Salinity is one of the fundamental ocean state variables. Variations of ocean salinity can be used to infer changes in the global water cycle and air-sea freshwater exchange. Many institutions have developed gridded Argo products of global coverage. However, the existing gridded salinity products have not yet been dedicatedly intercompare and assessed. In this study, the mean state, annual and interannual variabilities, and decadal changes of ocean salinity from five Argo-based gridded salinity products, available from UK Met Office, JAMSTEC, Scripps Institution of Oceanography, China Second Institute of Oceanography, and International Pacific Research Center, are examined and compared for their overlapping period of 2005-2015 within two depth intervals (0-700 m and 700-2000 m), as well as the sea surface. Though some global and regional features are relatively reproducible, obvious discrepancies are found particularly for the deeper layer. These discrepancies are not apparent on the 11-year climatological mean or the trend patterns, but are readily evident on temporal variations. For instance, the potentially undersampled current systems in the North Atlantic and Southern Ocean are one of the main reasons for the observed discrepancies. The gridded products from Scripps, JAMSTEC and Met Office show large deviation from the ensemble mean, particularly in regions like the Atlantic Ocean and the tropical Pacific. Large disagreements are found in the first and final years, which can lead to different estimates on decadal trends. This study can serve as a useful reference on how to utilize and improve the existing gridded salinity products.

It is evident that the sea ice cycle, from its formation to its melt, is governed by a complex interaction of the ocean, atmosphere and surrounding continents. Once sea water begins to freeze, physical, biological and chemical processes have implications on the evolution of the sea ice morphology [38]. The distinguishing factor between fresh and sea water ice is brine inclusions that get trapped within the ice pores during freezing. Salt inclusions within frozen ice influence the salinity as well as the physical properties of the sea ice [23]. These brine inclusions form part of a dynamic process within the ice characterized by the movement of brine and phase transition which are the foundation of many of its physical properties [23]. Brine removal subsequently begins to occur due to vertical gravity drainage into the underlying ocean water. This study introduces the application of a biphasic model based on the Theory of Porous Media (TPM) which considers a solid phase for the pore structure of the ice matrix as well as a liquid phase for the brine inclusions, respectively. This work explores the use of the TPM framework towards advancing the description and study of the various desalination mechanisms that are significant in aiding the salt flux into the Southern Ocean. This will foster understanding of brine rejection and how it is linked to the porous microstructure of Antarctic sea ice

Given its crucial role in atmospheric chemistry and its global warming potential, methane(CH4) deserves to be accurately budgeted. However, the recent renewed rise in atmosphericCH4 growth rates from 2007 on, after a few years of slow-down, attests that sources are notcompensated anymore by sinks, and calls for a better assessment of the processes contributingto the global CH4 budget. Among natural sources, oceanic emissions are still subject tomany uncertainties, due to the lack of sampling. This is particularly relevant in polar regions,where the role of sea ice on CH4 sea-air fluxes is largely unknown.In an effort to contribute to a better characterisation of CH4 dynamics in oceanic environments,we investigated very contrasted settings during a journey from temperate to polarregions and applied the concentration and stable isotope approach.We start by evaluating the performance of a commercially available in situ CH4 sensor(CONTROS HydroC® CH4 from Kongsberg Contros) in controlled and natural environments,with the hope of using it in the framework of our various field campaigns. Although thissensor has the potential to significantly increase the spatial and temporal resolution comparedto discrete sampling, the long response time prevents from using its measurements as absolutevalues in dynamic natural environments and calls for progress in the field of technologies forcontinuous in situ dissolved CH4 measurements. However, the sensor turns out to be veryuseful during cruises to observe relative changes in dissolved CH4 concentrations and guidethe discrete sampling episodes.Our journey starts in the Scheldt estuary, at the transition between land and sea. Stableisotope analyses reveal that the unusual enrichment of dissolved CH4 in 13C and D in theupper estuary could result from intense microbial oxidation or an unknown source upstream.In the lower part of the estuary, this enriched CH4 mixes with depleted CH4 produced bymethanogenesis in the sediments, before entering the North Sea.In the shallow coastal Wadden Sea, we highlight the dominant contribution of coastal areasto oceanic CH4 emissions. The progressive increase in dissolved CH4 concentrations coincidedwith a 2°C warming of seawater. Submarine groundwater discharge, controlled by thespring-neap tide cycle, and tidal pumping might also have contributed to temporal variationsin dissolved CH4 concentrations and isotopic composition.In the Barents Sea, sailing towards polar latitudes, we find that the fractional sea-ice coverdid not induce a significant change in CH4 concentration nor isotopic composition at theocean-atmosphere interface. Local CH4 seepages at the seafloor might be a relict of gashydrate dissociation after the retreat of the Scandinavian Ice Sheet from the continental shelfafter the Last Glacial Maximum.Trapped in landfast sea ice at Barrow (Arctic) and Cape Evans (Antarctic), we find thatthe processes governing CH4 dynamics in sea ice happen to be dependent on the season andthe regional setting, and can be unravelled thanks to stable isotope analyses. At Barrow,the range of delta-13C values points towards in-ice microbial oxidation of CH4 produced bymethanogenesis in the underlying sediments. At Cape Evans, the much higher delta-13C valuessuggest a hydrothermal origin of CH4 trapped in sea ice and/or aerobic production withinsea ice.The journey ends in the Ross Sea, where the high variability and supersaturation observed indissolved CH4 concentrations, as well as carbon isotope signatures typical of a thermogenicorigin, suggest that gas seepages on the continental shelf might be the main source of CH4 tothe water column.This unique dataset of CH4 concentration and stable isotope composition in seawater, in seaice and in the atmosphere, highlights the spatial and temporal variability of the processesgoverning CH4 dynamics across the various oceanic environments investigated. This thesisprovides an example of how the isotopic approach can be successfully applied to disentanglethe biogeochemical cycle of CH4. To better constrain oceanic emissions, we recommend theimplementation of an extensive monitoring network to measure dissolved CH4 continuously,particularly in shallow coastal regions, which contribute the most. Eventually, further studiesshould focus on the Southern Ocean, which has yet to reveal its secrets with regard to CH4dynamics. / Doctorat en Sciences / info:eu-repo/semantics/nonPublished

