Thesis (Ph. D.)--University of Washington, 2003. / Vita. Includes bibliographical references (leaves 80-91).

The Steam-Assisted Gravity Drainage (SAGD) Process involves the injection of steam through a horizontal well and the production of heavy oil through a lower horizontal well. Several authors have tried to model this process using analytical, semi-analytical and fully numerical means. In this dissertation, we improve the predictive ability of previous models by accounting for the effect of anisotropy, the effect of heat transfer on capillarity and the effect of water-in-oil (W/O) emulsion formation and transport which serves to enhance heat transfer during SAGD. We account for the effect of anisotropy during SAGD by performing elliptical transformation of the resultant gravity head and resultant oil drainage vectors on to a space described by the vertical and horizontal permeabilities. Our results, show that unlike for the isotropic case, the effect of anisotropy is time dependent and there exists a given time beyond which it ceases to have any effect on SAGD rates. This result will impact well spacing design and optimization during SAGD. Butler et al. (1981) derived their classical SAGD model by solving a 1-D heat conservation equation for single phase flow. This model has excellent predictive capability at experimental scales but performs poorly at field scales. By assuming a linear saturation -- temperature relationship, Sharma and Gates (2010b) developed a model that accounts for multiphase flow ahead of the steam chamber interface. In this work, by decomposing capillary pressure into its saturation and temperature components, we coupled the mass and energy conservation equations and showed that the multi-scale, multiphase flow phenomenon occurring during SAGD is the classical Marangoni (or thermo-capillary) effect which can be characterized by the Marangoni number. At low Marangoni numbers (typical of experimental scales) we get the Butler solution while at high Marangoni numbers (typical of field scales), we approximate the Sharma and Gates solution. The Marangoni flow concept was extended to the Expanding Solvent SAGD (ES-SAGD) process and our results show that there exists a given Marangoni number threshold below which the ES-SAGD process will not fare better than the SAGD process. Experimental results presented in Sasaki et al. (2002) demonstrate the existence of water-in-oil emulsions adjacent to the steam chamber wall during SAGD. In this work we show that these emulsions enhanced heat transfer at the chamber wall and hence oil recovery. We postulate that these W/O emulsions are principally hot water droplets that carry convective heat energy. We perform calculations to show that their presence can practically double the effective heat transfer coefficient across the steam chamber interface which overcomes the effect of reduced oil rates due to the increased emulsified phase viscosity. Our results also compared well with published experimental data. The SAGD (and ES-SAGD) process is a short length-scaled process and hence, short length-scaled phenomena (typically ignored in other EOR or conventional processes) such as thermo-capillarity and in-situ emulsification should not be ignored in predicting SAGD recoveries. This work will find unique application in predictive models used as fast proxies for predicting SAGD recovery and for history matching purposes. / text

Recently, there is emerging interests in deploying wireless sensor networks in forests for applications such as forest fire detection, environmental monitoring and remote surveillance. One challenge in the design of such networks is to ensure reliable communication between sensors located near the ground and over short distances. However, the propagation mechanisms in this type of scenario are complex and not well understood. Furthermore, the design of antennas that can exploit the resulting propagation mechanisms for optimal power transfer remains an open question. The objective of this dissertation is to understand wave propagation and antenna radiation in forested environments in the HF/VHF frequency range. To achieve this objective, several forest scaled models are introduced. The first scaled forest model is a periodic metal cut-wire array. The transmission data inside the cut-wire array are simulated and measured. The propagation mechanisms inside the array are extracted. Several interesting propagation phenomena associated with surface waves and leaky waves are observed and explained. Next, a dielectric rod array consisting of water-filled straws is investigated as a more realistic forest model. Water is chosen since its dielectric constant in the microwave range is close to that of tree trunks in the HF/VHF frequencies. The propagation mechanisms in the water rod array are investigated through scaled model measurements in the laboratory, numerical simulations and an effective medium theory. Randomization effects due to rod spacing and rod height on the propagation mechanisms are also studied. Finally, the transmission data in a real forest are collected in the HF/VHF frequency range to corroborate the findings from the models. The measurement site is located at Bastrop, Texas. For comparison, the transmission data are also measured in an open field. The transmission data are processed and the resulting propagation mechanisms are extracted and compared with the model predictions. As an extension of the propagation study, the potential to achieve directive antenna radiations in a forest is explored. A simple metal cut-wire array environment is considered for ease in modeling. For the case when both the transmit antenna and the receive antenna are embedded inside the array, two design ideas are presented. The first design tries to couple the antenna radiation into the dominant propagation mechanism through phase matching and the second design uses a closely spaced Yagi array to decouple the antenna from its surrounding medium. For the case when the transmit antenna is embedded inside the array and the receive antenna is located outside the array, the leaky wave mechanism is explored to achieve directive radiation. These designs are verified through theoretical predictions, numerical simulations and prototype measurements. / text

