The current design procedure for cantilever structures on spread footings in the Texas Department of Transportation (TxDOT) is based on horizontal pressure that is calculated by using Rankine's and Coulomb's theory. These are classical Geotechnical Engineering methods. Horizontal earth pressure due to moisture and volume change in high plasticity soil is not determined by these classical methods. However, horizontal pressure on most of the cantilever retaining structures in Texas is determined by following the classical methods. In recent years, a number of consultants have considered the horizontal pressure due to swelling on cantilever retaining structures in Texas. However, the proposed horizontal pressure by consultants is 10-20 times higher than the classical horizontal pressure. This method of cantilever retaining structure design without knowing the real pressure and stress pattern increases the thickness of the wall, and raises the cost of construction. This study focuses on providing adequate patterns of lateral earth pressure distribution on cantilever retaining structures in expansive soil. These retaining wall structures are subject to swelling pressures which cause horizontal pressures that are larger than the classical especially near the ground surface. Beside the prediction of lateral earth pressure distribution, the relations between water content, volume change and suction change are determined. Based on the laboratory testing program conducted, Soil Water Characteristic Curves (SWCC) are determined for a site located at the intersection of I-35 and Walters Street in San Antonio, Texas. Additionally, relations between volume change with confining pressure curve, water content change with the change of confining pressure curve, water content change with change of matric suction and volume change with change of matric suction curves are generated based on laboratory tests. There are a number of available mass volume measurement methods that use mostly mercury or paraffin to obtain volume measurements. Although these methods are reported in the literature, they are not used in practice due to application limitations like safety, time, and cost. In order to overcome these limitations, a new method was developed to measure the volume of soil mass by using sand displacement. This new method is an inexpensive, safe, and simple way to measure mass volume by Ottawa sand.

In many situations, the upper layers of soil above the ground water table are in a state of unsaturated condition. Although unsaturated soils are found throughout the world, they are predominant in arid or semi-arid regions. In these areas, the soil water characteristic curve (SWCC) which relates the water content to the matric suction could be used as key tool to implement the mechanics of unsaturated soils into the designs of geotechnical structures such as dams, embankments, pavements, canals, and foundations. Several experimental techniques are available for determining the SWCC in a laboratory environment. However, these experimental techniques are expensive, time consuming typically requiring days or weeks, depending on the soil type, and demanding intricate testing equipment. Due to these reasons, there has been a growing interest to find other means for estimating SWCC and encourage the adoption of unsaturated soils mechanics in geotechnical engineering practice. Several methods exist to indirectly estimate the SWCC from basic soil properties. Some may include statistical estimation of the water content at selected matric suction values, correlation of soil properties with the fitting parameters of an analytical equation that represents the SWCC, estimation of the SWCC using a physics-based conceptual model, and artificial intelligence methods such as neural networks or genetic programming. However, many studies have shown that environmental effects such as temperature, soil structure, initial water content, void ratio, stress history, compaction method, etc. can also affect the SWCC. This means that the estimation SWCC from set of conditions may not reliably predict the SWCC in other conditions. Due to this reason, it is crucial for engineers involved with unsaturated soils to take into account all the factors that influence the SWCC. The two key objectives of the present thesis are the development of a method based on first principles, using the capillary rise theory, to predict the variation of the SWCC as a function of temperature, as well as developing a technique for the prediction of the fixed parameters of a well-known function representing the SWCC based on basic soil properties together with the moisture profile of a soil column subjected to a known temperature gradient. A rational approach using capillary rise theory and the effect of temperature on surface tension and liquid density is developed to study the relation between temperature and the parameters of the Fredlund and Xing (1994) equation. Several tests, using a Tempe cell submerged in a controlled temperature bath, were performed to determine the SWCC of two coarse-grained soils at different temperatures. A good comparison between the predicted SWCC at different temperatures using the proposed model and the measured values from the Tempe cell test results is achieved. Within the scope of this thesis, a separate testing program was undertaken to indirectly estimate the SWCC of the same two coarse-grained soils from the measurement of their steady state soil-moisture profile while subjected to a fixed temperature differences. The water potential equation in the liquid and vapor phases is used to analyses the steady state flow conditions in the unsaturated soil. A good comparison is obtained for the SWCC estimated using this technique with the SWCC measured used a Tempe cell submerged in a controlled temperature bath. The results of this study indicate that knowledge of the moisture content of a soil specimen under a constant thermal gradient and basic soil properties can be used to estimate the SWCC of the soil at the desired temperature.

