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Application of surface enhanced raman spectroscopy to measurements of diffusion through silastic membranesSutton, C. P. January 2000 (has links)
No description available.
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Silica-silicone interactions: Non-linear viscoelastic behavior of silica-filled silicone rubberWarley, Russell Lee January 1993 (has links)
No description available.
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Detecting Inclusions in a Silicone Rubber Phantom Using Standing Lamb Waves and Multiple Frequency FootprintsJonsson, Ulf G January 2014 (has links)
The thesis deals with one major question: is it possible, using one piezoelectric sensor/vibrator, to detect a hard inclusion in a silicone rubber phantom? The question was approached with an open mind and the task was subdivided into three clearly identifiable parts: characterization of the piezoelectric sensor/vibrator (paper I), creating a model of the visco-elastic properties of a tissue-like material (phantom) in contact with the sensor/vibrator (paper II), and to detect the presence of a hard inclusion in the phantom (paper III). All vibrations of the sensor/vibrator and phantom was modeled using a finite element method (FEM). To minimize the computational time and to maximize the FEM model's ability to correctly reproduce the vibrations, a two-dimensional model system consisting of a cylindrical piezoelectric sensor/vibrator, emitting radial elastic waves in to a cylindrical disk-shaped phantom, was chosen. The piezoelectric sensor/vibrator was characterized using a parameter tuning procedure using harmonic overtones. The procedure enables tuning of the electro-elastic parameters of the sensor/vibrator so that the measured and calculated impedance frequency responses match. Silicone rubber was chosen as a phantom to mimic soft tissue. The properties of the phantom was modeled using a fractional derivative visco-elastic model. The hyperelastic effect at the first radial resonance of the sensor vibrator was corrected for by a compensating function. The high frequency complex visco-elastic modulus of the silicone rubber was determined using the transitions of standing Lamb waves in the phantom. The presence of a ring-shaped inclusion in the phantom, of polyamide, was detected using the change of the transitional Lamb wave patterns in the phantom. The tuning of the PZT5A1 sensor/vibrator parameters yielded a match between the calculated and the measured impedance spectra better than 0.54%. The average, complex, elastic modulus of three silicone rubber, Silgel 612, samples were: (0.97 + 0.009i) GPa at 100 kHz and (0.97 + 0.005i) GPa at 250 kHz. The presence of a polyamide inclusion, PA6GPE, was detected in the phantom using multiple frequency footprints. / Denna avhandling berör frågan: är det möjligt, med en piezoelektrisk sensor/vibrator, att detektera ett hårt objekt inneslutet i en fantom av silikongummi? Frågan närmades utan begränsningar och uppgiften delades upp i tre tydliga delar: karaktäriseringen av den piezoelektriska sensorn/vibratorn (paper I), skapa en modell av det viskoelastiska uppförandet hos ett vävnadsliknande material (fantom) som står i kontakt med sensorn-/vibratorn (paper II) och att detektera förekomsten av ett hårt objekt inneslutet i fantomen (paper III). En finit element modell (FEM) skapades för att beräkna vibrationerna hos sensorn/vibratorn och fantomen. För att minimera beräkningstiden och maximera modellens förmåga att återge vibrationer på ett korrekt sätt, så skapades ett tvådimensionellt modellsystem bestående av en cylindrisk piezoelektrisk sensor/vibrator i kontakt med en cylindrisk fantom av silikongummi. Sensorn/vibratorn skickar radiella elastiska vågor in i fantomen. Den piezoelektriska sensorn/vibratorn karakteriserades med hjälp av en procedur som anpassar parametervärden med hjälp av övertoner. Proceduren möjliggör en justering av parametervärdena så att uppmätta och beräknade impedansspektra överensstämmer. En 'fractional derivative' modell av de viskoelastiska egenskaperna hos silikongummit skapades. De hyperelastiska egenskaperna vid första radiella resonansen blev kompenserade med hjälp av en sigmoidformad funktion. Den komplexa viskoelastiska modulen bestämdes för höga frekvenser med hjälp av transitioner hos stående Lambvågor i fantomen. Närvaron av ett hårt ringformat objekt i fantomen detekterades med hjälp av förändringar i mönstret hos de stående Lambvågorna. Justeringen av de piezoelektriska parametrarna hos elementet PZT5A1 gav som mest en skillnad på 0.54% mellan uppmätta och beräknade impedansspektra. Medelvärdet hos tre prov av silikongummit Silgel 612 av den komplexa elastiska modulen uppmättes till (0.97 + 0.009i) GPa vid 100 kHz och (0.97 + 0.005i) GPa vid 250 kHz. Närvaron av ett hårt objekt, gjort av polyaramid (PA6GPE), detekterades i fantomen med hjälp av multifrekvensiella fotavtryck.
