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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Long Term Corrosion of Reinforcing Strips in Mechanically Stabilized Earth Walls

Berke, Brandon Seth 16 March 2009 (has links)
Mechanically stabilized earth (MSE) walls are a more advanced form of a retaining wall, often larger and able to hold back more backfill. This is achieved by reinforcing strips or meshes (most often galvanized steel) placed into the soil, which are held in place by friction. The strips mechanically stabilize the earth while undergoing tension. The wall is covered with concrete medallions that connect to the reinforcements. The medallions have only a secondary structural role in holding up the wall but provide cover that protects the soil from washing away. MSE walls are structures expected to have very long service lives (e.g. 100 years). Confirmation is needed that such durability can be achieved, especially to show that the progression of corrosion of the reinforcement is slow enough. Ten MSE walls around Florida were instrumented (electrical connections were made through the concrete covers to the buried elements) between 1996- 1998 and used to survey corrosion rates of galvanized strip or mesh soil reinforcements. Initial estimates of corrosion-related durability were obtained at that time, indicating a good prognosis for long term durability. The objective of the research in this thesis was to obtain additional indications of the durability of reinforcements in MSE walls in Florida so as to perform a more reliable projection of future performance. Corrosion behavior was measured at the same locations as the initial survey by electrochemical nondestructive tests and by destructive tests. The nondestructive testing consisted of half-cell potentials, polarization resistance measurements, and electrochemical impedance spectroscopy. Corrosion rates reported in this thesis are based upon polarization resistance measurements. The destructive testing consisted of soil extraction and hardware extraction. Hardware extraction enabled independent verification of estimates of electrochemical corrosion rate. Analysis of extracted soil verified that soil composition was within construction specifications. The data from the current survey were also used to further improve prediction of corrosion. The present series of evaluations confirm that the structures are performing as desired based upon the updated model projection of future corrosion.
2

Evaluating Corrosion Control Alternatives For A Reverse Osmosis, Nanofiltration And Anion-exchange Blended Water Supply

Wilder, Rebecca J 01 January 2012 (has links)
The research reported herein describes the study activities performed by University of Central Florida (UCF) on behalf of the Town of Jupiter Water Utilities (Town). The Town recently changed its water treatment operations from a combination of reverse osmosis (RO), lime softening (LS) and anion-exchange (IX) to a combination of RO, IX and nanofiltration (NF). Although this treatment change provided enhanced water to the surrounding community in terms of better contaminant removal and reduced DBP formation potential, integration of the NF process altered finished water quality parameters including pH, alkalinity and hardness. There was concern that these changes could result in secondary impacts related to accelerated corrosion of distribution system components and subsequent regulatory compliance. In addition, replacement of the LS process altered the in-plant blending operations by creating an unstable intermediate blend composed of RO and IX waters. There were concerns that this intermediate blend was affecting the integrity of in-plant hydraulic conveyance components. UCF developed a corrosion monitoring study to assess the potential impacts related to internal corrosion, water quality and regulatory compliance after integrating NF into the existing water supply. The intended purpose was to further highlight the complexities of corrosion, describe a unique approach to corrosion monitoring as well as offer various recommendations for corrosion control in a system that relies on a blended water supply. Research was conducted in three phases to address the in-plant and distribution system corrosion issues separately and identify appropriate corrosion control treatment alternatives. The three test phases included: a baseline conditions assessment to iv compare corrosion of the intermediate RO-IX blend with the finished water blend (ROIX-NF); an in-plant corrosion control evaluation; and a distribution system corrosion control evaluation. A test apparatus was constructed and operated at the Town’s facilities to monitor corrosion activity of mild steel, copper and lead solder metal components. The test apparatus consisted of looped PVC pipe segments housed with electrochemical probes and metal coupons to monitor corrosion rates of the metallic components. Electrochemical probes containing metal electrodes were used to obtain instantaneous corrosion rates by means of the Linear Polarization Resistance (LPR) technique while the metal coupons were gravimetrically evaluated for weight loss. The electrochemical probes permitted daily monitoring of each metal’s corrosion rates while metal coupons were analyzed at the conclusion of testing and used for comparison. Different test waters flowed through the corrosion rack according to each test phase and relative corrosion rates were compared to evaluate corrosion control techniques. Study findings indicated that the intermediate blend was more corrosive, in general, then the final blend; however, research also indicated that the final blend of water was increasing lead and copper concentrations within the distribution system. An orthophosphate corrosion inhibitor was evaluated for in-plant corrosion control. The inhibitor’s performance was assessed by comparing mild steel corrosion rates with and without the chemical. In addition, secondary impacts related to introduction of the chemical were evaluated by pre-corroding the metallic components prior to the introduction of the inhibitor. Results indicated that the inhibitor marginally decreased corrosion rates and increased the turbidity of the water supply. Based on these v observations, it was concluded that the inhibitor was not a viable solution for in-plant corrosion control. To resolve in-plant corrosion issues, recommendations were made for modification of in-plant blending operations to eliminate the corrosive intermediate blend from the process allowing the RO, IX and NF treated waters to be blended in a common location. The effectiveness of a poly/ortho blended phosphate chemical inhibitor was evaluated for reducing lead and copper corrosion to resolve distribution corrosion issues. A 50/50 poly/ortho blend was selected because of its analogous use in similar municipal water facilities. Metallic corrosion rates, particularly lead and copper, were compared with and without the inhibitor to assess the performance of the chemical. Like the previous test phase, the metallic components were pre-corroded prior to the chemical’s introduction to determine if secondary impacts could result from its presence. Results indicated that lead and copper corrosion rates were lower in the presence of the inhibitor, and secondary impacts related to increased turbidity were not observed for this chemical. Based on these results, it was recommended that a poly/ortho blended phosphate be used to decrease lead and copper corrosion within the Town’s distribution system.
3

