Weight is a critical parameter in the design of any system launched into space. Current launch costs are on the order of 10,000 dollars per pound of payload capacity. Reducing weight and thus increasing payload capacity is always in the forefront of the design process. One method of increasing the payload capacity of launch vehicles is to reduce the acoustic environment in the interior of the fairing. A major problem is that passive methods currently used for noise suppression do not exhibit significant energy dissipation at low frequencies. This motivates the use of active noise control. Using active noise control for frequencies below 200 to 300 Hz in addition to the passive control means has potential to provide broadband noise suppression and thus a smoother, cheaper ride for any payload. The problem with this technique is that active noise control commonly uses electromagnetic speakers as the control element. The weight of the speaker adds more cost to the application due to the approximate cost per pound to send a launch vehicle and payload to space. At 10,000 dollars per pound of payload capacity, the added cost spent on protecting the payload can potentially reduce the amount of payload capacity a customer receives due to monies spent on non-payload mass. Therefore, necessity dictates a light weight noise control solution. This work investigates the feasibility of a transducer with less mass than that of a conventional loudspeaker which dissipates energy at the acoustic resonances of an enclosed cavity. The test setup involves using the transducer to lower the sound pressure levels of acoustic resonances which are excited by an external source, thus simulating the launch phase of a launch vehicle. The transducer is used as an actuator to add damping through feedback control. The transducer is comprised of three thin flexures that are actuated by piezoceramic material attached to both sides. The flexures actuate a speaker cone that is attached to the end of the flexures. The transducer can act as a sensor or an actuator due to the nature of the piezoceramics. The sound absorbing transducer is modeled to couple to the first acoustic resonance of a six foot cylindrical cavity. The cavity acts as a simplified model of a launch vehicle payload fairing. Equations of motion are derived to model actuator motion and the acoustic impedance of the cavity. A state-space model of the system was derived for two cases: a collocated sensor/actuator pair exciting the tube and an external source exciting the tube with the transducer acting as an absorber. The transducer is designed to affect the first mode, however damping is noticed in the next acoustic resonance. Analysis of the theoretical model indicated up to 70 percent reduction of the open-loop RMS values or a reduction of 10 dB. Experimental results with the optimized transducer produced a 35 percent reduction of the open-loop RMS value or 3.73 dB. The first acoustic resonance coupled well with the first structural mode of the transducer providing optimal noise suppression for the first mode. Damping was also noted in the second acoustic mode. Neglecting the inertia of the tip mass introduced errors in the predictions of the transducer resonances at higher frequencies. This problem limited the ability to control the higher modes of the cavity. / Master of Science

Tiriamajame darbe nagrinėjamas ultragarso pritaikymas ultragarsinei levitacijai ore sukelti. Nagrinėjama ultragarsinės levitacijos taikymas medicinoje ir įvairių gabaritų įrenginiuose , taip pat didelių pramoninių agregatų veikime. Apžvelgiant tokių sistemų konstrukciją, galima rasti įvairių trūkumų, kuriuos ateityje galima tobulinti. Vienas iš didžiausių pastebėtų trūkumų - tai sistemos gabaritiniai matmenys. Todėl baigiamojo darbo metu buvo ieškota įvairių sprendimų kaip šį trūkumą išspręsti, ir buvo iškelti tikslai : 1. Optimizuoti Laboratorijoje turimą išilginių – lenkimo ultragarsinių virpesių T – tipo sistemą. 2. Sukurti ir ištirti naują radialinę lenkimo virpesių sistemą. Darbo uždaviniai : Išanalizuoti galingos ultragarsinių virpesių stovinčios bangos dideliame plote sukėlimo ypatybes. Susipažinti su Laboratorijoje esama T- tipo sistema, išanalizuoti jos darbą. Atlikti ultragarsinių sistemų kompiuterinį modeliavimą . Optimizuoti diskinio rezonatoriaus lenkimo virpesių rezonatoriaus skerspjūvį. Suprojektuoti, pagaminti ir suderinti optimizuotas sistemas. Iš elektrinės ir mechaninės pusės ištirti ultragarsines sistemas: nustatyti impedanso – dažninę ir fazinę bei amplitudines – dažnines charakteristikas prie įvairių elektrinių galių. Nustatyti levitacijos keliamos jėgos priklausomybę nuo paduodamos į pjezokeitiklį galios. Tiriamojo darbo metu nagrinėjamos jau sukurtos ir laboratorijoje... [toliau žr. visą tekstą] / The research is focused on the adaptation of ultrasound for creating airborne ultrasonic levitation. The study investigates the application of ultrasonic levitation