Optical frequency combs have resulted in significant advances in optical frequency metrology and found wide application to precise physical measurements and molecular fingerprinting. A direct analogue of frequency combs in the phononic or acoustic domain has not been reported to date. This thesis describes a series of results to provide the first clear evidence for the generation of phononic frequency combs in the domain of micromechanical resonators. These results are supported by a theoretical framework which was originally developed to predict the existence of such features of combs in physical systems described by Fermi-Pasta-Ulam dynamics. The phononic frequency combs is mediated by nonlinear coupling between a primary driven mode and one or more parametrically excited internal modes. We provide experimental evidence for the formation of such phononic frequency combs in systems comprising of 2 or more coupled modes, with results qualitatively consistent with previous numerical studies based on Fermi-Pasta-Ulam dynamics. Additionally, externally pumped comb processes are also reported. Through systematic experiments at different drive frequencies and amplitudes, we portray the well-connected processes of phononic frequency comb formation and define attributes to control their concomitant features. Further, the interplay between these new nonlinear resonances and the well-established Duffing phenomenon is also discussed. While the experimental verification of the existence of phononic frequency combs is of scientific interest, several potential engineering applications exist including the unique capability to track resonant frequency of a micromechanical resonator without the requirement for an external feedback loop to sustain oscillations at the resonant frequency. The initial experimental results also demonstrate that good short-term frequency stability may be obtained for such micromechanical resonators operated under ambient conditions.

[pt] Os sistemas micro eletromecânicos são dispositivos na escala dos micras que combinam estruturas mecânicas com circuitos elétricos, e são usados como sensores ou atuadores. Dentro destes dispositivos, estão os de onda superficial acústica (SAW em inglês) que usam variações na velocidade ou percurso de propagação da onda para fazer a detecção da variável a medir. Uma aplicação importante em processos químicos, é no acondicionamento de ambientes, monitorando a umidade. Para isso um sensor SAW comprado, foi coberto em sua superfície com uma camada de um polímero absorvente de vapor de agua. No qual o aumento na massa do polímero na superfície diminui a velocidade da onda. Por tanto o PolyVinyl Álcool foi escolhido para absorver o vapor de agua e foi preparado com 5.6 wt por cento, para ser depositado por meio de spin coating. Então uma serie de experimentos foram feitos numa câmara climática variando tanto a umidade como a temperatura, com o fim de avaliar o comportamento do sensor medindo a sua variação da frequência. Estes resultados foram comparados com um modelo analítico e uma simulação por elementos finitos. O modelo analítico foi presentado por Sielman, o qual determina como muda a densidade e espessura no polímero com a umidade. Estes valores foram substituídos na equação de Wohltjen que dá a variação da frequência de um SAW devido a absorção de gases. Em quanto a simulação por elementos finitos foi feita em Comsol Multiphysics achando a frequência para a qual o SAW ressona, com o aumento da densidade na camada acima do SAW para as umidades inseridas. / [en] Micro electromechanical systems (MEMS) are devices that combine mechanical structures with electrical circuits at the micro scale, to function as sensors or actuators. One type of MEMS are the surface acoustic waves (SAW) devices, which uses the surface wave velocity or propagation path variations to measure the variable of interest. One important application in chemical processes is related to environment condition control, specifically humidity measurement. With that purpose, a commercial SAW was purchased and coated with a polymer layer in its surface. The PolyVynil Alcohol (PVA) was chosen to be the sensing layer in the SAW due to water vapor absorption properties, that increases the mass over the surface and decrease the wave velocity, leading to sense this humidity changes. 5.6wt per cent PVA solution was prepared and deposited through spin coating. Therefore, a series of tests were carried out in a climatic chamber, varying the humidity and temperature conditions, with the aim to analyze the sensor behavior by measuring its frequency shift. These results were compared with an analytical model and a finite element simulation. The analytical model presented by Sielman determines how the polymer density changes with humidity. These density values were inserted into the Wohltjen equation, which gives the frequency shift of the SAW due to gas absorption. Regarding the finite element simulation, it was carried out in the Comsol Multiphysics software, by solving the different resonating frequencies as a function of the increase in the polymer density due to the insets of humidity values.