The Ross Sea, the southernmost sea on Earth, presents several iconic features of polar seas: sites of deep water formation, high summer primary production, floating ice shelves, the annual cycle of advance and retreat of sea ice, polynyas and katabatic winds. Furthermore, sea ice in McMurdo sound (western Ross Sea) is one of the most productive marine environments. However, sea ice inorganic carbon dynamics and related air-ice CO2 fluxes have never been documented in the Ross Sea.Two surveys were carried out in the western Ross Sea to bridge over a critical gap in the current understanding of sea ice: autumn and winter processes. The land-based YROSIAE project was a temporal survey from late winter to summer within landfast sea ice. The ship-based PIPERS project was an unique opportunity to study the early stages of sea ice formation (in polynyas) and more common consolidated pack ice in autumn. Based on these two consistent surveys, this work aims to (i) examine the bulk ice pCO2 dynamics in landfast sea ice from late winter to summer (ii) investigate the seasonal pattern (net source vs net sink) and diurnal pattern of air-ice CO2 fluxes (iii) analyse the depth-dependent physical and biogeochemical processes involved in inorganic carbon dynamics (iv) assess the precipitation of calcium carbonate in autumn and during a full bloom season.CO2 fluxes were measured using the chamber technique in autumn, late winter and spring, over open surface water, frazil ice patch, grey unconsolidated ice and consolidated first-year ice. These new autumn and winter data provide a first step to set up the budget of air-ice CO2 fluxes over the year and evaluate the large-scale influence of these fluxes on the annual uptake of CO2 by ice-covered oceans. Our results confirm that sea ice acts as a CO2 source for the atmosphere during ice growth, with enhanced fluxes reported at the early stages of sea ice formation, and shifts to a sink in spring. In late spring, diel pattern superimposed upon this seasonal pattern and was potentially assigned to either ice skin freeze-thaw cycles or diel changes in net community production. The snowpack plays a complex role in CO2 exchanges and can no longer be considered as an inert reservoir lying at the sea ice surface.The main features of the normalized DIC distribution (DIC35) through the ice column were: (i) a marked depletion at the surface from autumn to spring induced by the CO2 releases to the atmosphere (ii) bubble-driven gas enrichment below or within impermeable layers and (iii) an initial DIC35 enrichment in the bottom layer disappearing in spring when the seasonal peak in biomass occurs. At the bottom of landfast ice, in spring, a particular assemblage of microorganisms, the biofilm, led to a massive biomass build-up counterintuitively associated with nutrients accumulation. This biofilm formation may also promote calcium carbonate precipitation. However, in young pack ice or in cold landfast ice in early spring, limited calcium carbonate precipitation was reported. This suggests that calcium carbonate precipitation is not an ubiquitous process, especially in winter and autumn Antarctic sea ice. Comparison of calcium carbonate precipitation and pCO2 measurements advocates that the calcium carbonate precipitation is rather controlled by pCO2 than temperature. / Doctorat en Sciences / info:eu-repo/semantics/nonPublished