This work was carried out to study the effect of shot-peening on the fatigue behaviour of carbon steels. Differently heat treated medium and high carbon steel specimens were selected. Medium carbon steels, AISI 1141 and AISI 1151, were respectively air cooled and quenched-tempered. A high carbon steel, C70S6 (AISI 1070), was air cooled. The other material was a powder metal (0.5% C) steel. Each group of steels was divided into two. One was shot-peened. The other half remained in their original conditions. All were fatigue tested under fully reversed (R=-1) tension-compression loading conditions. Microhardness tests were carried out on both the grip and gage sections of selected non shot-peened and shot-peened specimens to determine the hardness profile and effect of cycling. Shot-peening was found to be deeper on one side of each specimen. Compressive residual stress profiles and surface roughness measurements were provided. Shot-peening increased the surface roughness from 0.26±0.03µm to 3.60±0.44µm. Compressive residual stresses induced by shot-peening reached a maximum of -463.9MPa at a depth of 0.1mm.The fatigue limit (N≈106 cycles) and microhardness profiles of the non shot-peened and shot-peened specimens were compared to determine the material behaviour changes after shot-peening and cycling. Also their fatigue properties were related to the manufacturing process including heat and surface treatments. Comparing the grip and gage microhardness profiles of each steel showed that neither cyclic softening nor hardening occurred in the non shot-peened condition. Cyclic softening was apparent in the shot-peened regions of all steels except powder metal (PM) steel. The amount of softening in the shot-peened region was 55.0% on the left side and 73.0% on the right in the AISI 1141 steel , 46.0% on the left side and 55.0% on the right in the C70S6AC steel and 31.0% on the right side in AISI 1151QT steel. Softening was accompanied by a decrease in the depth of surface hardness. It is suggested that although the beneficial effects of shot peening, compressive residual stresses and work hardening, were offset by surface roughness, crack initiation was more likely to occur below the surface. Surface roughness was not a significant factor in controlling the fatigue lives of AISI 1141AC and C70S6 steels, since they were essentially the same for the non shot-peened and shot-peened conditions. Shot-peening had very little effect on the push-pull fatigue limit of C70S6 steel (-2.1%), and its effect on AISI 1141AC steel was relatively small (6.0%). However, the influence of shot-peening on the AISI 1151QT and PM steels was more apparent. The fatigue limit of the PM steel increased 14.0% whereas the fatigue limit of the AISI 1151QT steel decreased 11.0% on shot peening.