Slug flow induced corrosion studies using electrochemical noise measurements

Deva, Yashika Poorvi January 1995 (has links)
No description available.
4

Assessment of Commercial Corrosion Inhibiting Admixtures for Reinforced Concrete

Brown, Michael Carey 09 January 2000 (has links)
Corrosion of reinforcing steel in concrete exposed to chloride-laden environments is a well-known and documented phenomenon. The need for cost effective systems for protection against corrosion has become increasingly clear since the first observations of severe corrosion damage to interstate bridges in the 1960's. As one potential solution to the mounting problem of corrosion deterioration of structures, corrosion-inhibiting admixtures have been researched and introduced into service. This report conveys the results of a three-part laboratory study of corrosion inhibiting admixtures in concrete. The commercial corrosion inhibiting admixtures for concrete have been analyzed by three evaluation methods, including: • Conventional concrete corrosion cell prisms under ponding, • Black steel reinforcing bars immersed in simulated concrete pore solutions, • Electrochemical screening tests of special carbon steel specimens in electrochemical corrosion cells containing filtered cement slurry solution. The purposes of the study include: • Determining the influence of a series of commercially available corrosion inhibiting admixtures on general concrete handling, performance and durability properties not related to corrosion. • Determining the effectiveness of corrosion inhibiting admixtures for reduction or prevention of corrosion of reinforcing steel in concrete, relative to untreated systems, under laboratory conditions. • Conducting a short-term pore solution immersion test for inhibitor performance and relating the results to those of the more conventional long-term corrosion monitoring techniques that employ admixtures in reinforced concrete prisms. • Determining whether instantaneous electrochemical techniques can be applied in screening potential inhibitor admixtures. Concrete properties under test included air content, slump, heat of hydration, compressive strength, and electrical indication of chloride permeability. Monitoring of concrete prism specimens included macro-cell corrosion current, mixed-cell corrosion activity as indicated by linear polarization, and ancillary temperature, relative humidity, and chloride concentration documentation. Simulated pore solution specimens were analyzed on the basis of weight loss and surface area corroded as a function of chloride exposure. Electrochemical screening involved polarization resistance of steel in solution. Results include corrosion potential, polarization resistance and corrosion current density. / Master of Science
5

ELECTRODOS AVANZADOS PARA PILAS DE COMBUSTIBLE DE ÓXIDO SÓLIDO (SOFCs)

