesis is divided into six parts: Part one offers a general introduction to DSSCs, dye design and device characterization. Part two is an investigation of a series of donor substituted dyes where structural benefits are compared against electronic benefits. In part three a dye assembly consisting of a chromophore tethered to two electronically decoupled donors is described. The assembly, capable of intramolecular regeneration, is found to impede recombination. Part four explores a method for rapidly synthesizing new D-π-A dyes by dividing them into donor, linker and acceptor fragments that can be assembled in two simple steps. The method is applied to synthesize a series of linker varied dyes for cobalt based redox mediators that builds upon the experience from part two. Part five describes the synthesis of a bromoacrylic acid based dye and explores the photoisomerization of a few bromo- and cyanoacrylic acid based dyes. Finally, in part six the experiences from previous chapters are combined in the design and synthesis of a D-π-A dye bearing a new pyridinedicarboxylic acid acceptor and anchoring group. / <p>QC 20140509</p>
280

Design and fabrication of nanostructures for light-trapping in ultra-thin solar cells

Massiot, Inès 22 October 2013 (has links) (PDF)
Reducing the absorber thickness is an attractive solution to decrease the production cost of solar cells. Furthermore, it allows to reduce the amount of material needed and improve the current collection in the cell. This thesis has been focused on the design of nanostructures to enhance light absorption in very small semiconductor volumes in order to achieve efficient ultra-thin solar cells. First, we have proposed an original light-trapping concept for ultra-thin amorphous silicon (a-Si:H) solar cells. A one-dimensional metallic grating is patterned on the front surface of the cell deposited on a metallic mirror. Broadband multi-resonant absorption has been demonstrated for both light polarizations. The metallic grating is also used as an alternative transparent electrode in order to reduce optical losses in the front contact. A detailed analysis of the multi-resonant absorption mechanism has been carried out through numerical calculations. The fabrication and optical characterization of ultra-thin a-Si:H solar cells with metallic gratings have validated the multi-resonant approach.Second, we have proposed a design with a two-dimensional metallic grid as a resonant front contact for very thin (25 nm) gallium arsenide (GaAs) layers. We have shown through the design and fabrication of a proof-of-concept structure the potential of metallic nanogrids to confine efficiently light absorption with an ultra-thin GaAs layer.Finally, advanced light-trapping structures could also allow a thickness reduction of crystalline silicon wafers of a factor 20 to 100 with respect to state-of-the-art cells. We have developed a process to transfer micron-thick epitaxial crystalline silicon (c-Si) layers onto a low-cost host substrate. Inverted nanopyramids have also been fabricated in crystalline silicon in order to achieve a broadband anti-reflection effect. It opens promising perspectives towards the realization of double-sided nanopatterned ultra-thin c-Si cells.

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