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No description available.

M.S.

Thesis (M.Ing.)--Stellenbosch University, 2000. / ENGLISH ABSTRACT: The objective of this research has been to compare nonpoint sources assessment techniques for simulating phosphorous production in rural catchments which have a variety ofland use types. Four nonpoint source assessment techniques capable of simulating phosphorous production, operating at different spatial and temporal resolutions, were selected after an intensive literature review. The model selection criteria included the capability to simulate phosphorous production, the need for the study to cover a range of spatial and temporal resolutions, model data requirements, model affordability and availability in South Africa. The models selected using these criteria are the Phosphorous Export Model (PEM) (Weddepohl & Meyer, 1992), Impoundment and River Management and Planning Assessment Tool for Water Quality Simulation Model (IMPAQ) (DWAF,1995), the Hydrological Simulation Program Fortran (HSPF) (Bricknell,1993) and the Agricultural Catchments Research Unit Model (ACRU) (Smithers and Caldecott, 1994). Four ofthe study catchments were selected within the Berg River basin in the Western Cape and the remaining four were selected within the Amatole catchments in the Eastern Cape. The four subcatchments in the Berg River basin are the Twenty-Four Rivers, Leeu River, Kompanjies River and Doring River catchments and the four in the Amatole catchments are the Upper Buffalo, Cwencwe, Yellowwoods and Gqunube River catchments. The range of land use/cover types comprises: Western Cape catchments : wheat, grapes, natural vegetation and forestry Eastern Cape catchments : natural vegetation and forestry The PEM and IMPAQ models were applied reasonably successfully to all the catchments to simulate phosphorous production, with the observed flow as the input. The HSPF model could not successfully be applied to the catchments to simulate both the catchment hydrology and phosphorous production. Hence, the investigation into HSPF was abandoned, and in its place, the ACRU daily phosphorous yield model was incorporated at a fairly late stage in the research. ACRU was applied to only the Western Cape catchments. The estimated parameters for different land use types were compared to investigate the potential for parameter transfer in space and time. Both the PEM and IMP AQ models showed promise that land use parameters could be transferred in time for catchments located in the Western Cape catchments, but did not show promise for catchments located in the Eastern Cape. The IMPAQ model showed promise that land use parameters could be transferred in space for catchments located in the Eastern Cape, but did not perform as well in the Western Cape catchments. The PEM model showed promise that land use parameters could be transferred in space for catchments located in the Western Cape, but did not perform as well in the Eastern Cape. Since the ACRU phosphorous yield model was included at a late stage of the research, the potential for land use parameter transfer in space and time could not investigated. The model results were verified at the relevant flow and water quality gauging stations. The ACRU phosphorous model verification results showed promise for catchments located in humid parts of the Berg River basin, but did not perform as well in the catchment located in the semi-arid part. RECOMMENDATIONS FOR FURTHER RESEARCH: I. Intensive research should be undertaken to develop a database ofland use parameters/ export coefficients related to phosphorous production (and other non-conservative constituents) in South African catchments. Availability of these parameters would make phosphorous modelling much easier. HSPF should be configured and calibrated, more especially its water quality component, for catchments with hourly rainfall and rainfall stations located within/on the catchment boundaries, to investigate its performance under South African conditions. Given the complexity of the HSPF algorithms and the time required to familiarise oneself with the model, it is recommended that such an investigation be undertaken which is not inclusive of any other models. The spatial resolution ofPEM is extremely coarse, and should be improved to allow the user to partition the total flow in the catchment according to contributions from the variety ofland use types and to estimate soluble and particulate phosphorous parameters for each land use type. A study should be undertaken to investigate