Orientador: Waldemir Silva de Lima / Dissertação (mestrado profissional) - Universidade Estadual de Campinas, Faculdade de Engenharia Mecanica / Made available in DSpace on 2018-08-03T22:41:40Z (GMT). No. of bitstreams: 1 Lopes_JoaquimTeixeira_M.pdf: 652152 bytes, checksum: 30fb462f17fd946501b68c1c70a58fa9 (MD5) Previous issue date: 2004 / Mestrado / Refrigeração e Condicionamento Ambiental / Mestre Profissional em Engenharia Mecanica

The main goal of my thesis is to carry out thermic calculations for adjusted conditions of electric and heat energy consumption. The power of the generator is 330 MW. In the proposal, you can find combustion trubines type GE 9171E. Steam-gas power plant is designed to combust metallurgical gases. Effort of the thesis focuses also on giving a new informations about trends in combinated production of electric and heat energy.

D.Ing. / Low system efficiency is a critical problem in photovoltaic (PV) applications due to low efficiency of solar cells. Despite this shortcoming, stand-alone PV systems, have proven to be economical and reliable choices in some applications such as telecommunications, vaccine refrigeration and water pumping in remote locations. In this study, CAD algorithms for the design of PV water pumping systems have been developed with the objective of maximizing the conversion efficiency from the solar irradiation to the potential energy of water by taking into account the variations in the pumping head. The study starts by developing loss models of various sub-systems in the photovoltaic dc and ac motor drive water pumping systems. Using MathCad, these models are then used in the simulation of the system. The simulation results are verified experimentally using their equivalent circuit configurations. The efficiency of the array, the pump and the motor are found to be the most critical parameters for the performance of the systems. The efficiencies of other components, such as the inverter, have also been shown to have a significant effect. The study has shown that for operation at the maximum power point, the inclusion of a maximum power tracker is necessary in a dc motor drive system but may be eliminated in PWM inverter-fed induction motor drive systems through proper matching of the system components. The study has further shown that matching of the drive system and the load with the insolation is essential, since maximum system efficiency occurs at a specific head, which varies as the insolation changes. Prior investigation of site insolation variations is therefore a critical requirement.

L’objectif de ce travail de thèse a été d’étudier une alternative à la cellule photovoltaïque à hétérojonction classique de silicium amorphe/cristallin avec un matériau (GaP) qui permettrait une amélioration de rendement grâce à ses propriétés optiques et électriques. L’étude du potentiel des hétérojonctions GaP/Si pour des applications PV nous a amené à étudier chacun des aspects critiques inhérents à leur réalisation. La préparation chimique de la surface des substrats et les mécanismes qui contrôlent la structuration de la surface de Si(100) ont été étudiés afin d’obtenir une surface de silicium mono-domaine (à marches diatomiques) et faiblement rugueuse par homoépitaxie (dépôts par UHV-CVD). Cette étude a été complétée par l’étude de l’influence de la préparation de surface (préparation chimique et homoépitaxie) du substrat sur la qualité cristalline du GaP déposé en deux étapes par MEE et MBE. La croissance de GaP par MEE a par la suite été effectuée sur des substrats de Si(100) ayant uniquement subi une préparation chimique de surface. Les paramètres de la séquence de croissances MEE ont été étudiés et ajustés afin d’optimiser la phase de nucléation du GaP. La qualité structurale des dépôts a été évaluée par des caractérisations par AFM et DRX. Les couches minces de faibles épaisseurs (20nm) présentent une faible rugosité de surface équivalente à une homoépitaxie et une fraction volumique de MTs inférieure à la limite de détection. La croissance MEE permet d’assurer une nucléation 2D. Cependant les caractérisations par TEM et STM révèlent la présence de parois d’antiphase. En parallèle, la simulation de structures HET GaP/Si (effectuée grâce au programme AFORS-HET) et la réalisation de diodes et de démonstrateurs cellules GaP/Si ont permis de démontrer les optimisations apportées par l’utilisation d’un émetteur de GaP. Ces composants ont été étudiés par caractérisations optiques et électriques. Nous avons constaté une limitation des performances due à la présence de pièges à l’interface et dans le volume. Ces différentes études ont donc permis d’identifier les verrous technologiques à lever pour exploiter pleinement les cellules à hétérojonctions GaP sur silicium afin d’obtenir des hauts rendements photovoltaïques. / The main objective of this thesis is to study an alternative to conventional amorphous/crystalline silicon heterojunction solar cell using gallium phosphide (GaP) as an emitter layer. This would allow a performance improvement because of its optical and electrical properties. The potential of GaP/Si heterojunction solar cells have been evaluated by studying each of the critical issues inherent to their fabrication process. The chemical preparation of the substrates surface and the mechanisms controling the structure of the Si (100) surface have been studied in order to obtain a single domain silicon surface (with diatomic steps) and slightly roughened by homoepitaxy (UHV-CVD). This work was completed by the study of the impact of surface preparation (chemical preparation and homoepitaxy) of the substrate on the crystalline quality of GaP deposited in two steps by MBE and MEE. The growth of GaP by MEE was subsequently carried out on Si(100) substrates having only undergone a chemical surface preparation. MEE growth sequence parameters were studied and adjusted to optimize GaP nucleation. The structural quality of the thin films was evaluated by AFM and XRD characterizations. Thin films of 20 nm have lower surface roughness equivalent to an homoepitaxy and a volume fraction of MTs below the detection limit. The MEE growth ensures a 2D nucleation. However, TEM and STM characterizations reveal the presence of antiphase boundaries. In parallel, simulations of the structure HET GaP/Si (with AFORS-HET) have been performed to evaluate the potential of the structure. First, diodes and demonstrator cells with GaP/Si junction have been fabricated and optically/electrically characterized. Limitations in performance due to the presence of traps at the interface and silicon volume degradation have been observed. All this work has allowed us to identify the technological issues to overcome in order to fully exploit the GaP/Si heterojunction cells to improve solar cell performance.

