Neste trabalho aplica-se um método semi-empírico que utiliza uma técnica de otimização não linear para determinação das eficiências volumétrica e combinada do compressor hermético alternativo. Relações para estimar aproximadamente o fluxo de massa e a potência elétrica do compressor também são propostas. Todas estas características do compressor são calculadas através das relações físicas do modelo, empregadas nos cálculos de otimização. O método é implementado no software EES (Engineering Equation Solver) e baseia-se nos trabalhos de Jahing (1999) e Jahing et al. (2000). No presente método, cinco medições experimentais do fluxo de massa e potência elétrica são suficientes para determinar os parâmetros de ajuste do modelo. Este procedimento permite a geração de mapas de compressores satisfatórios sem a necessidade de um maior número de dados experimentais como no caso da norma ARI 540. Estes resultados obtidos com o modelo podem ser usados para o projeto de novos compressores. / In the present work is applied a semi-empirical method that uses a non-linear optimization technique for determination of the volumetric and combined efficiencies of hermetic reciprocating compressor. Relations to approximately estimate the mass flow and the electric power of the compressor are also proposed. All these compressor characteristics are calculated through physical model relations, used in the optimization calculations. The method is implemented in the EES (Engineering Equation Solver) software and is based on the works of Jahing (1999) and Jahing et al. (2000). In the method, four experimental measurements of the mass flow and electric power are enough to determine the fitting parameters of the model. This procedure allows the generation of satisfactory compressor maps without the necessity of a higher number of experimental data, as in the case of norm ARI 540 application. The results obtained with the model can be used for the design of new compressors.

In the past few decades, several researchers have studied the effects of ASR induced expansion in concrete. Several models have been proposed to model the effects of ASR in concrete. While most of these models focus on plain concrete, there is limited amount of research to model the influence of ASR expansion in reinforced concrete. Additionally, the existing models are complex and difficult to implement for practicing engineers. In this study the shortcomings with the existing models are addressed. A minimalist semi-empirical model is developed to represent the degradation of reinforced concrete due to ASR expansion. The model is validated using historical experimental data. Only two key parameters are needed to represent the expansive behavior, specifically, the maximum unreinforced concrete strain due to ASR expansion and the rise time. Mechanical properties of the reinforced concrete are also needed. From the predicted expansions, it is then shown that it is possible to model the number and spacing of cracks of a partly restrained reinforced concrete beam affected by ASR gels. The model is validated with recent experimental results on large scale reinforced concrete specimens. Predictions agree well with the observed number of cracks.

Neste trabalho aplica-se um método semi-empírico que utiliza uma técnica de otimização não linear para determinação das eficiências volumétrica e combinada do compressor hermético alternativo. Relações para estimar aproximadamente o fluxo de massa e a potência elétrica do compressor também são propostas. Todas estas características do compressor são calculadas através das relações físicas do modelo, empregadas nos cálculos de otimização. O método é implementado no software EES (Engineering Equation Solver) e baseia-se nos trabalhos de Jahing (1999) e Jahing et al. (2000). No presente método, cinco medições experimentais do fluxo de massa e potência elétrica são suficientes para determinar os parâmetros de ajuste do modelo. Este procedimento permite a geração de mapas de compressores satisfatórios sem a necessidade de um maior número de dados experimentais como no caso da norma ARI 540. Estes resultados obtidos com o modelo podem ser usados para o projeto de novos compressores. / In the present work is applied a semi-empirical method that uses a non-linear optimization technique for determination of the volumetric and combined efficiencies of hermetic reciprocating compressor. Relations to approximately estimate the mass flow and the electric power of the compressor are also proposed. All these compressor characteristics are calculated through physical model relations, used in the optimization calculations. The method is implemented in the EES (Engineering Equation Solver) software and is based on the works of Jahing (1999) and Jahing et al. (2000). In the method, four experimental measurements of the mass flow and electric power are enough to determine the fitting parameters of the model. This procedure allows the generation of satisfactory compressor maps without the necessity of a higher number of experimental data, as in the case of norm ARI 540 application. The results obtained with the model can be used for the design of new compressors.

