M.Sc. (Geology) / Please refer to full text to view abstract

The Cape Supergroup (Sequence) comprises three groups, embracing a total of twenty-three formations, with a maximum combined thickness of approximately 8 km. The Table Mountain Group consists of medium-grained (occasionally fine- or coarse-grained), "clean", ultra-quartzose sandstone plus subordinate fine-grained, "dirty", subfeldspathic to feldspathic sandstone, mudrock, and rhythmitite. Average total thickness is about 3000 m. The Bokkeveld Group is composed of mudrock, rhythmitite and subordinate subfeldspathic to feldspathic sandstone (generally fine-grained and "dirty"), with a maximum total thickness of over 3000 m. The Witteberg Group comprises fine- to medium-grained ultra-quartzose sandstone, icaceous streaky rhythmitite, mudrock, and one thin diamictite unit; total thickness is about 1700 m. The strata belonging to the Cape Supergroup appear to have been largely deposited under marine conditions in environments ranging from outer shelf to beach. Deltaic deposits are,however, common in the upper part of the Bokkeveld Group and the Witteberg Group, while the main sandstone units in the upper third of the Table Mountain Group may have accumulated on a coastal alluvial plain. Deposition took place in a basin elongated in an east-west direction, with the palaeoslope inclined towards the south. Palaeocurrents were generally directed down the palaeoslope, but westerly 1 transport directions parallel to the palaeostrike and presumed shoreline are present in both the Table Mountain and Witteberg Groups. I The sedimentary rocks o~ the Karoo Sequence are subdivided into two groups (containing a total of eleven formations) and four ungrouped formations. Using the maximum thicknesses of the individual formations, a combined total thickness of about 12 km can be calculated. The sequence commences with the Dwyka Tillite, a 700-m-thick diamictite unit. The overlying Ecca Group consists of "varved" rhythmitite, dark, massive, fine- to very fine-grained ultra-lithofeldspathic sandstone and subordinate mudrock with a total thickness of 2000 - 3000 m. The Beaufort Group is composed of thick mudstone layers alternating with thinner fine-grained ultra-lithofeldspathic, lithofeldspathic and lithic sandstones, with the exception of the Katberg Formation which consists largely of sandstone. Fining-upward cycles are ubiquitous, while red mudstone is com~on, especially in the upper half of the group. A maximum thickness of about 6000 m was obtained in the East London area. The Molteno Formation Consists of up to 600 m of alternating fine- to coarse-grained sublithic sandstones (frequently pebbly) and grey mudstones, generally forming finingupward cycles. The Elliot Formation (up to 500 m thick) consists of red and grey mUdstones and subordinate fine-grained lithofeldspathic sandstones arranged in fining-upward cycles. The bulk of the Clarens Sandstone consists of very fine-grained massive (occasionally cross-bedded) sandstone, with a maximum thickness of 300 m. The Drakensberg Group, consisting of up to 1200 m of basalt with some pyroclastic intercalations near the base, caps the Karoo sedimentary succession. The deposition of the Dwyka Tillite by glacier action coincided with a major change from the generally shallow marine conditions which characterised the sedimentation of the Cape Supergroup (with the source area located on the craton to the north of the basin) to a deep linear trough receiving clastic sediments from a source area situated south and south-east of the basin. The Ecca Group,the lower half of which is characterised by the presence of "proximal" turbidite sandstones, records the gradual infilling of this basin, with deltaic conditions developing in the upper part of the group in the western half of the study area (i.e. in the Waterford Formation). The overlying strata were virtually all deposited under fluviatile conditions, the chief exceptions being a stratigraphic interval within the lower half of the Beaufort Group which appears to have formed in a large body of water, a~d the aeolian Clarens Sandstone. The fluviatile sediments were all deposite1 by rivers flowin~ towards the north and nort~-west, while the Clarens Sandstone was laid down by winds blowing from the west. The Ecca and Beaufort Group sandstones are characterised by a high rock fragment content with "felsit ic" gra ins being a prc;>minent constituent. This, together with the relative abundance of quartzfeldspar porphyry pebbles in the Katberg Sandstone unit (Beaufort Group) near East London, indicates that volcanic material probably formed a prominent part of the post-Dwyka Karoo provenance.

M.Sc. / Doornfontein Gold Mine is the westernmost member of a group of mines in the West Wits Line, extending from Westonaria to Carletonville. A study of the sedimentology and gold distribution of the Middelvlei Reef was carried out with the aim to acquire an understanding of the processes responsible for the economic concentration of gold ...

