The corrosion of infrastructure imposes a significant monetary cost, and at times human cost, upon society. Methods to improve corrosion resistance of materials are described herein which utilize the reversibility of the Diels-Alder reaction to impart thermal responsiveness upon materials. Such stimuli responsiveness can potentially play a role in self healing properties which lead to reduced cracking and thus increased corrosion protection. Reversible Diels-Alder chemistry was utilized to manipulate the surface energy of glass substrates. Hydrophobic dieneophiles were prepared and attached to glass slides and capillaries to yield a nonwetting surface. Thermal treatment of the surfaces cleaved the Diels-Alder linkage, and resulted in the fabrication of a hydrophilic surface. Preliminary analysis utilized contact angle (CA) measurements to monitor the change in surface energy, and observed a hydrophilic state (CA - 70±3°) before attachment of the dieneophile to a hydrophobic state (CA - 101±9°) followed by regeneration of the hydrophilic state (CA - 70±6°) upon cleavage of the Diels-Alder linkage. The treatments were then applied to glass capillaries, with effective treatment confirmed by fluid column measurements. Patterned treatments were also demonstrated to provide effective fluid flow gating. Reversible Diels-Alder linkages were incorporated into polymer thermoset binding resins in order to provide a means by which a crosslinked thermoset could undergo stimuli responsive reversible crosslinking. The binder systems which were utilized included two types of amine curing agents, polydimethylsiloxane (PDMS) and Jeffamine® polyetheramines (PEA), and two types of epoxy resins, EPON resin based on diglycidyl ether of Bisphenol-A and epoxidized soybean oil. Various dienes and dienophiles were employed to functionalize the selected binder systems and were met with various degrees of success. The synthetic technique which proved to be the most promising was the Diels-Alder modification of the epoxidized soybean oil.

The manufacturing systems operating within today's global enterprises are invariably dynamic and complicated. Lean manufacturing works well where demand is relatively stable and predictable where product diversity is low. However, we need a much higher agility where customer demand is volatile with high product variety. Frequent changes of product designs need quicker response times in ramp-up to volume. To stay competitive in this 21st century global industrialization, companies must posses a new operation design strategy for responsive manufacturing systems that react to unpredictable market changes as well as to launch new products in a cost-effective and efficient way. The objective of this research is to develop an alternative method to model, analyze, and design responsive manufacturing systems using classical control theory. This new approach permits industrial engineers to study and better predict the transient behavior of responsive manufacturing systems in terms of production lead time, WIP overshoot, system responsiveness, and lean finished inventory. We provide a one-to-one correspondence to translate manufacturing terminologies from the System Dynamics (SD) models into the block diagram representation and transfer functions. We can analytically determine the transient characteristics of responsive manufacturing systems. This analytical formulation is not offered in discrete event simulation or system dynamics approach. We further introduce the Root Locus design technique that investigates the sensitivity of the closed-loop poles location as they relate to the manufacturing world on a complex s-plane. This subsequent complex plane analysis offers new management strategies to better predict and control the dynamic responses of responsive manufacturing systems in terms of inventory build-up (i.e., leanness) and lead time. We define classical control theory terms and interpret their meanings according to the closed-loop poles locations to assist production management in utilizing the Root Locus design tool. Again, by applying this completely graphic view approach, we give a new design approach that determine the responsive manufacturing parametric set of values without iterative trial-and-error simulation replications as found in discrete event simulation or system dynamics approach. / Ph. D.

Waveguide architectures were inscribed within two different stimuli-responsive hydrogels capable of actuation. An electroactive hydrogel, which deforms when placed within an electric field, is demonstrated as a method for remote actuation and steering of light outputs. Lattices of waveguide with diameters on the microscale were embedded within hydrogel prisms, achieved through a nonlinear light propagation process known as self-trapping. This process is a result of balance between the natural divergence of light and self-focusing effects caused by an irreversible positive refractive index change during photopolymerization. Waveguiding structures are inscribed in the material because of this process. Square (2D) and near-cubic (3D) lattices were inscribed in hydrogel prisms, demonstrating the ability to remotely steer one or two light outputs simultaneously using an electric field. The overall optical effect is reminiscent of camouflaging techniques observed in marine creatures (ie. cephalopods). Additionally, a novel volumetric 3D printing technique previously demonstrated by the Saravanamuttu group was implemented to fabricate hydrogel cylinders capable of photothermal actuation. Coupling a thermoresponsive hydrogel material with a photoabsorber, areas irradiated by a light source are observed to contract. These contractions lead to the deflection of waveguiding cylinders towards the light source, reminiscent of the phototropic behaviours observed in particular plants (ie. sunflowers). The results of these studies provide insight for the fabrication of functional materials through nonlinear light propagation. Understanding these systems could provide knowledge for the fabrication of other stimuli-responsive materials with light-guiding properties. / Thesis / Master of Science (MSc)

Thesis advisor: Vincent Cho / The purpose of this study was to explore the strategies districts use to retain principals in their complex roles through the framework of culturally responsive district leadership. This qualitative case study explored how district leaders in one Massachusetts school district focused on principal retention and whether their actions influenced a principal's decision to remain in their role. The study took place during a global health pandemic placing principals at the center of navigating this crisis. This study is part of a larger study that investigated how principals benefit from and shape professional capital to improve schools. Data were gathered from semi-structured interviews with district level leaders and principals. Findings demonstrated that there are things districts can do that positively influence principal retention, although these practices are not necessarily culturally responsive. Data supported the literature that professional development and mentoring, improved working conditions, and autonomy all positively influence principal retention. In addition, this study concluded that focusing on positive relationships and “growing your own” leadership are also key strategies to promote principal retention. Inorder to enact culturally responsive retention, recommendations include exploring whiteness in leadership and the influence of race on principal retention. Additionally. further investigation needs to be done examining the influence of higher accountability for student outcomes on principal retention. / Thesis (EdD) — Boston College, 2022. / Submitted to: Boston College. Lynch School of Education. / Discipline: Educational Leadership and Higher Education.

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