for medical purposes and in the equipment of different dimensions, also in the operation of large industrial units. A closer look at the structure of such systems allows to detect multiple defects that could be eliminated in the future. One of the most evident defects is the size of the system. Thus, the purpose of this paper is the search of various solutions with the following objectives set forth: 1. Optimisation of longitudinal-bending ultrasonic vibration T type system used in the lab. 2. Creation and investigation of a new radial bending vibration system. Tasks of the study: To analyse the specifics of generating a powerful ultrasonic vibration standing wave in a big area. To get acquainted with T type system used in the lab, to analyse the operation of the system. To perform computer modeling of ultrasonic systems. Optimise the cross-section of disc type bending-mode resonator. To plan, build and fine-tune the optimised systems. To perform electrical and mechanical investigation of ultrasonic systems: to set frequency/phase and amplitude/frequency characteristics of impedance at different electrical voltages. To set the dependance of levitation power on the piezo converter input voltage. The study contains the analysis of the already created and used in the lab T type systems, their characteristics and... [to full text]

Piezoceramics BaTiO3 doped with ZrO2 was studied in this thesis. Six different compositions were prepared from base powders of BaTiO3 and ZrO2. with 10, 20, 40, 60, 80 and 90 wt% ZrO2. These mixtures were sintered using convetional sintering method and by Spark Plasma Sintering. Resuting ceramic compacts were subjected to measuring of density, dielectric constant, permitivity, polarization P-E curves, piezoelekctric faktor, loss factor and dilatometric measurements. From these results can be said that i tis possible to create piezoceramic BaTiO3 doped by ZrO2 with relative density higher than 94 %t.d. and these ceramics can possess piezoelectric properties. Value of highest piezoelectrick factor 33=9 / was achieved with addition of 20 wt% ZrO2. Dilatometric measurements discovered effect of increasing ammount of ZrO2 in BaTiO3. Rising amount of ZrO2 had a lowering effect on initial sintering temperature and materials achieved higher relative densities. This was also true for samples sintered using SPS, where it was less obvious. Measuring of electrical properties discoverad electric conductivity for SPS sintered samples, which was most probably caused by carbon introduced into samples during SPS cycle.

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / This dissertation presents the development of a system for converting the mechanical energy from vibrations into electrical energy. The conversion is performed in a low-cost piezoelectric transducer, commonly known as buzzer. The main purpose of this system is to charge, or to extend the time between charges, of chargeable batteries up to 2V. In order to control the charging process, an integrated energy processor was also designed. Processor design is presented from its specification, followed by circuit topology definition, electric simulation, layout, extraction of circuit from layout and a final simulation including layout effects. The main contribution of the investigation is to show how much energy could be obtained from vibrations with a low-cost transducer, comparing its performance to full custom generators. The final system implementation is very simple, composed by a generator (a buzzer with a steel ball glued onto its center) and an integrated circuit that controls the charge delivered to the battery, sensing the voltage across its terminals. An efficiency of 55% is expected, being comparable to results published by other researchers. / Esta dissertação apresenta o desenvolvimento de um sistema para converter energia mecânica de vibrações em energia elétrica. A conversão é realizada através de um transdutor de baixo custo comumente chamado de buzzer. O principal objetivo deste sistema é carregar ou estender o tempo entre cargas de baterias recarregáveis de até 2 V. Para o controle do processo de carga, um processador de energia integrado também foi desenvolvido. O projeto do processador de energia é apresentado segundo especificações como definição de topologia, simulação elétrica, layout, extração elétrica do circuito através do layout e a simulação final incluindo os efeitos do layout. A principal contribuição desta dissertação é mostrar como muita energia poderia ser obtida de vibrações com um transdutor de baixo custo, comparando sua performance a outros microgeradores. O sistema final implementado é muito simples, composto por um microgerador (buzzer com uma esfera de aço colada no centro) e um circuito integrado que controla a carga da bateria, através da monitoração da tensão da mesma. Uma eficiência de 55% é esperada, sendo comparável com os resultados obtidos por outros pesquisadores.

