The Kribi-Campo sub-basin is the northernmost of a series of Aptian basins along the coast of West Africa. These extensional basins developed as a result of the northward progressive rifting of South America from West Africa, initiated c. 130 Ma ago. Post-rift sediments of the Kribi-Campo sub -basin contain several regional unconformities and changes in basin-fill architecture that record regional tectonic events. The tectono-stratigraphic evolution and plumbing system has been investigated using a high-quality 3D seismic reflection dataset acquired to image the deep-water Cretaceous-to-Present-day post-rift sediments. The study area is located c. 40 km offshore Cameroon in 600 to 2000 m present-day water depth, with full 3D seismic coverage of 1500 km2, extending down to 6.5 seconds Two-Way Travel time. In the late Cretaceous the basin developed as a result of tectonism related to movement of the Kribi Fracture Zone (KFZ), which reactivated in the late Albian and early Senonian. This led to inversion of the early syn-rift section overlying the KFZ to the southeast. Two main fault-sets - N30 and N120 - developed in the center and south of the basin. These normal faults propagated from the syn-rift sequences: the N120 faults die out in the early post-rift sequence (Albian time) whilst N30 faults tend to be associated with the development of a number of fault-related folds in the late Cretaceous post-rift sequence, and have a significant control on later deposition. The basin is filled by Upper Cretaceous to Recent sediments that onlap the margin. Seismic facies analysis and correlation to analogue sections suggest the fill is predominantly fine-grained sediments. The interval also contains discrete large scale channels and fans whose location and geometry were controlled by the KFZ and fault-related folds. These are interpreted to contain coarser clastics. Subsequently, during the Cenozoic, the basin experienced several tectonic events caused by reactivation of the KFZ. During the Cenozoic, deposition was characterized by Mass Transport Complexes (MTCs), polygonal faulting, channels, fans and fan-lobes, and aggradational gullies. The main sediment feeder systems were, at various times, from the east, southeast and northeast. The plumbing system shows the effects of an interplay of stratigraphic and structural elements that control fluid flow in the subsurface. Evidence for effective fluid migration includes the occurrence of widespread gas-hydrate-related Bottom Simulating Reflections (BSRs) 104 - 250 m below the seabed (covering an area of c. 350 km2, in water depths of 940 m - 1750 m), pipes and pockmarks. Focused fluid flow pathways have been mapped and observed to root from two fan-lobe systems in the Mid-Miocene and Pliocene stratigraphic intervals. They terminate near, or on, the modern seafloor. It is interpreted that overpressure occurred following hydrocarbon generation, either sourced from biogenic degradation of shallow organic rich mudstone, or from effective migration from a thermally mature source rock at depth. This latter supports the possibility also of hydrocarbon charged reservoirs at depth. Theoretical thermal and pressure conditions for gas hydrate stability provide an opportunity to estimate the shallow geothermal gradient. Variations in the BSR indicate an active plumbing system and local thermal gradient anomalies are detected within gullies and along vertically stacked channels or pipes. The shallow subsurface thermal gradient is calculated to be 0.052 oC m-1. With future drilling planned in the basin, this study also documents potential drilling hazards in the form of shallow gas and possible remobilised sands linked with interconnected and steeply dipping sand bodies.