Thesis submitted in fulfillment of the requirements for the Degree of Doctor of Philosophy University of the Witwatersrand South Africa 2015 / A multidisciplinary sedimentological, stratigraphic, mineralogical and geochronological analysis of a small, fossil-bearing, Holocene hillslope deposit, flanking a mesa, has enabled a reconstruction of the palaeo-environmental history of the region. The hillslope deposit, located on the farm Heelbo in the eastern Free State Povince, South Africa, overlies Jurassic mudrock and sandstone of the Elliot Formation, Karoo Supergroup. The deposit is located on a steep (~10°) slope and covers an area of ~7 km2 in two separate sections. It extends ~475 m downslope and reaches a maximum thickness of at least 6-8 m towards the base. Mineralogy indicates the deposit is sourced from the mesa but its fine grain size and location on a steep slope position Heelbo outside the scope of traditionally described alluvial fans or colluvial deposits. The hillslope deposit is described as an alluvial slope based on the morphology of the deposit and the grain size distribution against the slope gradient. The deposit comprises fine-sand to silt- grain size, but is found on a steep (~10°) slope. The source of the sediment is shown to be the sediment of the mesa, rather than input from an aeolian source. The grains are described as sub-angular and poorly sorted which also suggests a local provenance for the sediment. Microscopic and XRF analysis confirm the derivation of the sediment from the Elliot Formation, with the lithic fragments derived from subarkoses to arkoses of the underlying bedrock of the Upper Elliot Formation (UEF) in the Karoo Supergroup. Secondary calcite was visible in only two of the thin sections, thus it is likely due to a diagenetic overprint that is constrained by depth from the surface or time and not to specific layers. The deposit is cut by several mature and continuous gully networks with V-shaped profiles in the proximal slope, and combined V- and U-shaped profiles in the medial and distal sections. Gully formation is linked to both the sodium adsorption ratio (SARs), and high soil clay content, which facilitates swelling and shrinking. The Heelbo deposit comprises two palaeosols (BT1 and BT2) and four sediment (B1, B2, RB and TS) horizons. Through luminescence dating, the ages were found to be approximately 6390 ± 740 years BP for the oldest Brown (B1) horizon and 250 ± 170 years BP for the Red Brown (RB) horizon. The radiocarbon ages of the sediment were inconclusive, but the 14C ages of the fossil bones were in agreement with the luminescence ages. The multiple palaeosol horizons identified suggest two cycles of deposition, pedogenesis and erosion of the alluvial succession. The palaeosols and the presence of calcareous nodules and rhizocretions, and smectite and mixed-layer clay minerals, together with the total absence of illite and kaolinite, suggest protracted, dry periods with intermittent short periods of high rainfall. This is a similar climate regime to what the region experiences currently. Main findings: The Heelbo alluvial slope comprises locally derived sediment, rather than an aeolian source. Heelbo suggests that the hillslope deposits classification system needs to be re-evaluated and opens opportunities for wider study of Pleistocene-Holocene hillslope deposits in central / northern South Africa. This study also contributes to climate change debates in the Holocene.

