This thesis investigates the properties of an atomic system exhibiting a giant Kerr nonlinearity. The atomic energy level scheme involves four energy levels. A three level A subsystem in the atom exhibits the effect of electromagnetically induced transparency (EIT), reducing the spontaneous emission noise. The fourth level leads to an ac-Stark shift of the ground state, which in turn leads to a giant, noiseless Kerr nonlinearity. Two different environments are explored. First, a system comprising of large number of atoms in an optical cavity is analysed. Detailed aspects of noise reduction in this system are investigated. In particular, strong squeezing in the quadrature in phase with the field driving the cavity mode is found, if the effective coupling of light to the atoms is strong. However, the linewidth of the predicted squeezing is found to be very narrow. This is attributed to a very steep linear susceptibility of the atomic medium. Since the widening of the squeezing window is possible only for weaker effective coupling, in turn reducing the squeezing level, a different environment is proposed. This involves a single four level atom, strongly coupled to the cavity mode. In such a strongly coupled system, the most appropriate approach is found to be that formulated in terms of polaritons – composite excitations of the 'atom-cavity molecule'. Adopting the polariton approach, nonclassical correlations in the field leaving the cavity are investigated. Strong photon antibunching is found and the effect of photon blockade predicted and described. The photon blockade effect can also be found in a system comprised of a two level atom coupled to the cavity mode, if the external driving is tuned to one of the vacuum Rabi resonances. A comparison between the two schemes is performed, and it is found that the four level scheme exhibits much better photon blockade. The reason for this is quantum interference between secondary transitions in the dressed states picture. Destructive interference cancels the transitions that would otherwise introduce a second photon into the system, hence producing a more robust photon blockade. All of these results are valid in the regime where external driving is weak. If the external driving strength is increased, the photon statistics (as measured by the zero-delay second order correlation function) changes from strong antibunching to strong bunching, over a relatively narrow range of driving strengths. The occurrence of this change can again be attributed to quantum interference. It is shown that the interference effect prevents the excitation of the composite system by a second photon, but not excitation by a two-photon transition (following the first excitation). Therefore, the third excitation manifold is excited, which then decays back to the first manifold in a two photon cascade. This two photon cascade is the source of correlated photon pairs causing an increase in the second order correlation function. The dynamics of forward scattering of light is presented, and nonclassical behaviour of the delay dependence of correlation function ('overshoots' and 'undershoots') is discussed. For the analytical treatment of this system, a method based on the polariton approach is devised, which includes the treatment of driving and damping. It is shown that this method is ideally suited to the analysis of strongly coupled systems, where only a few photons contribute to the dynamics.

The proton polarization in the 3He(d,p)4He reaction induced by unpolarized deuterons has been measured at deuteron lab. energies of 2.0, 2.8, 3.9 and 6.0MeV for 20 angles between 0° and 150° (c.m.). Statistical uncertainties are typically ± 0.01. The measurements were made with a proton polarimeter in which the left-right asymmetry of scattering at 60° (lab.) in 4He is determined. The polarimeter employs "venetian-blind" collimation of the protons by conical vanes and 75 cm2 plastic scintillator detectors. Four detectors are included for use in polarization transfer experiments. For 10.5 MeV protons and a helium pressure of 250 p.s.i. the target thickness is 3 MeV and the efficiency per detector per unpolarized proton incident is 10-4. For each polarimeter detector a triple coincidence with a 15 ns resolving time was required with two scintillator transmission detectors preceding the polarimeter. Spectra of random coincidences were accumulated simultaneously and subtracted. Asymmetries resulting from polarimeter-target misalignment and other geometrical effects are discussed. All results quoted are geometric means of pairs of measurements for 180° rotation of the polarimeter and are also arithmetic means of such measurements to left and right of the 3He target. The absolute analyzing power is estimated by computer simulation of trajectories to be -0.638 ± 0.020 for protons entering at 10.3 MeV. The product of polarization and cross section is fitted to an expansion of first-order associated Legendre polynomials using these results and earlier measurements. Only four terms are required except at 6.0MeV where a fifth is necessary. The energy dependence of these coefficients suggests resonances in 5Li at deuteron energies of 60MeV (odd coefficients) and 7.5 MeV (even coefficients) in agreement with results for the polarized-beam analyzing powers(1). Comparison of the results with vector-polarized-beam (1) and polarized-target(2) analyzing powers shows no evidence for the postulated simple relations(3) based on DWBA cal calculations. Comparison of the results with recent measurements of the neutron polarization in the mirror reaction(4) shows no significant differences. The theory of angular correlations in charged particle reactions is developed and used to calculate outgoing nucleon polarizations. Expressions are given for polarization transfer coefficients. These coefficients are evaluated in terms of the T-matrix elements for the interference of various channels with the dominant S-wave, JΠ = 3+/2 channel in 3He(d,p)4He at the 0.43 MeV resonance. Two experiments to measure combinations of these elements are discussed. (1) Gruebler, W. et al., 1971, Nucl. Phys. Al76, 631 (2) Leemann, Ch., W. Gruebler et al., 1971, in Polarization Phenomena in Nuclear Reactions (University of Wisconsin Press), p. 548 (3) Tanifuji,M. and K. Yazaki, 1968, Prog. Theor. Phys. 40, 1023 (4) Mutchler, G.S., W.B. Broste and J.E. Simmons, 1971, Phys. Rev. C3, 1031