This thesis deals with fabrication and optimization of lead-free piezoceramics based on (Ba0,85Ca0,15Zr0,1Ti0,9)O3 (BCZT). The BCZT precursor powder was synthesized by sol-gel method. Dependence of relative density, microstructure, phase structure and piezoelectric properties on the sintering temperature in a range from 1300–1500 °C was studied on disc shaped samples, which were prepared by cold isostatic pressing (CIP) using pressure of 700 MPa. It was found, that sintering at 1300 and 1350 °C leads to ceramics with fine-grain microstructure, which exhibits poor piezoelectric properties (d*33 = 50 pC·N1 and 65 pC·N1, respectively). The highest value of piezoelectric charge coefficient was obtained by sintering at 1500 °C (d*33 = 390 pC·N1). Furthermore, BCZT thick films were prepared by tape casting. The composition of the ceramic slurry was optimized and various sintering techniques were tested to obtain completely flat films of BCZT ceramics. The correct sintering configuration has not been found. The least deformation of the films was achieved when the samples were sintered hung on the ZrO2 rod. The highest value of d*33 for BCZT films was measured when the sample was sintered at 1400 °C with the dwell time for 4 h (d*33 = 340 pC·N1).

This diploma thesis deals with the preparation of doped piezoceramic materials based on BaTiO3 using electrophoretic deposition. Five rare earth oxides, i.e. Er2O3, Dy2O3, Eu2O3, Tb407 and CeO2, were used as dopants in amounts of 1, 3, and 5 wt. %. The prepared deposits were evaluated in terms of preparation methodology, high temperature dilatometry, X-ray diffraction analysis, relative density, mean grain size, hardness and fractographic analysis. The study of dilatometric curves described the sintering behavior and its changes at different material compositions. X-ray diffraction analysis revealed a tetragonal phase in all samples; the tetragonality of the BaTiO3 crystalline cell decreased with dopant content. By a suitable choice of dopant, it was possible to significantly increase the relative density of sintered samples, their hardness and at the same time prevent the samples from coarsening of the microstructure during heat treatment. A relative density up to 98 %, a mean grain size below 1 m and a hardness of over 10 GPa were achieved. Analysis of the fracture surfaces revealed that the fracture mode was transcrystalline for the most of studied materials; only the samples doped with cerium dioxide had fracture surfaces with both transcrystalline and intercrystalline fracture modes. Based on the obtained results, a suitable composition of the material for the intended use in a layered piezoceramic harvester was identified, which, in addition to the BaTiO3 layers, consists of functionally-protective Al2O3 and ZrO2 layers.

Aircraft and satellite structures are exposed to a wide range of temperatures during normal operation cycles. These fluctuations in temperature may result in significant changes of the structural dynamics. Aircraft, automotive, and satellite structures are also subject to various vibration sources. Passive and active vibration suppression techniques have been developed to minimize acoustic noise and fatigue stress damage. Featuring low weight solutions and high performance, active control techniques are becoming increasingly common. Structures with varying dynamics require more sophisticated active control techniques, such as adaptive control. This research uses a special vibration test rig for evaluating the performance of different vibration suppression systems on a representative aircraft panel. The test panel is clamped rigidly in a frame and can be excited in various frequencies with an electromagnetic shaker. To simulate temperature fluctuations the temperature on the panel can be increased up to 65°C (150°F). Smart material based sensors and actuators are used to interface the mechanical system with the electronic controller. The active controller utilizes three positive position feedback (PPF) filters implemented through a digital signal processor board. This research develops two different adaptation methods to perform vibration suppression in the presence of thermally induced frequency changes of the representative panel. To adjust the PPF filter parameters an open-loop adaptation method and an auto-tuning method are investigated. The open-loop adaptation method uses a measurement of the plate temperature and a look-up table with pre-determined parameters to update the filters accordingly. The auto-tuning methods identifies the frequencies of the poles and zeros in the structure's collocated transfer function. From the knowledge of the pole and zero locations the optimal PPF parameters are calculated online. The results show that both adaptation methods are capable of reducing the vibration levels of the test specimen over the temperature range of interest. Three PPF filters with parameter adaptation through temperature measurement achieve magnitude reductions of the resonance peaks as high as 13.6 decibel. Using the auto-tuning method resonance peak reductions up to 17.4 decibel are possible. The pole/zero identification routine proves to detect the frequencies correctly. The average identification error remained at around one percent even in the presence of external disturbances. / Master of Science

The thesis focuses on the development of instruments used for surfaces and nanostructures characterization. Individual techniques of scanning probe microscopy provide different information of the sample surface. The resolution of scanning probe microscopy, providing 3D topography information, reaches subnanometer values or even an atomic level. Therefore, the scanning probe microscopy is one of the most employed method in the field of nanotechnology. The thesis describes the details of development of two scanning probe microscopes intended for measurement under ultra high vacuum conditions. As for the first one, many changes were proposed leading to its better variability, extended functionality and increased user comfort. The second microscope is being design with the aim of its combination with other analytic techniques, especially with scanning electron microscopy. An integral part of scanning probe microscopes is a precise positioning system for navigation of the probe to the selected site. Therefore, the thesis also deals with the development of linear piezoceramic actuators used not only in the ultra high vacuum compatible microscopes but also as a general purpose nanomanipulators.