The performance of photovoltaic (PV) modules in terms of their ability to convert incident photon to electrical energy (efficiency) depends mostly on the spectral distribution of incident radiation from the sun. The incident spectrum finally perceived by the module depends strongly on the composition of the medium in which it has traveled. The composition of the earth’s atmosphere, which includes, amongst others, water vapour, gases such as carbon dioxide and oxygen, absorbs or scatters some of the sunlight. The incident solar spectrum is also modified by the diffuse aspect of radiation from the sky which strongly depends on aerosol concentration, cloudiness and local reflection of the earth’s surface. Although it is well known that the changes in outdoor spectrum affect device performance, little work has been conducted to support this theory. This is probably due to lack of spectral data or in certain instances where data is available, little knowledge of interpreting that data. The outdoor spectral data that one obtains in the field does not come clearly for just simple interpretation. Different analytical interpretation procedures have been proposed, all trying to explain and quantify the spectral influence on PV devices. In this study an assessment methodology for evaluating the effects of outdoor spectra on device performance parameters during the course of the day, seasons and or cloudy cover has been developed. The methodology consists of developing a device dependant concept, Weighted Useful Fraction (WUF) using the outdoor measured spectral data. For measuring PV module’s performance parameters, a current-voltage (I-V) tester was developed in order to monitor the performance of six different module technologies. The Gaussian distribution was used to interpret the data. For hot-spot analysis, different techniques were used, which include Infrared thermographic technique for identifying the hot-spots in the solar cells, SEM and EDX techniques. The AES technique was also used in order to identify other elements at hot-spots sites that could not be detected by the EDX technique. iii Results obtained indicate that multicrystalline modules performance is affected by the changes in the outdoor spectrum during summer or winter seasons. The modules prefer a spectrum characterized by WUF = 0.809 during summer season. This spectrum corresponds to AM 2.19 which is different from AM 1.5 used for device ratings. In winter, the mc-Si module’s WUF (0.7125) peaks at 13h00 at a value corresponding to AM 1.83. Although these devices have a wider wavelength range, they respond differently in real outdoor environment. Results for mono – Si module showed that the device performs best at WUF = 0.6457 which corresponds to AM 1.83 during summer season, while it operates optimally under a winter spectrum indicated by WUF of 0.5691 (AM2.58). The seasonal changes resulted in the shift in WUF during day time corresponding to the “preferred” spectrum. This shift indicates that these devices should be rated using AM values that correspond to the WUF values under which the device operates optimally. For poly-Si, it was also observed the WUF values are lower than the other two crystalline-Si counterparts. The pc-Si was observed to prefer a lower AM value indicated by WUF = 0.5813 during winter season while for summer it prefers a spectrum characterized by WUF = 0.5541 at AM 3.36. The performance of the single junction a-Si module degraded by 67 percent after an initial outdoor exposure of 16 kWh/m² while the HIT module did not exhibit the initial degradation regardless of their similarities in material composition. It was established that the WUF before degradation peaks at 15h00 at a value of 0.7130 corresponding to AM 4.50 while the WUF after degradation “prefers” the spectrum (WUF = 0.6578) experienced at 15h30 corresponding to AM value of 5.57. Comparing the before and after degradation scenarios of a-Si:H, it was observed that the device spends less time under the red spectrum which implies that the device “prefers” a full spectrum to operate optimally. The degradation of a-Si:H device revealed that the device spectral response was also shifted by a 7.7 percent after degradation. A higher percentage difference (61.8 percent) for spectral range for the HIT module is observed, but with no effects on device parameters. Seasonal changes (summer/winter) resulted in the outdoor spectrum of CuInSe2 to vary by WUF = 1.5 percent, which resulted in the decrease in Isc. This was ascertained by iv analyzing the percentage change in WUF and evaluating the corresponding change in Isc. The analysis showed that there was a large percentage difference of the module’s Isc as the outdoor spectrum changed during the course of the day. This confirmed that the 17 percent decrease in Isc was due to a WUF of 1.5 percent. In mc-Si solar cells used in this study, it was found that elemental composition across the entire solar cell was not homogenously distributed resulting in high concentration of transition metals which were detected at hot spot areas. The presence of transition metals causes hot-spot formation in crystalline solar cells. Although several transition elements exist at hot-spot regions, the presence of oxygen, carbon, iron and platinum was detected in high concentrations. From this study, it is highly recommended that transition elements and oxygen must be minimized so as to increase the life expectancy of these devices and improve overall systems reliability