This thesis investigates the properties of an atomic system exhibiting a giant Kerr nonlinearity. The atomic energy level scheme involves four energy levels. A three level A subsystem in the atom exhibits the effect of electromagnetically induced transparency (EIT), reducing the spontaneous emission noise. The fourth level leads to an ac-Stark shift of the ground state, which in turn leads to a giant, noiseless Kerr nonlinearity. Two different environments are explored. First, a system comprising of large number of atoms in an optical cavity is analysed. Detailed aspects of noise reduction in this system are investigated. In particular, strong squeezing in the quadrature in phase with the field driving the cavity mode is found, if the effective coupling of light to the atoms is strong. However, the linewidth of the predicted squeezing is found to be very narrow. This is attributed to a very steep linear susceptibility of the atomic medium. Since the widening of the squeezing window is possible only for weaker effective coupling, in turn reducing the squeezing level, a different environment is proposed. This involves a single four level atom, strongly coupled to the cavity mode. In such a strongly coupled system, the most appropriate approach is found to be that formulated in terms of polaritons – composite excitations of the 'atom-cavity molecule'. Adopting the polariton approach, nonclassical correlations in the field leaving the cavity are investigated. Strong photon antibunching is found and the effect of photon blockade predicted and described. The photon blockade effect can also be found in a system comprised of a two level atom coupled to the cavity mode, if the external driving is tuned to one of the vacuum Rabi resonances. A comparison between the two schemes is performed, and it is found that the four level scheme exhibits much better photon blockade. The reason for this is quantum interference between secondary transitions in the dressed states picture. Destructive interference cancels the transitions that would otherwise introduce a second photon into the system, hence producing a more robust photon blockade. All of these results are valid in the regime where external driving is weak. If the external driving strength is increased, the photon statistics (as measured by the zero-delay second order correlation function) changes from strong antibunching to strong bunching, over a relatively narrow range of driving strengths. The occurrence of this change can again be attributed to quantum interference. It is shown that the interference effect prevents the excitation of the composite system by a second photon, but not excitation by a two-photon transition (following the first excitation). Therefore, the third excitation manifold is excited, which then decays back to the first manifold in a two photon cascade. This two photon cascade is the source of correlated photon pairs causing an increase in the second order correlation function. The dynamics of forward scattering of light is presented, and nonclassical behaviour of the delay dependence of correlation function ('overshoots' and 'undershoots') is discussed. For the analytical treatment of this system, a method based on the polariton approach is devised, which includes the treatment of driving and damping. It is shown that this method is ideally suited to the analysis of strongly coupled systems, where only a few photons contribute to the dynamics.