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The Design, Fabrication and Performance Analysis of a Flexible Heat PipeYang, Ya-ju 21 August 2012 (has links)
This experiment produces a new flexible heat pipe, and further tests and explores its characteristics and performance. The heat pipe is made of silicone rubber, a kind of polymer material, and was molded by hot embossing. Characteristics of this material include good bending resistance, lightness, and good resistance to high temperature. Furthermore, copper sheets connected with silicone were placed at the evaporator section and condenser section to enhance heat transfer effects. DI water in the pipe was used as the working medium, and two-layer 250 mesh copper nets were used as a wick to strengthen the heat pipe¡¦s capillary effects. The researcher set the vacuum degree at 0.0658 atm to test the pipe¡¦s performances at different powers. Key findings include an optimum filling ratio of 40%, and a largest heat flux of 11.75 W/cm2 during the proficiency test. In addition to the proficiency test . The influence of different angles of bends (0 ~ -90¢X) on the pipe¡¦s heat transfer performance was also tested and based on heat thermal resistance obtained, found that the best bended angle of the flexible heat pipe was -15¢X, and thermal resistance will increase with the angle(-30 ~ -90¢X). The experiment proves a small angle bend that is helpful for the working medium to flow back to the evaporator section, but the heat transfer performance would shrink because the wick could not affix to the inner wall of the pipe if the angle is too large. This work shows the proper combination of pipe parameters will significantly improve heat transfer performance.
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Application of fracture mechanics to dielectric breakdown in air, silicone oil and silicone rubber /Cheung, Chi Wai. January 2009 (has links)
Thesis (M.Phil.)--Hong Kong University of Science and Technology, 2009. / Includes bibliographical references (p. 112-116).
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A clinical evaluation of silicone rubber as a denture base lining material a thesis submitted in partial fulfillment ... denture prosthesis ... /Sauer, John L. January 1964 (has links)
Thesis (M.S.)--University of Michigan, 1964.
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A clinical evaluation of silicone rubber as a denture base lining material a thesis submitted in partial fulfillment ... denture prosthesis ... /Sauer, John L. January 1964 (has links)
Thesis (M.S.)--University of Michigan, 1964.
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Study on Polyelectrolyte Brushes on Silicone Rubber And The Influence Of Hydrophobic RecoveryTong, Zifeng 28 April 2021 (has links)
No description available.
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Studies on Silicone Rubber Insulators used for High Voltage TransmissionChakraborty, Rahul January 2017 (has links) (PDF)
Recently high temperature vulcanized (HTV) silicone rubber (SIR) / polymeric/composite insulators are gaining wider acceptance as overhead transmission line insulators for extra high voltage (EHV) and ultra-high voltage (UHV) systems due to some promising features like hydrophobicity recovery, light weight, ease of handling and installation, better pollution ashover performance, admirable resistance against vandalism etc. Since polymeric insula-tors are of recent origin, their long-term eld performance is yet to be understood. Owing to their organic nature, and exposure to environmental stresses like pollution, temperature, UV radiation, humidity, fog, rain etc., the insulator performance degrades over a period. The sheds/petticoats of the insulators become wettable leading to frequent ashover in humid and contaminated environment. Hence, long term reliability of the composite insulators is of foremost concern to the power utilities. The available literature on the long term eld performance of these insulators for di erent climatic conditions and under multiple environ-mental stresses for both the HTV SIR and Liquid Silicone Rubber (LSR) is scant. Also there is no reference standard for evaluation of these insulators for pollution/contamination test methods in the laboratory. However currently, CIGRE Work Group is working towards the standardization of the test methods for arti cial pollution tests for polymeric insulators. The thesis addresses some of the issues in detail.