Vert Belenguer, Vicente Bernardo 10 February 2012 (has links)
Las celdas de combustible de óxido sólido (cuyo acrónimo en inglés es SOFC) son dispositivos energéticos capaces de convertir la energía química de un combustible directamente en energía eléctrica. Esto las dota de unas eficiencias eléctricas muy elevadas, que pueden llegar a ser del 80% si se aprovecha su calor residual de alta calidad mediante turbinas. Además, son capaces de funcionar con una gran variedad de combustibles: hidrógeno, gas natural, gas de síntesis, etanol, metanol, etc. Sin embargo, para su inserción en la cadena de producción energética, su temperatura de funcionamiento debería disminuir al rango de 500-700 ºC sin que se redujeran las densidades de potencias eléctricas generadas. Las SOFC convencionales se basan en la conducción de iones oxígeno de su electrolito, que separa la reacción de combustión del combustible en sus semi-reacciones electroquímicas, generando de este modo la energía eléctrica directamente. Al disminuir la temperatura de operación en este tipo de SOFC, con electrolitos (o membranas) delgados e hidrógeno como combustible, la principal limitación de funcionamiento se centra en la activación y reducción del oxígeno que tiene lugar en el electrodo denominado cátodo. Por otro lado, el empleo de otros combustibles basados en carbono no es compatible con los materiales de ánodos actualmente utilizados. Por tanto, es necesario el desarrollo de nuevos cátodos con mejoradas propiedades electrocatalíticas para la reducción de oxígeno a menores temperaturas, cuyas propiedades termo-mecánicas sean compatibles con las del resto de componentes de la celda, y la obtención de ánodos capaces de funcionar con combustibles basados en carbono. La combinación conjunta de varios lantánidos y bario en la estructura perovskita (LalPrpSmsBab)0.58Sr0.4Fe0.8Co0.2O3 ha permitido obtener compuestos con resistencias de polarización de electrodo significantemente menores que las mostradas por el cátodo del estado de la técnica La0.6Sr0.4Fe0.8Co0.2O3 en el rango de temperaturas 450-650 ºC. / Vert Belenguer, VB. (2011). ELECTRODOS AVANZADOS PARA PILAS DE COMBUSTIBLE DE ÓXIDO SÓLIDO (SOFCs) [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/14669 / Palancia
6

