The Environmental Radioactivity Laboratory (ERL) at iThemba LABS undertakes experimental work using a high purity germanium (HPGe) detector for laboratory measurements. In this study the Monte Carlo transport code, MCNPX, which is a general-purpose Monte Carlo N &minus / Particle code that extends the capabilities of the MCNP code, developed at the Los Alamos National Laboratory in New Mexico, was used. The study considers how various parameters such as (1) coincidence summing, (2) volume, (3) atomic number (Z) and (4) density, affects the absolute photopeak efficiency of the ERL&rsquo / s HPGe detector in a close geometry (Marinelli beaker) for soil, sand, KCl and liquid samples. The results from these simulations are presented here, together with an intercomparison exercise of two MC codes (MCNPX and a C++ program developed for this study) that determine the energy deposition of a point source in germanium spheres of radii 1 cm and 5 cm.<br /> <br /> A sensitivity analysis on the effect of the detector dimensions (dead layer and core of detector crystal) on the photopeak detection efficiency in a liquid sample and the effect of moisture content on the photopeak detection efficiency in sand and soil samples, was also carried out. This study has shown evidence that the dead layer of the ERL HPGe detector may be larger than stated by the manufacturer, possibly due to warming up of the detector crystal. This would result in a decrease in the photopeak efficiency of up to 8 % if the dead layer of the crystal were doubled from its original size of 0.05 cm. This study shows the need for coincidence summing correction factors for the gamma lines (911.1 keV and 968.1 keV) in the 232Th series for determining accurate activity concentrations in environmental samples. For the liquid source the gamma lines, 121.8 keV, 244.7 keV, 444.1 keV and 1085.5 keV of the 152Eu series, together with the 1173.2 keV and 1332.5 keV gamma lines of the 60Co, are particularly prone to coincidence summing. In the investigation into the effects of density and volume on the photopeak efficiency for the KCl samples, it has been found that the simulated results are in good agreement with experimental data. For the range of sample densities that are dealt with by the ERL it has been found that the drop in photopeak efficiency is less than 5 %. This study shows that the uncertainty of the KCl sample activity measurement due to the effect of different filling volumes in a Marinelli beaker is estimated in the range of 0.6 % per mm and is not expected to vary appreciably with photon energy. In the case of the effect of filling height on the efficiency for the soil sample, it was found that there is a large discrepancy in the trends of the simulated and experimental curves. This discrepancy could be a result of the use of only one sand sample in this study and therefore the homogeneity of the sample has to be investigated. The effect of atomic number has been found to be negligible for the soil and sand compositions for energies above 400 keV, however if the composition of the heavy elements is not properly considered when simulating soil and sand samples, the effect of atomic number on the absolute photopeak efficiency in the low energy (&lt / 400 keV) region can make a 14 % difference.

Past weapons production activities have resulted in mass quantities of trans-uranic waste being buried in drums at several sites in the United States. In an effort to relocate these waste drums to more permanent storage sites, Fluor Hanford has begun characterizing their contents to ensure compliance with various shipping and storage requirements. Non-destructive analysis techniques are regularly employed, among them passive radiation detection using a Canberra Gamma-Energy-Analyzer germanium detector vault. Necessary strict legal tolerances require strong quality assurance. The detectors are frequently calibrated in the traditional method with check sources, but it would be advantageous to have an estimate of system minimum detectable activity (MDA). However, any estimate is complicated by the fact that sources are distributed stochastically in the waste drums. In this study, a method was developed to predict system detector efficiency for a variety of detector configurations and drum fill materials and calculate MDA based on these efficiencies. The various system designs were modeled in Monte Carlo N-Particle Code, version 4b, to determine photopeak detection efficiency. An external code written in C programming language was used to randomly assign between one and 20 sources to volumetric regions of the waste drum. Twenty simulations were performed for each design and drum fill material combination, each time redefining the stochastically distributed source. This provided a normally distributed spectrum of 20 efficiencies for each situation. From this, mean and lower 95% confidence limit efficiencies were used to calculate MDA. The patterns among the results were then compared with values predicted by the MDA formula. Finally, an examination was made of the impact on the MDA of the system's true design in the case of single or multiple detector failure. The results indicate that this method of estimating minimum detectable activity, although costly in computing time, provides results consistent with intuitive and calculated expectations. Future work would allow easy calibration of the model to measured efficiency results. Used in coordination with physical experiments, this method may eventually prove useful in benchmarking system performance and accurately ensuring reliable waste drum characterizations. / Graduation date: 2003