Carbonate diagenesis encapsulates a wide range of water rock interactions that can occur within many environments and act to modify rock properties such as porosity, permeability, and mineralogical composition. These rock modification processes occur by the supply of reactant-laden fluids to areas where geochemical reactions are thermodynamically and kinetically favoured. As such, understanding the development of diagenesis requires an understanding of both palaeohydrology and geochemistry, both of which have their own complexities. However, within geological systems, both the conditions that control fluid migration and the distribution of thermodynamic conditions can change through time in response to external factors. Furthermore, they are often coupled, with rock modification exercising a control on fluid flow by altering the permeability of sediments. Numerical methods allow the coupling of multiple complex processes within a single mathematical formulation. As such, they are well suited to investigations into carbonate diagenesis, where multiple component subsystems interact. This thesis details the application of four separate types of numerical forward modelling to investigations of diagenesis within two Carboniferous carbonate platforms, the Derbyshire Platform (Northern England) and the Tengiz Platform (Western Kazakhstan). Investigations of Derbyshire Platform diagenesis are primarily concerned with explaining the presence of Pb-mineralisation and dolomitisation observed within the Dinantian carbonate succession. A coupled palaeohydrology and basin-development simulation and a series of geochemical simulations was used to investigate the potential for these products to form as a result of basin-derived fluids being driven into the platform by compaction. The results of these models suggest that this mechanism is appropriate for explaining Pb-mineralisation, but dolomitisation requires Mg concentrations within the basin-derived fluids that cannot be attained. Geothermal convection of seawater was thus proposed as an alternative hypothesis to explain the development of dolomitisation. This was tested using an advanced reactive transport model, capable of considering both platform growth and dolomitisation. The results of this suggests that significant dolomitisation may have occurred earlier on in the life of the Derbyshire Platform than has previously been recognised. An updated framework for the development of diagenesis in the Derbyshire Platform is proposed to incorporate these new insights. The Tengiz platform forms an important carbonate oil reservoir at the northeastern shore of the Caspian Sea. The effective exploitation of any reservoir lies in an understanding of its internal distributions of porosity and permeability. Within carbonate systems, this is critically controlled by the distribution of diagenetic products. A model of carbonate sedimentation and meteoric diagenesis is used to produce a framework of early diagenesis within a sequence stratigraphic context. The studies mentioned above provide a broad overview of the capabilities and applicability of forward numerical models to two data-limited systems. They reveal the potential for these methods to guide the ongoing assessment and development of our understanding of diagenetic systems and also help identify key questions for the progression of our understanding in the future.

>Magister Scientiae - MSc / The study area for this thesis focuses on the central northern part of the Bredasdorp Basin of southern offshore South Africa, where the depositional environments of wells E-M1, E-M3 and E-AB1 were inferred through electro sequence analysis and sequence stratigraphy analysis of the corresponding seismic line (E82-005). For that, the Petroleum Agency of South Africa (PASA) allowed access to the digital data which were loaded onto softwares such as PETREL and Kingdom SMT for interpretational purposes. The lithologies and sedimentary environments were inferred based on the shape of the gamma ray logs and reported core descriptions. The sequence stratigraphy of the basin comprises three main tectonic phases: Synrift phase, Transitional phase and Drift phase. Syn-rift phase, which began in the Middle Jurassic during a period of regional tectonism, consists of interbedded red claystones and discrete pebbly sandstone beds deposited in a non-marine setting. The syn-rift 1 succession is truncated by the regional Horizon ‘C’ (1At1 unconformity). The transitional phase was influenced by tectonic events, eustatic sea-level changes and thermal subsidence and characterized by repeated episodes of progradation and aggradation between 121Ma to 103Ma, from the top of the Horizon ‘C’ (1At1 unconformity) to the base of the 14At1 unconformity. Finally the drift phase was driven by thermal subsidence and marked by the Middle Albian14At1 unconformity which is associated with deep water submarine fan sandstones. During the Turonian (15At1 unconformity), highstand led to the deposition of thin organic-rich shales. In the thesis, it is concluded that the depositional environment is shallow marine, ranging from prograding marine shelf, a transgressive marine shelf and a prograding shelf edge delta environment.

The Middle Cambrian Spence Shale Member contains meter-scale, shallowing-up cycles (parasequences) and record approximately 360 ky of deposition. These meter-scale cycles are nested within transgressive systems tracts (TST) and highstand systems tracts (HST) which reflect different stages of a lower-order, higher-magnitude sea-level excursion. Fossil assemblages are located in stratigraphic positions within the Spence Shale Member that can be predicted on the basis of sequence architecture. The cycle architecture, taphonomy, and geochemistry of the Spence parasequences confirm synthetic sections and theoretical models of meter-scale cycles developed in other studies. Delineation of meterscale cycles, based on taphonomic and sedimentologic criteria, allows high-resolution (100-500 ky) correlation. This study also documented the Cambrian existence of the Tooele and Arco Arches and aided in further understanding paleoenvironmental conditions within the Spence Shale Member.