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Orientador: Bernardo Laks / Tese (doutorado) - Universidade Estadual de Campinas, Instituto de Fisica Gleb Wataghin / Made available in DSpace on 2018-08-12T11:04:39Z (GMT). No. of bitstreams: 1 Marcal_Nei_D.pdf: 86929566 bytes, checksum: 04c8aa7c4176175d973ff0990de45bad (MD5) Previous issue date: 2008 / Resumo: Antes da década de 70, todos os materiais poliméricos eram considerados como isolantes e suas aplicações tecnológicas levavam em conta esta característica. De lá para cá, uma nova classe desses materiais, os polímeros conjugados, determinaram uma nova forma de aplicação de sistemas poliméricos baseados em suas propriedades elétricas e de ótica não-linear. Um maior estímulo surgiu a partir do experimento de Mac Diarmid, Heeger e Shirakawa [1] que, expondo o Poliacetileno a agentes oxidantes, demonstraram ser possível obter um sistema no estado metálico. Atualmente encontramos filmes de Poliacetileno com condutividade elétrica da ordem do cobre (105 S/cm). O Poliacetileno, quando no regime metálico, i.e., sob alta dopagem, apresenta algumas características de metal comum: alta condutividade elétrica (cresce 13 ordens de grandeza), susceptibilidade de Pauli finita e absorção no infravermelho. Já outras propriedades como a presença de modos vibracionais localizados no infravermelho e o não comportamento da condutividade com o inverso da temperatura evidenciam ser este um material não usual. Estes polímeros conjugados que apresentam uma extensiva delocalização de elétrons são considerados semicondutores orgânicos com gap de energia relativamente pequeno, da ordem de 1,5 a 2,0 eV. O comportamento semicondutor e as propriedades decorrentes entre os elétrons e a luz têm originado a construção de vários dispositivos semicondutores e optoeletrônicos [2, 7, 3]. Problemas técnicos como estabilidade ao ambiente, processabilidade e solubilidade destes materiais provocaram a produção de uma nova classe de materiais poliméricos que foi obtida por polimerização eletroquímica [57, 58, 59] cuja estrutura molecular trata-se de sistemas que introduzem grupos vinilas (V) entre anéis de tiofeno (T). Experimentos de voltametria cíclica, espectroscopia de absorção ótica e ressonância eletrônica de spin indicam que esses sistemas possuem potencial de ionização e gap de energia menores que o apresentado pelo Politiofeno. Estudos com oligômeros de tiofeno (T) com vinilenos (V) sugerem a possibilidade de escolha desse material como alternativa ao politiofeno. O objetivo deste trabalho foi investigar teoricamente a influência do grupo vinila (V) sobre as propriedades eletrônicas nestes polímeros, reproduzir os resultados experimentais e determinar qual proporção de vinilenos (V) e tiofenos (T) que provoque o menor gap de energia de forma que quando sobre dopagem possibilite uma transição isolante metal. Desta maneira, primeiramente, determinamos as geometrias dos sistemas de interesse utilizando métodos semi-empíricos. Posteriormente investigamos a estrutura eletrônica dos polímeros de tiofeno (T) com vinilenos (V), sendo que estes polímeros foram estudados para o caso neutro e na presença de defeitos conformacionais do tipo pólaron e bipólaron. Finalizamos o estudo investigando as absorções ópticas UV-vis dos sistemas de interesse através de cálculos semi-empíricos utilizando o código ZINDO/S. / Abstract: Before the 1970s, all polymeric materials were considered insulators; therefore their technological applications would take this trait into account. Since then, a new development on these materials, the conjugated polymers, determined new applications for polymeric systems based in their electrical and nonlinear optical properties. Greater interest arose from the experiment by Mac Diarmid, Heeger and Shirakawa [1] who, by using polyacetylene and oxidizing agents, showed that it is possible to obtain a system in the metallic state. Nowadays it is possible to find polyacetylene films with electrical conductivity of the order of copper (10-5 S/cm). Polyacetylene, when in its metallic behavior, i.e., under high dopage, presents some characteristics of real metal: high electrical conductivity (increased by 13 orders of magnitude), finite Pauli susceptibility and infrared absorption. On the other hand, other properties such as the presence of vibrational modes localized on infrared and the odd behavior of conductivity versus the inverse of temperature make clear that this is a unusual material. These conjugated polymers, presenting an extensive delocalization of electrons, are considered organic semiconductors with relatively low