the potential for the ACRU phosphorous yield model parameter transfer in time and space. Sampling frequency of water quality data in South Africa should be improved, because it is difficult to assess the performance of the calibrated water quality models, more especially phosphorous export models, due to a lack of continuous data sets. Rainfall data collection in gauged catchments, more especially Western Cape catchments (e.g. Twenty-Four Rivers, Leeu, Kompanjies and the Doring River catchments), should be improved. There should be at least one rainfall gauging station located within the catchment boundaries. This would contribute towards achieving reasonable hydrological calibration or verification. Since runoff is the driving factor for water quality components, improved hydrological calibration/verification would result in reasonable water quality calibration/verification. / AFRIKAANSE OPSOMMING: Die doel van die navorsing was om die simulering van fosfaat produksie in landelike gebiede, wat 'n verskeidenheid grondgebruike het, met behulp van nie-punt bron evaluerings tegnieke te evulaeer. Vier nie-punt bron evaluerings tegnieke, met die vermoë om fosfaat produksie op verskillende ruimtelike en tyds resolusies te simuleer, is gekies na 'n intensiewe ondersoek van beskikbare literatuur. Die kriteria vir die keuse van die model het ingesluit die vermoë om fosfaat produksie te simuleer, die behoefte vir die studie om 'n reeks van ruimtelike en tyds resolusies te simuleer, model data vereistes, model bekostigbaarheid en beskikbaarheid in Suid Afrika. Die gekose modelle, gebaseer op bogemelde kriteria, was die PEM, IMPAQ, HSPF en ACRU modelle. Vier van die opvanggebiede gebruik in die studie, was in die Bergrivier bekken in die Wes-Kaap en vier was in die Amatole opvanggebiede in die Oos-Kaap. Die vier opvanggebiede in die Bergrivier bekken is die Vier-en- Twentigriviere, Leeurivier, Kompanjiesrivier en die Doringrivier en die vier opvanggebiede in die Amatole opvanggebiede is die Bo-Buffels, Cwencwe, Yellowwoods, en die Gunubierivier opvanggebiede. Grondgebruik beslaan die volgende: Wes-Kaap opvanggebiede : koring, druiwe, natuurlike weiding en plantasies. Oos-Kaap : natuurlike plantegroei en plantasies Die PEM en IMPAQ modelle is met redelike sukses in al die opvanggebiede gebruik vir die simulasie van fosfaat produksie, met die waargenome vloei as invoer. Die HSPF model kan nie met enige sukses gebruik word om beide die opvanggebied hidrologie en fosfaat produksie, te simuleer nie. Die HSPF model is dus uitgeskakel en in 'n redelike laat stadium van die studie met die ACRU daaglikse fosfaat leweringsmodel vervang. Die ACRU model is net op die Wes-Kaap opvanggebiede toegepas. Die beraamde parameters vir die verskillende grondgebruik tipes is vergelyk om die potensiaal vir parameter oordrag in ruimte en tyd te ondersoek. Beide die PEM en IMPAQ modelle het belowend vertoon ten opsigte van die oordrag van grondgebruik parameters in tyd vir opvanggebiede in die Wes- Kaap, maar het geensins belowend vertoon vir die Oos-Kaap opvanggebiede nie. Die IMPAQ model het belowend vertoon ten opsigte van die ruimtelike oordrag van grondgebruik parameters vir die Oos-Kaap opvanggebiede, maar het nie so goed vertoon in die Wes-Kaap opvanggebiede nie. Die PEM model het belowend vertoon ten opsigte van die ruimtelike oordrag dat grondgebruikte parameters in die Wes-Kaap opvanggebiede is, maar het nie so goed in die Oos-Kaap opvanggebiede vertoon nie. Aangesien die ACRU fosfaat leweringsmodel op 'n laat stadium van die navorsing ingesluit is, kan die potensiaal vir die oordrag van grondgebruik parameters in ruimte en tyd nie ondersoek word nie. Die model resultate is by die toepaslike vloei en waterkwaliteit meetstasies geverifiëer Die resultate van die ACRU fosfaat model verifikasie het belowend vertoon vir opvangebiede in die humiede gedeeltes van die Bergrivier bekken, maar het nie so goed vertoon in die semi-droeë deel van die opvangebied nie. AANBEVELINGS VIR VERDERE NAVORSING : Y4 Intensiewe navorsing moet onderneem word ten einde in 'n databasis van grondgebruik parameters/oordrag koëffisiente met betrekking tot fosfaat produksie (en ander niekonserwatiewe bestandelle ) in Suid Afrikaanse opvanggebiede op te bou. Beskikbaarheid van hierdie parameters sal fosfaat modellering vergemaklik. Die HSPF model moet opgestel en gekalibreer word, meer spesifiek ten opsigte van die waterkwaliteit komponent, vir opvanggebiede met uurlikse reënval en reënvalstasies binne of op die opvanggebied grense, om die model se vertoning onder Suid Afrikaanse omstandighede te ondersoek. Gegewe die kompleksiteit van die HSPF algoritmes en tyd benodig om met model vertroud te raak, word dit aanbeveel dat so 'n ondersoek onderneem word met uitsluiting van die ander modelle. Die ruimtelike resolusie van die PEM model is uitermatig grof, en behoort verbeter te word ten einde die gebruiker toe te laat om die totale vloei in die opvanggebied in ooreenstemming met die bydraes van die onderskeie grondgebruik tipes te verdeel en om oplosbare en partikulere fosfaat parameters vir elke grondgebruik tipe te beraam. 