The nose of the Eastern shelf of the Midland Basin is a prominent structural and depositional feature present in Glasscock, Sterling, and Howard counties, Texas. This feature has been expressed in many regional maps and mentioned in some literature, but has not otherwise been studied significantly. This study looks at the viability of using an acoustic impedance seismic inversion to interpret the 2nd and 3rd order sequence stratigraphy of the southern portion of the nose of the Eastern shelf along with its shelf to basin transition in Glasscock, Sterling, and Reagan counties during the Wolfcampian (Asselian-Sakmarian) time (Early Permian). The Wolfcamp Formation (Wolfcampian-Leonardian) was subdivided into six units based on regionally mapped shale markers that correlate with 3rd order sequence boundaries. These horizons were mapped throughout the study area utilizing 3D seismic data and well logs. Analysis of seismic amplitude and inversion (acoustic impedance) volumes, along with well logs were then used to create a 2nd and 3rd order sequence stratigraphic framework in the study area. Six 3rd order sequences and two 2nd order sequences were identified in the study area during the Wolfcampian. From this framework a 2nd order sea-level curve was developed. The oldest Wolfcampian 3rd order sequence is marked by sediment bypass of the shelf and slope into the basin during a 3rd order sea level fall. Shelfal deposition resumed during subsequent sequences as sea-level rose and carbonate production resumed. Carbonate production increased during sequences four through six as part of a 2nd order sea-level highstand. During this highstand the nose of the Eastern shelf grew vertically increasing the gradient of the slope from less than 1° to 3.5°. The end of Wolfcampian deposition is marked by a large number of gravity flows into the basin resulting from subaerial exposure and erosion after a second order sea-level fall.

The Jurassic Twist Gulch Formation of central Utah was deposited in the active Arapien sub-basin of the Western Cordillera foreland trough. We herein demonstrate the utility of integrating facies analysis, terrestrial sequence stratigraphy, and detrital zircon (U-Pb) ages to improve paleogeographic reconstructions as well as identify regional unconformities, locate fluvial depocenters, and infer sediment supply/accommodation space ratios. Strata of the Twist Gulch Formation in Pigeon Creek Canyon (PCC) near Levan, Utah consists primarily of alluvial deposits, while in Salina Canyon (SC) the Twist Gulch Formation is comprised of a mix of alluvial and marginal marine deposits associated with the Jurassic Western Interior Seaway. Within the PCC section, a change from high accommodation system (HAS) mudstones to low accommodation system (LAS) multi-storied channel sandstones and back to HAS deposits exists. This same pattern exists in the SC section but culminates with marine deposits. Terrestrial sequence stratigraphy predicts that the change from HAS to LAS deposits indicate a sequence boundary and thus an unconformity. The J-3 unconformity, a regional unconformity on the Colorado Plateau, separates strata of Callovian age from Oxfordian age in Utah. Using detrital zircons (U-Pb), the first radiometric ages were obtained for the Twist Gulch Formation. The J-3 unconformity is bracketed by detrital zircon (U-Pb) ages and stratigraphic relationships in the study area. These new ages suggest that the Twist Gulch Formation is time-equivalent to the Entrada Sandstone, Curtis, and Summerville formations of the Colorado Plateau. Further, integrating facies analysis, terrestrial sequence stratigraphy, and detrital zircon (U-Pb) ages predicts that the PCC section was an active depocenter during the early Oxfordian in which sedimentation outpaced accommodation space, prograding the Oxfordian shoreline of the Jurassic Western Interior Seaway shoreline eastward. This integration process also predicts that subsurface sandstones positioned above the J-3 unconformity on the west side of the Wasatch Plateau are of a different age, depositional system, and systems tract from subsurface sandstones on the east side of the Wasatch Plateau.