New electrochemical cells for energy conversion and storage

Navarrete Algaba, Laura 03 March 2017 (has links)
In this thesis different materials have been developed to use them in electrochemical cells. The electrochemical cells studied can be divided into two material big groups: solids oxides and acid salts materials. In the first group, materials to use them in electrodes for fuel cells an electrolyzer based on oxygen ion conductor electrolytes were optimized. Pertaining to this group, the influence of doping the Ba0.5Sr0.5Co0.8Fe0.2O3-d perovskite with 3% of Y, Zr and Sc in B position (ABO3-d) was checked. That optimization could reduce the polarization resistance of electrodes and improve the stability with time. Additionally, the limiting mechanisms in the oxygen reduction reaction were determined, and the influence of CO2 containing atmospheres was checked. La2NiO4+d;, pertaining to the Ruddlesden-Popper serie, is a mixed conductor of electron and oxygen ions. This compound was doped in La position (with Nd and Pr) and in Ni position (with Co). The dopants introduced were able to produce structural change and improve the cell performance, reducing in more than one order of magnitude the La1.5Pr0.5Ni0.8Co0.2O4+d; polarization resistance respect to the reference material (La2NiO4+d). In addition, the properties of an electrode based on the pure electronic conductor, La0.8Sr0.2MnO3-d; (LSM), were optimized. The triple phase boundary was enlarged by the addition of a second phase with ionic conductivity. That strategy made possible to reduce the electrode polarization resistance. In order to improve the oxygen reduction reaction, the addition of different catalysts by infiltration was studied. The different infiltrated oxides changed the electrochemistry properties, being the praseodymium oxide the catalyst which made possible a reduction in two orders of magnitude the electrode polarization resistance respects to the composite without infiltration. Furthermore, the efficiency of the cell working in fuel cell and electrolyzer mode was improved. Concerning the materials selected to use as electrodes on proton conductor electrolytes, the efficiency of electrodes based on LSM was optimized by using a second phase with protonic conductivity (La5.5WO12-d) and varying the sintering temperature of the electrode. Finally, the catalytic activity of the cell was boosted by infiltrating samaria doped ceria nanoparticles, achieving higher power densities for the fuel cell. The materials pertaining to the Ruddlesden-Popper series and studied for ionic conductor electrolytes were also used for cathodes in proton conductor fuel cells. After checking the compatibility with the electrolyte material, the influence of different electrode sintering temperatures and air containing atmospheres (dry, H2O y D2O) on the cathode performance was studied. Finally, the electrochemical cells based on acid salts (CsH2PO4) were designed and optimized. In that way, different cell configurations were studied, enabling to obtain thin and dense electrolytes and active electrodes for the hydrogen reduction/oxidation reactions. The thickness of the electrolyte was reduced by using steel and nickel porous supports. Furthermore, an epoxy resin type was added to the electrolyte material to enhance the mechanical properties. The electrodes configuration was modified from pure electronic conductors to composite electrodes. Moreover, copper was selected as an alternative of the expensive platinum working at high operation pressures. The cells developed were able to work with high pressures and with high content of water steam in fuel cell and electrolyzer modes. / En la presente tesis doctoral se han desarrollado materiales para su uso en celdas electroquímicas. Las celdas electroquímicas estudiadas, se podrían separar en dos grandes grupos: materiales de óxido sólido y sales ácidas. En el primer grupo, se optimizaron materiales para su uso como electrodos en pilas de combustible y electrolizadores, basados en electrolitos con conducción puramente iónica. Dentro de este grupo, se comprobó la influencia de dopar la perovskita Ba0.5Sr0.5Co0.8Fe0.2O3-d, con un 3% de Y, Zr y Sc en la posición B (ABO3-d). Esta optimización llevó a la reducción de la resistencia de polarización así como a una mejora de la estabilidad con el tiempo. Así mismo, se determinaron los mecanismos limitantes en la reacción de reducción de oxígeno, y se comprobó la influencia de la presencia de CO2 en condiciones de operación. El La2NiO4+d perteneciente a la serie de Ruddlesden-Popper, es un conductor mixto de iones oxígeno y electrones. Éste, fue dopado tanto en la posición del La (con Nd y Pr) como en la posición del Ni (con Co). Los dopantes introducidos además de producir cambios estructurales, provocaron mejoras en el rendimiento de la celda, reduciendo para alguno de ellos, como el La1.5Pr0.5Ni0.8Co0.2O4+d, en casi un orden de magnitud la resistencia de polarización del electrodo de referencia (La2NiO4+d). De la misma manera, se optimizaron las propiedades del electrodo basado en el conductor electrónico puro La0.8Sr0.2MnO3-d (LSM). La adición de una segunda fase, con conductividad iónica, permitió aumentar los puntos triples (TPB) en los que la reacción de reducción de oxígeno tiene lugar y reducir la resistencia de polarización. Con el fin de mejorar la reacción de reducción de oxígeno, se estudió la adición de nanocatalizadores mediante la técnica de infiltración. Los diferentes óxidos infiltrados produjeron el cambio de las propiedades electroquímicas del electrodo, siendo el óxido de praseodimio el catalizador que consiguió disminuir en dos órdenes de magnitud la resistencia de polarización del composite no infiltrado. De la misma manera, la mejora de la eficiencia del electrodo