The proton polarization in the 3He(d,p)4He reaction induced by unpolarized deuterons has been measured at deuteron lab. energies of 2.0, 2.8, 3.9 and 6.0MeV for 20 angles between 0° and 150° (c.m.). Statistical uncertainties are typically ± 0.01. The measurements were made with a proton polarimeter in which the left-right asymmetry of scattering at 60° (lab.) in 4He is determined. The polarimeter employs "venetian-blind" collimation of the protons by conical vanes and 75 cm2 plastic scintillator detectors. Four detectors are included for use in polarization transfer experiments. For 10.5 MeV protons and a helium pressure of 250 p.s.i. the target thickness is 3 MeV and the efficiency per detector per unpolarized proton incident is 10-4. For each polarimeter detector a triple coincidence with a 15 ns resolving time was required with two scintillator transmission detectors preceding the polarimeter. Spectra of random coincidences were accumulated simultaneously and subtracted. Asymmetries resulting from polarimeter-target misalignment and other geometrical effects are discussed. All results quoted are geometric means of pairs of measurements for 180° rotation of the polarimeter and are also arithmetic means of such measurements to left and right of the 3He target. The absolute analyzing power is estimated by computer simulation of trajectories to be -0.638 ± 0.020 for protons entering at 10.3 MeV. The product of polarization and cross section is fitted to an expansion of first-order associated Legendre polynomials using these results and earlier measurements. Only four terms are required except at 6.0MeV where a fifth is necessary. The energy dependence of these coefficients suggests resonances in 5Li at deuteron energies of 60MeV (odd coefficients) and 7.5 MeV (even coefficients) in agreement with results for the polarized-beam analyzing powers(1). Comparison of the results with vector-polarized-beam (1) and polarized-target(2) analyzing powers shows no evidence for the postulated simple relations(3) based on DWBA cal calculations. Comparison of the results with recent measurements of the neutron polarization in the mirror reaction(4) shows no significant differences. The theory of angular correlations in charged particle reactions is developed and used to calculate outgoing nucleon polarizations. Expressions are given for polarization transfer coefficients. These coefficients are evaluated in terms of the T-matrix elements for the interference of various channels with the dominant S-wave, JΠ = 3+/2 channel in 3He(d,p)4He at the 0.43 MeV resonance. Two experiments to measure combinations of these elements are discussed. (1) Gruebler, W. et al., 1971, Nucl. Phys. Al76, 631 (2) Leemann, Ch., W. Gruebler et al., 1971, in Polarization Phenomena in Nuclear Reactions (University of Wisconsin Press), p. 548 (3) Tanifuji,M. and K. Yazaki, 1968, Prog. Theor. Phys. 40, 1023 (4) Mutchler, G.S., W.B. Broste and J.E. Simmons, 1971, Phys. Rev. C3, 1031

This thesis investigates the properties of an atomic system exhibiting a giant Kerr nonlinearity. The atomic energy level scheme involves four energy levels. A three level A subsystem in the atom exhibits the effect of electromagnetically induced transparency (EIT), reducing the spontaneous emission noise. The fourth level leads to an ac-Stark shift of the ground state, which in turn leads to a giant, noiseless Kerr nonlinearity. Two different environments are explored. First, a system comprising of large number of atoms in an optical cavity is analysed. Detailed aspects of noise reduction in this system are investigated. In particular, strong squeezing in the quadrature in phase with the field driving the cavity mode is found, if the effective coupling of light to the atoms is strong. However, the linewidth of the predicted squeezing is found to be very narrow. This is attributed to a very steep linear susceptibility of the atomic medium. Since the widening of the squeezing window is possible only for weaker effective coupling, in turn reducing the squeezing level, a different environment is proposed. This involves a single four level atom, strongly coupled to the cavity mode. In such a strongly coupled system, the most appropriate approach is found to be that formulated in terms of polaritons – composite excitations of the 'atom-cavity molecule'. Adopting the polariton approach, nonclassical correlations in the field leaving the cavity are investigated. Strong photon antibunching is found and the effect of photon blockade predicted and described. The photon blockade effect can also be found in a system comprised of a two level atom coupled to the cavity mode, if the external driving is tuned to one of the vacuum Rabi resonances. A comparison between the two schemes is performed, and it is found that the four level scheme exhibits much better photon blockade. The reason for this is quantum interference between secondary transitions in the dressed states picture. Destructive interference cancels the transitions that would otherwise introduce a second photon into the system, hence producing a more robust photon blockade. All of these results are valid in the regime where external driving is weak. If the external driving strength is increased, the photon statistics (as measured by the zero-delay second order correlation function) changes from strong antibunching to strong bunching, over a relatively narrow range of driving strengths. The occurrence of this change can again be attributed to quantum interference. It is shown that the interference effect prevents the excitation of the composite system by a second photon, but not excitation by a two-photon transition (following the first excitation). Therefore, the third excitation manifold is excited, which then decays back to the first manifold in a two photon cascade. This two photon cascade is the source of correlated photon pairs causing an increase in the second order correlation function. The dynamics of forward scattering of light is presented, and nonclassical behaviour of the delay dependence of correlation function ('overshoots' and 'undershoots') is discussed. For the analytical treatment of this system, a method based on the polariton approach is devised, which includes the treatment of driving and damping. It is shown that this method is ideally suited to the analysis of strongly coupled systems, where only a few photons contribute to the dynamics.