'n Studie om die potensiaal vir die ruimtelike en tydsoordrag van die ACRU fosfaat leweringsmodel parameters te ondersoek, moet onderneem word. Die frekwensie van waterkwaliteit monitering in Suid Afrika moet verbeter word, aangesien dit moelik is om, weens 'n gebrek aan deurlopend waargenome data, die vertoning van gekalibreerde waterkwaliteit modelle te ondersoek, meer spesifiek nog fosfaat uitvoer modelle. Reënval inligting versameling in gemete opvanggebied, meer spesifiek die Wes-Kaap opvanggebiede (bv.Vier-en-Twintigriviere, Leeu, Kompanjies en Doringrivier opvanggebiede), behoort verbeter te word. Daar behoort ten minste een reënval stasie binne die opvanggebied grense te wees. Dit sal bydra tot die bereiking van redelike hidrologiese kalibrasie ofverifikasie. Aangesien afloop die dryfveer van die waterkwaliteit komponente is, sal verbeterde hidrologiese kalibrasie/verifikasie lei tot redelike waterkwaliteit kalibrasie/verifikasie.

A principal limitação da Avaliação do Ciclo de Vida (ACV) é a necessidade da coleta de um elevado número de dados representativos para a região em estudo. Esta limitação pode ser contornada pela construção de bancos de dados regionais, ou seja, de inventários de elementos que são comuns aos ciclos de vida de inúmeros produtos. Entre esses elementos encontram-se os fertilizantes químicos. Nesse contexto este trabalho de doutorado apresenta uma contribuição ao banco de dados brasileiro para apoio aos estudos de ACV, qual seja: os inventários do ciclo de vida da uréia; do nitrato de amônio e do sulfato de amônio adequados às condições brasileiras. Para a elaboração dos inventários foi necessário obter o perfil detalhado do setor de fertilizantes nitrogenados no país. Em seguida, efetuou-se a identificação e quantificação das entradas de recursos naturais e das disposições de rejeitos associados ao ciclo de vida dos fertilizantes estudados. Por fim, fez-se uma discussão dos principais aspectos ambientais associados à produção dos três fertilizantes no Brasil. Os dados obtidos no inventário da uréia revelaram 45 aspectos ambientais. No que diz respeito às emissões atmosféricas, verificou-se que o dióxido de carbono foi responsável por 98,3% do total e em relação aos efluentes líquidos, os compostos nitrogenados corresponderam a 73,5% do total. Quanto ao inventário do nitrato de amônio, foram encontrados 42 aspectos ambientais. Verificou-se que o dióxido de carbono foi responsável por 79% do total de emissões atmosféricas e que em relação aos efluentes líquidos, os compostos nitrogenados corresponderam a 25,3% do total. O inventário do sulfato de amônio revelou a existência de 46 aspectos ambientais. Concluiu-se que o dióxido de carbono contribuiu por 99% do total de emissões e que os compostos nitrogenados e de enxofre foram responsáveis, respectivamente, por 5% e 41% do total de efluentes líquidos gerados. A partir dos resultados deste trabalho torna-se possível identificar oportunidades para a melhoria de desempenho ambiental dos processos industriais analisados. / The main limitation of Life Cycle Assessment (LCA) is the necessity for collection a large number of representative data for the region under study. This limitation can get rounded by the construction of regional databases, or inventories of elements that are common to the life cycle of many products. Among these elements are the chemical fertilizers. In this context is inserted this doctorate thesis which presents a contribution to the Brazilian database for support LCA studies which is: the life cycle inventories of urea, ammonium nitrate and ammonium sulfate for the Brazilian conditions. For the elaboration of inventories was necessary to get the detailed profile of nitrogen fertilizers industry in Brazil. Following, the quantified identification of the natural resources inputs and the waste dispositions associated to the fertilizers life cycle referred in this study is made. Finally, there was a discussion of main environmental aspects