L’objectif de ce travail est d’étudier l’influence de jets d’impact libres utilisés comme mode de mise en contact des phases dans les procédés de recristallisation utilisant un fluide supercritique comme anti-solvant. L’influence des variations de plusieurs paramètres opératoires sur l’hydrodynamique des jets et sur les caractéristiques des poudres de Sulfathiazole a été étudiée. Les paramètres sont la vitesse des jets (de 0,25 m.s-1 à 25,92 m,s-1), le rapport molaire solvant/CO2 (de 2,5 % à 20 %), la température (de 313 K à 343 K), la pression (10 MPa à 20 MPa) et la concentration du soluté dans la solution (de 0,5 % à 1,8 %). Les conditions de mélange ont été caractérisées par l’estimation des puissances dissipées par les jets d’impact, variant de 0,1 à 158 W.kg-1 dans les conditions étudiées. Les résultats ont montré que la vitesse des jets et la sursaturation sont deux paramètres-clés contrôlant la cristallisation avec un effet prépondérant de la sursaturation. Les cristaux obtenus ont des tailles, distributions de taille, faciès et nature polymorphique différents selon les conditions. La forme polymorphique la plus stable a été obtenue pure ou en mélange. Une comparaison avec le procédé SAS classique a montré que les particules sont significativement plus petites lorsqu’elles sont cristallisées avec les jets d’impact, ce qui confirme que ce dispositif créant un mélange plus intense, permet d’accélérer la cinétique de nucléation.Ce travail devrait contribuer à une meilleure maîtrise des procédés de cristallisation en milieu supercritique. / The aim of this work is to study the influence of free impinging jets used for the fluids’introduction in supercritical anti-solvent (SAS) processes. The influence of the variations of several operating parameters upon jets’ hydrodynamics and upon the powder characteristics is studied. Parameters are jets velocity (0.25 m.s-1 to 25.92 m.s-1), molar ratio solvent / CO2 (2.5 % to 20 %), temperature (313 K to 343 K), pressure (10 MPa to 20 MPa) and solute concentration in the organic solution (0.5 % to 1.8 %). Mixing conditions have been characterized estimating the dissipated powers of the impinging jets, varying from 0,1 à 158 W.kg-1 in the studied conditions. The results showed that jets velocity and supersaturation are two key-parameters controlling the crystallization with a preponderant effect of supersaturation. The obtained crystals have different size, particle size distribution, habit and polymorphic nature depending on the conditions. The most stable polymorphic form has been obtained pure or in mixture.A comparison with the classical SAS process showed that mean particle sizes are significantly smaller with impinging jets device proving that this device, creating a more efficient mixing, enhances the nucleation kinetics.This work may contribute to a better control of processes of crystallization in supercritical media.

Orientador: Amarildo Tabone Paschoalini / Banca: Luiz de Paula do Nascimento / Banca: Marcelo Moreira Ganzarolli / Resumo: Os objetivos deste trabalho são determinar a potência térmica dissipada dos componentes eletrônicos de forma experimental e verificar a eficácia do método através de simulações numéricas computacionais utilizando o software comercial ANSYS. O Software ANSYS foi usado como ferramenta de Dinâmica de Fluidos Computacional neste trabalho. Para a realização deste trabalho um ensaio experimental foi executado a fim de obter alguns dados para o cálculo da potência térmica dissipada, outros foram fornecidos pelo CPqD e Trópico. Foi montado um Laboratório Computacional com o apoio da Trópico e do CPqD na UNESP, campus de Ilha Solteira para a simulações numéricas. O método de cálculo de potência apresentou-se eficaz, de modo na melhor situação os resultados apresentaram um erro relativo médio de 1,94%. / Abstract: The purpose of this study is to determine the thermal power dissipation of electronic components through an experimental test and verify the effectiveness of the method through numerical simulations using the computational software ANSYS commercial. Software ANSYS was used as a tool for Computational Fluid Dynamics for this work. For this work an experimental test was done to obtain some data to calculate the thermal power dissipation, others were supplied by CPqD, Nilko and Trópico. It was dubbed a Computer Laboratory with the support of the Trópico, CPqD and at UNESP, campus de Ilha Solteira for the numerical simulations. The method of calculation of power proved to be effective, that the better the results showed a mean relative error is 1.94%. / Mestre

Made available in DSpace on 2014-06-11T19:27:14Z (GMT). No. of bitstreams: 0 Previous issue date: 2008-11-28Bitstream added on 2014-06-13T19:55:37Z : No. of bitstreams: 1 sousa_rr_me_ilha.pdf: 2111422 bytes, checksum: 55ec661a37c8225f8f3075712c8ec225 (MD5) / Fundação de Ensino Pesquisa e Extensão de Ilha Solteira (FEPISA) / Os objetivos deste trabalho são determinar a potência térmica dissipada dos componentes eletrônicos de forma experimental e verificar a eficácia do método através de simulações numéricas computacionais utilizando o software comercial ANSYS. O Software ANSYS foi usado como ferramenta de Dinâmica de Fluidos Computacional neste trabalho. Para a realização deste trabalho um ensaio experimental foi executado a fim de obter alguns dados para o cálculo da potência térmica dissipada, outros foram fornecidos pelo CPqD e Trópico. Foi montado um Laboratório Computacional com o apoio da Trópico e do CPqD na UNESP, campus de Ilha Solteira para a simulações numéricas. O método de cálculo de potência apresentou-se eficaz, de modo na melhor situação os resultados apresentaram um erro relativo médio de 1,94%. / The purpose of this study is to determine the thermal power dissipation of electronic components through an experimental test and verify the effectiveness of the method through numerical simulations using the computational software ANSYS commercial. Software ANSYS was used as a tool for Computational Fluid Dynamics for this work. For this work an experimental test was done to obtain some data to calculate the thermal power dissipation, others were supplied by CPqD, Nilko and Trópico. It was dubbed a Computer Laboratory with the support of the Trópico, CPqD and at UNESP, campus de Ilha Solteira for the numerical simulations. The method of calculation of power proved to be effective, that the better the results showed a mean relative error is 1.94%.