The eleven illuminated missals at the core of this thesis share a distinctive scale that sets them apart from the majority of other decorated missals. Their scale was a key factor in the visual and ritual experiences they offered their patrons and their earliest users. Missals made in the later fourteenth century and the early fifteenth century included some of the physically largest examples of this genre of book ever made. Containing the text of the late medieval Mass, and read by its priest during the ritual’s performance, they were essential components of the ritual that resulted in the physical embodiment of Christ in the Eucharist. Large missals were a distinctive variation of the Mass book. However, existing scholarship has not offered sufficient reasons for a wide-ranging phenomenon of large missal patronage and manufacture. This thesis argues that the scale of these books was a central rhetorical device that magnified their significance and reception. At the heart of this adoption of the large-scale format was the aggrandisement of the Mass itself, reaffirming its place as the central rite of the Christian Church and contemporary devotions about the ritual. Study of these eleven manuscripts suggests that their exceptional size and the treatment of their interior designs supporting their visuality were issues for this particular period. Explanations for the adoption of large Mass books are given by examining their visibility in the Mass, as part of what is termed here the ‘altarscape’. Having established this, this thesis offers reasons for why patrons and clerics used a cumbersome large format for the text of the ritual. The missals unmistakeably reasserted orthodox values in the face of challenges to conventional understanding of the Eucharist from those holding non-conforming views. Simultaneously, the emphasis on expanded proportions arguably reflects contemporary practices of commemoration where being remembered was an essential part of dying well. And finally, the interior and exterior scale of these books was used for new devotional themes, including the Virgin.

Une échelle de taille contenant 20 substituants usuels en chimie a été construite à partir des barrières de rotations de N-aryl-thiazoline-2-thiones. L’énergie d’activation ΔG≠rot qui est mesurée reflète l’encombrement stérique du substituant en ortho du cycle benzénique. Les perturbations électroniques, et les facteurs externes tels que la température ou le solvant sont négligeables. La grande sensibilité du modèle proposé conduit au classement suivant Me > Cl et CN > OMe > OH. Ces classements divergents décrits dans la littérature seront discutés. Une limitation du modèle proposé concerne les substituants très volumineux comme le CF3 et l’iPr qui apparaissent plus petit qu’ils ne le sont en réalité à cause d’un encombrement stérique dans l’état fondamental qui abaissent la valeur de la barrière de rotation. / A steric scale of 20 recurrent groups was established from comparison of rotational barriers on N-(o-substituted-aryl)-thiazoline-2-thione atropisomers. The resulting energy of activation ΔG≠rot reflects the spatial requirement of the ortho substituent borne by the aryl moiety, electronic aspects and external parameters (temperature and solvent) generating negligible contributions. Concerning divergent rankings reported in literature, the great sensitivity of this model allowed to show unambiguously that a methyl appears bigger than a chlorine, and gave the following order in size: CN > OMe > OH. For the very bulky CF3 and iPr groups, constraints in the ground state decreased the expected ΔG≠rot values resulting in a minimization of their apparent sizes.

Experimental physical model studies of hydraulic structures are often conducted to replicate flow behavior that may occur at the prototype scale. Geometric similitude is most often maintained between the prototype and model when studying reservoir and open channel hydraulic structures to account for the dominant gravity and inertia forces while other fluid forces (e.g., viscosity,surface tension) are assumed negligible. However, as model size and/or upstream head decreases, other fluid forces can exceed the negligible level and influence model flow behavior. This phenomenon is referred to as size-scale effects and is one potential origin of error in predicting the prototype behavior through testing geometrically similar models. To extend the existing research of size-scale effects on nonlinear weirs half-and quarter-round trapezoidal labyrinth weirs and piano key weirs were fabricated at length ratios of 1, 2, 3, 6, and 12. The largest weir model for each weir type (i.e., a weir height of 36 in for labyrinth weir models and a weir height of 33 in for piano key weir models) served as the corresponding prototype.Weir models were hydraulically tested to assess differences among head-discharge relationships and flow behavior. Limiting criteria were recommended to avoid size-scale effects depending on the weir type and model size. The results of this study will help hydraulic modelers determine what limiting criteria should be met to avoid size-scale effects.

Linear weirs are a common hydraulic structure that have been used for centuries with many different applications. One characteristic of weirs that is particularly useful is the head-discharge relationship where the discharge over the weir is directly related to the upstream water depth above the crest. In general, the head-discharge relationship for a weir is determined experimentally in laboratories using geometrically similar models. Due to space, time, money, and discharge capacity limitations at water laboratories, creating full scale models is not always a feasible option when determining head-discharge relationships for large prototype weirs. It is typically more cost effective to create a scale model than to build a full scale model or conduct tests on the prototype. Because of this fact, physical modeling has been one the most important tools in determining head-discharge relationships for weirs. However, as the physical size of the model decreases, size scale effects associated with surface tension and viscosity forces can significantly affect the results from the physical model and cause the results to differ from what would actually occur at the prototype scale. Therefore, it is important to understand what affects surface tension and viscosity forces have on the head-discharge relationship for different size weirs and when those effects are no longer negligible. The purpose of this research was to evaluate size scale effects for linear weirs. Weirs models of three different crest shapes (flat-top, quarter-round, and half-round) were constructed and tested at four different geometrically similar sizes [weir heights (P) = 24-, 12-, 6-, and 3-in]. This was done in order to evaluate how size scale effects affect the head-discharge relationship as model size decreases for different crest shapes. Discharge coefficients were calculated for relative upstream head values ranging from 0.01 ≤ Ht/P ≤ 2.0 for vented and non-vented conditions. Nappe aeration behavior was documented and compared to determine where differences in the nappe trajectory occurred as a result of scale effects. Comparisons were made with data from others researchers to determine if the recommendations for minimum head limits were similar to the results from this study. This study examined the errors in the discharge coefficient associated with size scale effects and suggested limits to avoidance depending on model scale and crest shape.

The objective of this dissertation centers on gaining a better understanding of the structure - property - performance relations of nickel and copper through the advanced multiscale theoretical framework and integrated computational methods. The goal of this dissertation also includes to combine material science and computational mechanics to acquire a transformative understanding of how the different crystal orientations, size scales, and penetration velocities affect plastic deformation and damage behavior of metallic materials during high strain rate (> 103s-1) processes. A multiscale computational framework for understanding plasticity and shearing mechanisms of metallic materials during the high rate process was developed, which for the first time reveals micromechanical insights on how different crystal orientations, size scales, and penetration velocities affect the atomistic simulations which render structure property information for plasticity, shearing and damage mechanisms. The contributions of this dissertation include: (1) Comprehensive understanding of the plasticity and shearing mechanisms between the nickel penetrator and copper target under high strain rates (2) Development of a multiscale study of a nickel penetrator striking a copper plate by employing macroscale simulations and atomistic simulations to better understand the micromechanisms. (3) An essential description of how different crystal orientations, size scales, and strain rates affect the plasticity and shearing mechanisms.