infiltrado con Pr, mejoró los resultados de la celda electroquímica trabajando como pila (mayores densidades de potencia) y como electrolizador (menores voltajes). En lo que respecta a los materiales seleccionados para su uso como electrodos en electrolitos con conductividad protónica, se optimizó la eficiencia del cátodo basado en LSM, mediante el uso de una segunda fase conductora protónica (La5.5WO12-d) y variando la temperatura de sinterización del electrodo. Finalmente, se mejoró la actividad catalítica mediante la infiltración de nanopartículas de ceria dopada con samario, produciendo mayores densidades de corriente de la pila de combustible. Los materiales pertenecientes a la serie de Ruddlesden-Popper y usados para cátodos en pilas iónicas, fueron empleados también para cátodos en pilas protónicas. Después de comprobar que el material electrolítico (LWO) era compatible con los compuestos de la serie de Ruddlesden-Popper, se estudió la influencia de la temperatura de sinterización de los electrodos en el rendimiento, así como de la composición de la atmosfera de aire (seca, H2O y D2O). Finalmente, se diseñó y optimizó las celdas electroquímicas basadas en sales ácidas (CsH2PO4). En este sentido, se estudiaron diferentes configuraciones de celda, que permitieran obtener un electrolito denso con el menor espesor posible y unos electrodos activos a la reacción de reducción/oxidación de hidrógeno. Se consiguió reducir el espesor del electrolito soportando la celda en discos de acero y níquel porosos. Se añadió una resina tipo epoxi al material electrolítico para aumentar sus propiedades mecánicas. De la misma manera, se cambió la configuración de los electrodos pasando por conductores electrónicos puros a electrodos compuestos por conductores / En la present tesis doctoral es van desenvolupar materials per al seu ús en cel·les electroquímiques. Les cel·les electroquímiques estudiades poden ser dividides en dos grans grups: materials d'òxid sòlid i sals àcides. En el primer grup, es van optimitzar materials per al seu ús com a elèctrodes en piles de combustible i electrolitzadors, basats en electròlits amb conducció purament iònica. Dins d'este grup, es va comprovar la influència de dopar la perovskita Ba0.5Sr0.5Co0.8Fe0.2O3-d amb un 3% de Y, Zr i Sc en la posició B (ABO3-d;). Esta optimització va portar a la reducció de la resistència de polarització així com a una millora de l'estabilitat amb el temps. Així mateix, es van determinar els mecanismes limitants en la reacció de reducció d'oxigen, i es va comprovar la influència de la presència de CO2 en condicions d'operació. El La2NiO4+d pertanyent a la sèrie de Ruddlesden-Popper, és un conductor mixt d'ions oxigen i electrons. Este, va ser dopat tant en la posició del La (amb Nd i Pr) com en la posició del Ni (amb Co). Els dopants introduïts a més de produir canvis estructurals, van provocar millores en el rendiment de la cel·la, reduint per a algun d'ells, com el La1.5Pr0.5Ni0.8Co0.2O4+d, en quasi un ordre de magnitud la resistència de polarització de l'elèctrode de referència (La2NiO4+d). De la mateixa manera, es van optimitzar les propietats de l'elèctrode basat en el conductor electrònic pur La0.8Sr0.2MnO3-d (LSM). L'addició d'una segona fase, amb conductivitat iònica, va permetre augmentar els punts triples (TPB), en els que la reacció de reducció d'oxigen té lloc, i reduir la resistència de polarització. A fi de millorar la reacció de reducció d'oxigen, es va estudiar l'adició de nanocatalitzadors per mitjà de la tècnica d'infiltració. Els diferents òxids infiltrats van produir el canvi de les propietats electroquímiques de l'elèctrode, sent l'òxid de praseodimi el catalitzador que va aconseguir disminuir en dos ordres de magnitud la resistència de polarització del composite no infiltrat. De la mateixa manera, la millora de l'eficiència de l'elèctrode infiltrat amb Pr, va millorar els resultats de la cel·la electroquímica treballant com a pila (majors densitats de potència) i com a electrolitzador (menors voltatges). Pel que fa als materials seleccionats per al seu ús com a elèctrodes en electròlits amb conductivitat protònica, es va optimitzar l'eficiència del càtode basat en LSM, per mitjà de l'ús d'una segona fase conductora protònica (La5.5WO12-d;) i variant la temperatura de sinterització de l'elèctrode. Finalment, es va millorar l'activitat catalítica mitjançant la infiltració de nanopartícules de ceria dopada amb samari, produint majors densitats de corrent de la pila de combustible. Els materials pertanyents a la sèrie de Ruddlesden-Popper i usats per a càtodes en piles iòniques, van ser empleats també per a càtodes en piles protòniques. Després de comprovar que el material electrolític (LWO) era compatible amb els compostos de la sèrie de Ruddlesden-Popper, es va estudiar la influència de la temperatura de sinterització dels elèctrodes en el rendiment, així com de la composició de l'atmosfera d'aire (seca, H2O i D2O). Finalment, es van dissenyar i optimitzar les cel·les electroquímiques basades en sals àcides (CsH2PO4). En este sentit, es van estudiar diferents configuracions de cel·la, que permeteren obtindre un electròlit dens amb el menor espessor possible i uns elèctrodes actius a la reacció de reducció/oxidació d'hidrogen. Es va aconseguir reduir l'espessor de l'electròlit suportant la cel·la en discos d'acer i níquel porosos. Es va afegir una resina tipus epoxi al material electrolític per a augmentar les seues propietats mecàniques. De la mateixa manera, es va canviar la configuració dels elèctrodes passant per conductors electrònics purs a elèctrodes compostos per conductors protònics / Navarrete Algaba, L. (2017). New electrochemical cells for energy conversion and storage [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/78458 / TESIS
7