abstract: The primary objective of this study is to understand the effect of soil cracking on foundation performance for expansive soil profiles. Two major effects of cracks were studied to assess the effect of cracks on foundation performance. First, the effect of cracks on soil volume change response was studied. Second, the effect of cracks on unsaturated flow properties and extent and degree of wetting were evaluated. Multiple oedometer-type pressure plate tests were conducted to evaluate the effect of cracks on soil properties commonly used in volume change (heave) analyses, such as swell pressure, soil water characteristic curve (SWCC), and swell potential. Additionally, the effect of cracks on saturated and unsaturated hydraulic conductivity was studied experimentally to assess the impact of cracks on properties critical to evaluation of extent and degree of wetting. Laboratory experiments were performed on both intact and cracked specimen so that the effect of cracks on behavior could be benchmarked against intact soil response. Based on laboratory observations, the SWCC of a cracked soil is bimodal. However, this bimodal behavior is only observed in the very low suction ranges. Because the bimodal nature of the SWCC of cracked clays is only distinguishable at extremely low suctions, the bimodal behavior is unlikely to have engineering significance when soils remain unsaturated. A "lumped mass" parameter approach has been studied as a practical approach for modeling of cracked soils for both fluid flow and volume change determination. Laboratory unsaturated flow experiments were simulated using a saturated-unsaturated flow finite element code, SVFlux, to back-analyze unsaturated hydraulic conductivity functions for the subject soils. These back-analyzed results were compared to the results from traditionally-applied analyses of the laboratory instantaneous profile tests on intact and cracked specimens. Based on this comparison, empirical adjustments were suggested for modeling "lumped mass" cracked soil behavior in numerical codes for fluid flow through cracked soils. Using the empirically adjusted flow parameters for unsaturated flow modeling, example analyses were performed for slab-on-grade problems to demonstrate the impact of cracks on degree and extent of wetting under unsaturated and saturated flow conditions for different surface flux boundary conditions. / Dissertation/Thesis / Ph.D. Civil and Environmental Engineering 2011

abstract: Unsaturated soil mechanics is becoming a part of geotechnical engineering practice, particularly in applications to moisture sensitive soils such as expansive and collapsible soils and in geoenvironmental applications. The soil water characteristic curve, which describes the amount of water in a soil versus soil suction, is perhaps the most important soil property function for application of unsaturated soil mechanics. The soil water characteristic curve has been used extensively for estimating unsaturated soil properties, and a number of fitting equations for development of soil water characteristic curves from laboratory data have been proposed by researchers. Although not always mentioned, the underlying assumption of soil water characteristic curve fitting equations is that the soil is sufficiently stiff so that there is no change in total volume of the soil while measuring the soil water characteristic curve in the laboratory, and researchers rarely take volume change of soils into account when generating or using the soil water characteristic curve. Further, there has been little attention to the applied net normal stress during laboratory soil water characteristic curve measurement, and often zero to only token net normal stress is applied. The applied net normal stress also affects the volume change of the specimen during soil suction change. When a soil changes volume in response to suction change, failure to consider the volume change of the soil leads to errors in the estimated air-entry value and the slope of the soil water characteristic curve between the air-entry value and the residual moisture state. Inaccuracies in the soil water characteristic curve may lead to inaccuracies in estimated soil property functions such as unsaturated hydraulic conductivity. A number of researchers have recently recognized the importance of considering soil volume change in soil water characteristic curves. The study of correct methods of soil water characteristic curve measurement and determination considering soil volume change, and impacts on the unsaturated hydraulic conductivity function was of the primary focus of this study. Emphasis was placed upon study of the effect of volume change consideration on soil water characteristic curves, for expansive clays and other high volume change soils. The research involved extensive literature review and laboratory soil water characteristic curve testing on expansive soils. The effect of the initial state of the specimen (i.e. slurry versus compacted) on soil water characteristic curves, with regard to volume change effects, and effect of net normal stress on volume change for determination of these curves, was studied for expansive clays. Hysteresis effects were included in laboratory measurements of soil water characteristic curves as both wetting and drying paths were used. Impacts of soil water characteristic curve volume change considerations on fluid flow computations and associated suction-change induced soil deformations were studied through numerical simulations. The study includes both coupled and uncoupled flow and stress-deformation analyses, demonstrating that the impact of volume change consideration on the soil water characteristic curve and the estimated unsaturated hydraulic conductivity function can be quite substantial for high volume change soils. / Dissertation/Thesis / Ph.D. Civil and Environmental Engineering 2013