The Ecca Group of Karoo Supergroup is a sedimentary rock sequence that deposited between the Late Carboniferous (Dwyka Group) and the Late Permian-Middle Triassic (Beaufort Group). The Ecca Group investigated in this study is situated in the Eastern Cape Province of South Africa and it comprises mainly of shales, mudstones, siltstones and sandstones. The Ecca Group sequence contains considerable carbon content and suitable thickness to make it an ideal target for shale gas exploration. Previous studies put more emphasis on the geology and stratigraphy of the Ecca Group, this study revised the stratigraphy, and put new insight on the petrography, depositional processes, sedimentary facies, provenance, paleoweathering, tectonic setting, subsidence rates and history, electrical resistivity, source rock characteristics and diagenesis of the potentially feasible sandstone and mudrock reservoir rocks of the Ecca Group. Based on the lithological features, sedimentary structures and facies characteristics, the stratigraphy of the Prince Albert, Whitehill, Collingham and Fort Brown Formations of the Ecca Group is now subdivided into two informal members each, i.e. Lower Member and Upper Member. Furthermore, the Ripon Formation is now subdivided into three informal members. Each member has been asigned a lithological name. The grain size parameters show that most of the Ecca Group sandstones are very fine to fine grained, poorly to moderately well sorted, mostly near-symmetrical and mesokurtic in grain-size distribution. The linear discriminant function analysis is dominantly indicative of turbidity current deposits under deep marine environment for Prince Albert, Whitehill and Collingham Formations, shallow marine environment for Ripon Formation, while the Fort Brown Formation is lacustrine-deltaic deposits. Modal composition analysis and petrography studies revealed that the detrital components of the sandstones are dominated by monocrystalline quartz, feldspar and lithic fragments. The sandstones are compositionally and texturally immature and can be classified as feldspathic wacke and lithic wacke. The provenance analysis revealed plutonic and metamorphic terrains as the main source rocks with minor debris derived from recycled sedimentary rocks. The detrital modal compositions of these sandstones are related to back arc to island and continental margin of tectonic setting. Based on the detailed sedimentological analyses of outcrop and borehole data, fourteen lithofacies were identified and seven facies associations (FAs) were recognised. The facies associations are: FA 1: Shale and mudstones intercalated with siltstones, FA 2: Carbonaceous shale, mudstone with subordinate chert and sandstone, FA 3: Mudstones rhythmite with thin bedded mudstone and lenticular siltstone, FA 4: Greyish medium bedded sandstone intercalated with laminated mudstone, FA 5: Dark-grey medium to thick bedded mudstone and siltstone, FA 6: Thin to medium bedded sandstone alternated with thin bedded carbonaceous mudstone, and FA 7: Varved mudstone rhythmite intercalated with siltstone and minor sandstone. Sedimentological characteristics of the identified facies associations indicate four deposition environments, namely, deep marine basin, turbidite, shallow marine and lacustrine environments, which constitute a gradually regression sequence as a result of sea-level dropping and shallowing of the basin during the developmental processes. Geochemical analysis of the Ecca mudrocks and sandstones revealed that the rocks are of quartzose sedimentary provenance, suggesting that they were derived from a cratonic interior or recycled orogen. The petrography and geochemistry of the sandstones indicated that the source areas are composed of plutonic and metamorphic rocks with a minor component from sedimentary rocks. The geochemical diagrams and indices of weathering suggested that the granitic source rocks underwent moderate to high degree of chemical weathering. The tectonic setting discrimination diagrams support passive continental margin setting of the provenance.

Ph.D. (Aquatic Health) / Please refer to full text to view abstract

M.Sc. / Please refer to full text to view abstract

In the recent years, the shale gas discourse has become central to discussions about future energy supply in South Africa. In particular, the Permian black shales of the Lower Ecca Group formations in the Karoo Basin are considered potential source rocks for shale gas. The research presented in this thesis advances the understanding of the shale gas potential of mainly the Prince Albert, Whitehill and Tierberg/Collingham Formations. These shale sequences were sampled from eight deep boreholes spread across the main Karoo Basin and geochemically analysed at the GFZ - Helmholtz Centre Potsdam, Germany. Three key questions guided the study, these are: (i) what is the lithology of the sequence; (ii) where in the basin do the shale sequences attain maximum thickness at optimum depth i.e. beneath 1000-1500m; and (iii) and their shale characteristics. To evaluate these, borehole core logging, petrology and organic geochemistry were used extensively. Petrology involved the use of thin section, scanned electron and transmission electron microscopy for mineralogy as well as the identification of sedimentary features, organic matter and nano-scale porosity. These were coupled with standard organic geochemistry techniques such as Rock Eval. analysis, open pyrolysis gas chromatography and thermovaporisation to quantify the free gas, total organic carbon (TOC), present-day gas generative potential and kerogen type. The results show that the Whitehill Formation, away from the CFB and not intruded by dolerite, has the most potential for shale gas. Microscopic studies of this pyritic black shale reveal the occurrence of porous amorphous matter, indicating thermal maturity within the gas generation zone (i.e. > 1.1 percent Ro, 120ºC). The TOC content is consistently high within the Whitehill (exceeding industry requirement of 2 percent), attaining maximum of 7.3 percent. The highest yields of free and desorbed gas, especially methane, were emitted within this formation (S1 and nC1 peaks); mostly within its dolomitic units. In addition, dissolution porosity within dolomite units of the Whitehill Formation was identified as the predominant type of porosity. Thus, it is deduced that the dolomitic units of Whitehill Formation potentially contain the greatest volumes of free gas. HI values attain maximum of 25 mg HC/g TOC, whereas the OI values 26 mg CO2/g TOC. Such low HI and OI values are typically attributed to the dominance of Type IV kerogen, and consistent with overmaturity. Open pyrolysis (GC) show the main the chemical compound of the organic matter to be m-p-xylene, consistent with a mix of Type III, Type I/II and Type IV kerogen. Lithologically, the Whitehill Formation is composed of ~ 35 quartz, 13 percent feldspar, 26 percent illite and ~ 23 percent dolomite with variable amounts of pyrite. The dominance of quartz is directly proportional to the brittleness of the rock. Thus it can be deduced that the Whitehill Formation is relatively brittle and therefore fraccable. Burial trends indicate increasing depth (from ground level) to the top of the Whitehill Formation towards the south and south-eastern portion of the basin. It is in the southern region where thicknesses of this black shale exceeding 50m occur at depths more than 1500m; 1000m beneath fresh water aquifers. It therefore concluded that Whitehill Formation in the southern portion of Karoo Basin, but away from the thermo-tectonic overprint of the Cape Orogeny, is the most probable shale gas reservoir in South Africa.

