Stuttgart, Univ., Diss., 2006.

Universiẗat, Diss., 1999--Essen.

Techn. Universiẗat, Diss., 2004--Berlin.

We synthesize polyamide compounds containing bithiophene functional group and lexitropsin analogs and study their biological activity.

An important component in understanding the laser sintering process is knowledge of the thermal properties of the processed material. Thermal conductivity measurements of pure polyamide 12 and polyamide11 with multi-wall carbon nanotubes were conducted based on transient plane source technology using a Hot Disk® TPS500 conductivity measurement device. Polyamide powder was packed to three different densities in nitrogen at room temperature. Thermal diffusivity and conductivity were measured from 40°C to 170°C for both fresh powder and previously heated (“recycled”) powder. The fresh powder tests revealed that thermal conductivity increased linearly with temperature whereas for previously heated powder, more constant and higher thermal conductivity was observed as it formed a powder cake. Tests were also performed on fully dense polyamide 12 to establish a baseline. Polyamide 12 powder had a room-temperature thermal conductivity of approximately 0.1 W/mK which increased with temperature, whereas the bulk laser sintered polyamide 12 room-temperature value was 0.26 W/mK and generally decreased with increasing temperature. / text

Lithophane is a translucent image created by varying the plate thickness; the image is observed using a back lit light source. Software Bmp2CnC linearly converts the black and white image grayscale into the thickness, thus generates CAD file and lithophane is fabricated by additive manufacturing machines. Additive manufacturing makes highly complex lithophane fabrication possible. It is a convenient, rapid, green, design-driven, and high precision way to make lithophanes, and no post processing is needed. Optical properties of laser sintered polyamide 12 translucent additive manufactured parts were analyzed in this dissertation. First, selected optical properties of laser sintered polyamide 12 blank plates under different monochromatic light and white light were investigated and applied in production of laser sintered lithophanes to achieve better performance. A spectrophotometer was used to measure the transmittance of visible light through laser sintered polyamide 12 plates as a function of plate thickness. The transmittance decreased with increasing plate thickness according to a modified Beer-Lambert Law, and it varied significantly depending on the monochromatic wavelength. Monochromatic LEDs were used to assess the wavelength dependence on the transmission and contrast. Highest transmission was observed with green light (540 nm), and poorest transmission was measured for yellow light (560 nm). Second, several parameters affecting lithophane manufacturing performance were analyzed including lithophane orientation with respect to light source, brightness and contrast versus plate thickness and grayscale level, quantized plate thickness correction, surface finish quality, and manufacturing orientation. It was found that brightness was relative to the plate thickness. The contrast was defined by the lithophane grayscale level, which was influenced by sintering layer thickness, plate thickness, and sintering orientation. Thinner sintering layers resulted in more grayscale levels of the image and smaller difference between the theoretical thickness and actual thickness. Relatively larger plate thickness defined greater contrast; however, the plate thickness was limited due to the light transmission. Lithophane quality was largely improved by changing the manufacturing orientation from the XY plane orientation to the ZX/ZY plane orientation. The grayscale level changed continuously when parts were constructed in the z orientation. Third, other thermoplastic semi-crystalline materials were analyzed for LS optically translucent part production. Last, plates and lithophanes were built using a different AM platform: stereolithography (SL) with Somos® ProtoGen[Trademark] O- XT 18420 white resin. Different optical properties and lithophane performance were found and compared with PA 12 parts. In conclusion, laser sintered polyamide 12 optical properties varied with light wavelength and reached the maximum under green light. When building in the XY plane, thinner layer thickness (0.07 mm) and relative thicker maximum plate thickness (3.81 mm) leaded to higher contrast and greyscale level. Lithophane quality was largely improved when fabricated in the ZX/ZY plane orientation. Lithophanes made from stereolithography were analyzed but showed lower contrast due to the optical property difference of the white resin. Laser sintered lithophanes serve as an interesting and complex LS industrial application. Optical properties, manufacturing aspects, and other related issues were analyzed and discussed in this dissertation. Future work may include the use of nanocomposites for optimal lithophane performance, and more precise manufacturing processing to improve the lithophane resolution. / text

Universiẗat-Gesamthochsch., Diss.--Paderborn, 1999.