In many situations, the upper layers of soil above the ground water table are in a state of unsaturated condition. Although unsaturated soils are found throughout the world, they are predominant in arid or semi-arid regions. In these areas, the soil water characteristic curve (SWCC) which relates the water content to the matric suction could be used as key tool to implement the mechanics of unsaturated soils into the designs of geotechnical structures such as dams, embankments, pavements, canals, and foundations. Several experimental techniques are available for determining the SWCC in a laboratory environment. However, these experimental techniques are expensive, time consuming typically requiring days or weeks, depending on the soil type, and demanding intricate testing equipment. Due to these reasons, there has been a growing interest to find other means for estimating SWCC and encourage the adoption of unsaturated soils mechanics in geotechnical engineering practice. Several methods exist to indirectly estimate the SWCC from basic soil properties. Some may include statistical estimation of the water content at selected matric suction values, correlation of soil properties with the fitting parameters of an analytical equation that represents the SWCC, estimation of the SWCC using a physics-based conceptual model, and artificial intelligence methods such as neural networks or genetic programming. However, many studies have shown that environmental effects such as temperature, soil structure, initial water content, void ratio, stress history, compaction method, etc. can also affect the SWCC. This means that the estimation SWCC from set of conditions may not reliably predict the SWCC in other conditions. Due to this reason, it is crucial for engineers involved with unsaturated soils to take into account all the factors that influence the SWCC. The two key objectives of the present thesis are the development of a method based on first principles, using the capillary rise theory, to predict the variation of the SWCC as a function of temperature, as well as developing a technique for the prediction of the fixed parameters of a well-known function representing the SWCC based on basic soil properties together with the moisture profile of a soil column subjected to a known temperature gradient. A rational approach using capillary rise theory and the effect of temperature on surface tension and liquid density is developed to study the relation between temperature and the parameters of the Fredlund and Xing (1994) equation. Several tests, using a Tempe cell submerged in a controlled temperature bath, were performed to determine the SWCC of two coarse-grained soils at different temperatures. A good comparison between the predicted SWCC at different temperatures using the proposed model and the measured values from the Tempe cell test results is achieved. Within the scope of this thesis, a separate testing program was undertaken to indirectly estimate the SWCC of the same two coarse-grained soils from the measurement of their steady state soil-moisture profile while subjected to a fixed temperature differences. The water potential equation in the liquid and vapor phases is used to analyses the steady state flow conditions in the unsaturated soil. A good comparison is obtained for the SWCC estimated using this technique with the SWCC measured used a Tempe cell submerged in a controlled temperature bath. The results of this study indicate that knowledge of the moisture content of a soil specimen under a constant thermal gradient and basic soil properties can be used to estimate the SWCC of the soil at the desired temperature.

京都大学 / 0048 / 新制・課程博士 / 博士(地球環境学) / 甲第22678号 / 地環博第199号 / 新制||地環||39(附属図書館) / 京都大学大学院地球環境学舎地球環境学専攻 / (主査)教授 勝見 武, 教授 三村 衛, 准教授 高井 敦史 / 学位規則第4条第1項該当 / Doctor of Global Environmental Studies / Kyoto University / DFAM

Reservoir release patterns are determined by a number of purposes, the most fundamental of which is to manage water resources for human use. Managing our water resources means not only controlling the water in reservoirs but also determining the optimum release rate taking into account factors such as reservoir stability, power generation, water supply for domestic, industrial, and agricultural uses, and the river ecosystem. However, riverbank stability has generally not been considered as a factor, even though release rates may have a significant effect on downstream riverbank stability. Riverbank retreat not only impacts land properties but also damages structures along the river such as roads, bridges and even buildings. Thus, reservoir releases need to also take into account the downstream riverbank stability and erosion issues. The study presented here investigates the riverbank stability and erosion at five study sites representing straight as well as inside and outside channel meander bends located on the lower Roanoke River near Scotland Neck, North Carolina. Extensive laboratory and field experiments were performed to define the hydraulic and geotechnical properties of the riverbank soils at each site. Specifically, soil water characteristic curves were determined using six different techniques and the results compared to existing mathematical models. Hydraulic conductivity was estimated using both laboratory and in situ tests. Due to the wide range of experimentally obtained values, the values determined by each of