Terahertz (THz) radiation has become increasingly important in many scientific and commercial fields in recent years. It possesses many remarkable features resulting in an increased use of THz radiation for various applications, like biomedical imaging, security screening, and industrial quality control. The capability of these applications depends directly on the availability of powerful THz sources and high-responsivity, fast THz detectors. Current commercial products used to detect THz radiation, like Golay cells and pyroelectric detectors, have only slow detection rates and poor sensitivities. Other commercial THz detectors, like bolometers, are more sensitive but require liquid helium cooling. In this thesis, two types of room-temperature high-responsivity graphene-based THz detectors are presented, relying on the unique properties of graphene and the function of plasmonic antenna arrays which boost the interaction between THz waves and graphene. Graphene has been demonstrated as a promising material for THz detection. However, the challenge is its insufficient light absorption that largely limits the responsivity. The first design is based on an array of planar antennas arranged in series and shorted by graphene squares. Highly efficient photodetection can be achieved by using the metallic antenna to simultaneously improve both light absorption, as resonant elements, and photocarrier collection, as electrodes. The device has been characterized with quantum cascade lasers, yielding a maximum responsivity of ~2 mA/W at 2 THz. The second detector is based on an array of interdigitated bow-tie antennas connected in parallel and shunted by graphene squares. The arms of the bow-tie antennas were made of two metals with different work functions to create a built-in electric field and improve the responsivity. The device has been characterized and yields a maximum responsivity of ∼34 μA/W at 2 THz. Efficient THz imaging is presented by integrating the detector in a QCL-based THz imaging system.

The Raman Injection Laser is a new type of laser which is based on triply resonant stimulated Raman scattering between quantum confined states within the active region of a Quantum Cascade Laser that serves as an internal optical pump. The Raman Injection Laser is driven electrically and no external laser pump is required. Triple resonance leads to an enhancement of orders of magnitude in the Raman gain, high conversion efficiency and low threshold. We studied this new type of laser and conclude some basic equations. With reasonable experimental parameters, we calculated the laser gain, losses and the output power of the Raman Injection Laser by using Mathematica and FEMLab. Finally we compared the theoretical and experimental results.

Quantum cascade laser (QCL), as a unipolar semiconductor laser based on intersubband transitions in quantum wells, covers a large portion of the Mid and Far Infrared electromagnetic spectrum. The frequency of the optical transition can be determined by engineering the layer sequence of the heterostructure. The focus of this work is on Terahertz (THz) frequency range (frequency of 1 - 10 THz and photon energy of ~ 4 - 40 meV), which is lacking of high power, coherent, and efficient narrowband radiation sources. THz QCL, demonstrated in 2002, as a perfect candidate of coherent THz source, is still suffering from the empirical operating temperature limiting factor of T ≈ ħω/kB, which allows this source to work only under a cryogenic system. Most of high performance THz QCLs, including the world record design which lased up to ~ 200 K, are based on a resonant phonon (RP) scheme, whose population inversion is always less than 50%. The indirectly-pumped (IDP) QCL, nicely implemented in MIR frequency, starts to be a good candidate to overcome the aforementioned limiting factor of RP-QCL. A rate equation (RE) formalism, which includes both coherent and incoherent transport process, will be introduced to model the carrier transport of all presented structures in this thesis. The second order tunneling which employed the intrasubband roughness and impurity scattering, was implemented in our model to nicely predict the behavior of the QCL designs. This model, which is easy to implement and fast to calculate, could help us to engineer the electron wavefunctions of the structure with optimization tools. We developed a new design scheme which employs the phonon scattering mechanism for both injecting carrier to the upper lasing state and extracting carrier from lower lasing state. Since there is no injection/extraction state to be in resonance with lasing states, this simple design scheme does not suffer from broadening due to the tunneling. Finally, three different THz IDP-QCLs, based on phonon-photon-phonon (3P) scheme were designed, grown, fabricated, and characterized. The performance of those structures in terms of operating temperature, threshold current density, maximum current density, output optical power, lasing frequency, differential resistance at threshold, intermediate resonant current before threshold, and kBT/ħω factor will be compared. We could improve the kBT/ħω factor of the 3P-QCL design from 0.9 in first iteration to 1.3 and the output optical power of the structure from 0.9 mW in first design to 3.4 mW. The performance of the structure in terms of intermediate resonant current and the change in differential resistance at threshold was improved.