associated to production of the three fertilizers in Brazil. Data from urea inventory showed 45 environmental aspects. With regard to air emissions, it was found that carbon dioxide was responsible for 98.3% of the total and for the liquid effluents, the nitrogen compounds accounted for 73.5% of the total. As ammonium nitrate inventory, were found 42 environmental aspects. It was found that carbon dioxide was responsible for 79% of total emissions and in relation to liquid effluents, the nitrogen compounds accounted for 25.3% of the total. The ammonium sulfate inventory revealed the existence of 46 environmental aspects. It was concluded that carbon dioxide contributed by 99% of total emissions and the sulfur and nitrogen compounds were responsible, respectively, for 5% and 41% of all liquid effluents generated. From the results of this study becomes possible to identify opportunities for improving the environmental performance of industrial processes analyzed.

Resumo: Atualmente, no campo da engenharia de produção o termo desenvolvimento sustentável está sendo amplamente divulgado como uma oportunidade para melhoria na qualidade de vida que alia conservação e proteção do meio ambiente. Ao se observar a questão da poluição industrial, é possível perceber que ela vem agravando a deterioração do meio ambiente e da saúde pública, conseqüentemente, exigindo uma nova postura das empresas no sentido de mitigar seus impactos ambientais. Neste sentido, emergiu o objetivo deste trabalho: diagnosticar as ações ambientais das indústrias calçadistas considerando, a priori, a importância local do pólo produtivo calçadista de Franca-SP. Assim, desenvolveu-se uma estrutura teórica baseada em Sistema de Gestão Ambiental, Legislação Ambiental e Programas de Prevenção à Poluição, cada qual com um instrumento em evidência, quer seja a norma ISO 14001, o Licenciamento Ambiental e o Programa Produção mais Limpa. Todos estes elementos subsidiaram detalhamentos específicos dentro do contexto em que se examinavam ações efetivas praticadas por empresas calçadistas. Sucintamente, os resultados alcançados na pesquisa exploratória nos levou a perceber que há uma lacuna entre os benefícios apresentados na literatura sobre a ISO 14001 e a real percepção dos empresários entrevistados; basicamente, estes mesmos (empresários) apenas "reagem" para não serem punidos, fato que adverte a relevância de se manter controles mais rígidos sobre ferramentas como o Licenciamento Ambiental e, por último, concluiu-se que o Programa "Produção mais Limpa" se apresenta com potencial para articular as ações ambientais identificadas, partindo da aplicação de know-how na gestão privada para a articulação à governança pública, visando mudanças de atitudes para melhoria ambiental na cadeia calçadista como um todo. Portanto, os resultados dessa pesquisa identificaram ações tímidas e incipientes... / Abstract: In the hole world, sustainable development to improve life quality with environment protection is becoming a strong and weel aceptable idea. It is possible to observe that industrial pollution is increasing enviroment and health deterioration, and so, demanding a new attitude from organizations concerning their environment impacts. So, the objective of this paper is to diagnose environmental actions in shoes manufactures, a priori, the importance of local shoes industries in Franca city. So, a theorictical structure was developed based in Environmental Management System, Laws, and Pollution Prevention Programs, each one with a tool, such as ISO 14001, Environmental Licensing and More Clean Production Program. All these elements helped in specific detail in a context that elective actions were studies. The results obtained in the research made us realize that there is a void between benefits presented in the literature about ISO 14001 and real perception of interviewed managers: they just react to avoid legal punishments, wat points the need to keep more rigorous controlson tools such as Environmental Licensing and, at last, it was concluded that More Clean Production Program presented a potential to articulate environment action, applying know-how in private management to public "governança", willing to change attitudes to environments improve in shoes supply chain as a hole. So, results of this research identified shy ans incipients actions from interviewed managers to the sustentability of the sector. / Orientador: Jair Wagner de Souza Manfrinato / Coorientador: Agnaldo de Sousa Barbosa / Banca: Adílson Renófio / Banca: Aldo Roberto Ometto / Mestre