xi, 125 p. : ill. (some col.) A print copy of this thesis is available through the UO Libraries. Search the library catalog for the location and call number. / This dissertation presents experimental and theoretical studies of radiation pressure cooling in silica optomechanical microresonators where whispering gallery modes (WGMs) are coupled to thermal mechanical vibrations. In an optomechanical system, circulating optical fields couple to mechanical vibrations via radiation pressure, inducing Stokes and anti-Stokes scattering of photons. In analogy to laser cooling of trapped ions, the mechanical motion can in principle be cooled to its ground state via the anti-Stokes process in the resolved-sideband limit, in which the cavity photon lifetime far exceeds the mechanical oscillation period. Our optomechanical system is a slightly deformed silica microsphere (with a diameter 25-30 μm ), featuring extremely high Q -factors for both optical ( Q o ∼ 10 8 ) and mechanical ( Q m ∼ 10 4 ) systems. Exploiting the unique property of directional evanescent escape in the deformed resonator, we have developed a free-space configuration for the excitation of WGMs and for the interferometric detection of mechanical displacement, for which the part of input laser that is not coupled into the microsphere serves as a local oscillator. Measurement sensitivity better than 5 × 10 -18 m /[Special characters omitted.] has been achieved. The three optically active mechanical modes observed in the displacement power spectrum are well described by finite element analysis. Both radiation pressure cooling and parametric instabilities have been observed in our experiments. The dependence of the mechanical resonator frequency and linewidth on the detuning as well as the intensity of the input laser show excellent agreement with theoretical calculations with no adjustable parameters. The free-space excitation technique has enabled us to combine resolved sideband cooling with cryogenic cooling. At a cryogenic temperature of 1.4 K, the sideband cooling leads to an effective temperature as low as 210 m K for a 110 MHz mechanical oscillator, corresponding to an average phonon occupation of 37, which is one of the three lowest phonon occupations achieved thus far for optomechanical systems. The cooling process is limited by ultrasonic attenuation in fused silica, which should diminish when bath temperature is further lowered, with a 3 He cryostat, to a few hundred millikelvin. Our experimental studies thus indicate that we are tantalizingly close to realizing the ground-state cooling for the exploration of quantum effects in an otherwise macroscopic mechanical system. / Committee in charge: Michael Raymer, Chairperson, Physics; Jens Noeckel, Member, Physics; Hailin Wang, Member, Physics; Paul Csonka, Member, Physics; Jeffrey Cina, Outside Member, Chemistry

We study different phenomena associated with single-photon propagation in optical cavities coupled through optical fibers. We first address the issue of storing and delaying single-photon wavepackets in an array of microcavities. This has possible applications in developing reliable and efficient quantum repeaters that will be utilized in building long distance quantum networks. Second, we investigate a Hong-Ou-Mandel (HOM) type of interference between two photons that are produced in two coupled atom-cavity systems. The HOM effect in this setup can test the degree of indistinguishability between photons when they are stored inside cavities. This part of the dissertation also includes the study of entanglement between atoms, cavities and atom-cavity systems induced by the photons. Finally, we focus on single-photon interactions with a tiny movable mirror in the context of quantum optomechanics. We investigate how the mechanical motion of the mirror leaves its imprints on the optical spectrum of the photon This dissertation includes previously published and unpublished co-authored material. / 10000-01-01

Dissertation/Thesis / Masters Thesis Electrical Engineering 2015

abstract: The accurate and fast determination of organic air pollutants for many applications and studies is critical. Exposure to volatile organic compounds (VOCs) has become an important public health concern, which may induce a lot of health effects such as respiratory irritation, headaches and dizziness. In order to monitor the personal VOCs exposure level at point-of-care, a wearable real time monitor for VOCs detection is necessary. For it to be useful in real world application, it requires low cost, small size and weight, low power consumption, high sensitivity and selectivity. To meet these requirements, a novel mobile device for personal VOCs exposure monitor has been developed. The key sensing element is a disposable molecularly imprinted polymer based quartz tuning fork resonator. The sensor and fabrication protocol are low cost, reproducible and stable. Characterization on the sensing material and device has been done. Comparisons with gold standards in the field such as GC-MS have been conducted. And the device’s functionality and capability have been validated in field tests, proving that it’s a great tool for VOCs monitoring under different scenarios. / Dissertation/Thesis / Doctoral Dissertation Chemical Engineering 2017