The Triassic Molteno Formation is a clastic sedimentary sequence consisting of a series of cycles, dominated lithologically by coarse grained sandstones. Aspects of the petrography have been examined using the conventional petrographic microscope as well as the scanning electron microscope. Both solution and overgrowth features are present not only on the quartz grains but also on certain of the heavy mineral species present. Intrastratal solution of garnet would appear to be a significant feature in the Molteno Formation. Mineralogical examination of the laterally persistent Indwe Sandstone Member indicates no significant variation in heavy mineral content. Evidence from a study of zircon elongation ratios shows the presence of two distinct zircon populations indicating two provenance areas. X-ray diffraction and electron microprobe analysis has identified mineral species characteristic of granites, pegmatitic granite and metamorphic rocks, especially amphibolites. Palaeocurrent data indicates that this source area lay to the south-east; to the south the source area consisted mainly of the Cape Supergroup sediments. Analysis for Nb, Zr, Y, Sr, Rb, Zn, Mn, Ba, Cu, Ni, Co, Cr, V and Ti for 22 samples from the Molteno Formation, indicates, as expected for a highly arenaceous sequence, a substantial depletion in these trace elements. No consistent variation of trace element concentration occurs with height in the sequence so trace element content may not be used for purposes of stratigraphic correlation. There are indications of trace element variation with geographical position, no doubt a reflection of the contribution of 2 source areas of different compositions. Factor analysis of the interelement correlations has identified 3 factors which influence the trace element content of the Molteno Formation these are a "heavy mineral" factor, a "pH-Eh" factor and a "clay mineral" factor. These trace factors are ultimately an expression of the source rock composition, the prevailing climate and a combination of the two. Comparison with the more argillaceous overlying Elliot Formation, indicates that factors influencing geochemical variation in this sequence were far more complex than for the Molteno Formation

A Dissertation submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the Degree of Master of Science in Geology. Johannesburg 2013 / The Nyl River floodplain, located in the Limpopo Province, is one of the few active sedimentary basins that exist within the South African interior, providing a unique opportunity to study the effect of climate change on fluvial systems. Progradation of tributary fans into the Nyl/Mogalakwena River has raised the surface by 30 m and forced the course of the river westwards towards the Waterberg. Periods of progradation deposited thick sequences of coarse-grained sediments with sand- to gravel-sized mean grain sizes and coarsely-skewed populations in the distal reaches of the tributary fans. These periods were interspersed with periods of relative non-deposition, when active sedimentation on the fan ceased and shallow lakes (or vleis) developed in the trunk river, resulting in deposition of fine-grained, organic-rich, floodplain sediment layers with silt-sized mean grain sizes and finely-skewed distributions in the extreme outer reaches of the tributary fan. The alternating progradational sequences and non-deposition events produced interlayered floodplain and fan deposits in the furthest reaches of the tributary fans along the banks of the Nyl/Mogalakwena River. Incised river cuts within the Rooisloot tributary fan were dated using OSL and 14C techniques. For OSL samples, the SAR protocol was used to measure the equivalent dose and the burial dose was determined using the CAM and MAM. Emission counting methods, including TSAC, GM-beta counting and HRGS were used to determine the dose-rate. The OSL ages ranged from 99 years to 3884 years, constraining the sampled deposits within the late Holocene. Although the 14C ages agreed with this range, carbon contamination of the samples resulted in inverted and overestimated ages. Based on stratigraphic relationships the non-deposition events have been dated at approximately 750–800 years ago, 600 years ago, 475 years BP and 100–150 years ago and two major periods of aggradation at ~ 800–1000 years ago and ~ 500–700 years ago. The rate of aggradation (0.29 cm/year) calculated implies that the entire 30 m deposit could have been deposited in 9 000 years. However, an independent study by McCarthy et al. (2011) proved that tributary sedimentation began prior to 220 ka. Therefore, in order to deposit 30 m of sediment over 220 ka, either the mid – late Quaternary sedimentation rate was lower than the recent past (Late Holocene) or the system periodically undergoes extensive erosion in order to flush the accumulated sediment from the tributary fan system.