No presente trabalho propomos a utilização de uma técnica refratométrica baseada na determinação do ângulo crítico para o desenvolvimento de um sensor de umidade relativa e, no mesmo escopo de aplicação, um medidor de vácuo primário. A técnica proposta tira vantagem da diferença de fase adquirida pelas componentes paralela e perpendicular de um feixe luminoso, linearmente polarizado, passando por reflexão interna, para produzir um laser de HeNe sintonizável, um polarizador, um prisma semicilíndrico de índice de refração conhecido fabricado em vidro tipo flint, um analisador, um mínimo de intensidade, facilmente detectável no perfil refletido correspondendo à posição do ângulo crítico. Desenvolvemos um estudo acerca dos principais aspectos teóricos envolvidos no fenômeno da reflexão total interna, onde realizamos algumas simulações buscando avaliar as variações da posição angular do ângulo crítico a partir de alterações no índice de refração. A montagem básica utilizada nos experimentos consiste de um CCD linear e de um computador, onde as informações coletadas pelo CCD foram tratadas por meio de um programa de aquisição de dados desenvolvido na plataforma LabVIEWTM. O programa empregado permite o acompanhamento das variações do perfil refletido da base do prisma ponto a ponto, ou seja, é possível acompanhar toda a dinâmica de evolução do índice de refração da amostra analisada em tempo real. Para confirmação da efetividade da técnica, realizamos medidas da variação do índice de refração de amostras gasosas em função da umidade relativa e da pressão. O sistema demonstrou sensibilidade suficiente para acompanhar mudanças da ordem de 10-5em unidades do índice de refração. / In the present work we propose the use of a refractometric technique based on the determination of the critical angle for the development of a relative humidity sensor and, in the same application scope, a primary vacuum gauge. The proposed technique takes advantage of the phase difference acquired by the parallel and perpendicular components of a, linearly polarized, light beam undergoing internal reflection, to produce an easily detectable intensity minimum in the reflected profile corresponding to the position of the critical angle. We develop a study about the main theoretical aspects involved in the total internal reflection phenomenon, where we perform some simulations aiming to evaluate the variations of the critical angle angular position from changes on the refractive index. The basic set up used in the experiments consist of a HeNe tunable laser, a polarizer, a semi-cylindrical prism with known refractive index made of flint glass type, a analyzer, a linear CCD and a computer, where the information collected by de CCD were treated by means of a data acquisition program developed on the LabVIEWTM platform. The used program allows the point-by-point monitoring of the changes of the profile reflected from the prism base, in other words, one can monitor all the evolution dynamics of the refractive index of the analyzed sample in real time. To confirm the effectiveness of the technique, we perform measurements of changes of the refractive index of gaseous samples as function of the relative humidity and the pressure. The system has shown enough sensitivity to track changes of the order of 10-5 in units of the index of refraction.

No presente trabalho propomos a utilização de uma técnica refratométrica baseada na determinação do ângulo crítico para o desenvolvimento de um sensor de umidade relativa e, no mesmo escopo de aplicação, um medidor de vácuo primário. A técnica proposta tira vantagem da diferença de fase adquirida pelas componentes paralela e perpendicular de um feixe luminoso, linearmente polarizado, passando por reflexão interna, para produzir um laser de HeNe sintonizável, um polarizador, um prisma semicilíndrico de índice de refração conhecido fabricado em vidro tipo flint, um analisador, um mínimo de intensidade, facilmente detectável no perfil refletido correspondendo à posição do ângulo crítico. Desenvolvemos um estudo acerca dos principais aspectos teóricos envolvidos no fenômeno da reflexão total interna, onde realizamos algumas simulações buscando avaliar as variações da posição angular do ângulo crítico a partir de alterações no índice de refração. A montagem básica utilizada nos experimentos consiste de um CCD linear e de um computador, onde as informações coletadas pelo CCD foram tratadas por meio de um programa de aquisição de dados desenvolvido na plataforma LabVIEWTM. O programa empregado permite o acompanhamento das variações do perfil refletido da base do prisma ponto a ponto, ou seja, é possível acompanhar toda a dinâmica de evolução do índice de refração