The concomitant occurrence and reported discrepant behavior of uranium and arsenic in water bodies is a major health and environmental concern. This study combined batch and column experiments, hydrogeochemical simulations and XAFS spectroscopy to uncover the exchange mechanisms governing uranium fate between water and scrap metallic iron, minerals and Shewanella putrefaciens surfaces in the presence of arsenic. The main results suggest that both water chemistry and the solid phase composition influence uranium fate in the presence of arsenic. The importance of uranyl-arsenate species as a major control of uranium behavior in the presence of arsenic is shown. The toxicity of arsenic and the presence of nitrate are interpreted as limiting factors of the enzymatic reduction of both toxins. Besides, XANES fingerprinting and EXAFS modeling have confirmed precipitation/co-precipitation of uranyl-arsenates as a major mechanism controlling uranium behavior in the presence of arsenic.

科学研究費補助金 研究種目:基盤研究(B)(2) 課題番号:10555255 研究代表者:藤澤 敏治 研究期間:1998-2000年度

Scrap tyres provide numerous advantages from the viewpoint of civil engineering practices. Scrap tyres are light weight, have high vibration absorption, high elastic compressibility, high hydraulic conductivity, and temperature isolation potential. Scrap tyres have a thermal resistivity that is about seven times higher than soil; they produce low earth pressure and absorb vibrations. Many new techniques have emerged with time to utilize these advantageous characteristics for practical purposes in civil engineering. Though current reuse and recovery of scrap tyres has reduced the amount of landfills, but still there is a need for developing additional practices for the reuse of scrap tyres. Moreover, most of present practices do not use its vibration absorption capacity efficiently. To use the scrap tyres as individual material or mixed with soil in civil engineering applications, the systematic understanding of static and dynamic properties of sand-rubber mixtures (SRM) are of prime importance. In the present study an attempt has been made to characterize the SRM to use them as low-cost isolation material for low-to-medium rise buildings. Proposal of this isolation system using SRM is addressed in this study in four parts; in the first part, the estimation of shear strength and volumetric characteristics of the SRM were carried out. A total of seven different rubber sizes (six sizes of granulated rubber; 2 - 1 mm; 4.75 - 2 mm; 5.6 - 4.75 mm; 8 - 5.6 mm; 8 - 9.5 mm; 12.5 - 9.5 mm and one size of tyre chips; 20 - 12.5 mm) were considered for characterizing the SRM, and the rubber size which has higher shear strength characteristics is identified as optimum size for further studies. Second part deals with the effect of reinforcement on SRM with higher rubber content (50% and 75% rubber by volume). In the third part, dynamic properties of selected SRM combination with and without reinforcement were generated from experimental studies. In the last part, the numerical analysis was carried out using finite element program Strand7 to find out optimum dimension of proposed isolation scheme and reduction of spectral accelerations. In addition, the laboratory model tests were also carried out on square footing supported on unreinforced and reinforced SRM. The relative performances of reinforcement on settlement characteristics of SRM for 50% and 75% SRM have been compared with unreinforced SRM. Engineering behaviour of SRM has been studied by considering different rubber sizes and compositions by carrying out large scale direct shear test and Unconsolidated Undrained (UU) triaxial test. The shear strength characteristics such as peak shear stress, cohesion, friction angle, secant/elastic modulus, volumetric strain, failure and ultimate strength, ductility/brittleness index, and energy absorption capacity of sand and SRM were determined. The optimum percentage rubber content based on maximum shear strength and energy absorption capacity has been arrived. The granulated rubber size (12.5 - 9.5 mm) and percentage ratio, 30% by volume is found to be optimum size and content, which gives the maximum energy absorption capacity and lower brittleness index values compared to other rubber sizes. This chapter also describes the applicability of concept of Response Surface Methodology (RSM) to identify an approximate response surface model from experimental investigations on the engineering properties of sand and SRM. The experimental data were quantitatively analyzed by