The advances achieved using X-ray Free Electron Lasers such as the Linac Coherent Light Source (LCLS), have revolutionised the routine production of uniform solid-density plasmas. Pulses of X-rays above 1 keV and with durations shorter than 100 fs attaining intensities on target of around 10¹⁷ Wcm^-2 are now routinely created. Through simple single-photon photoionization events with atoms in ambient solid conditions, it is possible to create uniform samples that are simultaneously hot, dense, and highly ionized which may be easily modelled. This thesis describes measurements of the spectrally-resolved X-rays emitted from solid-density magnesium targets of varying sub-μm thicknesses isochorically heated by an X-ray laser. The data exhibit a thickness-independent source function, allowing the extraction of a measure of the opacity to K-shell X-rays within well-defined regimes of electron density and temperature, extremely close to Local Thermodynamic Equilibrium conditions by fitting to the simple 1D slab solution of the equation of radiative transfer. The deduced opacities at the peak of the K-α transitions of the ions are consistent with those predicted by detailed atomic-kinetics calculations. The extracted opacities transpire to be robust to a plethora of variations in X-ray drive conditions, including the shape, pulse-length, and energy content. Furthermore the approximations in using the 1D slab solution are examined in detail and found to be good. A full three-dimensional model of the plasma is advanced which includes attenuation, line-of-sight effects, full longitudinal and transverse gradients, and photon time-of-flight effects. The results from this model are found to also agree with the simpler 1D slab solution. This novel method of elucidating opacities may complement other methods based on absorption and could be important for further benchmarking of opacities in solar-interior relevant conditions.

The transport of heat out of tokamak plasmas by turbulence is the dominant mechanism limiting the performance of fusion reactors. Turbulence can be driven by the ion temperature gradient (ITG) and suppressed by toroidal equilibrium scale sheared flows. Numerical simulations attempting to understand, and ultimately reduce, turbulence are crucial for guiding the design and optimisation of future reactors. In this thesis, we investigate ion-scale turbulence by means of local gyrokinetic simulations in the outer core of the Mega Ampere Spherical Tokamak (MAST).We perform a parameter scan in the values of the ITG and the flow shear. We show that nonlinear simulations reproduce the experimental ion heat flux and that the experimentally measured values of the ITG and the flow shear lie close to the turbulence threshold. We demonstrate that the system is subcritical in the presence of flow shear, i.e., the system is formally stable to small perturbations, but transitions to a turbulent state given a large enough initial perturbation. We propose a scenario for the transition to subcritical turbulence previously unreported in tokamak plasmas: close to the threshold, the plasma is dominated by a low number of coherent long-lived structures; as the system is taken away from the threshold into the more unstable regime, the number of these structures increases until they fill the domain and a more conventional turbulence emerges. We make quantitative comparisons of correlation properties between our simulations and experimental measurements of ion-scale density fluctuations from the MAST BES diagnostic. We apply a synthetic diagnostic to our simulation data and find reasonable agreement of the correlation properties of the simulated and experimental turbulence, most notably of the correlation time, for which significant discrepancies were found in previous numerical studies of MAST turbulence. We show that the properties of turbulence are essentially functions of the distance to threshold, as quantified by the ion heat flux. We find that turbulence close to the threshold is strongly affected by flow shear, whereas far from threshold, the turbulence resembles a conventional ITG-driven, zonal-flow damped regime.