the methods was used for transient seepage modeling and the modeling results compared to the actual ground water table measured in the field. The results indicate that although the hydraulic conductivities determined by in situ tests were much larger than those typically reported for the soils by lab tests, numerical predictions of the ground water table using the in situ values provided a good fit for the measured ground water table elevation. Shear strengths of unsaturated soils were determined using multistage suction controlled direct shear tests. The test method was validated, and saturated and unsaturated shear strength parameters determined. These parameters, which were determined on the basis of results from both laboratory and field measurements, and the associated boundary conditions, which took into account representative flow rates and patterns including peaking, drawdown and step-down scenarios, were then utilized for transient seepage analyses and slope stability analyses performed using SLIDE, a software package developed by Rocscience. The analyses confirmed that the riverbanks are stable for all flow conditions, although the presence of lower permeability soils in some areas may create excess pore water pressures, especially during drawdown and step-down events, that result in the slope becoming unstable in those locations. These findings indicate that overall, the current reservoir release patterns do not cause adverse impacts on the downstream riverbanks, although a gradual drawdown after a prolonged high flow event during the wet season would reduce unfavorable conditions that threaten riverbank stability. / Ph. D.

Deep geological repository (DGR) for disposal of high-level radioactive waste (HLW) is designed to rely on successive superimposed barrier systems to isolate the waste from the biosphere. This multiple barrier system comprises the natural geological barrier provided by the repository host rock and its surrounding and an engineered barrier system (EBS). The EBS represents the synthetic, engineered materials placed within the natural barrier, comprising array of components such as waste form, waste canisters, buffer materials, backfill and seals. The buffer will enclose the waste canisters from all directions and act as a barrier between canisters and host rock of the repository. It is designed to stabilise the evolving thermo-hydro-mechanical-chemical stresses in the repository over a long period (nearly 1000 years) to retard radionuclides from reaching biosphere. Bentonite clay or bentonite-sand mix have been chosen as buffer materials in EBS design in various countries pursuing deep geological repository method. The bentonite buffer is the most important barrier among the other EBS components for a geological repository. The safety of repository depends to a large extent on proper functioning of buffer over a very long period of time during which it must remain physically, chemically and mineralogically stable. The long term stability of bentonite buffer depends on varying temperature and evolution of groundwater composition of host rocks in a complex way. The groundwater in the vicinity of deep crystalline rock is often characterized by high solute concentrations and the geotechnical engineering response of bentonite buffer could be affected by the dissolved salt concentration of the inflowing ground water. Also during the initial period, radiogenic heat produced in waste canisters would radiate into buffer and the heat generated would lead to drying and some shrinkage of bentonite buffer close to canister. This could alter the dry density, moisture content and in turn the hydro-mechanical properties of bentonite buffer in DGR conditions. India has variety of bentonite deposits in North-Western states of Rajasthan and Gujarat. Previous studies on Indian bentonites suggest that bentonite from Barmer district of Rajasthan (termed as Barmer-1 bentonite) is suitable to serve as buffer material in DGR conditions. Nuclear power agencies of several countries have identified suitable bentonites for use as buffer in DGR through laboratory experiments and large scale underground testing facilities. Physico-chemical, mineralogical and engineering properties of Kunigel VI, Kyungju, GMZ, FoCa clay, MX-80, FEBEX and Avonseal bentonites have been extensively studied by Japan, South Korea, China, Belgium, Sweden, Spain, Canada. It is hence essential to examine the suitability of Barmer-1 bentonite as potential buffer in DGR and compare its physico-chemical and hydromechanical properties with bentonite buffers identified by other countries. The significant factors that impact the long-term stability of bentonite buffer in DGR include variations in moisture content, dry density and pore water chemistry. With a view to address these issues, the hydromechanical response of 70 % Barmer-1 bentonite + 30 % river sand mix (termed bentonite enhanced sand, BES specimens) under varying moisture content, dry density and pore water salt concentration conditions have been examined. The broad scope of the work includes: 1) Characterise the physico-chemical and hydro-mechanical properties of Barmer-1 bentonite from Rajasthan, India and compare its properties with bentonite buffers reported in literature. 