Environmental Impact Assessment (EIA) is recognised worldwide as a tool for identifying the potential adverse effects of a proposed development on the environment. Very little attention has been given to determining the actual environmental effects resulting from a development. The need for EIA follow–up (i.e. monitoring, auditing, evaluation, management and communication) was identified and would form the building blocks within the EIA process. Follow–up provides information about the consequences of an activity and presents opportunities to implement adequate mitigation measures. EIA follow–up is not developed to its full potential even though the need for it is acknowledged and supported in legislation, scientific journals and scientific books. EIA follow–up necessitates feedback in the EIA process to ensure lessons learnt and outcomes from past experiences can be applied in future actions. Follow–up is only a legal requirement if conditions are specified in the environmental authorisation (EA). Of particular concern to follow–up is the accuracy of prediction and secondly, the level of compliance to conditions set out in the authorization and management plans. This study will focus primarily on critically analysing predictions and compliance from the construction phase of a high profile mega shopping mall project, namely the Mooi River Mall (MRM), with an analysis to gauge the actual effect and contribution of the EIA process to decision making and implementation practices. Multiple data sources were used to determine the accuracy of predictions and legal compliance level of the Mooi River Mall. The Mooi River Mall's accuracy of predictions (66%) and legal compliance (83%) suggest that some of the impacts were unavoidable; that mitigation measures were either not implemented or identified or that EIA follow–up served its purpose in the form of implementing effective auditing programmes to monitor legal compliance. / Thesis (M.Sc (Environmental Science))--North-West University, Potchefstroom Campus, 2011.

Environmental Impact Assessment (EIA) is recognised worldwide as a tool for identifying the potential adverse effects of a proposed development on the environment. Very little attention has been given to determining the actual environmental effects resulting from a development. The need for EIA follow–up (i.e. monitoring, auditing, evaluation, management and communication) was identified and would form the building blocks within the EIA process. Follow–up provides information about the consequences of an activity and presents opportunities to implement adequate mitigation measures. EIA follow–up is not developed to its full potential even though the need for it is acknowledged and supported in legislation, scientific journals and scientific books. EIA follow–up necessitates feedback in the EIA process to ensure lessons learnt and outcomes from past experiences can be applied in future actions. Follow–up is only a legal requirement if conditions are specified in the environmental authorisation (EA). Of particular concern to follow–up is the accuracy of prediction and secondly, the level of compliance to conditions set out in the authorization and management plans. This study will focus primarily on critically analysing predictions and compliance from the construction phase of a high profile mega shopping mall project, namely the Mooi River Mall (MRM), with an analysis to gauge the actual effect and contribution of the EIA process to decision making and implementation practices. Multiple data sources were used to determine the accuracy of predictions and legal compliance level of the Mooi River Mall. The Mooi River Mall's accuracy of predictions (66%) and legal compliance (83%) suggest that some of the impacts were unavoidable; that mitigation measures were either not implemented or identified or that EIA follow–up served its purpose in the form of implementing effective auditing programmes to monitor legal compliance. / Thesis (M.Sc (Environmental Science))--North-West University, Potchefstroom Campus, 2011.

<p>Rod photoreceptors are specialized neurons responsible for capturing photons and translating visual information into electrical signals. Visual signal transduction in rods is confined to the unique outer segment organelle, a modified primary cilium consisting of a stack of hundreds of flattened disc membranes enveloped by a single plasma membrane. By concentrating important signaling molecules on disc membranes, the outer segment provides an ideal biochemical environment for the production of vision with high sensitivity and temporal resolution.</p><p>This dissertation focuses primarily on a molecular dissection of two multifunctional outer segment proteins, R9AP and rhodopsin, and also reassesses the localization of Glut1, a third protein formerly believed to reside in the outer segment. All three experimental lines relied on in vivo expression of novel protein constructs in vertebrate rods using several gene delivery strategies: conventional transgenics, retinal electroporation, and retinal infection with recombinant adeno-associated virus.</p><p>The tail-anchored protein R9AP, in conjunction with RGS9-1 and G-beta5, comprises the transducin GTPase activating complex, which catalyzes the rate-limiting step in rod photoresponse recovery. In addition to maximizing the enzymatic activity of the complex, R9AP is responsible for both the post-translational stability and outer segment targeting of RGS9-1-G-beta5. We investigated the mechanism behind R9AP's poorly understood function in protecting RGS9-1-G-beta5 from proteolysis and found that it is performed simply by recruiting the complex to cellular membranes and can be entirely dissociated from R9AP's outer segment targeting function. Furthermore, we demonstrated that replacement of R9AP's transmembrane domain with a lipid anchor preserves the ability of the GTPase activating complex to function in outer segments.</p><p>Rhodopsin, the visual pigment of rods, has a second important, yet poorly defined, function as a rod outer segment building block: outer segments disc membranes fail to form in the absence of rhodopsin. Our goal was to identify the molecular features of rhodopsin mechanistically involved in outer segment morphogenesis by designing artificial membrane proteins that could fully substitute for rhodopsin in performing this function. We observed that rhodopsin's C-terminal VXPX outer segment targeting motif is unnecessary for outer segment disc formation since it could be replaced with a targeting motif from an unrelated protein, peripherin. Furthermore, we obtained surprising evidence that rhodopsin's role in this process is limited to providing an abundance of transmembrane protein material to disc membranes.</p><p>Finally, while attempting to find a targeting motif to substitute for the VXPX motif of rhodopsin, we made an unexpected observation that the facilitative glucose transporter Glut1, long thought to reside in the outer segment, is actively excluded from this organelle. This revises our understanding of the energy flow in rods by showing that the outer segment is entirely dependent on the inner segment for its energy supply.</p> / Dissertation