Terahertz (THz) frequency range (wavelength of 300-30 μm, frequency of 1-10 THz and photon energy of ~4-40meV), the gap between infrared and microwave electromagnetic waves, have remained relatively unexplored for a long time, due to lack of a high power, coherent, and compact source, as well as the lack of an appropriate detector and the transmission devices. THz wave has recently received considerable attention for potential applications in non-invasive medical imaging, detecting trace of gases in the environment, sensing of organic and biological molecules, security controls, local oscillators for heterodyne receiver systems, free space communication, etc. THz quantum cascade laser (QCL), as the relatively high power and coherent THz radiation source, was demonstrated in 2002. After near a decade of intense research, THz QCLs operate only up to 186K in pulse mode with maximum power of 250 mW at 10 K. This thesis discusses many aspects of theoretical and experimental design considerations for THz QCLs. The objective is to obtain a laser device that emits high powers and works towards the temperatures achievable by thermoelectric coolers. This work includes designing the active gain medium, and the engineering of the waveguide and heat removal structures. A density matrix based model is developed to explain the charge transport and gain mechanism in the intersubband devices, particularly for three well resonant phonon based THz QCLs. The model allows for designing of the optimum and novel active gain mediums that work at higher temperatures. The designed active gain mediums are fabricated using discussed low loss waveguide and efficient heat removal structures. The maximum operating temperatures as high as ~176 K is achieved. Finally a promising lasing scheme based on phonon-photon-phonon emissions is proposed that improves the population inversion and offers high gain peak.

The Raman Injection Laser is a new type of laser which is based on triply resonant stimulated Raman scattering between quantum confined states within the active region of a Quantum Cascade Laser that serves as an internal optical pump. The Raman Injection Laser is driven electrically and no external laser pump is required. Triple resonance leads to an enhancement of orders of magnitude in the Raman gain, high conversion efficiency and low threshold. We studied this new type of laser and conclude some basic equations. With reasonable experimental parameters, we calculated the laser gain, losses and the output power of the Raman Injection Laser by using Mathematica and FEMLab. Finally we compared the theoretical and experimental results.

Terahertz (THz) frequency range (wavelength of 300-30 μm, frequency of 1-10 THz and photon energy of ~4-40meV), the gap between infrared and microwave electromagnetic waves, have remained relatively unexplored for a long time, due to lack of a high power, coherent, and compact source, as well as the lack of an appropriate detector and the transmission devices. THz wave has recently received considerable attention for potential applications in non-invasive medical imaging, detecting trace of gases in the environment, sensing of organic and biological molecules, security controls, local oscillators for heterodyne receiver systems, free space communication, etc. THz quantum cascade laser (QCL), as the relatively high power and coherent THz radiation source, was demonstrated in 2002. After near a decade of intense research, THz QCLs operate only up to 186K in pulse mode with maximum power of 250 mW at 10 K. This thesis discusses many aspects of theoretical and experimental design considerations for THz QCLs. The objective is to obtain a laser device that emits high powers and works towards the temperatures achievable by thermoelectric coolers. This work includes designing the active gain medium, and the engineering of the waveguide and heat removal structures. A density matrix based model is developed to explain the charge transport and gain mechanism in the intersubband devices, particularly for three well resonant phonon based THz QCLs. The model allows for designing of the optimum and novel active gain mediums that work at higher temperatures. The designed active gain mediums are fabricated using discussed low loss waveguide and efficient heat removal structures. The maximum operating temperatures as high as ~176 K is achieved. Finally a promising lasing scheme based on phonon-photon-phonon emissions is proposed that improves the population inversion and offers high gain peak.