multiple regression models by correlating response variables with input variables in this study. To consume more tyres in SRM, rubber mix of 50 % and 75 % mixes are studied and these SRM results in lower shear strength and higher volume change when compared to 30 % SRM. To improve shear strength and reduce compressibility, geosynthetic reinforcement study has been carried out for 50% and 75% rubber by volume. Here geotextile, geogrid and geonets were used as reinforcement and number of layers and spacing between layers were varied. Finally type of reinforcement, number of layers and optimum spacing are arrived for the optimum rubber size of 12.5 - 9.5 mm for reinforced SRM. This study found that 4 layers with equal spacing of geotextile for 50 % SRM and geonet for 75 % SRM shows better strength when compared to other combinations. Further dynamic properties such as shear modulus and damping values at different strain level are estimated for red soil, sand, 30 % SRM and unreinforced and reinforced 50 % and 75 % SRM by carrying out resonant column tests and cyclic triaxial tests. The normalized shear modulus and damping ratio curves have been developed for these materials. The experimental results indicate that, shear modulus increases for 30% rubber by volume when compared to sand, thereafter the shear modulus values decreased with a further increase in rubber content in SRM. Whereas the damping ratio increases with increasing rubber content in SRM. For sand and SRM, with an increase in confining pressure shear modulus increases and damping ratio decreases. Based on the comprehensive set of experimental results, a modified hyperbolic model has been proposed. These properties are further used in the numerical analysis to find out the effectiveness of SRM as isolation material. Numerical dynamic analysis has been carried out on a 2-D finite element model of the soil-foundation-structure system. The building model has been generated considering the typical G+2 building resting on 20 m thick soil followed by rock depth and foundation is placed at 2.0 m below ground level. The beams and columns in the superstructure are modeled using 2-D frame elements. The soil column has been modeled using 4-noded 2-D plane strain plate elements. Considering the transmitting boundary condition, viscous dampers are implemented at the base of the computational soil domain in order to mitigate the reflective effects of waves. The Newmark family method (average acceleration method) has been used to calculate the displacement, velocity and acceleration vectors. Comprehensive numerical simulations have been carried out on the soil-foundation-structure system by varying rubber content in SRM (30%, 50% and 75% granulated rubber by volume), depth and thickness of SRM around footing and considering two input earthquake acceleration time history. It was found that earthquake vibrations are considerably reduced for SRM with higher rubber content. The optimum dimension of SRM giving maximum reduction in shaking level is found to be 3B below the footing and 0.75B (where B is the width of footing) on the side of the footing. Generally, the shaking levels at different floor can be reduced by 30-50%, with the use of 75% SRM. The results also indicated that the effectiveness of proposed system would depend on the characteristics of ground motion. To study the bearing capacity of square footing on SRM, laboratory model tests were carried out on square footing supported on unreinforced and reinforced SRM. The SRM combination which have been used for numerical studies are used in this model studies to know the bearing capacity and settlement characteristics. The optimum dimension of SRM around footing has been constructed. Model tests results show that, the bearing capacity decreases and settlement increases steadily with the increase in rubber content in SRM. Addition of reinforcement to SRM significantly improved the bearing capacity and reduced settlement characteristics. Reinforced SRM may be used as an effective low cost isolation scheme to reduce earthquake vibrations.

The aim of the diploma´s thesis is analysis of the scrap of the chosen process, using the tools of statistical process control and proposal of appropriate containment to reduce the scrap. The thesis describes all seven basic tools of quality and the greatest attention is aimed to Shewart's control charts. One chapter discusses three methods of problem solving in technical practice, while one of the described methods is used in the practical part of the thesis.