Within the greater movement of sustainable development, industrial practices have been identified as a key area in which much improvement is both necessary and possible. The development and operation of industrial parks have become a focus of these efforts. The basic premise of this thesis is that a sustainable industrial park should function in an economically competitive manner that provides for human needs through market mechanisms while doing so in alliance with the local community, in congruence with the local ecosystem and within the carrying capacity of the planet. From a municipal planning and economic development perspective, this thesis focuses upon the development of a municipal strategy to effectuate sustainable industrial development and operations. Utilizing a blended theoretical approach incorporating general systems theory and planning theories, the proposed industrial park surrounding the Hamilton International Airport, in the City of Hamilton, Ontario, Canada, has been analyzed to develop a viable sustainability vision for the park, identify barriers to implementing and achieving that vision, and formulate a municipal strategy to promote and enable the pursuit and realization of that vision. It was found that there is an important role for the municipality to assume and numerous opportunities for concrete municipal action throughout the planning, development and operational stages of the industrial park. Upon reflection of the research process, the findings were extrapolated to garner wider applicability and relevance to other municipalities provincially, nationally, and internationally, as well as to the professional and academic community involved in industrial sustainability.

Within the greater movement of sustainable development, industrial practices have been identified as a key area in which much improvement is both necessary and possible. The development and operation of industrial parks have become a focus of these efforts. The basic premise of this thesis is that a sustainable industrial park should function in an economically competitive manner that provides for human needs through market mechanisms while doing so in alliance with the local community, in congruence with the local ecosystem and within the carrying capacity of the planet. From a municipal planning and economic development perspective, this thesis focuses upon the development of a municipal strategy to effectuate sustainable industrial development and operations. Utilizing a blended theoretical approach incorporating general systems theory and planning theories, the proposed industrial park surrounding the Hamilton International Airport, in the City of Hamilton, Ontario, Canada, has been analyzed to develop a viable sustainability vision for the park, identify barriers to implementing and achieving that vision, and formulate a municipal strategy to promote and enable the pursuit and realization of that vision. It was found that there is an important role for the municipality to assume and numerous opportunities for concrete municipal action throughout the planning, development and operational stages of the industrial park. Upon reflection of the research process, the findings were extrapolated to garner wider applicability and relevance to other municipalities provincially, nationally, and internationally, as well as to the professional and academic community involved in industrial sustainability.

This thesis investigates the use of a combined set of quantitative and qualitative tools to help address known barriers associated with adopting and sustaining pollution prevention (P2) in an industrial manufacturing setting. The research was conducted at an Ontario dairy processing facility in the form of a case study. P2 is an alternative approach to traditional pollution control or abatement techniques. P2 is a preferred method for pollution management, both environmentally and economically, as it focuses on the efficient use of resources to prevent pollution at the source. The tools used in this research included: wastewater treatability testing, hierarchical process mapping, employee interviews, and causal loop diagrams (CLDs). The application of these tools assisted the participating facility in better characterizing its existing environmental problems, uncovering concrete resource saving opportunities within its processes, and providing more adaptive visual approaches of documenting and conveying P2 concepts. / OMAFRA Agri-Food and Rural Link KTT Funding Program

Dissertation (D.P.H.)--University of Michigan.