Quantum cascade laser (QCL), as a unipolar semiconductor laser based on intersubband transitions in quantum wells, covers a large portion of the Mid and Far Infrared electromagnetic spectrum. The frequency of the optical transition can be determined by engineering the layer sequence of the heterostructure. The focus of this work is on Terahertz (THz) frequency range (frequency of 1 - 10 THz and photon energy of ~ 4 - 40 meV), which is lacking of high power, coherent, and efficient narrowband radiation sources. THz QCL, demonstrated in 2002, as a perfect candidate of coherent THz source, is still suffering from the empirical operating temperature limiting factor of T ≈ ħω/kB, which allows this source to work only under a cryogenic system. Most of high performance THz QCLs, including the world record design which lased up to ~ 200 K, are based on a resonant phonon (RP) scheme, whose population inversion is always less than 50%. The indirectly-pumped (IDP) QCL, nicely implemented in MIR frequency, starts to be a good candidate to overcome the aforementioned limiting factor of RP-QCL. A rate equation (RE) formalism, which includes both coherent and incoherent transport process, will be introduced to model the carrier transport of all presented structures in this thesis. The second order tunneling which employed the intrasubband roughness and impurity scattering, was implemented in our model to nicely predict the behavior of the QCL designs. This model, which is easy to implement and fast to calculate, could help us to engineer the electron wavefunctions of the structure with optimization tools. We developed a new design scheme which employs the phonon scattering mechanism for both injecting carrier to the upper lasing state and extracting carrier from lower lasing state. Since there is no injection/extraction state to be in resonance with lasing states, this simple design scheme does not suffer from broadening due to the tunneling. Finally, three different THz IDP-QCLs, based on phonon-photon-phonon (3P) scheme were designed, grown, fabricated, and characterized. The performance of those structures in terms of operating temperature, threshold current density, maximum current density, output optical power, lasing frequency, differential resistance at threshold, intermediate resonant current before threshold, and kBT/ħω factor will be compared. We could improve the kBT/ħω factor of the 3P-QCL design from 0.9 in first iteration to 1.3 and the output optical power of the structure from 0.9 mW in first design to 3.4 mW. The performance of the structure in terms of intermediate resonant current and the change in differential resistance at threshold was improved.

This thesis focuses on addressing some important aspects of the life cycle of interstellar clouds through observational submillimeter and millimeter-wave studies of star formation and molecular cloud environments and the development of instrumentation to enable these studies.We examine the influence of star formation on parent molecular clouds through a case study of protostellar sources in the Mon OB1 northern cloud complex. An energetics analysis of these star forming regions and associated molecular outflows was carried out, suggesting that the cloud complex maintains its overall integrity, except along outflow axes and that the coupling between outflow kinetic energy and cloud turbulent energy is weak, < ~0.5%. In order to study the larger picture of cloud formation and disruption, this work was expanded to explore the molecular environment at cloud boundaries. To this end, acloud edge survey was undertaken consisting of multi-transition strip scan observations of CO and 13CO toward molecular clouds with a broad range of stellar and star forming characteristics. Our work supports the interpretation that cloud formation is taking place along the southeastern edge of Heiles Cloud 2, and the results will be used as a framework for guiding the analysis of other surveyed cloud edges.Achieving observational capabilities enabling effective studies of life cycles of the ISM is becoming possible through a new generation of heterodyne spectroscopic instruments. Here, we report on characterization measurements of a prototype mixer unit for the 64-pixel SuperCam array, an instrument commissioned to mapover 500 square degrees of the Galactic Plane with very high resolution at 345 GHz. These measurements were crucial to verifying the overall array design and anticipating its performance. Spectroscopic capabilities at THz (< 300 microns) frequencies permits access to a host of diagnostic tools (e.g., high-J CO, CI, NII, & CII) uniquely suited to probe crucial properties of the ISM. The development of heterodynetechnology at these frequencies is largely limited by availability of compact, powerful sources of local oscillator power. We explore the use of waveguide spatial filters in conjunction with Quantum Cascade Lasers, a promising power source at frequenciesabove ~ 2 THz.