2) Examine the influence of variations in dissolved salt concentration (of infiltrating solution), dry density and moisture content of compacted BES specimens on their hydro-mechanical response; the hydro-mechanical properties include, swell pressure, soil water characteristic curve (SWCC), unsaturated hydraulic conductivity, moisture diffusivity and unconfined compression strength. Organization of thesis: After the first introductory chapter, a detailed review of literature is performed to highlight the need for detailed characterisation of physico-chemical and hydromechanical properties of Barmer-1 bentonite for its possible application in DGR in the Indian context. Further, existing literature on hydro-mechanical response of bentonite buffer to changes in physical (degree of saturation/moisture content, dry density) and physico-chemical (solute concentration in pore water) is reviewed to define the scope and objectives of the present thesis in Chapter 2. Chapter 3 presents a detailed experimental programme of the study. Chapter 4 characterises Barmer-1 bentonite for physico-chemical (cation exchange capacity, pore water salinity, exchangeable sodium percentage) and hydro-mechanical properties, such as, swell pressure, saturated permeability, soil water characteristic curve (SWCC) and unconfined compression strength. The properties of Barmer-1 bentonite are compared with bentonite buffers reported in literature and generalized equations for determining swell pressure and saturated permeability coefficient of bentonite buffers are arrived at. Chapter 5 describes a method to determine solute concentrations in the inter-lamellar and free-solutions of compacted BES (bentonite enhanced sand) specimens. The solute concentrations in micro and macro pore solutions are used to examine the role of osmotic flow on swell pressures developed by compacted BES specimens (dry density 1.50-2.00 Mg/m3) inundated with distilled water and NaCl solutions (1000-5000 mg/L). The number of hydration layers developed by the compacted BES specimens on inundation with salt solutions in constant volume swell pressure tests is controlled by cation hydration/osmotic flow. The cation hydration of specimens compacted to dry density of 2.00 Mg/m3 is mainly driven by matric suction prevailing in the clay microtructure as the number of hydration layers developed at wetting equilibrium are independent of the total dissolved solids (TDS) of the wetting solution. Consequently, the swell pressures of specimens compacted to 2.00 Mg/m3 were insensitive to the salt concentration of the inundating solution. The cation hydration of specimens compacted to dry density of 1.50 Mg/m3 is driven by both matric suction (prevailing in the clay micro-structure) and osmotic flow as the number of hydration layers developed at wetting equilibrium is sensitive to the TDS of the wetting solution. Expectedly, the swell pressures of specimens compacted to 1.50 Mg/m3 responded to changes in salt concentration of the inundating solution. The 1.75 Mg/m3 specimens show behaviour that is intermediate to the 1.50 and 2.00 Mg/m3 series specimens. Chapter 6 examines the influence of initial degree of saturation on swell pressures developed by the compacted BES specimens (dry density range: 1.40- 2.00 Mg/m3) on wetting with distilled water from micro-structural considerations. The micro-structure of the bentonite specimens are examined in the compacted and wetted states by performing X-ray diffraction measurements. The initial degree of saturation is varied by adding requisite amount of distilled water to the oven-dried BES mix and compacting the moist mixes to the desired density. The montmorillonite fraction in the BES specimens is responsible for moisture absorption during compaction and development of swell pressure in the constant volume oedometer tests. Consequently, it was considered reasonable to calculate degree of saturation based on EMDD (effective montmorillonite dry density) values and correlate the developed swell pressure values with degree of saturation of montmorillonite voids (Sr,MF). XRD measurements with compacted and wetted specimens demonstrated that if specimens of density series developed similar number of hydration layers on wetting under constant volume condition they exhibited similar swell pressures, as was the case for specimens belonging to 1.40 and 1.50 Mg/m3 series. With specimens belonging to 1.75 and 2.00 Mg/m3 series, greater number of hydration layers were developed by specimens that were less saturated initially (smaller initial Sr,MF) and consequently such specimens developed larger swell pressures. When specimens developed similar number of hydration layers in the wetted state, the compaction dry density determined the swell pressure. Chapter 7 examines the influence of salt concentration of infiltrating solution (sodium chloride concentration ranges from 1000- 5000 mg/L) on SWCC relations, unsaturated permeability and moisture diffusivity of compacted BES specimens. Analysis of the experimental and Brooks and Corey best fit plots revealed that infiltration of sodium chloride solutions had progressively lesser influence on the micro-structure and consequently on the SWCC relations with increase in dry density of the compacted specimens. The micro-structure and SWCC relations of specimens compacted to 1.50 Mg/m3 were most affected, specimens compacted to 1.75 Mg/m3 were less affected, while specimens compacted to 2.00 Mg/m3 were unaffected by infiltration of sodium chloride solutions. Variations in dry density of compacted bentonite impacts the pore space available for moisture flow, while, salinity of wetting fluid impacts the pore structure from associated physico-chemical changes in clay structure. Experimental results showed that the unsaturated permeability coefficient is insensitive to variations in dry density and solute concentration of wetting liquid, while, the effective hydraulic diffusivity is impacted by variations in these parameters. Chapter 8 summarises the major findings of the study.