da amostra analisada em tempo real. Para confirmação da efetividade da técnica, realizamos medidas da variação do índice de refração de amostras gasosas em função da umidade relativa e da pressão. O sistema demonstrou sensibilidade suficiente para acompanhar mudanças da ordem de 10-5em unidades do índice de refração. / In the present work we propose the use of a refractometric technique based on the determination of the critical angle for the development of a relative humidity sensor and, in the same application scope, a primary vacuum gauge. The proposed technique takes advantage of the phase difference acquired by the parallel and perpendicular components of a, linearly polarized, light beam undergoing internal reflection, to produce an easily detectable intensity minimum in the reflected profile corresponding to the position of the critical angle. We develop a study about the main theoretical aspects involved in the total internal reflection phenomenon, where we perform some simulations aiming to evaluate the variations of the critical angle angular position from changes on the refractive index. The basic set up used in the experiments consist of a HeNe tunable laser, a polarizer, a semi-cylindrical prism with known refractive index made of flint glass type, a analyzer, a linear CCD and a computer, where the information collected by de CCD were treated by means of a data acquisition program developed on the LabVIEWTM platform. The used program allows the point-by-point monitoring of the changes of the profile reflected from the prism base, in other words, one can monitor all the evolution dynamics of the refractive index of the analyzed sample in real time. To confirm the effectiveness of the technique, we perform measurements of changes of the refractive index of gaseous samples as function of the relative humidity and the pressure. The system has shown enough sensitivity to track changes of the order of 10-5 in units of the index of refraction.

This work explores the blending of e-textile technology with the porous electrode of polymer electrolyte membrane fuel cells (PEMFCs) and with smart wound patches to allow monitoring and in-situ diagnostics. This work includes contributions to understanding water transport and conductivity in the carbon cloth gas diffusion layer (GDL), and further developing thread-based relative humidity (RH) and temperature sensors, which can be sewn on a cloth GDL in PEMFCs. We also explore the application of the developed RH and temperature sensors in wearable biomonitoring. First, an experimental prototype is developed for evaluating water transport, thermal conductivity and electrical conductivity of carbon cloth GDLs under different hydrophobic coatings and compressions. Second, we demonstrate the addition of external threads to the carbon cloth GDL to (1) facilitate water transport and (2) measure local RH and temperature with a minimal impact on the physical, microstructural and transport properties of the GDL. We illustrate the roll-to-roll process for fabricating RH and temperature sensors by dip-coating commodity threads into a carbon nanotubes (CNTs) suspension. The thread-based sensors response to RH and temperature in the working environment of PEMFCs is investigated. As a proof-of-concept, the local temperature of carbon cloth GDL is monitored in an ex-situ experiment. Finally, we optimized the coating parameters (e.g. CNTs concentration, surfactant concentration and a number of dipping) for the thread-based sensors. The response of the thread-based sensors in room conditions is evaluated and shows a linear resistance decrease to temperature and a quadratic resistance increase to RH. We also evaluated the biocompatibility of the sensors by performing cell cytotoxicity and studying wound healing in an animal model. The novel thread-based sensors are not only applicable for textile electrochemical devices but also, show a promising future in wearable biomonitoring applications. / Graduate

The thesis deals with preparation of graphene nanostructures and their applications in the measurement of transport properties of graphene. The contacts for measurement of resistance are fabricated by electron beam lithography on graphene exfoliated flakes, CVD graphene layers and grains. Graphene is also shaped using the same method. Resistivity of the layer, concentration and mobility of charge carriers are determined by different approaches. Hysteresis appearing in dependence of resistivity on the gate voltage is discussed as well. A significant part of the work is dedicated to monitoring the response of graphene resistance to relative humidity changes and potential use of graphene as a sensor of relative humidity.