In the first part of the thesis, a new and simple pre-treatment methodology to achieve uniform contamination layer on inherently hydrophobic HTV SIR Insulator samples is presented for laboratory pollution performance evaluation. The surface water level di usion in the dipping period is found to make the insulator surface temporarily hydrophilic. Then the uniform contamination layer is applied by dipping the sample immediately in the pollution slurry. Exhaustive experiments were conducted on full scale SIR insulators as well as SIR slabs to investigate the hydrophilicity appearance on the SIR surface. A specially fabricated arrangement for assessment of Wettability Class (WC) is made as per IEC stds. The results of WC measurement and wet ashover studies support the temporary reduction in hydrophobicity of SIR due to dipping phase in the proposed pre-treatment methodology.
The next part of the thesis presents the results for the effeect of long term thermal aging experimentation conducted on HTV SIR with difffeerent degrees of pollution (medium, heavy), the effeect of arid desert climate on polymeric insulators is studied. The experimental set-up consists of controlled HVAC source, temperature controlled furnace with a provision for high voltage (HV) and Leakage Current (LC) monitoring, a Digital Storage Oscilloscope (DSO), compact DAQ-9201 of National Instruments operated in LabVIEW platform etc. Two types of HTV SIR Insulators are considered for the study. Flat slabs as well as full-scale insulator samples of creepage length 725 mm are stressed simultaneously to simulate the in-service condition. The experimentation is conducted for about 575 hours with application of 21.0 kVrms at 60oC. The results of the hydrophobicity recovery for thermally aged contaminated polymeric insulators are reported. Besides, monitoring electrical and mechanical proper-ties, changes in material properties of SIR are also analyzed using Physiochemical analysis techniques like Fourier transform infrared (FTIR) spectroscopy, X-Ray Photoelectron Spectroscopy (XPS), Scanning Electron Microscopy (SEM), Thermo-Gravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC). Some of the key findings of the study are increased surface oxidation, surface roughness and mechanical stress due to thermal aging of polymeric insulators. Experimental investigations show that the characteristics of power frequency component of leakage current can be linked with thermal aging of SIR.
Further, a unique climatic aging experimental facility is established to evaluate the long-term reliability of SIR under environmental stresses like UV, Humidity, temperature and applied electric stress. The investigations are conducted on two different types of HTV SIR and LSR at samples as well as full-scale insulator samples. The experimentation is conducted for 500 hours with 10.0 kVrms at 50oC, with 85% humidity and 1 W/m2 UV ir-radiation which is in accordance with the aging cycle specified in IEC standard. The results of the comparative studies conducted for the electrical, mechanical and material properties indicate leakage current pulses, brittleness, Salt deposition for multistress aged samples.
In summary, an attempt has been made to contribute a pollution methodology with sim-ple pre-treatment technique for inherently hydrophobic HTV SIR surface to achieve better uniformity of contamination layer. Also, electro-thermal and multiple stresses investigations were conducted for long term performance on polymeric insulators.
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Evaluation of Room Temperature Vulcanized (RTV) Silicone Rubber Coated Porcelain Post Insulators under Contaminated ConditionsJanuary 2013 (has links)
abstract: This thesis concerns the flashover issue of the substation insulators operating in a polluted environment. The outdoor insulation equipment used in the power delivery infrastructure encounter different types of pollutants due to varied environmental conditions. Various methods have been developed by manufacturers and researchers to mitigate the flashover problem. The application of Room Temperature Vulcanized (RTV) silicone rubber is one such favorable method as it can be applied over the already installed units. Field experience has already showed that the RTV silicone rubber coated insulators have a lower flashover probability than the uncoated insulators. The scope of this research is to quantify the improvement in the flashover performance. Artificial contamination tests were carried on station post insulators for assessing their performance. A factorial experiment design was used to model the flashover performance. The formulation included the severity of contamination and leakage distance of the insulator samples. Regression analysis was used to develop a mathematical model from the data obtained from the experiments. The main conclusion drawn from the study is that the RTV coated insulators withstood much higher levels of contamination even when the coating had lost its hydrophobicity. This improvement in flashover performance was found to be in the range of 20-40%. A much better flashover performance was observed when the coating recovered its hydrophobicity. It was also seen that the adhesion of coating was excellent even after many tests which involved substantial discharge activity. / Dissertation/Thesis / M.S. Electrical Engineering 2013
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