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M.Sc. (Physics) / Amorhous silicon is one of the most promising materials for large area solar cells for terestrial photovoltaic applications. Unfortunately these cells suffer from two serious problems: the efficiencies drop when laboratory processes are scaled up and the cells degrade after some exposure to sunlight. The exact causes of these two problems are still unknown. In this project some aspects of the above two problems where investigated. The drop in efficiency due to scaling up of laboratory processes can be ascribed to macroscopic inhomogeneities in the film. An investigation was done by changing the chamber geometry and gas flow pattern to establish empirical conditions to obtain films with maximum macroscopic homogeneity. It was found that a uniform electric field above the substrate was the most important factor determining the macroscopic homogeneity of the film. The hydronamic gas flow pattern was of secondary importance. Some techniques to obtain a uniform electric field has been devised. The photo-degradation was investigated by illuminating films of o-Si.H with simulated sunlight for different lenghts of time. The change in the electrical and optical properties of the intrinsic films were determined as function of total photon flux. No change in the optical properties could be detected. The effect of the photo-degradation manifests itself in a drop in the the dark conductivity and photoconductivity. The observed phenomena is explained in terms of photo-induced deep levels in the gap. The Fermi level shifts to the middle of the gap due to these defect states, causing a drop in the free carrier concentration and conductivity. These defect levels increase the absorptiom coefficient in the long wavelength region, but they also decrease the lifetime of the photo-generated carriers. The photo-induced defects were investigated with the CPM-technique. A large part of this project involved the construction and commissioning of the CPM-apparatus. It was found that the light introduced two types of defects at energies 0.5 eV and 0.75 eV below the conduction band edge. The concentration of the defects increases with illumination, but saturates after about 24 hours of illumination. The defects could almost completely be annealed at ISOaC. The photo-degradation of o-Si.H solar cells is ascribed to the reduction in the carrier lifetimes of photo-generated carriers due to recombination at these defect centers.

