The formation and dissolution of the North Water Polynya (an area of open water surrounded by a sea-ice covered ocean) was examined to determine the spatial and temporal variability of the Smith Sound ice arch (a feature that prevents ice from covering the polynya). A passive microwave, sea ice concentration dataset was used to create an index classification algorithm that categorized the formation and dissolution of the North Water Polynya from 1979 to 2012. Multiple years were classified as atypical, with the polynya forming earlier, the ice arch not forming at Smith Sound, or the ice arch not forming at all. Secondly, we compare and contrast atmospheric factors that influenced the formation of the ice arch during a typical (2010-2011) and an atypical (2009-2010) formation year. A significant southerly wind event in 2009-2010 could have displaced the ice pack and prevented the consolidation of the ice arch. The importance of the changing ice pack in Nares Strait to the formation of the polynya is also discussed. / May 2016

During the fourth International Polar Year, an interdisciplinary study was conducted to examine the couplings between sea ice, ocean, atmosphere, and ecosystem in the southeastern Beaufort Sea. This thesis examines components of the system that control the air–sea exchange of carbon dioxide. Using eddy covariance measurements, we found enhanced CO2 exchange associated with new ice formation in winter flaw leads. This exchange was typically directed towards the surface, although we also measured one instance of outgassing. Sea surface dissolved CO2 measurements (pCO2sw) in Amundsen Gulf showed significant undersaturation with respect to the atmosphere at freeze–up, followed by a slow increase over the winter until spring phytoplankton blooms caused strong undersaturation at break–up. Over the summer, pCO2sw increased until becoming slightly supersaturated due to surface warming. Along the southern margins of Amundsen Gulf and on the Mackenzie Shelf we found pCO2sw supersaturations in the fall due to wind–driven coastal upwelling. In the spring, this upwelling occurred along the landfast ice edges of Amundsen Gulf. By combining observations of enhanced winter gas exchange with observations of pCO2sw in Amundsen Gulf, we derived an annual budget of air–sea CO2 exchange for the region. This exercise showed that uptake through the winter season was as important as the open water season, making the overall annual uptake of CO2 about double what had previously been calculated. Prior to this work, the prevailing paradigm of air–sea CO2 cycling in Arctic polynya regions posited that strong CO2 absorption occurs in the open water seasons, and that a potential outgassing during the winter is inhibited by the sea ice cover. As a new paradigm, we propose that the spatial and temporal variability of many processes – including phytoplankton blooms, sea surface temperature and salinity changes, upwelling, river input, continental shelf processes, and the potential for high rates of winter gas exchange – need to be considered in order to understand the carbon source/sink status of a given Arctic polynya region. A paradigm that considers such varied processes is useful in understanding how climate change in the Arctic can impact air–sea CO2 exchange.

During the fourth International Polar Year, an interdisciplinary study was conducted to examine the couplings between sea ice, ocean, atmosphere, and ecosystem in the southeastern Beaufort Sea. This thesis examines components of the system that control the air–sea exchange of carbon dioxide. Using eddy covariance measurements, we found enhanced CO2 exchange associated with new ice formation in winter flaw leads. This exchange was typically directed towards the surface, although we also measured one instance of outgassing. Sea surface dissolved CO2 measurements (pCO2sw) in Amundsen Gulf showed significant undersaturation with respect to the atmosphere at freeze–up, followed by a slow increase over the winter until spring phytoplankton blooms caused strong undersaturation at break–up. Over the summer, pCO2sw increased until becoming slightly supersaturated due to surface warming. Along the southern margins of Amundsen Gulf and on the Mackenzie Shelf we found pCO2sw supersaturations in the fall due to wind–driven coastal upwelling. In the spring, this upwelling occurred along the landfast ice edges of Amundsen Gulf. By combining observations of enhanced winter gas exchange with observations of pCO2sw in Amundsen Gulf, we derived an annual budget of air–sea CO2 exchange for the region. This exercise showed that uptake through the winter season was as important as the open water season, making the overall annual uptake of CO2 about double what had previously been calculated. Prior to this work, the prevailing paradigm of air–sea CO2 cycling in Arctic polynya regions posited that strong CO2 absorption occurs in the open water seasons, and that a potential outgassing during the winter is inhibited by the sea ice cover. As a new paradigm, we propose that the spatial and temporal variability of many processes – including phytoplankton blooms, sea surface temperature and salinity changes, upwelling, river input, continental shelf processes, and the potential for high rates of winter gas exchange – need to be considered in order to understand the carbon source/sink status of a given Arctic polynya region. A paradigm that considers such varied processes is useful in understanding how climate change in the Arctic can impact air–sea CO2 exchange.