Performing high-fidelity plasma simulations remains computationally expensive because of their large dimension and complex chemistry. Atmospheric re-entry plasmas for instance, involve hundreds of species in thousands of reactions used in detailed physical models. These models are very complex as they describe the non-equilibrium phenomena due to finite-rate processes in the flow. Chemical non-equilibrium arises because of the many dissociation, ionization and excitation reaction at various time-scales. Vibrational, rotational, electronic and translational temperatures characterize the flow and exchange energy between species, which leads to thermal non-equilibrium.With the current computational resources, detailed three-dimensional simulations are still out of reach. Detailed calculations using the full dynamics are often restricted to a zero- or one-dimensional description. A trade-off has to be made between the level of accuracy of the model and its computational cost. This thesis presents various methods to develop accurate reduced kinetic models for plasma flows. Starting from detailed chemistry, high-fidelity reductions are achieved through the application of either physics-based techniques, such as presented by the binning methods and time-scale based reductions, either empirical techniques given by principal component analysis. As an original contribution to the existing methods, the physics-based techniques are combined with principal component analysis uniting both communities. The different techniques are trained on a 34 species collisional-radiative model for argon plasma by comparing shock relaxation simulations.The best performing method is applied on the large N-N2 mechanism containing 9391 species and 23 million reactions calculated by the NASA Ames Research Center. As a preliminary step, the system dynamics is analyzed to improve our understanding of the various processes occurring in plasma flows. The reactions are analyzed and classified according to their importance. A deep investigation of the kinetics enables finding the main variables and parameters characterizing the plasma, which can thereafter be used to develop or improve existing reductions.As a result, a novel coarse grain model has been developed for argon by binning the electronic excited levels and the ionized species into 2 Boltzmann averaged energy bins. The ground state is solved individually together with the free electrons, reducing the species mass conservation equations from 34 to 4. Principal component analysis has been transferred from the combustion community to plasma flows by investigating the Manifold-Generated and Score-PCA techniques. PCA identifies low dimensional manifolds empirically, projecting the full kinetics to its base of principal components. A novel approach combines the binning techniques with PCA, finding an optimized model for reducing the N3 rovibrational collisional model. / Doctorat en Sciences de l'ingénieur et technologie / info:eu-repo/semantics/nonPublished

Incoherent scatter radar (ISR) measurements were used in conjunction with plasma simulations to study two micro-scale plasma processes that commonly occur in the auroral ionosphere. These are 1) ion acoustic turbulence and 2) Langmuir turbulence. Through an ISR experiment we investigated the dependence of ion acoustic turbulence on magnetic aspect angle. The results showed a very strong aspect angle sensitivity which could be utilized to classify the turbulence according to allowable generation mechanisms and sources of free energy. In addition, this work presents results that led to the discovery of a new type of ISR echo, explained as a signature of cavitating Langmuir turbulence. A number of incoherent scatter radar experiments, exploiting a variety of beam and pulse patterns, were designed or revisited to investigate the Langmuir turbulence underlying the radar echoes. The experimental results revealed that Langmuir turbulence is a common feature of the auroral ionosphere. The experimental efforts also led to uncovering a relationship between Langmuir turbulence and one type of natural electromagnetic emission that is sometimes detected on the ground, so-called “medium frequency burst”, providing an explanation for the generation mechanism of these emissions. In an attempt to gain insights into the source mechanism underlying Langmuir turbulence, 1-dimensional Zakharov simulations were employed to study the interactions of ionospheric electron beams with a broad range of parameters with the background plasma at the F region peak. A variety of processes were observed, ranging from a cascade of parametric decays, to formation of stationary wave packets and density cavities in the condensate region, and to direct nucleation and collapse at the initial stage of the turbulence. The simulation results were then compared with the ISR measurements where inconsistencies were found in the spectral details and intensity of the simulated and measured Langmuir turbulence echoes, suggesting the possibility that the direct energy for the turbulence was provided by unstable low-energy (5 − 20 eV) electron populations produced locally in the F region of the ionosphere rather than by electron beams originating from the magnetosphere.

This master thesis deals with examination of the parameters of low temperature plasma which is used for the deposition of thin layer of ITO. The method which is used in this thesis is the probe diagnostics. This thesis is divided into two parts. The first is the theoretical part, in which the basic parameters of low temperature plasma, principles of the probe diagnostics, and theories for this method are explained. The second part is the practical part, which presents the results of the measurement depending on changes in conditions of deposition.