Orientador: Ennio Peres da Silva / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Mecânica / Made available in DSpace on 2018-08-27T02:08:03Z (GMT). No. of bitstreams: 1 Castro_RodolfoDamasiode_M.pdf: 3152478 bytes, checksum: a4e0e80e4ac1f8804a7b3aa8589139b4 (MD5) Previous issue date: 2015 / Resumo: A busca por meios de geração de energia para atender às necessidades humanas com menores impactos sociais e ambientais é constante. A geração de energia elétrica por meio de fontes renováveis na forma distribuída, ou não centralizada, é um meio ou método de minimizar tais impactos. O objetivo da pesquisa foi analisar a viabilidade econômica, frente a tarifa de energia elétrica das concessionárias locais, da utilização de sistemas de geração solar em residências brasileiras situadas nas capitais dos estados, na capital federal, Brasília e na cidade de Campinas (SP). Diferentes situações de dimensionamento foram utilizadas para dois tipos de sistemas: um sistema fotovoltaico puro, para atender toda a necessidade energética da residência, incluindo o chuveiro elétrico, e um sistema solar híbrido, composto por aquecimento solar para atender a demanda por água quente no banho em conjunto com geração fotovoltaica para atender as necessidades em equipamentos elétricos. As situações de dimensionamento utilizadas foram três, onde em cada uma o sistema fotovoltaico foi projetado para uma determinada produção de energia. Os sistemas fotovoltaico e de aquecimento solar foram dimensionados com o auxílio dos softwares PVSyst e Dimensol, respectivamente. O custo total dos sistemas foi estimado a partir de pesquisa em lojas com endereço eletrônico na rede de computadores e de orçamentos fornecidos por empresas do ramo. Determinou-se o preço final da energia elétrica convencional para todas as cidades a partir da tarifa definida pela ANEEL, do valor médio do PIS efetivo cobrado pelas concessionárias e da alíquota de ICMS que os governos estaduais recolhem. Após realizados os cálculos, chegou-se ao resultado de que somente nas cidades de Macapá (AP) e Boa Vista (RR), devido principalmente ao baixo custo das tarifas de energia elétrica, o usuário não economizaria com a instalação dos sistemas. Porém, em cidades de elevada tarifa, como Belém (PA) e Belo Horizonte (MG), o usuário pagaria cerca de R$ 0,30 por quilowatt hora consumido a menos / Abstract: The search for power generation means to meet human needs with lower social and environmental impacts is constant. The distributed generation of electricity by renewable energies is a method to minimize those impacts. The research aimed to analyze the economic viability against local electricity tariff of the use of solar power generation systems in Brazilian households located in the capitals of the states, in the federal capital, Brasilia, and in the city of Campinas (SP) Different sizing situations were used for two types of systems: a pure PV system to meet all the energy needs of the residence, including electric shower, and a hybrid solar system, consisting of solar heating to meet the demand for hot water in the bath together with photovoltaic generation to meet the needs in electrical equipment. Sizing situations used were three, where in each one the PV system is designed for a certain production of energy. The photovoltaic systems and solar heating were sized with the help of the softwares PVSyst and Dimensol, respectively. The total cost of the systems was estimated by a research in webstores and budgets provided by companies in the field. Was determined the final price of conventional electricity to all cities from the tariff set by ANEEL, the average value of the effective PIS charged by concessionaires and ICMS aliquot that state governments collect. After performing the calculations, came to the result that only the cities of Macapa (AP) and Boa Vista (RR), mainly due to the low cost of electricity tariffs, the user does not save due to the installation of the systems. However, in cities of high tariff, as Belém (PA) and Belo Horizonte (MG), the user would save about R$ 0.30 per quilowatt-hour / Mestrado / Planejamento de Sistemas Energeticos / Mestre em Planejamento de Sistemas Energéticos

A redução do consumo de energia dos sistemas eletrônicos, fez com que a pesquisa de novas fontes de energia para alimentar estes dispositivos tivesse enorme importância na última década. Algumas destas fontes são provenientes da conversão de energia de vibrações mecânicas em energia elétrica. Veículos aéreos não tripulados (UAVs) e micro veículos aéreos (MAVs) constituem uma aplicação importante para utilização de geradores de energia baseados em vibrações. Este trabalho tem seu foco na conversão de oscilações aeroelásticas em eletricidade utilizando o efeito piezelétrico direto. Um modelo numérico piezoaeroelasticamente acoplado, proveniente da associação de um modelo por elementos finitos eletromecânico e um modelo aerodinâmico não estacionário é apresentado. Uma asa geradora de energia composta por uma subestrutura metálica e piezocerâmicas embutidas é modelada. Apresentam-se como resultados, saídas elétricas (tensão, corrente e potência elétrica) e mecânicas no domínio do tempo. Uma carga resistiva é assumida no domínio elétrico do problema. Uma rajada discreta do tipo \'1-cos\' é assumida para várias velocidades do escoamento e valores de resistências elétricas, utilizando eletrodos contínuos e segmentados. Aponta que os melhores resultados foram obtidos com a utilização de eletrodos segmentados e que em razão do melhor acoplamento eletromecânico, obtêm-se um maior efeito shunt damping, um aumento na velocidade de flutter (1 m/s neste trabalho) e uma maior geração de potência. / Reducing the power consumption of electronic systems, has led the research for new sources of energy to power these devices have great importance in the last decade. Some of these sources are from the conversion of energy from mechanical vibrations into electrical energy. Unmanned Aerial Vehicles (UAVs) and Micro Air Vehicles (MAVs) are an important application for use of vibration energy harvesting. This work focuses on conversion of aeroelastic oscillations into electricity using piezoelectric direct effect. A numerical model coupled piezoaeroelastically derived from the combination of an electro-mechanical finite element model and an unsteady aerodynamic model is presented. A power generator wing consists of a metal substructure and embedded piezoceramic is modeled. They appear as results, electrical outputs (voltage, current and electric power) and mechanical time domain. A resistive load is assumed in the electric domain of the problem. A discrete gust of shape \'1-cos\' is taken for various flow velocities and values of electrical resistances, using continuous and segmented electrodes. Indicates that the best results were obtained with the use of segmented electrodes and because of better electromechanical coupling, we obtain a higher shunt damping effect, an increase flutter speed (1 m/s in this work) and greater power generation.