The Antarctic plays an important role in the global climate system. On the one hand, the Antarctic Ice Sheet is the largest freshwater reservoir on Earth. On the other hand, a major proportion of the global bottom-water formation takes place in Antarctic shelf regions, forcing the global thermohaline circulation. The main goal of this dissertation is to provide new insights into the dynamics and stability of the EAIS during the Quaternary. Additionally, variations in the activity of bottom-water formation and their causes are investigated. The dissertation is a German contribution to the International Polar Year 2007/ 2008 and was funded by the ‘Deutsche Forschungsgesellschaft’ (DFG) within the scope of priority program 1158 ‘Antarctic research with comparative studies in Arctic ice regions’. During RV Polarstern expedition ANT-XXIII/9, glaciomarine sediments were recovered from the Prydz Bay-Kerguelen region. Prydz Bay is a key region for the study of East EAIS dynamics, as 16% of the EAIS are drained through the Lambert Glacier into the bay. Thereby, the glacier transports sediment into Prydz Bay which is then further distributed by calving icebergs or by current transport. The scientific approach of this dissertation is the reconstruction of past glaciomarine environments to infer on the response of the Lambert Glacier-Amery Ice Shelf system to climate shifts during the Quaternary. To characterize the depositional setting, sedimentological methods are used and statistical analyses are applied. Mineralogical and (bio)geochemical methods provide a means to reconstruct sediment provenances and to provide evidence on changes in the primary production in the surface water column. Age-depth models were constructed based on palaeomagnetic and palaeointensity measurements, diatom stratigraphy and radiocarbon dating. Sea-bed surface sediments in the investigation area show distinct variations in terms of their clay minerals and heavy-mineral assemblages. Considerable differences in the mineralogical composition of surface sediments are determined on the continental shelf. Clay minerals as well as heavy minerals provide useful parameters to differentiate between sediments which originated from erosion of crystalline rocks and sediments originating from Permo-Triassic deposits. Consequently, mineralogical parameters can be used to reconstruct the provenance of current-transported and ice-rafted material. The investigated sediment cores cover the time intervals of the last 1.4 Ma (continental slope) and the last 12.8 cal. ka BP (MacRobertson shelf). The sediment deposits were mainly influenced by glacial and oceanographic processes and further by biological activity (continental shelf), meltwater input and possibly gravitational transport. Sediments from the continental slope document two major deglacial events: the first deglaciation is associated with the mid-Pleistocene warming recognized around the Antarctic. In Prydz Bay, the Lambert Glacier-Amery Ice Shelf retreated far to the south and high biogenic productivity commenced or biogenic remains were better preserved due to increased sedimentation rates. Thereafter, stable glacial conditions continued until 400 - 500 ka BP. Calving of icebergs was restricted to the western part of the Lambert Glacier. The deeper bathymetry in this area allows for floating ice shelf even during times of decreased sea-level. Between 400 - 500 ka BP and the last interglacial (marine isotope stage 5) the glacier was more dynamic. During or shortly after the last interglacial the LAIS retreated again due to sea-level rise of 6 - 9 m. Both deglacial events correlate with a reduction in the thickness of ice masses in the Prince Charles Mountains. It indicates that a disintegration of the Amery Ice Shelf possibly led to increased drainage of ice masses from the Prydz Bay hinterland. A new end-member modelling algorithm was successfully applied on sediments from the MacRobertson shelf used to unmix the sand grain size fractions sorted by current activity and ice transport, respectively. Ice retreat on MacRobertson Shelf commenced 12.8 cal. ka BP and ended around 5.5 cal. ka BP. During the Holocene, strong fluctuations of the bottomwater activity were observed, probably related to variations of sea-ice formation in the Cape Darnley polynya. Increased activity of bottom-water flow was reconstructed at transitions from warm to cool conditions, whereas bottom-water activity receded during the mid- Holocene climate optimum. It can be concluded that the Lambert Glacier-Amery Ice Shelf system was relatively stable in terms of climate variations during the Quaternary. In contrast, bottom-water formation due to polynya activity was very sensitive to changes in atmospheric forcing and should gain more attention in future research. / Die Antarktis spielt im globalen Umweltsystem eine tragende Rolle. Mit ihrem mächtigen