Thesis (Ph. D.)--Institute of Paper Science and Technology, 1992. / Includes bibliographical references (leaves 187-191).

A new technique for measuring the water content of fiber is presented. Tritiated water is added to a pulp/water suspension whereupon the tritium partitions between the bulk water and the pulp. Through this technique a fiber:water partition coefficient is developed, Kpw. This thesis will cover the development of the Kpw procedure and three different case studies. The first study involves comparing Kpw to traditional methods of fiber water content. The procedure provides a value of ten percent for the tightly bound water content of unrefined hardwood or softwood kraft fiber, either bleached or unbleached. If this water is assumed to cover the fiber surface as a monolayer, then an estimate of the wet surface area of fiber can be obtained. This estimate compares well to independent measurements of surface area. Kpw has also been found to be valuable in furthering the understanding of refining. Based on the study, it is proposed that refining occurs in three discrete stages. First, refining removes the primary cell wall and S1 layer while beginning to swell the S2 layer. Next, internal delamination occurs within the S2 layer. Finally, fiber destruction occurs at high refining levels. By using Kpw, the three stages of refining are clearly recognized. Lastly, Kpw is used to study the effect of hornification on bleached softwood kraft fiber. The recycling effects at three refining levels were characterized by Kpw and followed closely the findings of the refining study. At low and high refining levels, the impact of recycling was minimal according to Kpw results, but at 400 mL csf the impact of recycling was much more pronounced. This could be attributed to the closing of internal delaminations within the fiber.

This study presents quantitative results on the effect on individual fiber length during fiber flocculation. Flocculation was induced by a cationic polyacrylamide (cPAM). A high speed camera recorded 25 second video clips. The videos were image-analyzed and the fiber length and the amount of fiber in each sample were measured. Prior to the flocculation process, fibers were fractionated into short and long fibers. Trials were conducted using the unfractionated fiber, short fiber, and long fiber. The short and long fibers were mixed in several trials to study the effect of fiber length. The concentration of cPAM was varied as well as the motor speed of the impeller (RPM). It was found that the average fiber length decreased more rapidly with increasing motor speed. Increasing the concentration of cPAM also led to a greater decrease in average fiber length. A key finding was that a plateau was reached where further increasing the amount of cPAM had no effect. Hence, fibers below a critical length resisted flocculation even if the chemical dose or shear was increased. This critical length was related to the initial length of the fiber.

The rapid growth of plastic waste from food packaging around the world demands renewable substitutes, such as natural fibers and biocomposites. Wood fibers are natural fibers extracted from trees and are commonly used in packaging. In order for renewable alternatives to compete against plastics and other non-renewable materials, a better understanding of the mechanical properties of single fibers at the micro-scale are necessary. A great deal of previous research into the mechanical properties of single wood fibers has focused on their tensile behavior, however, little work has been published about their compressive behavior. It is difficult to measure the compressive strength of single fibers directly due to fiber buckling. The purpose of this study is to investigate how post-buckling of single wood pulp fibers affects the mechanical properties of fibers in tension. Two alternative hypotheses were tested through experiments in The Odqvist Laboratory for Experimental Mechanics at KTH. The major part of the thesis process has been invested in developing components called grippers, and testing methods for the Single Fiber Testing System, in order to be able to perform the experiments. The existing grippers were tested and alternative grippers were developed, as well as an alternative testing method without grippers, called the Paper frame method (PFM). PFM was used in the final experimental work to test the hypotheses. The main finding from this study is that there is not enough evidence to suggest that the tensile strength or tensile stiffness of single wood fibers are significantly reduced by post-buckling damage. This finding is mostly relevant in the research and development of fibrous material with larger distances between individual fibers, such as low-density fiber network materials. The main findings from the single fiber testing methods development were that the existing grippers cannot prevent fiber slippage. Furthermore, the alternative gripper 22A with its arc design generates higher grip force than previous grippers but lacks surface friction in the contact region in order to prevent fiber slippage. PFM has an experimental success rate of over 80 % for trained users and easy usage for the operator. The testing equipment Single Fiber Testing System displays several systematic errors occurring in the post-processing process of tests with cyclic loads. / Den snabba tillväxten av plastavfall från livsmedelsförpackningar runt om i världen kräver förnybara alternativ, såsom förpackningar gjorda av naturfibrer och biokompositer. Träfibrer är naturliga fibrer som utvinns från trä och används ofta i förpackningar. För att dessa förnybara alternativ ska kunna konkurrera mot plast och andra icke-förnybara material krävs en bättre förståelse av de mekaniska egenskaperna hos enskilda fibrer på mikronivå. Det finns en omfattande forskning om de mekaniska egenskaperna i drag hos enskilda träfibrer. Däremot existerar det lite publicerad forskning om träfibrers kompressionsegenskaper. Kompressionsegenskaperna är svåra att mäta direkt på grund av fiberknäckning. Syftet med denna studie är att undersöka hur skadan som uppstår efter knäckning av enskilda träfibrer påverkar de mekaniska egenskaperna hos fibrer i drag. Två alternativa hypoteser testades genom experiment i Odqvistlaboratoriet för experimentell mekanik vid KTH. Huvuddelen av examensarbetet har investerats i att utveckla grepparmar och testmetoder för testmaskinen Single Fiber Testing System, för att kunna utföra experiment. De befintliga grepparmarna testades och nya grepparmar utvecklades, och även en alternativ testmetod utan grepparmar som kallas Paper frame method (PFM) utvecklades. PFM användes i det sista experimentella arbetet för att pröva hypoteserna. Huvudslutsatsen från denna studie är att det inte finns tillräckligt med bevis för att stödja hypotesen att enskilda träfibrers draghållfasthet eller dragstyvhet reduceras av skada som uppstår efter knäckning. Detta resultat är mest relevant för forskning och utveckling av fibernätverks material med större avstånd mellan fibrerna, såsom fibermaterial med låg densitet. Huvudslutsatserna från utvecklingen av testmetoder var att de befintliga grepparmarna inte kunde förhindra fiberglidning. Den alternativa grepparmen 22A med sin bågkonstruktion genererade högre greppkraft än tidigare grepparmar men saknar rätt beläggning i kontaktområdet för att förhindra glidning av fiber. PFM har en hög test framgångsgrad med över 80 % för erfarna användare och den är enkel att arbeta med. Testmaskinen Single Fiber Testing System visar flera systematiska fel som blir märkbar under dataanalys av tester med cykliska belastningar.