Es ist in dieser Arbeit gelungen, starre Oligospiroketal(OSK)-Stäbe als Grundbausteine für komplexe 2D- und 3D-Systeme zu verwenden. Dazu wurde ein difunktionalisierter starrer Stab synthetisiert, der mit seines Gleichen und anderen verzweigten Funktionalisierungseinheiten in Azid-Alkin-Klickreaktionen eingesetzt wurde. An zwei über Klickreaktion verknüpften OSK-Stäben konnten mittels theoretischer Berechnungen Aussagen über die neuartige Bimodalität der Konformation getroffen werden. Es wurde dafür der Begriff Gelenkstab eingeführt, da die Moleküle um ein Gelenk gedreht sowohl gestreckt als auch geknickt vorliegen können. Aufbauend auf diesen Erkenntnissen konnte gezeigt werden, dass nicht nur gezielt große Polymere aus bis zu vier OSK-Stäben synthetisiert werden können, sondern es auch möglich ist, durch gezielte Änderung von Reaktionsbedingungen der Klickreaktion auch Cyclen aus starren OSK-Stäben herzustellen. Die neu entwickelte Substanzklasse der Gelenkstäbe wurde im Hinblick auf die Steuerung des vorliegenden Gleichgewichts zwischen geknicktem und gestrecktem Gelenkstab hin untersucht. Dafür wurde der Gelenkstab mit Pyrenylresten in terminaler Position versehen. Es wurde durch Fluoreszenzmessungen festgestellt, dass das Gleichgewicht z. B. durch die Temperatur oder die Wahl des Lösungsmittels beeinflussbar ist. Für vielfache Anwendungen wurde eine vereinfachte Synthesestrategie gefunden, mit der eine beliebige Funktionalisierung in nur einem Syntheseschritt erreicht werden konnte. Es konnten photoaktive Gelenkstäbe synthetisiert werden, die gezielt zur intramolekularen Dimerisierung geführt werden konnten. Zusätzlich wurde durch Aminosäuren ein Verknüpfungselement am Ende der Gelenkstäbe gefunden, das eine stereoselektive Synthese von Mehrfachfunktionalisierungen zulässt. Die Synthese der komplexen Gelenkstäbe wurde als ein neuartiges Gebiet aufgezeigt und bietet ein breites Forschungspotential für weitere Anwendungen z. B. in der Biologie (als molekulare Schalter für Ionentransporte) und in der Materialchemie (als Ladungs- oder Energietransporteure). / In this dissertation the use of rigid Oligospiroketal (OSK)-rods as basic model for 2D- and 3D-systems was shown. For that purpose a bifunctionalized rigid rod was synthesized and was used in Azide-Alkine-clickreaction with itself and with other branched functionalized units. By theoretical calculations a statement about the novel bimodulation of the conformation of two OSK-rods which are linked by a clickreaction could be made. “Articulated rod” was introduced as new term, because the molecules could exist elongated or buckled. Based on this knowledge it became apparent that not only the size selective synthesis of polymers by using up to four OSK-rods is possible but also cycles with OSK-rods by using different click-reaction conditions can be synthesized. The newly developed group of “articulated rod” substances was examined regarding the equilibrium between buckled and elongated “articulated rod”. That for the articulated rod was functionalized with pyrenyl moieties in terminal position. By fluorescence measurements of these rods it could be shown that the equilibration is influenced by different temperatures and different solvents. For multiple applications a simplified strategy for synthesis with a wide range of functionalization in only one step of synthesis could be achieved. Photoactive articulated rods were synthesized, that could be selectively intramolecular dimerized. Additionally, amino acids were introduced as linker at the end of a articulated rod. By this a stereoselective synthesis of multiple functionaliations is possible. By the synthesis of complex articulated rods a novel field of research was found. There is a wide potential of research for more applications for example in biology (as molecular switch for transportation of ions) and in materials chemistry (as transporter for charge or energy).