energy gap, of the order of 1.5 to 2.0 eV. The semiconductive behavior and the resulting properties of the interaction between electrons and light have been the drive for the manufacturing of several semiconductor and optoelectronic devices [2, 7, 3]. Technical problems, such as environmental stability, processability and solubility of these materials, gave rise to the production of a new kind of polymeric materials that were obtained by electrochemical polymerization [57, 58, 59], in which the molecular structure is a system that introduces vinylene groups (V) between tiophene rings (T). Experiments involving cyclic voltametry, optical absorption spectrometry and spin electronic ressonance indicate that these systems have ionization potential and energy gap smaller than those presented by Polythiophene. Studies with thiopene oligomers (T) with vinylene (V) suggest this material can be chosen as an alternative to Polytiophene. The goal of this work is to theoretically investigate the in uence of the vinyle group (V) on the electronic properties on these polymers, reproduce experimental results and determine what is the vinylene (V) to thiophene (T) rate that causes the smallest energy gap, such that doping will produce a insulator-metal transition. Therefore, we first determine the target systems' geometry using semi-empirical methods. Then we investigate the electronic structure of the tiophene (T) and vinylene (V) polymers both for neutral systems and in the presence of conformational defects of polaron and bipolaron types. We nalized the study by investigating the UV-vis optical absorption of the target systems through semi-empirical calculations using ZINDO/S code. / Doutorado / Estrutura Eletronica de Atomos e Moleculas ; Teoria / Doutor em Ciências

Concrete has proven to be, by far, one of the most reliable materials for the construction of critical infrastructure. However, despite its structural capacity, concrete members are susceptible to damage mechanisms that may decrease its performance and durability throughout its service life. One such mechanism is alkali-silica reaction (ASR), which takes place when unstable siliceous phases present in coarse or fine aggregates react with the alkali hydroxides from the concrete pore solution, generating a secondary product (i.e., ASR gel); this product swells upon moisture uptake from the surrounding environment, leading to cracking and expansion of the affected concrete. In severe cases of ASR-affected infrastructure, structural safety could become a problem, and thus requiring the demolition of affected members. It is, therefore, necessary to adopt effective protocols for the diagnosis and prognosis of aging infrastructure, to ensure its performance over time along with properly planning for rehabilitation strategies, whether required. This work presents a two-stage case study of the S.I.T.E. building at the University of Ottawa for the diagnosis and prognosis of ASR-affected members (i.e., columns) after nearly 20 years in service. The diagnosis phase was conducted with the aim of evaluating the cause and extent of distress and interpreting its impact on the performance of the affected structure. First, a visual inspection was conducted to evaluate potentially damaged members, in order to select the best location for core-drilling. Once ASR was confirmed through petrographic examination, specimens were evaluated through the multi-level assessment (i.e., coupling of microscopic and mechanical assessment). A range of damage was discovered among the examined columns (i.e., 0.03%, 0.05%, and 0.08% expansion). Moreover, evidence of developing freeze and thaw (FT) damage was discovered in columns with greater levels of expansion, raising future concerns regarding the durability and serviceability of members affected by this coupling of damage (i.e., ASR+FT). For the second stage of this project (i.e., prognosis), a novel ASR semi-empirical model was developed with the aim of predicting future ASR-induced expansion and damage in the S.I.T.E. building. The above model was developed and validated (using ASR exposure site data) through the coupling of existing chemo-mechanical macro-models, which were used to predict material behaviour on the structural scale, and novel mathematical relationships for the prediction of anisotropy in the columns. Moreover, the use of the multi-level assessment to predict the mechanical implications of predicted distress was found to enhance the model’s capacity for prognosis and demonstrated important potential for the accurate prediction of multi-level damage in the S.I.T.E. columns.