Seasonal sea ice is an important component of the global climate system. Sea ice influences exchange rates of heat, moisture, and gas between the ocean and atmosphere. Sea ice also plays critical roles in high latitude ecosystems and marine carbon cycling. Records of sea-ice extent and duration in the Arctic Ocean and its marginal seas through geologic time are valuable resources for better understanding the intricate relationships between sea ice and climate. IP25, a compound biosynthesized exclusively by diatoms associated with sea ice, has been used to construct qualitative records of sea ice from sediment cores in some areas of the Arctic. However, IP25 has not previously been applied to sediments from the Bering and Chukchi Seas. This area exhibits a wide range of interannual seasonal ice duration, which makes the region a promising natural laboratory for developing a quantitative core-top calibration between sea ice and the IP25 biomarker. A sample suite of surface sediments from the Bering and Chukchi Seas representing a range of latitudes (60-72o N) and durations of sea ice per year (0.5-11 months/year) are analyzed for this study. Gas chromatography/mass spectrometry analysis of sediment solvent extracts reveals the presence of IP25 in all samples and higher IP25 concentrations in the Chukchi Sea compared to in the Bering Sea. IP25 concentrations are compared with data for several sea surface conditions: mean annual sea-ice duration, sea surface temperature and salinity, and insolation data. An exponential relationship between TOC-normalized IP25 concentration and average annual duration of sea ice is identified. Negative exponential relationships are identified between IP25 and the other sea surface conditions: average annual and August sea surface temperature and average annual and August sea surface salinity. Exponential relationships are also identified between TOC-normalized IP25 concentrations and insolation, and insolation coupled with sea-ice concentration. IP25 in surface sediments is a viable quantitative proxy for sea-ice duration in the Bering and Chukchi Seas. However, sea surface conditions, such as temperature, salinity, sea-ice duration/concentration, and insolation are not independent variables. Therefore it is difficult to determine which of these environmental factors has/have the most influence on IP25 production. Further research and statistical analysis may serve to refine these relationships.

Polar amplification (PA), defined as the enhanced warming of the polar region relative to the global average, is a robust feature of historical observations and simulations of future climate. Because PA has yet to be realized in the Antarctic, I mainly focus on Arctic amplification (AA). Despite the far-reaching consequences of Arctic warming and sea ice loss, the causes of AA and their relative importance remain contested. This dissertation highlights some of the most important AA-producing mechanisms by analyzing the different timescales over which AA develops following an increase in CO₂ in climate model simulations. First, an Arctic and global average energy budget analysis is derived for a collection of Coupled Model Intercomparison Project version 5 (CMIP5) models subjected to an instantaneous quadrupling of CO₂ (4xCO₂). I quantify the relative contributions of various AA mechanisms using radiative kernels for 150 years after 4xCO₂ and compare mechanisms important at the beginning of the simulations against those when the models are in a quasi-equilibrium state. To focus on the fast timescales of AA, a new ensemble of Community Earth System Model (CESM) simulations was generated to observe the development of AA on ultrafast timescales (< 1 month) and to investigate the impact of the season in which CO₂ is increased. Finally, AA mechanisms and their seasonality are compared to those acting to produce Antarctic amplification (AnA). Motivated by this analysis, a new Python package called ClimKern was developed to simplify feedback calculations using radiative kernels and intercompare results based on different kernels. This work shows that AA occurs on incredibly fast timescales following CO₂ forcing, developing within three months in CMIP5 models and on the order of days in the CESM simulations in which CO₂ increases in January. The feedbacks important for AA immediately following CO₂ increase are not the same as those important decades afterward, demonstrating a strong time dependence of AA mechanism strength. Although sea ice loss and the associated surface albedo feedback play leading roles in the long-term development of AA, other mechanisms more clearly explain the rapid development of AA, namely, temperature feedbacks and the surface latent heat flux response. AnA also develops on ultrafast timescales, though on timescales greater than one month, AA is considerably greater than AnA. This results from a stronger SHU response and temperature feedbacks in the Arctic compared to the Antarctic. Lastly, I find that the magnitudes of feedbacks, especially the surface albedo feedback, exhibit considerable sensitivity to the kernel choice, indicating that using several different sets of kernels will make future feedback studies more robust.

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Previous research indicates that future reductions in Arctic sea ice cover (SIC) could alter storm tracks and precipitation patterns in western North America and negatively impact water resources in the American southwest. Other research suggests that multiple periods of increased precipitation and/or cooler temperatures in the American southwest during the Little Ice Age (LIA) were due to strong El Niño events; historical records also describe expanded Arctic SIC at this time. We use 16th-19th century Arctic SIC records from the ACSYS Historical Ice Chart Archive as a basis for expanding Arctic SIC from 1870 HadISST data to theoretical LIA extents. Then, in a suite of sensitivity studies, we investigate the relative influences of and interactions between El Niño-Southern Oscillation (ENSO) related sea surface temperature (SST) variation and varying Arctic SIC in controlling storm tracks, precipitation patterns, and overall climate conditions in the American southwest. We find that tropical Pacific SSTs greatly influence climate system response to variability in Arctic SIC, with ENSO-Neutral SSTs permitting the greatest response. Additionally, the degree of expansion and symmetry of Arctic SIC also influence precipitation regime response. These findings suggest that the climate response to future Arctic SIC retreat may not only be highly dependent on the spatial patterns and extent of SIC reductions, but also upon ENSO variability, such that El Nino events may reduce the potential climate impact of ice reductions as compared to Neutral or La Nina events. / Master of Science