The Clamp-Rod Internal Fixator (CRIF) is a fracture fixation implant with growing popularity among veterinarian’s for its versatility and ease of use. Although the CRIF is currently in clinical use, relatively few reports exist describing the biomechanical properties and clinical results of this system. The objective of this study was to determine the in vitro biomechanical properties of a 5mm CRIF/rod construct to a 3.5mm Limited Contact-Dynamic Compression Plate (LC-DCP/rod) construct using a canine femoral gap model. Paired canine femora were treated with 40mm mid-diaphyseal ostectomies and randomly assigned to CRIF/rod or LC-DCP/rod. Five pairs of constructs were tested in bending and five pairs were evaluated in torsion. Single ramp to failure tests were conducted to evaluate construct stiffness, yield load, and failure mode. While CRIF/rod and LC-DCP/rod were not significantly different when evaluated in bending, LC-DCP/rod constructs are significantly more rigid than CRIF/rod constructs at higher torsional loads. Below 10degrees of twist, or 4.92Nm torque, the LC-DCP/rod and CRIF/rod were not statistically different in torsion. Catastrophic injuries of the metacarpophalangeal joint resulting in the disruption of the suspensory apparatus are the most common fatal injuries in thoroughbred racehorses. Fetlock arthrodesis is a procedure designed to mitigate suffering from injury as well as degenerative diseases affecting articulation. The objective of this study is to assess the in vitro biomechanical behavior of techniques for fetlock arthrodesis. Twelve forelimb pairs were collected from adult horses euthanized for reasons unrelated to disease of the metacarpophalangeal joint (MCP). A 14-16-hole broad 4.5mm Locking Compression Plate (LCP) was compared to a 14-16 hole broad Dynamic Compression Plate (DCP). Both constructs used a two “figure-eight” 1.25mm stainless steel wire tension band. Fatigue tests and to failure tests were conducted. There were no significant differences in stiffness between groups for fatigue tests. Stiffness increased after the first fatigue cycle for the LCP/wire (80.56+/-52.22%) and DCP/wire (56.58+/-14.85%). Above 3.5mm of axial deformation there was a statistical difference between the stiffness of the LCP/wire (3824.12+/-751.84 N/mm) and the DCP/wire (3009.65+/-718.25 N/mm) (P=0.038). The LCP/wire showed increased stiffness above 3.5mm compression compared to the DCP/wire. Under fatigue testing conditions the constructs are not statistically different.

There are some alternatives of artificial lift methods to increase the production of oil well or to keep it producing. Sucker rod pumping (SRP) and electrical submersible pumping (ESP) systems are selected for the design and economical evaluation of thirteen oil wells of R field. Although selected wells are already producing artificially, they are redesigned for SRP and ESP. LoadCalC software developed by Lufkin and SubPUMP developed by DSSC are used for SRP and ESP designs respectively. For economic evaluation, the rate of return (ROR) of each design is calculated for ten year period. In technical comparison, advantage of higher production ability with lower power consumption was observed in ESP applications. In wells which have lower production than 100 bpd, SRP takes the advantage as it has the ability of low volume lifting. In economical comparison it was observed that using both methods together was given better result. By increasing the number of wells that were applied ESP, 3.61% of increment in ROR was obtained relative to the present status.