Utilisés dans de nombreux domaines, les matériaux piézoélectriques sont régulièrement soumis à des sollicitations externes ou internes qui modifient leurs propriétés. Dans le but de prévoir et d’anticiper ces altérations, ce travail étudie les propriétés de matériaux piézoélectriques soumis à une contrainte statique de type mécanique ou électrique. Dans un premier temps, nous développons les équations du mouvement d’un matériau piézoélectrique (non hystérétique) au second ordre, en tenant compte des déformations dynamiques, mais aussi statiques. L’étude numérique des vitesses et du coefficient de couplage est faite sur le niobate de lithium, dans différents plans de coupe et différents systèmes de coordonnées afin d’évaluer dans quelles configurations l’application d’une contrainte externe électrique ou mécanique améliore ou dégrade les propriétés du matériau. Nous caractérisons ensuite les comportements hystérétiques de piézocéramiques sous contraintes en modélisant l’évolution des polarisations et déformations rémanentes microscopiques via les mouvements de murs de domaines. La comparaison des résultats numériques avec des évolutions de 4 piézocéramiques nous permet de définir le domaine de validation de nos hypothèses et d’expliciter les comportements hystérétiques de piézocéramiques. Dans une dernière partie, nous mettons en place un dispositif expérimental de mesure de déformations et du déplacement électrique de structures piézoélectriques sous contrainte mécanique. Ces résultats nous permettent de dimensionner notre étude sur le niobate de lithium et apportent une meilleure compréhension de l’évolution des déformations transversales dans les piézocéramiques. / Used in many domains, piezoelectric materials are frequently submitted to external or internaI stresses which modify their properties. In order to prevent and anticipate these modifications, this work studies the properties of piezoelectric materials under static electrical or mechanical stress. First, the motion equations of a piezoelectric (non hysteretic) rnaterial are developed at the second order taking to account the static strain and the dynamic ones. The numerical study of plane wave velocities and coupling coefficients is performed on lithium niobate, in different cuts and different coordinate systems. Then, we evaluate in which configurations the application of an electrical or mechanical stress improves or degrades the material properties. In a second part, the hysteretic behaviours of piezocerarnic materials under electrical and mechanical stresses are characterized by modelling the evolutions of microscopic remanent polarization and strains through the movements of domain walls. Numerical results are compared to evolutions of 4 piezoceramics and allow us to define the validation domain of our hypothesis and to explain hysteretic behaviours of soft and hard piezoceramics. In the last part, an experimental device to measure strains and electrical displacements under mechanical stress is developped. Results allow study on lithium niobate to be planned and bring a better understanding of transversal strain evolutions in piezoceramics.