abstract: The mechanism of loss in high performance microwave dielectrics with complex perovskite structure, including Ba(Zn1/3Ta2/3)O3, Ba(Cd1/3Ta2/3)O3, ZrTiO4-ZnNb2O6, Ba(Zn1/3Nb2/3)O3, and BaTi4O9-BaZn2Ti4O11, has been investigated. We studied materials synthesized in our own lab and from commercial vendors. Then the measured loss tangent was correlated to the optical, structural, and electrical properties of the material. To accurately and quantitatively determine the microwave loss and Electron Paramagnetic Resonance (EPR) spectra as a function of temperature and magnetic field, we developed parallel plate resonator (PPR) and dielectric resonator (DR) techniques. Our studies found a marked increase in the loss at low temperatures is found in materials containing transition metal with unpaired d-electrons as a result of resonant spin excitations in isolated atoms (light doping) or exchange coupled clusters (moderate to high doping) ; a mechanism that differs from the usual suspects. The loss tangent can be drastically reduced by applying static magnetic fields. Our measurements also show that this mechanism significantly contributes to room temperature loss, but does not dominate. In order to study the electronic structure of these materials, we grew single crystal thin film dielectrics for spectroscopic studies, including angular resolved photoemission spectroscopy (ARPES) experiment. We have synthesized stoichiometric Ba(Cd1/3Ta2/3)O3 [BCT] (100) dielectric thin films on MgO (100) substrates using Pulsed Laser Deposition. Over 99% of the BCT film was found to be epitaxial when grown with an elevated substrate temperature of 635 C, an enhanced oxygen pressures of 53 Pa and a Cd-enriched BCT target with a 1 mol BCT: 1.5 mol CdO composition. Analysis of ultra violet optical absorption results indicate that BCT has a bandgap of 4.9 eV. / Dissertation/Thesis / Ph.D. Materials Science and Engineering 2013