The transmission of electric power over long distances has historically posed challenges. However, the advent of high-voltage engineering has not only addressed distance barriers and power losses in electricity transmission and distribution, but it has also significantly improved the efficiency and transmission capacity of power grids. However, the use of high-voltage techniques has presented new challenges in identifying suitable insulator materials capable of withstanding high electrical stresses associated with elevated voltages. A significant issue arising from these extreme electrical stresses is the occurrence of partial discharges (PDs). Those are electrical sparks or pulses in the magnitude order of pico- or nano-coulombs (pC or nC) emitted from high voltage conductors due to the presence of impurities, contaminants or defects in their insulation system. PDs pose a serious threat to the insulation material due to their aggressive nature in breaking down weak points or links inside the insulation system leading to short-circuit and system failure. Means of offline or conventional testing of power assets against partial discharges has proven to be extremely precise but it is often an unavailable option since it requires a total power shutdown. In this paper, the performance of existing online PD detection techniques is tested and evaluated in terms of performance against conventional PD monitoring methods. Five non-intrusive detectors including an infrared camera (IR-camera), an ultrasonic sensor , a temperature and relative humidity sensor (TRH-sensor), high-frequency current transformer (HFCT sensor) and transient earth voltage antenna (TEV-antenna) were tested in a laboratory experiment for detection of PDs emitted by artificially-created defects inside a medium-voltage cable termination. The results showed varying sensitivity levels among the sensors, with the HFCT sensor demonstrating the highest sensitivity to all types and magnitudes of PDs. The IR-camera and ultrasonic sensor also showed potential, while the TRH-sensor exhibited poor sensitivity. The TEV-antenna had limited reliability. The findings of this study are that the HFCT system proved to be highly reliable for online PD monitoring, followed by the IR-camera and ultrasonic sensor, while the TEV-antenna and TRH-sensor showed lower reliability. In future work, further research on testing the HFCT system on-site can be conducted along with performing longer thermographic detection tests using the IR-camera to further investigate their potential in online PD detection. / Överföring av elektrisk kraft över långa avstånd har historiskt sett varit utmanande. Införandet av högspänningsteknik har inte bara övervunnit avståndsbarriärer och effektförluster vid överföring och distribution av elkraft, utan det har också avsevärt förbättrat kraftnätens effektivitet och överföringskapacitet. Användningen av högspänningsteknik har dock också inneburit nya utmaningar såsom utveckling av lämpliga isoleringsmaterial som tål höga elektriska påfrestningar vid höga spänningar. Ett betydande problem som härrör från dessa extrema elektriska spänningar är förekomsten av partiella urladdningar. Dessa urladdningar identifieras vara elektriska gnistor eller pulser i storleksordningen pico- eller nanocoulombs (pC eller nC) som emitteras från högspänningsledare på grund av närvaron av föroreningar eller defekter i närliggande isoleringssystem. PD:er utgör ett allvarligt hot mot isoleringsmaterialet på grund av deras aggressiva natur för att bryta ner svaga punkter eller länkar i isoleringssystemet, vilket kan leda till kortslutningar och systemfel. Konventionella metoder för att testa nätkomponenter mot partiella urladdningar har visat sig vara extremt noggranna, men detta är ofta inte ett tillgängligt alternativ eftersom det kräver ett totalt strömavbrott för att utföras. I denna studie testades och utvärderades prestandan hos befintliga metoder för online-detektering av partiell urladdning i förhållande till konventionella övervakningsmetoder. Fem icke-invasiva detektorer, inklusive en infraröd kamera, en ultraljudssensor, en temperatur- och relativ fuktighetssensor, en högfrekvent strömtransformator och en transient jordspänningsantenn, testades i ett laboratorieexperiment för att upptäcka partiella urladdningar orsakade av artificiellt skapade defekter i en mellanspänningskabelavslutning. Resultaten visade varierande känslighetsnivåer bland sensorerna, där högfrekventa strömtransformatorn visade den högsta känsligheten för alla typer och storlekar av partiella urladdningar. Den infraröda kameran och ultraljudssensorn visade också potential, medan temperatur- och relativ fuktighetssensorn visade låg känslighet. Den transienta jordspänningsantennen hade begränsad tillförlitlighet. Slutsatsen av denna studie är att den högfrekventa strömtransformatorn visade sig vara mycket tillförlitlig för online-övervakning av partiella urladdningar, följt av den infraröda kameran och ultraljudssensorn, medan den transienta jordspänningsantennen, temperatur- och fuktighetssensorn visade lägre tillförlitlighet. I framtida forskning kan ytterligare undersökningar av det högfrekventa strömtransformatorsystemet utföras på plats, tillsammans med längre termografiska detekteringstester med hjälp av den infraröda kameran för att ytterligare undersöka deras potential för onlinedetektering av partiella urladdningar.