In this research a unique linear pulse amplifier was developed that significantly reduces the spread in pulse amplitudes of those pulses selected from a Ge(Li) detector by a single channel analyzer. This circuit utilizes an operational amplifier with its closed-loop gain automatically controlled by a P-channel junction field.-effect transistor. The amplification is adjusted for each pulse such that the output pulses are constant in amplitude. The performance of the system was analyzed with a multichannel analyzer and it was shown that an improvement in pulse amplitude variation of as much as 29.1 percent was achieved.Ball State UniversityMuncie, IN 47306

The Environmental Radioactivity Laboratory (ERL) at iThemba LABS undertakes experimental work using a high purity germanium (HPGe) detector for laboratory measurements. In this study the Monte Carlo transport code, MCNPX, which is a general-purpose Monte Carlo N &minus / Particle code that extends the capabilities of the MCNP code, developed at the Los Alamos National Laboratory in New Mexico, was used. The study considers how various parameters such as (1) coincidence summing, (2) volume, (3) atomic number (Z) and (4) density, affects the absolute photopeak efficiency of the ERL&rsquo / s HPGe detector in a close geometry (Marinelli beaker) for soil, sand, KCl and liquid samples. The results from these simulations are presented here, together with an intercomparison exercise of two MC codes (MCNPX and a C++ program developed for this study) that determine the energy deposition of a point source in germanium spheres of radii 1 cm and 5 cm.<br /> <br /> A sensitivity analysis on the effect of the detector dimensions (dead layer and core of detector crystal) on the photopeak detection efficiency in a liquid sample and the effect of moisture content on the photopeak detection efficiency in sand and soil samples, was also carried out. This study has shown evidence that the dead layer of the ERL HPGe detector may be larger than stated by the manufacturer, possibly due to warming up of the detector crystal. This would result in a decrease in the photopeak efficiency of up to 8 % if the dead layer of the crystal were doubled from its original size of 0.05 cm. This study shows the need for coincidence summing correction factors for the gamma lines (911.1 keV and 968.1 keV) in the 232Th series for determining accurate activity concentrations in environmental samples. For the liquid source the gamma lines, 121.8 keV, 244.7 keV, 444.1 keV and 1085.5 keV of the 152Eu series, together with the 1173.2 keV and 1332.5 keV gamma lines of the 60Co, are particularly prone to coincidence summing. In the investigation into the effects of density and volume on the photopeak efficiency for the KCl samples, it has been found that the simulated results are in good agreement with experimental data. For the range of sample densities that are dealt with by the ERL it has been found that the drop in photopeak efficiency is less than 5 %. This study shows that the uncertainty of the KCl sample activity measurement due to the effect of different filling volumes in a Marinelli beaker is estimated in the range of 0.6 % per mm and is not expected to vary appreciably with photon energy. In the case of the effect of filling height on the efficiency for the soil sample, it was found that there is a large discrepancy in the trends of the simulated and experimental curves. This discrepancy could be a result of the use of only one sand sample in this study and therefore the homogeneity of the sample has to be investigated. The effect of atomic number has been found to be negligible for the soil and sand compositions for energies above 400 keV, however if the composition of the heavy elements is not properly considered when simulating soil and sand samples, the effect of atomic number on the absolute photopeak efficiency in the low energy (&lt / 400 keV) region can make a 14 % difference.

This thesis is concerned with the estimation of the strength of a radioactive source when decay is rapid so that the usual assumption of a Poisson distribution of counts is not applicable. We distinguish two main cases according as the background radiation is small or large. In the former case the common procedure of simply subtracting off a constant background radiation is adequate. If the background radiation is neglected altogether the method of maximum likelihood may be used to estimate both source strength and decay-constant for counts taken at any arbitrary times. The large-sample variances and covariances of these estimates are obtained and the procedure is illustrated on an actual set of experimental results. When the background radiation is large their randomness should be taken into account. The exact distribution of counts is the sum of two independent variates, one a binomial and one a Poisson. However, a normal approximation with the same mean and variance will often suffice. We draw attention to a procedure due to Tandberg who considered the problem of obtaining a single optimum count. The method of maximum likelihood applied in conjunction with the assumption of normality of total counts is compared with his method in a numerical example. The possibility of taking two counts is also considered and the source strength is estimated by a least squares approach. / M.S.

