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Study of Rheological Behaviour of Coating Paste containing conductive polymer complexIQBAL, KASHIF January 2010 (has links)
Conducting polymer coating is the new developing area in the field of advanced textiles. In this project the rheological behaviour of paste containing conducting polymer was studied during formulation to coating application. The literature study is done by keeping all the contents of project in mind and a wide area of conductive polymer, coating methods, binder system and rheology modifier is covered. The rheological behaviour of different fluid containing newtanion and non-newtanion behaviour is discussed for better understanding of the project working. Polyester fabric was coated by knife coating method. In paste formulation, the chemicals used were polyurethane binder with two HEUR based rheology modifiers. A lot of experiments were performed to determine the right amount of rheology modifier alone or in combination for paste formulation and coating application and interesting findings were observed during the experimental work which had been justified in results and analysis. After application, the coated fabric was checked for resistivity. / Program: Magisterutbildning i textilteknologi
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Mise en émulsion sans tensioactif de résines alkydes et formulation de peintures biosourcées / Free surfactants alkyd resin emulsification and biobased paints formulationsRomand, Alison 21 January 2016 (has links)
Les peintures sont omniprésentes dans nos civilisations modernes et décorent presque tous les supports et ce dans des domaines très variés. L'utilisation massive des peintures pose cependant des problèmes environnementaux et de santé publique, de par la présence de solvants qui, lors du séchage, s'évaporent et émettent des composés organiques volatiles (COV) néfastes pour l'environnement et l'homme. Une démarche européenne et mondiale de réduction d'émission des COV est donc en cours depuis quelques années. De plus, l'engouement croissant pour le développement durable pousse à la transition de produits pétrosourcés vers des produits biosourcés, à coûts et performances similaires. Les résines alkydes en émulsions, développées au début du XXème siècle, constituent une alternative de choix car émettant une quantité limitée de COV et obtenues par polycondensation de matières premières renouvelables. Après un état de l'art sur le contexte des peintures actuelles et la composition d'une peinture alkyde en émulsion, leurs propriétés physiques et chimiques ont été étudiées. Après ce travail de formulation, deux additifs ont été synthétisés afin d'augmenter le taux de biosourcé des peintures alkydes en émulsion : un épaississant et un agent dispersant. De par la présence de surfactants, les formules de peintures alkydes en émulsion sont pour l'heure moins compétitives que les peintures alkydes en phase solvant. En conséquence, la première émulsion alkyde sans tensioactif a été développée et ses performances évaluées en peinture / Paints and coatings occupy a prominent place in the cultural history of mankind. People have always been fascinated by colors and used paints to decorate and beautify themselves and their environment. Nevertheless, these products bring a lot of problems. For instance, some paints still contain organic solvents, which have negative impacts on the environment and human health. Due to environmental legislations and the need to reduce VOCs emission (volatile organic compounds), water-based paints have attracted a lot of interest. Moreover, the raising sustainability awareness is a driving force for the transition from petrobased to biobased products with equivalent costs and performances. In this context, alkyd resin emulsion, introduced in the 1990s, still continue to be the most widely used binder, because they have low VOCs level and are synthesized by polycondensation reactions of renewable raw materials. After reviewing the current state of the art regarding the alkyd paint emulsion, their physical and chemical properties were studied. Two additives, respectively a rheology modifier and a dispersing agent, were also synthesized, in order to increase the biobased content of alkyd paint emulsion Due to the presence of wetting agent, alkyd emulsion paints are still less competitive than solvent-borne alkyd paints. The first surfactant free alkyd emulsion was consequently developed and its film properties characterized in paint formulation
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