Materiais dielétricos para operação em microondas constituem um ponto importante para usos em sistemas de comunicação móvel/via satélite, incluindo sistemas de monitoramento terrestres, internet/telefonia para celulares, internet das coisas, além do interesse militar para elaboração de radares. Avanços importantes nesse setor tecnológico só foram outorgados, graças ao emprego ostensivo de ressoadores dielétricos (RDs). Esses dispositivos constituem cerâmicas óxidas com baixa perda dielétrica em microondas, com demanda para sua miniaturização. O sistema deverá possuir alta constante dielétrica nesse intervalo e o dispositivo deve ser termicamente estável, ou seja, suas propriedades dielétricas não se alterarão com a temperatura. A busca por materiais de alto desempenho resultou na descoberta das perovskitas ordenadas 1:1 e 1:2, com estequiometria A2BBO6 e A3BB2O9, respectivamente. Tais sistemas ordenam o sítio B, da perovskita ABO3, gerando o empilhamento dos planos cristalinos com B e B, intercalados e na direção [1 1 1]c. Os resultados da literatura mostram que o ordenamento possui papel fundamental na obtenção de ressoadores de baixa perda dielétrica. Ademais, poucos estudos reportam as propriedades dos sistemas contendo os cátions Ca e Nb, no sítio B. Portanto, essa tese dedicou-se à investigação das propriedades dielétricas do sistema Ba3CaNb2O9 e, posteriormente, a modificação desse com a substituição dos cátions Ba2+ por Sr2+ e La3+. As amostras foram preparadas pelo método de reação do estado sólido e, posteriormente, caracterizadas pela difração de raios X, espalhamento Raman, espectroscopia de impedância e desempenho em microondas, além de técnicas complementares como análise térmica, densidade por imersão e microscopia eletrônica de varredura. Os resultados demonstraram a coexistência dos domínios 1:1 e 1:2 no sistema Ba3CaNb2O9, sendo possível manipulá-los mediante condições da sinterização. Microestruturalmente, esses domínios são regiões no cristalito com diferentes ordens catiônicas e, assim, com propriedades cristalográficas e vibracionais diferentes. Pela impedância, notou-se que o ressoador Ba3CaNb2O9 tende a conduzir mais quando possui uma tendência para o domínio 1:1. Tal resultado foi confirmado em microondas, onde a redução da perda dielétrica foi correlacionada à diminuição do domínio 1:1 na estrutura cristalina dos ressoadores. Na solução sólida com Sr2+, uma transição da fase trigonal D3d3 para monoclínica C2h3 foi detectada nos pós-calcinados, sendo oriunda das inclinações octaédricas do sistema de Glazer a0b-b-. As cerâmicas desse sistema foram sinterizadas a 1500 °C por 26 h, cujo resultado ilustrou uma tendência à ordem 1:1 para x ≥ 0,30. No sistema com La3+, observou-se, além da coexistência, os monodomínios 1:1 e 1:2. O sistema com monodomínios 1:1, BaLaCaNbO6 (y = 0,50), evidenciou uma distorção monoclínica intrínseca. Esta distorção foi associada às inclinações octaédricas do sistema de Glazer a0b-b-, reduzindo a simetria da fase cúbica Oh5 para monoclínica C2h3. Por fim, o desempenho como ressoador dielétrico dos sistemas BaLaCaNbO6 e Ba3CaNb2O9 foi avaliado. O primeiro sistema mostrou os seguintes valores: permissividade relativa εg ∼ 26, Qu × fR ∼ 10.506 GHz e coeficiente τf ∼ -55 ppm.K-1. O segundo sistema revelou os dados: permissividade εg ∼ 43, Qu × fR ∼ 15.752 GHz e o coeficiente τf ∼ 278 ppm.K-1. / Dielectric materials for microwave applications play an important role in mobile and satellite communication systems, including terrestrial monitoring, internet/mobile devices, internet of things, as well as the military uses as the radar developments. Advances in this technological field were only possible due to the ostensive use of dielectric resonators (DRs). These devices constitute oxide ceramics with a low dielectric loss in microwave frequency. The system must have high dielectric constant and such a device must be thermally stable. The search for highperformance materials granted the discovery of 1:1 and 1:2 ordered perovskites, with general formula A2BBO6 and A3BB2O9, respectively. These systems depict the B-site ordering of ABO3 perovskite, inducing the crystalline planes stacking in the [1 1 1]c direction. The literature results showed that the ordering plays an essential role in the low loss ceramics. Moreover, few studies reported the features of the systems containing the Ca and Nb cations at the B-site. Therefore, our work drives the dielectric properties of the Ba3CaNb2O9 system and, then, the modification induced by Ba2+ substitution by Sr2+ and La3+. The samples were prepared by the conventional solid-state reaction method and probed by X-ray diffraction, Raman scattering, impedance spectroscopy and microwave performance, as well as other techniques such as thermal analysis, density measurement, and electron microscopy. Our findings elucidated the coexistence of 1:1 and 1:2 domains in Ba3CaNb2O9 ceramics, being possible to manipulate them by sintering conditions. Such an ordered domain denotes regions in the crystallites with different cationic order and with different crystallographic and vibrational behavior. By the impedance spectroscopy, it was observed that Ba3CaNb2O9 ceramics tend to conduct more when they present a tendency towards the 1:1 domains. The earlier result was also confirmed in microwave frequency, in which the dielectric loss decreasing was correlated to the decrease of the 1:1 domain in the crystal structure. In the strontium solid solution, a transition from the D3d3 trigonal phase to the C2h3 monoclinic one was noted in powder samples, being derived from octahedral tilting (a0b-b- Glazer system). In the lanthanum system, besides the coexistence, the monodomains 1:1 and 1:2 were observed. Otherwise, the 1:1 monodomain system, BaLaCaNbO6 (y = 0.50), exhibited an intrinsic monoclinic distortion. This distortion was ascribed to the octahedral tilting (a0b-b- Glazer system), lowering the crystal symmetry from Oh5 cubic phase to the C2h3 monoclinic phase. The dielectric resonator performances of the BaLaCaNbO6 and Ba3CaNb2O9 systems were evaluated. The first system showed the following values: permittivity εg ∼ 26, Qu × fR ∼ 10.506 GHz and coefficient τf ∼ -55 ppm.K-1. The second system exhibited the data: permittivity εg ∼ 43, Qu × fR ∼ 15.752 GHz and coefficient τf ∼ 278 ppm.K-1.