Non-centrosymmetric materials that can be polarized under applied mechanical stress or electric field are piezoelectric in nature and the phenomenon is called piezoelectric effect. They are broadly classified as direct and converse piezoelectric effects. Piezo-ceramics have a wide range of applications such as piezoelectric actuators, sensors, and transducers. Among piezoceramics, ferroelectric based materials are imperative owing to the existence of spontaneous polarization in these systems. Several materials are investigated starting from naturally occurring crystals to synthetic ceramics but are limited in their application range. The piezoelectric and ferroelectrics properties of the solid-solutions based on lead zirconate and lead titanate called lead zirconate titanate (PZT), lead magnesium niobate-lead titanate (PMN-PT), lead zinc niobate-lead titanate (PZN-PT) (near morphotrophic phase boundary (MPB)) demonstrate their potential for myriad device applications besides inciting a great deal of academic interest. They have been widely used for commercial applications such as ultra sound transducers, ultrasonic motors, fuel injector actuators, nano positioners in scanning electron microscope etc. However, these materials contain more than 60% lead by weight and volatization of Pb at higher temperature, and disposal of lead results in environmental pollution and are fatal to human health. This gave an insight to search for lead-free solid solutions covering a wide spectrum of applications akin to that of PZT. The search for alternatives to lead based piezoelectric materials is now being focused on modified barium titanates and alkali niobates in which the incidence of MPB was reported similar to that of PZT. In this thesis the results pertaining to the various investigations carried out on modified barium titanates, Ba(Zr0.2Ti0.8)O3- x(Ba0.7Ca0.3)TiO3(BCZT), and alkali niobates, potassium sodium niobate (KNN), are presented. Especially, lead-free piezoelectric material Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3(BCZT) with x= 0.5 has attracted great attention due to its excellent piezoelectric properties. Contrary to the other Pb-free systems, the BZT–BCT phase diagram shows a Morphotropic Phase Boundary (MPB) characterized by the existence of a tri-critical point (TCP), which is also the case for PZT and PMN–PT. One drawback of the BZT–xBCT (x=0.5) is its high sintering temperature (where it exhibits the largest d33 of 550 – 620pC/N). Several methods have been adopted and various additives are being added to bring down the sintering temperature, since high d33 requires an optimized sintering temperature of around 1540oC which also shows excellent ferroelectric properties. However, the methods that were reported in the literature to synthesize the above materials do not guarantee compositional homogeneity and also there is a limitation in obtaining ceramics of enhanced grain size as the ceramics comprising larger grains are demonstrated to exhibit high piezoelectric coefficients. Therefore to address these issues, the simple soft chemical route was adopted to synthesize chemically homogenous powder and the influence of microstructure (grain size) and ferroelectric domains on piezoelectric properties of the BCZT at nano and micron sized crystallites was studied. The results obtained are classified into chapter 3 and chapter 4 accordingly apart from introduction, materials, and methods. Another challenging area of research in lead free piezoceramics for nanoscale device application is to synthesize materials and to visualize the piezoelectric properties at nanoscale with controlled shapes and sizes. For that, Mg2+ ion was chosen as the dopant especially on Ba2+ sites to synthesize Ba0.95Mg0.05Zr0.1Ti0.9O3 (BMZT) nanocrystals, as MgO is known to be an effective grain growth inhibitor in many functional and structural ceramics. Therefore in the present thesis Mg2+ ion was chosen to exercise a strict control over the grain size. The results obtained from this title compound are discussed in chapter 5. Another class of material is K0.5Na0.5NbO3 (KNN), which has been considered a good candidate for lead-free piezoelectric materials. KNN exhibits an MPB around 50% K and 50% Na separating two orthorhombic phases from the complete solid solution of NaNbO3 (Anti-ferroelectric) and KNbO3 (ferroelectric). The major problem associated with KNN ceramic is its complex densification process; difficulty in processing and volatilization of sodium at higher sintering temperature leading to stoichiometric discrepancy. To overcome these difficulties, in the present investigations, an attempt has been made to fabricate KNN ceramics by employing the liquid phase sintering method. In this chapter, B2O3 and borate based glass (0.5 Li2O - 0.5K2O- 2B2O3) were chosen to improve the densification, grain size and their effects on the physical properties of the KNN ceramics are discussed in chapter 6. In chapter 7, KNN crystallites (with size