Lower Pennsylvanian, coal-bearing, siliciclastic strata of the central Appalachian foreland basin were deposited in continental to marginal marine environments influenced by high-amplitude relative sea level fluctuations. Sediment was derived from both the low-grade metamorphic terrain of the emergent Alleghanian orogen towards the southeast, and the cratonic Archean Superior Province in the north. Immature sediments derived proximally from the Alleghanian orogen, including sublithic sandstone bodies, were deposited as a southeasterly-thickening clastic wedge within a southeast-northwest oriented transverse drainage system. Texturally and mineralogically mature quartzarenites were deposited in strike-parallel elongate belts along the western periphery of the basin. These mature quartzarenites are braided fluvial in origin and were deposited within northeast-southwest oriented axial drainage head-watered in a northerly cratonic source area. The contemporaneity of transverse and axial fluvial systems defines a trunk--tributary drainage system operating in the central Appalachian foreland basin during the early Pennsylvanian. Detailed analysis of core, gamma ray logs, and cross-sections reveals a hierarchy of bounding discontinuities and architectural elements within the study interval. Discontinuities are both erosional and depositional (condensed) surfaces of interpreted 3rd-order (~ 2.5 Ma) and 4th-order (~ 400 k.y.) origin. Architectural elements within 4th-order sequences consist of upward-fining lowstand and transgressive incised valley fill, alluvial, and estuarine deposits, and upward-coarsening highstand deltaic deposits that are separated by condensed sections. 4th-order sequences are stacked into 3rd-order composite sequences. Sequence stratigraphic architecture in the central Appalachian basin can therefore be attributed to 4th-order Milankovitch orbital eccentricity cycles superimposed on 3rd-order orogenically driven subsidence, or more likely, 4th-order Milankovitch orbital eccentricity cycles superimposed on a lower-frequency eccentricity cycle. The widespread nature of both 3rd- and 4th-order marine flooding zones and sequence boundaries enables both genetic and depositional sequence stratigraphy to be applied to terrigenous to marginal marine coal-bearing strata of the central Appalachian basin. Regionally extensive coal beds occur in close association with both 4th-order condensed sections as well as within highstand deltaic deposits. Formation of coal beds in the central Appalachian basin of southwest Virginia is therefore attributed to both an allocyclic glacio-eustatic mechanism, associated with Milankovitch orbital eccentricity cycles, and autocyclic deltaic processes related to channel avulsion and delta lobe switching. / Master of Science

Lower Pennsylvanian siliciclastic sedimentary rocks of the central Appalachian Basin consist predominantly of nonmarine, coal-bearing facies that developed within a fluvio-estuarine, trunk-tributary drainage system in a foreland-basin setting. Sheet-like, sandstone-mudstone bodies (up to 100 km wide and 70 m thick) developed in an axial trunk drainage system, whereas channel-like, sandstone-mudstone bodies (up to several km wide and 30 m thick) developed in tributaries oriented transverse to the thrust front. The origin of these strata has been debated largely because the paleogeomorphology and facies architecture of the New River Formation (NRF) are poorly understood. A sequence stratigraphic framework for the NRF, based on a combination of outcrop mapping and subsurface well-log analysis, reveals: 1) regionally significant erosional surfaces along the bases of sheet-like and channel-like sandstone bodies (sequence-boundaries), 2) fluvial- to estuarine-facies transitions (marine flooding surfaces), 3) erosionally based, framework-supported, quartz-pebble conglomerates (ravinement beds), and 4) regionally traceable, coarsening-upward intervals of strata (highstand deposits above maximum flooding surfaces). Using these criteria, both 3rd- and 4th-order sequences have been identified. An idealized 4th-order sequence consists of deeply incised, fluvial channel sandstone separated from overlying tidally modified estuarine sandstone and mudrock by a ravinement bed, and capped by coarsening-upward bayhead delta facies. The relative thickness of fluvial versus estuarine facies within a fourth-order sequence reflects a balance between accommodation and sediment supply within a 3rd-order relative sea level cycle. Lowermost 4th-order sequences are dominated by fluvial facies, whereas the uppermost sequences are dominated by estuarine facies. Therefore, 3rd-order sequence boundaries are interpreted to lie at the bases of the lowermost, fluvial-dominated fourth-order sequences. Coarsening-upward intervals that record the maximum landward extent of marine conditions are interpreted as highstand deposits of the composite third order sequence. Thus, the NRF consists of thick, superimposed fluvial sandstone of the lowstand systems tracts and anomalously thin transgressive and highstand systems tracts. Asymmetrical subsidence within the foreland basin resulted in westward amalgamation of multiple, 4th-order, fluvial valley-fill successions and sequence boundaries. The Early Pennsylvanian time period was characterized by global icehouse conditions and the tectonic assembly of Pangea. These events affected the geometry of the overall stratigraphic package, which can be attributed to high-magnitude, high-frequency, glacioeustatic sea-level fluctuations superimposed on asymmetric tectonic subsidence. / Master of Science