Today’s steelmaking industry is highly dependent on steel scrap supply. In order to reduce the greenhouse gas emissions (GHGs) deriving from the steel industry, it is of utmost importance to ensure that high percentages of steel scrap are recycled, reducing the reliance on the traditional ore-based steelmaking, which is significantly more environmentally impactful. To reach this goal, a better steel scrap quality has to be achieved during the sorting process. This thesis work aims to propose an optimized sorting process able to separate the stainless steel scrap from the carbon steel scrap, both obtained in the ferrous fraction after a magnetic separation. This improved sorting process would be able to sort different types of stainless steel scraps according to their alloying content, ensuring a better recovery of chromium, nickel and molybdenum for stainless steel production. This would lead to a considerable reduction of CO2 emissions for the stainless steel production. In addition, an economic benefit could be obtained from the optimized sorting process, obtaining steel scrap of higher quality and thus selling the scrap at higher price. In this thesis work, technological considerations are addressed in order to select the most suitable technology to reach significant improvements in alloy recoveries in steel scrap. An economic and environmental model is then used in order to showcase the possible economic and environmental impacts resulting from the implementation of the proposed optimized sorting process. The results obtained are encouraging, showing that this improved sorting would save high amounts of CO2 emissions deriving from raw materials extraction and production, and showing that good profits can be obtained from the selling of the different stainless steel scrap sorted. In the future, where an increased production of steel is expected, this process would be even more beneficial both for the economy and for the environment. / Dagens stål tillverkningsindustri är starkt beroende av utbudet av stålskrot. För att minska utsläppen av växthusgaser (GHG) från stålindustrin är det av yttersta vikt att säkerställa att höga andelar stålskrot återvinns, vilket minskar beroendet av den traditionella malmbaserade ståltillverkningen, som är betydligt mer miljöpåverkande. För att nå detta mål måste en bättre stålskrotskvalitet uppnås under sorteringsprocessen. Detta examensarbete syftar till att föreslå en optimerad sorteringsprocess som kan separera det rostfria stålskrotet från kolstålsskrotet, båda erhållna i järnfraktionen efter magnetisk separation. Denna förbättrade sorteringsprocess skulle kunna sortera olika typer av rostfritt stålskrot efter deras legeringsinnehåll, vilket säkerställer en bättre återvinning av krom, nickel och molybden för produktion av rostfritt stål. Detta skulle leda till en avsevärd minskning av CO2-utsläppen för produktionen av rostfritt stål. Dessutom skulle en ekonomisk fördel kunna erhållas från den optimerade sorteringsprocesser, att få stålskrot av högre kvalitet och därmed sälja skrotet till ett högre pris. I detta examensarbete behandlas tekniska överväganden för att välja den mest lämpliga tekniken för att uppnå betydande förbättringar av legeringsåtervinning av stålskrot.En ekonomisk och miljömässig modell används sedan för att visa upp de möjliga ekonomiska och miljömässiga effekterna av implementeringen av den föreslagna optimerade sorteringsprocessen. Resultaten som erhålls är uppmuntrande, och visar att denna förbättrade sortering skulle spara stora mängder CO2-utsläpp från råvaruutvinning och produktion, och visar att goda vinster kan erhållas från försäljning av olika sorterade rostfritt stålskrot. I framtiden, där en ökad produktion av stål förväntas, skulle denna process vara ännu mer fördelaktig både för ekonomin och för miljön.