varying from nano to micrometers) were dispersed in the Polyvinylidene fluoride (PVDF) matrix to obtain a polymer/nano or micro crystal composites and the effect of nano and micron sized KNN fillers on the structural, dielectric and piezoelectric properties were investigated. The results obtained pertaining to these aforementioned investigations are organized as follows. In Chapter 1, a brief introduction to the field of ferroelectricity, piezoelectricity, and piezoelectric materials. The emphasis has been on the ferroelectric based piezoelectric materials belonging to the perovskite family of oxides. A brief exposure to the conventional lead based piezoceramics, lead zirconate titanate (PZT) is discussed. Furthermore, drawbacks associated with lead based ceramics are highlighted and alternatives to PZT based ceramics such as modified barium titanate and alkali niobate solid solutions are focused, leading to the motivation and objectives of our work. Chapter 2 describes the various experimental techniques that are employed to synthesize and characterize the materials under investigation. Chapter 3 deals with details concerning the characterization of Ba0.85Ca0.15Zr0.1Ti0.9O3 (BCZT) nanocrystals prepared via complex oxalate precursor route at a relatively low temperature (800°C/5h). The phase formation temperature of BCZT at nanoscale was confirmed by thermogravimetric (TG), differential thermal analysis (DTA) followed by X-ray powder diffraction (XRD) studies. Fourier Transform Infrared (FTIR) spectroscopy was carried out to confirm the complete decomposition of oxalate precursor into BCZT phase. The XRD and profile fitting revealed the coexistence of cubic and tetragonal phases and was also corroborated by Raman study. Transmission electron microscopy (TEM) studies carried out at 800°C and 1000°C/5h heat treated BCZT powder revealed the crystallite size to be in the range of 20 – 50 nm and 40 – 200 nm respectively. The optical band gap for BCZT nanocrystalline powder was obtained using Kubelka Munk function and was found to be around 3.12 ± 0.02 eV and 3.03± 0.02 eV respectively for 800°C (20 – 50 nm) and 1000°C/5h (40 – 200 nm) heat treated samples. The piezoelectric properties were studied for two different crystallite sizes (30 and 70 nm) using piezoresponse force microscope (PFM). The d33 coefficients obtained for 30 nm and 70 nm sized crystallites were 4 pm/V and 47 pm/V respectively. These were superior to those of BaTiO3 nanocrystal (≈ 50 nm) and promising from the technological/industrial applications perspective. Chapter 4 deals with the studies concerning the effect of microstructure (Grain size) and ferroelectric domains on physical properties of Ba0.85Ca0.15Zr0.1Ti0.9O3 ceramics. Fine powders comprising nanocrystallites of Ba0.85Ca0.15Zr0.1Ti0.9O3 (BCZT) were synthesized via oxalate precursor method which facilitated to obtain homogenous and large grain sized ceramics at a lower sintering temperature. The compacted powders were sintered at various temperatures in the range of 1200°C - 1500°C for an optimized duration of 10h. Interestingly the one that was sintered at 1450°C/10h exhibited well resolved Morphotrophic Phase Boundary (MPB). The average grain size associated with this sample was 30 µm accompanied by higher domain density mostly with 90° twinning. These were believed to make a significant contribution towards obtaining large strain of about 0.2 % and piezoelectric coefficient as high as 563 pC/N. The maximum force that was generated by BCZT ceramic (having 30 µm grain size) was found to be 161 MPa which is much higher than that of known actuator materials such as PZT (40 MPa) and NKN-5-LT (7 MPa). Chapter 5 reports the details involving the synthesis, structural, optical, and piezoelectric response of lead free Ba0.95Mg0.05Zr0.1Ti0.9O3 nanocrystalline powder. Nanocrystalline powders of Ba1-xMgxZr0.1Ti0.9O3 (x=0.025 - 0.1) were synthesized via citrate assisted sol-gel method. Interestingly, the one with x=0.05 in the system Ba1-xMgxZr0.1Ti0.9O3 exhibited fairly good piezoelectric response apart from the other physical properties. The phase and structural confirmation of synthesized powder was established by X-ray powder diffraction (XRD) and Raman Spectroscopic techniques. Two distinct Raman bands i.e., 303 cm-1 and 723 cm-1 characteristic of the tetragonal phase were observed. Thermogravimetric analysis (TGA) was performed to evaluate the phase decomposition of the as-synthesized Ba0.95Mg0.05Zr0.1Ti0.9O3 sample as a function of temperature. The average crystallite size associated with Ba0.95Mg0.05Zr0.1Ti0.9O3 was calculated using Scherrer formula based on the XRD data and was found to be 25 nm. However, Scanning and Transmission Electron Microscopy studies revealed the average crystallite size to be in the range of 30-40 nm. Kubelka-Munk function was employed to determine the optical band gap of these nanocrystallites. The piezoelectric response of 26 pm/V was observed for Ba0.95Mg0.05Zr0.1Ti0.9O3 nanocrystal