Carbon dioxide sequestration in coal-bed methane fields has potential to add significant recoverable reserves and extend the production life of coal-bed methane fields while at the same time providing a geologic sink for atmospheric greenhouse gases. The ability to relate the thickness, extent, and quality of coal seams to their relative position within a sequence is fundamental in determining the sequestration potential of a geologic formation. This thesis documents the carbon dioxide storage capacity and enhanced coalbed methane recovery of lower Pennsylvanian coal-bearing siliciclastic strata within the Bradshaw CBM field, southern McDowell County, WV. Analysis of outcrop, gamma ray and density logs, and eight cross-sections within the study area reveals a hierarchy of bounding discontinuities and architectural elements. Discontinuities are both erosional (unconformable) and depositional (condensed) surfaces of 3rd-order (~2.5 Ma) and 4th-order (~400 k.y.) origin. Architectural elements bound by 4th-order erosional discontinuities consist of upward-fining lowstand and transgressive incised valley fill, alluvial, and estuarine deposits, and upward-coarsening highstand deltaic deposits, representing 4th-order sequences. 4th-order sequences are stacked into composite 3rd-order sequences. Sequence development is attributed to higher frequency (~400 k.y.) 4th-order Milankovitch orbital eccentricity cycles superimposed on lower frequence (~2.5 Ma) orbital eccentricity cycles. Coal seams occur in the transgressive and highstand systems tracts, associated with 4th-order flooding surfaces and high-frequency deltaic autocycles, respectively. Transgressive coal-bed development is attributed to Milankovitch driven glacio-eustacy while highstand coal-bed development is attributed to autocyclic deltaic influences. Assessment of carbon dioxide storage capacity within coals of the lower Pennsylvanian Pocahontas and Bottom Creek formations in the Bradshaw CBM field indicates that 19 million tons of carbon dioxide can be sequestered. Sequestration of carbon dioxide within the Bradshaw CBM field has the potential to increase coal-bed methane recovery by as much as 52 billion cubic feet. / Master of Science

The lower Pennsylvanian, coal-bearing, siliciclastic strata in Dickenson/Wise counties of southwest Virginia were deposited in continental to marginal marine environments influenced by high-amplitude relative sea level fluctuations. Coal-bearing siliciclastics of the eastern facies belt are fluvio-deltaic in origin, with sediment derived from the erosion of low-grade metamorphic and Grenvillian-Avalonian terranes of the Alleghanian orogen to the southeast. Elongate NNE trending quartzarenite belts in the northwestern region of the basin are braided-fluvial deposits and were sourced by the cratonic Archean Superior Province to the north. This orthogonal relationship between the southeastern coal-bearing siliciclastics and the northwestern quartzarenites reflect a trunk-tributary drainage system operating during the lower Pennsylvanian in the central Appalachian basin. Analysis of core, gamma ray and density logs, and six cross-sections within an approximately 20 km² study area reveals a hierarchy of bounding discontinuities and architectural elements. Discontinuities are both erosional (unconformable) and depositional (condensed) and are 3rd-order (~ 2.5 Ma) and 4th-order (~ 400 k.y.) in origin. Architectural elements are bound by 4th-order discontinuities and consist of upward-fining lowstand and transgressive incised valley fill, alluvial, and estuarine deposits, and upward-coarsening highstand deltaic deposits and represent 4th-order sequences. Lowstand and transgressive deposits are separated from the highstand deposits by marine flooding zones (condensed sections). 4th-order sequences are stacked into composite 3rd-order sequences. Sequence development can be attributed to 4th-order Milankovitch orbital eccentricity cycles superimposed on a lower-frequency eccentricity cycle. Extensive coals occur in both transgressive and highstand systems tracts. Coals within the transgressive systems tract are associated with 4th-order flooding surfaces, while coals within the highstand systems tract occur within high-frequency deltaic autocycles. Therefore, coals formation in the central Appalachian basin can be attributed to be of both allocyclic (glacio-eustacy) and autocyclic (deltaic processes) mechanisms. / Master of Science