Thesis (doctoral)--Universität Köln, 2007.

This research was undertaken to improve the understanding of structure-property-performance relationships in crosslinked polyamide (PA) thin-film composite (TFC) membranes as characterized by liquid and gas permeation studies. The ultrathin PA selective layer formed by interfacial polymerization between meta-phenylene diamine and trimesoyl chloride was confirmed to contain dense polymer matrix regions and defective regions in both dry and hydrated states. The first part of this research studied the effect of non-selective convection through defective regions on water flux and solute flux in pressure-assisted forward osmosis (PAFO). Through systematic comparison with cellulose triacetate (CTA) and PEBAX-coated PA-TFC membranes, the existence of defects in pristine, hydrated PA-TFC membranes was verified, and their effects were quantified by experimental and modeling methods. In the membrane orientation of selective layer facing the draw solution, water flux increases of up to 10-fold were observed to result from application of low hydraulic pressure (1.25 bar). Convective water flux through the defects was low (< 1% of total water flux for PA-TFC membranes) and of little consequence in practical FO or reverse osmosis (RO) applications. However, it effectively mitigated the concentration polarization in PAFO and therefore greatly increased the diffusive flux through the dense regions. The second part of this research characterized the structures of the PA material and the PA selective layer by gas adsorption and gas permeation measurements. Gas adsorption isotherms (N2 at 77K, CO2 at 273K) confirmed the microporous nature of PA in comparison with dense CTA and polysulfone materials. Gas permeation through the commercial PA-TFC membranes tested occurred primarily in the defective regions, resulting in Knudsen gas selectivity for various gas pairs. Applying a Nafion coating layer effectively plugged the defects and allowed gas permeation through the dense PA regions, which significantly decreased gas permeance and increased gas selectivity. Specifically, high He and H2 selectivity against CO2 suggests the potential applications of this membrane in He recovery and CO2 capture in pre-combustion. Finally, the dense PA matrix was modified with two types of novel nanofiller to improve desalination performance in RO. A series of dense, nano-sized (1-3 nm) polyhedral oligomeric silsesquioxanes (POSS) with different functional groups were systematically incorporated into the PA matrix by physical blending or chemical fixation. The free volume of the PA matrix increased with addition of POSS, leading to water flux increases of up to 67 %, while maintaining high NaCl rejections. The effects of adding microporous, hydrophobic zeolitic imidazolate framework-8 (ZIF-8) nanoparticles into PA are presented in the last chapter. A 162 % water flux increase was achieved without decreasing NaCl rejection. This interesting result can be attributed to a less crosslinked PA structure and to the intrinsic desalination properties of ZIF-8.

Yes / Recycling of polymers is a necessity in our intensively consuming polymer world but the nature of polymers is such that they are prone to thermal degradation when re-extruded and this poses technical challenges to recycling. This article describes research that seeks to rebuild the structure of degraded PA6. We present data from controlled experiments with pristine pPA6 extruded to form a base recycle rPA6 to which we added two chain extenders, separately: one with anhydride multifunctionality (ANHY), highly reactive with amide groups and one with epoxy multifunctionality (EPOX), less reactive. We found from rheological data carried out in the linear viscoelastic region (so as to study structural changes) a striking difference in the ability of the chain extenders to rebuild structure: 306% increase in the complex viscosity of rPA6/ANHY compared to 25% in that of rPA6/EPOX of the base rPA6. Mechanical and thermal (DSC and TGA) tests confirmed the superior efficacy of the multifunctional anhydride chain extender. Beside the practical benefit that ensues from this research, it also provides a strategic platform to develop chain extenders for other degrading polymers on the basis of understanding the degradation chemical reaction and targeting the most reactive end group of the split chains.