Comparative Investigation of Detection Techniques for Chloride-induced Corrosion of Loaded Reinforced Concrete Slabs

Chabi, Parham 21 August 2012 (has links)
This study involved a comparative investigation of chloride-induced corrosion detection techniques on loaded reinforced concrete slabs which were exposed to deicing salts and wetting-drying cycles to simulate typical aggressive environments in cold climates. The studied techniques involved linear polarization technique, galvanostatic pulse technique, electrochemical impedance spectroscopy, half-cell potential and concrete electrical resistivity mapping. The results showed that concrete quality and moisture content have a direct effect on corrosion activity, and these properties are represented well with concrete electrical resistivity. The galvanostatic pulse technique was shown to correlate well with electrochemical impedance spectroscopy, which was used as a benchmark for corrosion rate measurements in this study; however, the galvanostatic pulse technique was not capable of detecting corrosion activity in saturated concrete accurately. The results of this research do not support the criteria provided by the ASTM C876-09 standard for using half-cell potentials to estimate the probability of reinforcing steel corrosion in reinforced concrete structures.
8

Material characterisation, phase transitions, electrochemical properties and possible fuel cell applications of Nd₂₋ₓPrₓCuO₄ and Nd2-x-y LayPrₓCuO₄ systems

Patabendige, Chami N. K. January 2012 (has links)
The well-known lanthanide cuprates exist in two principal forms, T and T´, which behave as p-type and n-type conductors, respectively. In order to understand the structural properties and crystal chemistry from the T to T´ phase, the Nd₁.₈₋ₓLaₓPr₀.₂CuO₄ (NLPCO) system was studied varying the La substitution ratio (0≤x≤1.8) and then characterised using high temperature X-ray powder diffraction. From analysis of the X-ray diffraction patterns obtained at room temperature, there are clearly five distinguishable regions for the NLPCO system. They are, (1) monophasic T´ solid–solution (2) two phase mixture T´ + T´´ (3) monophasic T´´solid–solution (4) two phase mixture T´´ + O and finally (5) monophasic O phase solid–solution. The T´´ form has previously been suggested as an ordered form of T´; however here we show via high temperature X-ray diffraction studies that it is a non-transformable metastable phase formed on quenching of the T phase via an orthorhombically distorted variant. Also neutron diffraction and selected area electron diffraction (SAED) studies confirmed that the T ´´phase is 4- fold Cu coordinated. The structural, magnetic and electrical properties of this NLPCO series have been investigated for the selected compositions using X-ray diffraction, magnetization measurements, thermal analysis and conductivity measurements. The aim of the second half of this work was to discover the basic high temperature electrical characteristics of Nd₂₋ₓPrₓCuO₄ and investigate how this matches with those required for components on the SOFC cathode side to identify which dopant level shows highest conductivity and whether it is stable at different temperatures. The idea was to make a new concept in SOFC cathodes and current collector development, using n-type conductors instead of p- type conductors and to try to produce a high conductivity material which is stable under the chemical and thermal stresses that exist while under load that can be used in cathode or current collector applications. The Nd₂₋ₓPrₓCuO₄ (NPCO) series has been studied over a range of dopant levels (x=0.15 - 0.25) and maximum conductivity of 86.7 Scm⁻¹ has been obtained for the composition where x = 0.25. Also NPCO shows n-type semiconductor behaviour which gives operational advantages when operating at mild oxygen deficiency. AC impedance studies have been carried out on symmetrical cells to investigate the performance of NPCO as a cathode material. These studies mainly focused on polarization resistance and the activation energies of the cells. Low Rp values and low activation energies are obtained for a composite cathode compared to pure cathode material. Two configurations of NPCO as cathode materials were tested, pre-fired and in-siu fired. Pre-fired NPCO exhibited better performance than in-situ fired NPCO. Both in-situ and pre-fired current collecting NPCO still showed lowest activation energies which suggest good catalytic activity. From all of these studies, it is evident that the praseodymium doped neodymium cuprate material shows considerable promise as a potential cathode material for solid oxide fuel cell applications.
9

Comparative Investigation of Detection Techniques for Chloride-induced Corrosion of Loaded Reinforced Concrete Slabs