Deep geological repository (DGR) for disposal of high-level radioactive waste (HLW) is designed to rely on successive superimposed barrier systems to isolate the waste from the biosphere. This multiple barrier system comprises the natural geological barrier provided by the repository host rock and its surrounding and an engineered barrier system (EBS). The EBS represents the synthetic, engineered materials placed within the natural barrier, comprising array of components such as waste form, waste canisters, buffer materials, backfill and seals. The buffer will enclose the waste canisters from all directions and act as a barrier between canisters and host rock of the repository. It is designed to stabilise the evolving thermo-hydro-mechanical-chemical stresses in the repository over a long period (nearly 1000 years) to retard radionuclides from reaching biosphere. Bentonite clay or bentonite-sand mix have been chosen as buffer materials in EBS design in various countries pursuing deep geological repository method. The bentonite buffer is the most important barrier among the other EBS components for a geological repository. The safety of repository depends to a large extent on proper functioning of buffer over a very long period of time during which it must remain physically, chemically and mineralogically stable. The long term stability of bentonite buffer depends on varying temperature and evolution of groundwater composition of host rocks in a complex way. The groundwater in the vicinity of deep crystalline rock is often characterized by high solute concentrations and the geotechnical engineering response of bentonite buffer could be affected by the dissolved salt concentration of the inflowing ground water. Also during the initial period, radiogenic heat produced in waste canisters would radiate into buffer and the heat generated would lead to drying and some shrinkage of bentonite buffer close to canister. This could alter the dry density, moisture content and in turn the hydro-mechanical properties of bentonite buffer in DGR conditions. India has variety of bentonite deposits in North-Western states of Rajasthan and Gujarat. Previous studies on Indian bentonites suggest that bentonite from Barmer district of Rajasthan (termed as Barmer-1 bentonite) is suitable to serve as buffer material in DGR conditions. Nuclear power agencies of several countries have identified suitable bentonites for use as buffer in DGR through laboratory experiments and large scale underground testing facilities. Physico-chemical, mineralogical and engineering properties of Kunigel VI, Kyungju, GMZ, FoCa clay, MX-80, FEBEX and Avonseal bentonites have been extensively studied by Japan, South Korea, China, Belgium, Sweden, Spain, Canada. It is hence essential to examine the suitability of Barmer-1 bentonite as potential buffer in DGR and compare its physico-chemical and hydromechanical properties with bentonite buffers identified by other countries. The significant factors that impact the long-term stability of bentonite buffer in DGR include variations in moisture content, dry density and pore water chemistry. With a view to address these issues, the hydromechanical response of 70 % Barmer-1 bentonite + 30 % river sand mix (termed bentonite enhanced sand, BES specimens) under varying moisture content, dry density and pore water salt concentration conditions have been examined. The broad scope of the work includes: 1) Characterise the physico-chemical and hydro-mechanical properties of Barmer-1 bentonite from Rajasthan, India and compare its properties with bentonite buffers reported in literature. 2) Examine the influence of variations in dissolved salt concentration (of infiltrating solution), dry density and moisture content of compacted BES specimens on their hydro-mechanical response; the hydro-mechanical properties include, swell pressure, soil water characteristic curve (SWCC), unsaturated hydraulic conductivity, moisture diffusivity and unconfined compression strength. Organization of thesis: After the first introductory chapter, a detailed review of literature is performed to highlight the need for detailed characterisation of physico-chemical and hydromechanical properties of Barmer-1 bentonite for its possible application in DGR in the Indian context. Further, existing literature on hydro-mechanical response of bentonite buffer to changes in physical (degree of saturation/moisture content, dry density) and physico-chemical (solute concentration in pore water) is reviewed to define the scope and objectives of the present thesis in Chapter 2. Chapter 3 presents a detailed experimental programme of the study. Chapter 4 characterises Barmer-1 bentonite for physico-chemical (cation exchange capacity, pore water salinity, exchangeable sodium percentage) and hydro-mechanical properties, such