Lubricated friction issues are central to all hydraulic actuation systems undergoing motion and any in-depth understanding of the nature of lubricated friction will advance future component design. The classic friction models of hydraulic actuation systems under steady state conditions and their dependency on velocity and temperature have been studied extensively over the past years. A model which is commonly employed to represent the characteristics of friction is that of Stribeck in which the dependency of the friction force is based on velocity alone. However, experimentally, it has been found that lubricated friction is dependent on acceleration. Thus, the Stribeck model can be considered as a subset of a dynamic friction model in which acceleration is zero. Thus, it can be concluded that the Stribeck model is best applied to cases when the change rate of the velocities is very small. This thesis considers the dependency of lubricated friction on acceleration when pressure and temperature changes are relatively constant. As such, the basic hypothesis for this study was proposed as follows: “Lubricated friction in hydraulic actuation systems is not only a function of velocity, but is also a function of both velocity and acceleration”. In this thesis several terms are defined which facilitate the description under which friction models are developed. For example, the term non-steady state friction is used to account for the effect of acceleration on lubricated friction force while in motion. Further, the lubricated friction models are divided into two groups: steady state friction models and non-steady state friction models. Nonlinear friction modeling and measuring methods are reviewed in this dissertation. This review also includes nonlinear lubricated friction modeling in hydraulic actuation systems. A conclusion from this review was that limited research has been done in documenting and explicitly demonstrating the role of acceleration on lubricated friction. The research first introduced a methodology to experimentally measure friction as a function of acceleration and to demonstrate this dependency in the form of a three dimensional graph. A novel technique to experimentally obtain data for the lubricated friction model was introduced. This allowed the lubricated friction forces to be measured as a function of velocity in a continuous manner, but with acceleration being held constant as a family parameter. Two different valve controlled hydraulic actuation systems (VCHAS) were studied under a wide variety of accelerations at constant temperature and pressure. To enable repeatable data collection for the different friction conditions and to accommodate for the effect of hysteresis, a periodic parabolic displacement waveform was chosen which enabled the acceleration to be a family parameter. The second phase of the research introduced a method of representing the data (lubricated friction model) in a lookup table form. The relationship of lubricated friction (in this work, pressure differential, ΔP across the actuator) as a function of velocity and acceleration was presented in a unique semi-empirical 2D lookup table (2D LUT). Limitations of this experimental approach were identified, but the dependency on acceleration was clearly established. The last phase of the study implemented this 2D LUT model into a practical software model of an actuator and demonstrated its accuracy when compared to its experimental counterpart. The semi-empirical model (2D LUT) was experimentally verified by implementing the semi-empirical and Stribeck models into a real time simulation of an actuator and by comparing the experimental outputs against simulated outputs for a common sinusoidal input. A sinusoidal actuator displacement input was chosen to test the simulations as it was not used in the collection of the original data. The output of the simulation was compared to the experimental results and it was evident that for the range in which data could be collected in developing the model, the proposed 2D LUT model predicted an output that was superior to a model which used a standard Stribeck model. It was concluded that the semi-empirical model could be integrated into a simulation environment and predict outputs in a superior fashion when compared to the Stribeck friction model. Thus it was concluded that the stated hypothesis is consistent with the experimental evidence shown by all hydraulic actuators considered. Further, it was also observed that the traditional Stribeck form (steady state dynamic friction) does change with increasing acceleration to the point that the standard breakaway friction almost disappears. It is evident that the 2D LUT is a viable tool for modeling the non-steady state friction of hydraulic actuation systems. The semi-empirical 2D LUT model so developed is a more global representation of hydraulic actuator lubricated friction. In this research, only linear hydraulic actuators were considered; however, the novel nonlinear semi-empirical 2D LUT lubricated friction model can be applied to any actuator (linear and rotary) and provides a new way in which the dynamic friction can be viewed and modeled.