High-fidelity chemical kinetic models for low-temperature combustion processes require high-fidelity data from fundamental experiments conducted in idealized transient reactors, such as shock tubes and rapid compression machines (RCM). Non-intrusive laser absorption diagnostics, in particular quantum cascade lasers (QCL) in the mid-infrared wavelength region, provide a unique opportunity to obtain quantitative, time-resolved species concentration and temperature from these reactive systems. In this work, three novel laser absorption diagnostics in the mid-infrared wavelength region are presented for three different experimental applications. The first diagnostic was developed for measuring CO2 concentration using an external cavity QCL centered in the ν3 fundamental vibrational band of CO2. Absorption cross-sections were measured in a shock tube, at a fixed wavelength for the R(32) line centered at 2371.42 cm-1 (4.217 µm) over 700 – 2900 K and nominal pressures of 1, 5 and 10 bar. The diagnostic was used to measure rate coefficients for the reaction between carbon monoxide and hydroxyl radical over 700 – 1230 K and 1.2 – 9.8 bar using highly dilute mixtures. The second diagnostic was developed for measuring CO concentration using a pulsed QCL centered at 2046.28 cm-1 (4.887 µm) and an off-axis cavity implemented on the RCM. The duty cycle and pulse repetition rate of the laser were optimized for increased tuning range, high chirp rate and increased line-width to achieve effective laser-cavity coupling. A gain factor of 133 and time resolution of 10 μs were demonstrated. CO concentration-time profiles during the oxidation of highly dilute n-heptane/air mixtures were recorded and compared with chemical kinetic models. This represents the first application of a cavity-enhanced absorption diagnostic in an RCM. Finally, a calibration-free temperature diagnostic based on a pair of pulsed QCLs centered at 2196.66 cm-1 and 2046.28 cm-1 was implemented on the RCM. The down-chirp phenomenon resulted in large spectral tuning (∆v ~ 2.8 cm-1) within a single pulse of each laser at a high pulse repetition frequency (100 kHz). The diagnostic for was used to measure the temperature rise during first-stage ignition of n-pentane at nominal pressures of 10 and 15 bar for the first time.

Quantum cascade laser (QCL) diodes have potential applications in many areas including emissions analysis and explosives detection, but like many solid-state devices they suer from degraded performance at higher temperatures. To alleviate this drawback, the thermal properties of the QCL diodes must be better understood. Using molecular dynamics (MD) and photothermal radiometry (PTR), the thermal conductivity of a representative QCL diode is computed and measured respectively. The MD results demonstrate that size eects are present in the simulated systems, but if these are accounted for by normalization to experimental results the thermal conductivity of the QCL can be reasonably obtained. The cross-plane conductivity is found to be in the range of 1.8 to 4.3 W=m K, while the in-plane results are in the range of 3.7 to 4.0 W=m K. These values compare well with experimental results from the literature for both QCL materials and for AlInAs and GaInAs, which the QCL is composed of. The cross-plane conductivity results are lower than those of either AlInAs or GaInAs, which demonstrates the phonon scattering at the interfaces. The in-plane results are between AlInAs and GaInAs, which is to be expected. The PTR results are less concrete, as there seem to be heat transfer eects active in the samples which are not included in the models used to t the frequency scans. These effects are not 2D heat transfer artifacts nor are they the result of volumetric absorption. It is possible that they are the results of plasmon induction, but this is only supposition. As the data stand, the PTR and MD results are within an order of magnitude of each other and follow reasonable trends, which suggests that both results are not too far o from reality. While the experimental results are not entirely conclusive, the simulations and experiments corroborate each other suciently to warrant further investigation using these techniques. Additionally, the simulations present sucient internal consistency so as to be useful for thermal property investigation independent of the PTR results.