English, Zulu and Northern Sotho summaries / This study aims to evaluate the Non-Ferrous Metals Crime Combating Committee's impact on combating copper cable theft in South Africa. Data was collected via in-depth interviews with awaiting trial detainees charged with copper cable theft at the Pollsmoor Correctional Centre in the Western Cape; members of the Mpumalanga and Gauteng Provincial Non-Ferrous Metals Crime Combating Committee; members of Business Against Crime South Africa; and investigators attached to Combined Private Investigations who investigate copper theft nationally. The in-depth interviews provided a comprehensive understanding of participant experiences relating to the impact of the Non-Ferrous Metals Crime Combating Committee on the combating of copper cable theft in South Africa. Moreover, the researcher performed a thorough literature study of the phenomenon locally and internationally. Research findings indicate shortcomings in the Non-Ferrous Metals Crime Combating Committee's effectiveness, limiting its impact on preventing copper cable theft. Based on these findings, the study recommends that the Non-Ferrous Metals Crime Combating Committee be replaced with a specialised South African Police Service Non-Ferrous Metals Theft Unit. Consequently, this study puts forward a set of recommendations proposing a systematic pro-active plan to address and minimise copper cable theft in South Africa. The proposed plan convincingly presents practical solutions to minimise copper cable theft and contributes to the current body of scholarship on copper cable theft in South Africa. / Inhloso yalolu cwaningo ukuhlola umthelela wohlelo lwe-Non-Ferrous Metals Crime Combating Committee mayelana nokuqedwa kokutshontshwa kwentambo yogesi (copper cable). Idatha iqoqwe ngokusebenzisa izinhlolovo ezijulile ezenziwa ngokusebenzisa iziboshwa eziboshelwe izintambo zikagesi ezisamele ukugwetshwa ejele lase Pollsmoor Correctional Centre ngaseNtshonalanga Kapa, amalunga eMpumalanga and Gauteng Provincial Non-Ferrous Metals Crime Combating Committee, amalunga eBusiness Against Crime South Africa kanye nabaphenyi abahambisana nophiko lweCombined Private Investigations oluphenya ukutshontshwa kwezintambo zikagesi ezweni lonke. Lezi zinhlolovo ezijulile zinikeze ulwazi olubanzi lwabadlalindima olumayelana nomthelela weNon-Ferrous Metals Crime Combating Committee mayelana nokuqedwa kokutshontshwa kwezintambo zikagesi. Ngaphezu kwalokho, umcwaningi wenze ucwaningo olunzulu lombhalo wobuciko mayelana nokutshontshwa kwezintambo zikagesi lapha ekhaya kanye nasemhlabeni wonke jikelele. Ulwazi olutholakele lukhombisa iziqi ezikhinyabeza ukusebenza kahle kweKomithi mayelana nokuvimbela umthelela walo mayelana nokutshontshwa kwezintambo zikagesi. Ngezizathu ezisuselwa phezu kwalolu lwazi, lolu cwaningo lubeka phambili isethi lezincomo ezinganceda iKomiti ekuqiniseni umthintela walo ngokuhlongoza uhlelo olugqugquzelayo lokunciphisa izinga lokutshontshwa kwezintambo zikagesi eNingizimu Afrika. Lolu hlelo oluhlongoziwe ngaphandle kokungabaza lwethula izixazululo ezenzeka empilweni yangempela ukunciphisa ukwetshiwa kwezintambo zikagesi kanti lokhu kunegalelo kwiziko lamanje futhi luqhubekisa iziko lamanje lwezifundo esimayelana nokwetshiwa kwezintambo zikagesi. / Maikemisetso a thutelo ye ke go lekola khuetso ya Komiti ya Twantsho ya Bosenyi bja Dimetale tse di Sego tsa Tshipi ka ga go lwantsha kutso ya megala ya koporo. Datha e kgobokeditswe ka mokgwa wa ditherisano tse di tseneletsego tseo di sepeditswego le mahodu a megala ya koporo ao a golegilwego ao a letetsego go sekiswa Senthareng ya Tshokollo ya Pollsmoor go la Kapa Bodikela, maloko a Diprofense tsa Mpumalanga le Gauteng a Komiti ya Twantsho ya Bosenyi bja Dimetale tse di sego tsa Tshipi, maloko a Dikgwebo tsa Kgahlanong le Bosenyi tsa Afrika Borwa le banyakisisi bao ba dirisanago le Dinyakisiso tsa Praebete tse Kopantswego tseo di nyakisisago kutso ya koporo kemong ya bosetshaba. Ditherisano tse di tseneletsego tse di file kwesiso ka botlalo ya maitemogelo a batseakarolo ye e sepelelanago le khuetso ya Komiti ya Twantsho ya Bosenyi bja Dimetale tse di sego tsa Tshipi ka ga go lwantsha kutso ya megala ya koporo. Gape, monyakisisi o dirile thutelo ya dingwalo ka botebo ya kutso ya megala ya koporo tikologong ya leagong le kemong ya boditshabatshaba. Dikhwetso tsa dinyakisiso di supa mafokodi ao a lebanego bokgoni bja Komiti tshitisong ya khuetso ya yona go kutso ya megala ya koporo. Go ya ka dikhwetso tse, thutelo ye e hlagisa sehlopha sa dikeletso tseo di ka thusago Komiti go tswetsa khuetso ya yona pele ka go sisinya leano la go itokisetsa seemo se ka diregago ka mokgwa wo o beakantswego go fokotsa kutso ya megala ya koporo ka Afrika Borwa. Leano leo le sisintswego le hlagisa ka mo go kgodisago ditharollo tse di ka phethagatswago go fokotsa kutso ya megala ya koporo ka gona la ba la seabe go le go tswetsa pele popego ya bjale ya borutegi ka ga kutso ya megala ya koporo. / Criminology and Security Science / Ph. D. (Criminal Justice)