Nous assistons aujourd'hui à une explosion des demandes de calcul, de stockage et de transfert de données. Dans ce contexte, le développement des ordinateurs à haute performance est crucial mais il est limité par le débit et la consommation des interconnexions électriques entre puces ou intra-puces. La photonique sur silicium propose de lever ce verrou technologique en utilisant la maturité des procédés de fabrication de microélectronique pour concevoir des interconnexions optiques à très haut débit et à faible énergie par bit. Dans ces travaux, nous nous proposons de dimensionner un lien optique intégré sur silicium pour par exemple adresser le défi technologique des interconnexions intra-puces entre un processeur et une mémoire DRAM de dernière génération. Le lien optique conçu est multiplexé en longueur d’onde et utilise des composants intégrés à faible empreinte appelés anneaux résonants pour les fonctions de modulation et de démultiplexage. Les sources laser dont seront munis ces interconnexions consomment une puissance importante : nous nous attachons à optimiser la performance des composants utilisés en termes de puissance optique. A partir d’une analyse système, nous proposons une architecture de lien et construisons un modèle pour évaluer les pénalités en puissance optique associées au transmetteur et au récepteur du lien de communication à l’aide de simulations statiques et dynamiques. Ce modèle comprend des contributions des modulateurs et des filtres du démultiplexeur considérés individuellement ainsi que des contributions liées au multiplexage en longueur d’onde à l’émission et à la réception. Des modulateurs optiques en anneau sont fabriqués en technologie PIC25G, caractérisés en statique et en dynamique puis comparés au modèle. Enfin, des démonstrateurs multiplexés en longueur d’onde sont conçus et mis en œuvre permettant de valider nos modèles prédictifs et d'en soulever de futurs perfectionnements. / The 21st century is characterized by the explosion of demand for computing power as well as data storage and transfer. In this context, the development of high-performance computers is crucial but it is limited by the bandwidth and the energy efficiency of chip-to-chip and intra-chip electrical interconnects. Silicon photonics is a promising solution that uses microelectronics manufacturing techniques to fabricate optical components dedicated to efficient and high-bit-rate optical communication links.This work aims at designing a silicon photonic intra-chip high-bandwidth interconnect based on the example of latest-generation DRAM specifications. Wavelength division multiplexing (WDM) is used with low-footprint components called optical ring resonators for modulation and filtering.Lasers sources are a non-negligible contributor to overall system power consumption. For this reason, this thesis focuses on the optimization of ring resonators in terms of optical power. We first carry out a system analysis and propose an architecture that consists of parallel WDM links. Then a system model that evaluates optical power penalties related to the transmitter and the receiver is built up using static and dynamic simulations. Individual contributions of modulators, filters as well as the impact of adjacent channels at the transmitter and receiver sides are taken into account. Optical ring modulators are fabricated in PIC25G technology and characterized through static and dynamic measurements in order to validate our model. Finally, wavelength division multiplexed prototypes are designed and demonstrations corresponding to different WDM configurations are carried out which allows for suggestions of future improvements from the comparison with our predictive model.

L’objectif de ce travail est le développement de dispositifs de contrôle de la diffusion des ondes acoustiques à l’aide de surfaces hétérogènes, pour des applications à l’acoustique urbaine. Pour remplir cet objectif, deux méthodes sont employées. La première à l’aide d’une métasurface, la direction d’une onde réfléchie est contrôlée. La seconde étude concerne l’influence d’un traitement inhomogène aux parois d’un guide ouvert sur les effets conjoints ou compétitifs d’absorption, de confinement et de rayonnement de l’onde. Nous montrons expérimentalement la possibilité de dissimuler un objet disposé sur un mur pour une onde acoustique audible. Pour y parvenir, une métasurface composée de différents résonateurs de Helmholtz est conçue et est réalisée de façon à être la plus fine possible. Ces travaux sont réalisés dans le domaine fréquentiel mais également dans le domaine temporel, ce qui permet de mettre en avant le caractère large bande de la métasurface. Il est démontré numériquement et expérimentalement que la direction des ondes réfléchies peut être contrôlée. Enfin la dernière partie est consacrée à l’influence d’une paroi hétérogène sur la propagation d’une onde acoustique à l’intérieur d’une rue. Une rue pouvant être assimilée à un guide d’onde ouvert engendre donc des modes de propagation complexes, dus aux pertes par rayonnement. La présence d’un matériau poreux sur les parois d’un guide vient perturber fortement la localisation spatiale des modes, ce qui les rend plus ou moins fuyants. / The aim of this thesis is to develop a scheme for controling the propagation of acoustic waves using heteregenous surfaces. Its results can be applied in the field of urban acoustic. The thesis is composed of two sections, each of them employing a different method. The first section focuses on controling the direction of a reflected wave, using a metasurface. The second concentrates on the influence of an inconsistent treatment to the side of an open waveguide on the wave joint and competitive effects of absorption, confinement and radiation. Part one provides experimental evidence that it is possible to conceal an object placed on a wall from an audible acoustic wave. To prove it, the thinest possible metasurface was constructed with Helmholtz resonators. The experimental results were compared to a numerical study realized with finite elements. This work was made in both temporal and frequency domains, allowing to point out the wide frequency characteristics of the metasurface. The numerical and experimental results show that the direction of a reflected wave can, indeed, be controled. Part two analyse the impact of a heterogeneous wall on the spreadinf of an acoustic wave in a street. Due to radiation losses, the street produces complex ways of propagation. The presence of a porous material on a waveguide‘ side deeply disrupt the spatial location of these waves, making them more or less fleeting. In particular, depending on the position of the material in the street, certain waves will be more confined to the inside of the street, radiating less towards the open external environment. They are consequently, less cushioned.