In this study, two methods of analysing activity concentrations of natural radionuclides (U, Th and K) in soil are critically compared. These are the Window Analysis (WA) and Full Spectrum Analysis (FSA). In the usual WA method, the activity concentrations are determined from the net counts of the windows set around individual &gamma / -ray peaks associated with the decay of U, Th and K. In the FSA method, the full energy spectrum is considered and the measured spectrum is described as the sum of the three standard spectra (associated with U, Th and K, respectively), each multiplied by an unknown concentration. The concentrations are determined from the FSA and correspond to the activity concentrations of U, Th and K in the soil. The standard spectra derived from separate calibration measurements using the HPGe detector, represents the response of the HPGe to a Marinelli sample beaker containing an activity concentration of 1 Bq/kg.

A delayed-coincidence spectrometer system was developed to measure nuclear lifetimes in the picosecond region by the centroid-shift method. liming signals were derived from two plastic scintillators. A specially constructed NaI(Tl) detector was used to detect the gamma-rays which were Corrpton-scattered from one of the plastic scintillators. Energy identification was achieved by sumning the signals from the plastic detector and the NaI(Tl) detector to give the full energy photopeaks. In order to test the effectiveness of the system, the mean lives of the first excited states of Ni60 and Ba134 were measured. The 1.0-psec mean life in Ni60 could not be measured with the present system. The gamma-gamma and beta-gamma coincidence experiments gave the mean life of the first excited state of Ba134 as 6.1 ±0.8 psec and 4.8 ±0.6 psec, respectively. It is concluded that the shortest mean life that can reliably be measured by the present system is about 5 psec.Ball State UniversityMuncie, IN 47306

In this study, two methods of analysing activity concentrations of natural radionuclides (U, Th and K) in soil are critically compared. These are the Window Analysis (WA) and Full Spectrum Analysis (FSA). In the usual WA method, the activity concentrations are determined from the net counts of the windows set around individual &gamma / -ray peaks associated with the decay of U, Th and K. In the FSA method, the full energy spectrum is considered and the measured spectrum is described as the sum of the three standard spectra (associated with U, Th and K, respectively), each multiplied by an unknown concentration. The concentrations are determined from the FSA and correspond to the activity concentrations of U, Th and K in the soil. The standard spectra derived from separate calibration measurements using the HPGe detector, represents the response of the HPGe to a Marinelli sample beaker containing an activity concentration of 1 Bq/kg.

In dem Bericht werden Strahlungsquelle aufgeführt, die den Untergrund bei der Messung geringer Radioaktivitäten verursachen und dargestellt wie zur Unterdrückung der kosmischen Strahlung Laboratorien untertägig eingerichtet werden und wie durch Koinzidenz und Antikoinzidenzverfahren der verbleibende Untergrund weiter reduziert werden kann. / The radiation sources are described, which causes the background at the measurement of low radioactivities. To reduce the influence of cosmic rays counting devises are installed in underground laboratories. The remaining background may be further reduced by coincidence and anti-coincidence methods.

Tailoring the radiative properties of periodic micro/nanostructures can be used as an efficient way to create devices which have applications in energy harvesting, bioengineering and optical sensing. These structures are analyzed by a rigorous solution of the electromagnetic wave phenomena at the interfaces. The thesis explores the application of rigorous coupled-wave analysis (RCWA) method to study the optical responses of microstructure arrays. First section of the thesis elucidates the various mechanisms which are responsible for causing enhanced light absorption in inclined parallel plate grating arrays. Illustrative evidences of surface plasmon and magnetic resonances are provided by one and two-dimensional plots prepared by RCWA. Analytical agreement with visual data is obtained through use of LC circuit models. Finally, the effects of different geometric parameters on the resonance conditions are investigated. The second part of the thesis deals with application of RCWA to study the effect of light scattering on inclined silver nanorod (AgNR) arrays grown on compact disc (CD) gratings. Depending on the manner in which AgNRs are oriented with respect to CD gratings, they exhibit different optical behavior to incoming light. Effects of both incident light polarization and AgNR orientation with respect to the grating have been studied through the use of RCWA and effective medium theory. Calculated results are compared with experimental values and good agreements are observed for total reflection as well as trends of individual diffraction orders.