as, swell pressure, saturated permeability, soil water characteristic curve (SWCC) and unconfined compression strength. The properties of Barmer-1 bentonite are compared with bentonite buffers reported in literature and generalized equations for determining swell pressure and saturated permeability coefficient of bentonite buffers are arrived at. Chapter 5 describes a method to determine solute concentrations in the inter-lamellar and free-solutions of compacted BES (bentonite enhanced sand) specimens. The solute concentrations in micro and macro pore solutions are used to examine the role of osmotic flow on swell pressures developed by compacted BES specimens (dry density 1.50-2.00 Mg/m3) inundated with distilled water and NaCl solutions (1000-5000 mg/L). The number of hydration layers developed by the compacted BES specimens on inundation with salt solutions in constant volume swell pressure tests is controlled by cation hydration/osmotic flow. The cation hydration of specimens compacted to dry density of 2.00 Mg/m3 is mainly driven by matric suction prevailing in the clay microtructure as the number of hydration layers developed at wetting equilibrium are independent of the total dissolved solids (TDS) of the wetting solution. Consequently, the swell pressures of specimens compacted to 2.00 Mg/m3 were insensitive to the salt concentration of the inundating solution. The cation hydration of specimens compacted to dry density of 1.50 Mg/m3 is driven by both matric suction (prevailing in the clay micro-structure) and osmotic flow as the number of hydration layers developed at wetting equilibrium is sensitive to the TDS of the wetting solution. Expectedly, the swell pressures of specimens compacted to 1.50 Mg/m3 responded to changes in salt concentration of the inundating solution. The 1.75 Mg/m3 specimens show behaviour that is intermediate to the 1.50 and 2.00 Mg/m3 series specimens. Chapter 6 examines the influence of initial degree of saturation on swell pressures developed by the compacted BES specimens (dry density range: 1.40- 2.00 Mg/m3) on wetting with distilled water from micro-structural considerations. The micro-structure of the bentonite specimens are examined in the compacted and wetted states by performing X-ray diffraction measurements. The initial degree of saturation is varied by adding requisite amount of distilled water to the oven-dried BES mix and compacting the moist mixes to the desired density. The montmorillonite fraction in the BES specimens is responsible for moisture absorption during compaction and development of swell pressure in the constant volume oedometer tests. Consequently, it was considered reasonable to calculate degree of saturation based on EMDD (effective montmorillonite dry density) values and correlate the developed swell pressure values with degree of saturation of montmorillonite voids (Sr,MF). XRD measurements with compacted and wetted specimens demonstrated that if specimens of density series developed similar number of hydration layers on wetting under constant volume condition they exhibited similar swell pressures, as was the case for specimens belonging to 1.40 and 1.50 Mg/m3 series. With specimens belonging to 1.75 and 2.00 Mg/m3 series, greater number of hydration layers were developed by specimens that were less saturated initially (smaller initial Sr,MF) and consequently such specimens developed larger swell pressures. When specimens developed similar number of hydration layers in the wetted state, the compaction dry density determined the swell pressure. Chapter 7 examines the influence of salt concentration of infiltrating solution (sodium chloride concentration ranges from 1000- 5000 mg/L) on SWCC relations, unsaturated permeability and moisture diffusivity of compacted BES specimens. Analysis of the experimental and Brooks and Corey best fit plots revealed that infiltration of sodium chloride solutions had progressively lesser influence on the micro-structure and consequently on the SWCC relations with increase in dry density of the compacted specimens. The micro-structure and SWCC relations of specimens compacted to 1.50 Mg/m3 were most affected, specimens compacted to 1.75 Mg/m3 were less affected, while specimens compacted to 2.00 Mg/m3 were unaffected by infiltration of sodium chloride solutions. Variations in dry density of compacted bentonite impacts the pore space available for moisture flow, while, salinity of wetting fluid impacts the pore structure from associated physico-chemical changes in clay structure. Experimental results showed that the unsaturated permeability coefficient is insensitive to variations in dry density and solute concentration of wetting liquid, while, the effective hydraulic diffusivity is impacted by variations in these parameters. Chapter 8 summarises the major findings of the study.