Eispanzer ist sie nicht nur der größte Süsswasserspeicher auf der Erde, in ihren Schelfregionen wird auch ein Großteil der globalen Bodenwassermassen gebildet, welche die globale thermohaline Zirkulation antreiben. Hauptziel dieser Arbeit, welche einen deutschen Beitrag zum Internationalen Polarjahr 2007/ 2008 liefert, war es, neue Erkenntnisse hinsichtlich der Stabilität des Ostantarktischen Eisschildes während des Quartärs zu liefern. Weiterhin sollten Aussagen über Variationen in der Bildung von Antarktischem Bodenwasser und deren Ursachen getroffen werden. Dazu wurde im Rahmen der ‚Polarstern‘ Expedition ANT-XXIII/9 eine Beprobung glaziomariner Sedimente zwischen Prydz Bucht und Kerguelen Plateau durchgeführt. Diese Region eignet sich zur Untersuchung der Ostantarktischen Eisdynamik besonders gut, da hier der Lambert Gletscher, etwa 16% des Ostantarktischen Eispanzers drainiert. Er transportiert dabei Sediment nach Norden, das schließlich die Prydz Bucht erreicht und durch direkten Transport über kalbende Eisberge oder durch Umlagerung und Verteilung mithilfe von Meeresströmungen weiter verfrachtet wird. Der wissenschaftliche Ansatz dieser Arbeit besteht darin, über die Verteilung dieser Sedimente in Raum und Zeit, d.h. über Variationen des glaziomarinen Paläoregimes, die Reaktion des Lambert Gletschers und des vorgelagerten Amery Schelfeises auf Klimaschwankungen während des Quartärs zu rekonstruieren. Dabei werden sowohl sedimentologische Methoden unter Einbeziehung neuer statistischer Möglichkeiten angewandt, um Sedimentationsprozesse zu charakterisieren, als auch mineralogische und (bio)geochemische Parameter verwendet, um Aussagen über die Herkunft der Sedimente und Änderungen in der Produktivität im Oberflächenwasser treffen zu können. Die Altersbestimmung der Sedimentkerne erfolgte mittels Paläomagnetik, Paläointensitäten, Biostratigraphie und Radiokarbondatierungen. Die Oberflächensedimente im Untersuchungsgebiet zeigen deutliche Unterschiede sowohl hinsichtlich ihrer Tonmineral- als auch Schwermineralzusammensetzung. Beide mineralogischen Parameter zeigen die größten Differerenzen auf dem Schelf. Dort lassen sich deutlich Sedimente der Prydz Bucht von Sedimenten des MacRobertson Shelfes differenzieren. Sie stellen daher ein gutes Hilfsmittel dar, um sowohl die Herkunft von eis- als auch strömungstransportiertem Material zu rekonstruieren. Die untersuchten Sedimentkerne decken den Zeitraum der letzten 1,4 Millionen Jahre (Kontinentalhang) bzw. der letzten 12,8 tausend kal. Jahre v. H. ab (MacRobertson Schelf). Die abgelagerten Sedimente wurden i. W. durch glaziale und ozeanographische Einflüsse geprägt, aber auch durch Bioproduktion (Schelf) bzw. durch Schmelzwassereinträge und möglicherweise gravitative Prozesse (Kontinentalhang). In den Sedimenten des Kontinentalhangs sind zwei starke Enteisungsereignisse überliefert: Das erste Ereignis steht mit dem mittelpleistozänen Klimaoptimum in Verbindung, das auch in anderen antarktischen Regionen nachgewiesen wurde. Es führte in der Prydz Bucht zu einem weitreichenden Rückzug des Lambert Gletscher-Amery Schelfeises (LAIS) und gleichzeitig zu einer hohen Primärproduktion. Danach herrschten bis etwa 400 - 500 tausend Jahre v. H. stabile glaziale Bedingungen. Kalbung von Eisbergen war wahrscheinlich auf den westlichen Teil des Lambert Gletschers begrenzt, wo eine tiefere Bathymetrie auch bei niedrigerem globalen Meeresspiegel noch Aufschwimmen des Gletschereises erlaubt. Zwischen 400 - 500 tausend Jahren v. H. und vermutlich dem letzten Interglazial wurde der Gletscher schließlich wieder dynamischer, um mit oder kurz nach dem letzten Interglazial (Meeresspiegel etwa 6 - 9 m höher) eine weitere Phase deutlichen Rückzuges zu durchlaufen. Beide Ereignisse lassen sich mit Phasen der Eisreduktion in den Prinz Charles Bergen korrelieren, d.h. der Rückzug des Lambert Gletschers hatte möglicherweise ein erhöhtes Nachfließen von Eismassen aus dem Hinterland zur Folge. An den Sedimenten des Schelfkernes wurde ein neu entwickeltes Verfahren der Endmember-Modellierung erfolgreich getestet. Der Eisrückzug auf dem MacRobertson Schelf begann etwa 12,8 tausend kal. Jahre v. H. und war gegen 5,5 tausend kal. Jahre v. H. abgeschlossen. Während des Holozäns kam es zu starken Schwankungen in der Bodenwasseraktivität, die höchst wahrscheinlich mit der Neubildungsrate von Meereis in der Kap Darnley Polynia in Zusammenhang stehen. Besonders auffallend war eine erhöhte Bodenwasseraktivität am Übergang von Warm- zu Kaltphasen bzw. ihr extremer Rückgang während des Mittel-Holozänen Klimaoptimums. Insgesamt zeigen die Ergebnisse der Arbeit, dass sich das LAIS während des Quartärs relativ stabil gegenüber Klimaveränderungen verhalten hat. Die Bodenwasserproduktion in Polynien dagegen reagierte sehr empfindlich auf relative geringe atmosphärische Veränderungen und bedarf in Zukunft verstärkter Aufmerksamkeit.