Chabi, Parham 21 August 2012 (has links)
This study involved a comparative investigation of chloride-induced corrosion detection techniques on loaded reinforced concrete slabs which were exposed to deicing salts and wetting-drying cycles to simulate typical aggressive environments in cold climates. The studied techniques involved linear polarization technique, galvanostatic pulse technique, electrochemical impedance spectroscopy, half-cell potential and concrete electrical resistivity mapping. The results showed that concrete quality and moisture content have a direct effect on corrosion activity, and these properties are represented well with concrete electrical resistivity. The galvanostatic pulse technique was shown to correlate well with electrochemical impedance spectroscopy, which was used as a benchmark for corrosion rate measurements in this study; however, the galvanostatic pulse technique was not capable of detecting corrosion activity in saturated concrete accurately. The results of this research do not support the criteria provided by the ASTM C876-09 standard for using half-cell potentials to estimate the probability of reinforcing steel corrosion in reinforced concrete structures.
10

Contribuição ao estudo da Erosão-corrosão de um Aço de Baixo Carbono na presença de Água contendo 3,5% de sal, areia e Inibidor de Corrosão / Contribution to Erosion-Corrosion study of a Low Carbon Steel in the presence of Water containing 3.5% salt, sand and Corrosion Inhibitor

Magalhães, Luciano da Rocha 09 March 2018 (has links)
CAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / CNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico / A extração de petróleo em águas profundas impõe diversos desafios às empresas de óleo e gás e, dentre eles, destaca-se o desgaste sofrido na parte interna dos dutos de transporte devido à ação da água produzida (elevado teor salino), gases e particulados, principalmente a areia produzida. O objetivo deste trabalho foi estudar a erosão-corrosão de um aço com baixo teor de carbono (VMEC 134AP) em um flowloop sob condições dinâmicas: fluido em escoamento com 3,5 % de NaCl, areia em concentração de 40 g cm-3 e adição de substância inibidora de corrosão, com foco principal em observar a possível interação entre o agente erosivo e o inibidor. Para isso, realizaram-se ensaios de erosão-corrosão em um circuito fechado de tubulações com quatro polegadas de diâmetro interno (101,2 mm) e foram aplicadas as técnicas de medição da taxa de desgaste: cupons de perda de massa, resistência à polarização linear e espectroscopia de impedância eletroquímica. Foram monitoradas também a concentração de inibidor no fluido e as modificações na superfície dos corpos de prova por microscopia eletrônica de varredura. Ao fim deste trabalho, concluiu-se que o aço apresenta uma taxa de corrosão de 3,5 mm ano-1 sem a adição de inibidor e 0,4 mm ano-1 com a adição de inibidor. Não foi observada interação direta entre a areia e o inibidor de corrosão que pudesse comprometer a eficiência do mesmo. A técnica de espectroscopia eletroquímica foi empregada com sucesso em condições dinâmicas por meio de uma célula projetado especificamente para tubulações. Os resultados mostraram que a célula e a técnica foram capazes de identificar o efeito sinergético da erosão-corrosão na parte inferior da tubulação e também a atuação do inibidor de corrosão. / Deep water oil production imposes several challenges for oil and gas companies, and among them, the wear suffered in the interior of the transportation pipelines due to the action of produced water (high salt content), gases and particulates, especially produced sand. The objective of this work was to study the erosion-corrosion of a low carbon steel in a flowloop under dynamic conditions: fluid with 3.5% NaCl, sand at a concentration of 40 g cm-3 and addition of a corrosion inhibitory substance, with a main focus on observing the possible interaction between the erosive agent and the inhibitor. For this purpose, we performed erosion-corrosion tests in a closed circuit of pipes of four inches of internal diameter and we applied the corrosion rate measurement techniques of mass loss coupons, linear polarization resistance and electrochemical impedance spectroscopy. We also monitored the concentration of inhibitor in the fluid and the modifications on the surface of the specimens by scanning electron microscopy. At the end of this work, we concluded that the steel presents a corrosion rate of 3.5 mm year-1 without the addition of inhibitor and 0.4 mm year-1 with the addition of inhibitor. We did not observe any direct interaction between the sand and corrosion inhibitor that could compromise the efficiency of the substance. We also concluded that electrochemical techniques can be successfully employed in dynamic conditions by means of a cell specifically designed for pipelines. The results showed that the cell and the technique were able to identify the synergistic effect of erosion-corrosion in the bottom of the pipe and also the action of the corrosion inhibitor. / Tese (Doutorado)

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