by Piezoresponse Force Microscopy (PFM) technique. Photoluminescence (PL) study carried out on these nanocrystals exhibited a blue emission (470 nm) at room temperature. Chapter 6 describes the effect of the addition of B2O3 on the density, microstructure, dielectric, piezoelectric and ferroelectric properties of K0.5Na0.5NbO3 ceramics. Boron oxide (B2O3) addition to pre-reacted K0.5Na0.5NbO3 (KNN) powders facilitated swift densification at relatively low sintering temperatures which was believed to be a key to minimize potassium and sodium loss. The base KNN powder was synthesized via solid-state reaction route. The different amounts (0.1 to 1 wt %) of B2O3 were added, and ceramics were sintered at different temperatures and durations to optimize the amount of B2O3 needed to obtain KNN pellets with the highest possible density and grain size. The 0.1 wt% B2O3 added KNN ceramics sintered at 1100°C for 7h exhibited higher density (98%) with grain size of ~5 µm. Scanning electron microscopy (SEM) studies confirmed an increase in average grain size with increasing B2O3 content at the appropriate temperature of sintering and duration. The B2O3 added KNN ceramics exhibited improved dielectric and piezoelectric properties at room temperature. For instance, 0.1 wt% B2O3 added KNN ceramic exhibited d33 value of 116 pC/N which is much higher than that of pure KNN ceramics. Interestingly, all the B2O3 added (0.1 to 1wt %) KNN ceramics exhibited polarization – electric field (P vs E) hysteresis loops at room temperature. The remnant polarization (Pr) and coercive field (Ec) values are dependent on the B2O3 content and crystallite size. The details pertaining to the effect of the addition of borate based glass (0.5 Li2O - 0.5K2O- 2B2O3) on the physical properties of K0.5Na0.5NbO3 ceramics are also reported in this chapter. The addition of powdered 0.5 Li2O - 0.5K2O- 2B2O3 (LKBO) glass (0.5 to 2 wt%) to potassium sodium niobate, K0.5Na0.5NbO3 (KNN) powder facilitated higher densification which resulted in improved physical properties that include dielectric, piezoelectric and ferroelectric. The required polycrystalline powders of KNN were synthesized through solid-state reaction route, while LKBO glass was obtained via the conventional melt-quenching technique. Pulverized glass was added to KNN powders in different wt% and compacted at room temperature and these were sintered around 1100°C. Indeed the addition of optimum amount (1 wt %) of LKBO glass to KNN ceramics facilitated lowering of sintering temperature accompanied by larger grains (8 µm) with improved density. The dielectric constant (εr) measured at room temperature was 475 (at 10 kHz), whereas it was only 199 for the LKBO glass free KNN. The piezoelectric coefficient (d33) was found to be 130 pC/N for 1wt% LKBO added glass, which was much higher than that of pure KNN ceramics (85 pC/N). Indeed, the LKBO glass added samples did exhibit well saturated P versus E hysteresis loops at room temperature. Though there was no particular trend observed in the variation of Pr with the increase in glass content, the Pr values were higher than those obtained for KNN ceramics. The improved physical properties of KNN ceramics encountered in these studies were primarily attributed to enhancement in density and grain size. Chapter 7 presents a comparative study on the structural, dielectric and piezoelectric properties of nano and micron sized K0.5Na0.5NbO3 fillers in PVDF composites. Polymer nanocrystal composites were fabricated by embedding polyvinylidene fluoride (PVDF) with different vol% of K0.5Na0.5NbO3 (KNN) nanocrystallites using hot-pressing technique. For comparison, PVDF-KNN microcrystal composites of the same compositions were also fabricated which facilitated the crystallite size (wide range) effect studies on the dielectric and piezoelectric properties. The structural, morphological, dielectric, and piezoelectric properties of these nano and micro crystal composites were investigated. The incorporation of KNN fillers in PVDF at both nano and micrometer scale above 10vol% resulted in the formation of polar β-form of PVDF. The room temperature dielectric constant as high as 3273 at 100Hz was obtained for PVDF comprising 40 vol% KNN nanocrystallites due to dipole –dipole interactions (as the presence of β-PVDF is prominent), whereas it was only 236 for PVDF containing the same amount (40 vol%) of micron sized crystallites of KNN at the same frequency. Various theoretical models were employed to predict the dielectric constants of the PVDF-KNN nano and microcrystal composites. PVDF comprising 70 vol% micronmeter sized crystallites of KNN exhibited d33 value of 35pC/N, while the nanocrystal composites of PVDF-KNN did not exhibit any piezoelectric response perhaps due to unrelieved internal stress within each grain besides having less number of domain walls. The Thesis ends with summary and conclusions, though each chapter is provided with conclusions and a complete list of references.