Currently, a lack of accurate emission data exits for particulate matter (PM) in agricultural air quality studies (USDA-AAQTF, 2000). PM samplers, however, tend to over estimate the concentration of most agricultural dusts because of the interaction of the particle size distribution (PSD) and performance characteristics of the sampler (Buser, 2004). This research attempts to find a practical method to characterize and correct this error for the Federal Reference Method (FRM) PM10 sampler. First, a new dust wind tunnel testing facility that satisfies the USEPA’s requirement of testing PM10 samplers was designed, built, and evaluated. Second, the wind tunnel testing protocol using poly-dispersed aerosol as the test dust was proved to be able to provide results consistent with mono-dispersed dusts. Third, this study quantified the variation of over sampling ratios for the various cut point and slopes of FRM PM10 samplers and proposed an averaged over sampling ratio as a correction factor for various ranges of PSD. Finally, a method of using total suspended particle (TSP) samplers as a field reference for determining PM10 concentrations and aerosol PSD was explored computationally. Overall, this dissertation developed successfully the methodology to correct the sampling error associated with the FRM PM10 sampler: (1) wind tunnel testing facilities and protocol for experimental evaluation of samplers; (2) the variation of the oversampling ratios of FRM PM10 samplers for computational evaluation of samplers; (3) the evaluation of TSP sampler effectiveness as a potential field reference for field evaluation of samplers.

Recent growth of the Internet in both scale and complexity has imposed a number of difficult challenges on existing measurement techniques and approaches, which are essential for both network management and many ongoing research projects. For any measurement algorithm, achieving both accuracy and scalability is very challenging given hard resource constraints (e.g., bandwidth, delay, physical memory, and CPU speed). My dissertation research tackles this problem by first proposing a novel mechanism called residual sampling, which intentionally introduces a predetermined amount of bias into the measurement process. We show that such biased sampling can be extremely scalable; moreover, we develop residual estimation algorithms that can unbiasedly recover the original information from the sampled data. Utilizing these results, we further develop two versions of the residual sampling mechanism: a continuous version for characterizing the user lifetime distribution in large-scale peer-to-peer networks and a discrete version for monitoring flow statistics (including per-flow counts and the flow size distribution) in high-speed Internet routers. For the former application in P2P networks, this work presents two methods: ResIDual-based Estimator (RIDE), which takes single-point snapshots of the system and assumes systems with stationary arrivals, and Uniform RIDE (U-RIDE), which takes multiple snapshots and adapts to systems with arbitrary (including non-stationary) arrival processes. For the latter application in traffic monitoring, we introduce Discrete RIDE (D-RIDE), which allows one to sample each flow with a geometric random variable. Our numerous simulations and experiments with P2P networks and real Internet traces confirm that these algorithms are able to make accurate estimation about the monitored metrics and simultaneously meet the requirements of hard resource constraints. These results show that residual sampling indeed provides an ideal solution to balancing between accuracy and scalability.

This research focuses on aircraft observational studies of aerosol-cloud interactions in cumulus clouds. The data were collected in the summer of 2004, the spring of 2007 and the mid-winter and spring of 2008 in Texas, central Saudi Arabia and Istanbul, Turkey, respectively. A set of 24 pairs of sub-cloud aerosol and cloud penetration data are analyzed. Measurements of fine and coarse mode aerosol concentrations from 3 different instruments were combined and fitted with lognormal distributions. The fit parameters of the lognormal distributions are compared with cloud droplet effective radii retrieved from 260 cloud penetrations. Cloud condensation nuclei (CCN) measurements for a subset of 10 cases from the Istanbul region are compared with concentrations predicted from aerosol size distributions. Ammonium sulfate was assumed to represent the soluble component of aerosol with dry sizes smaller than 0.5 mm and sodium chloride for aerosol larger than 0.5 mm. The measured CCN spectrum was used to estimate the soluble fraction. The correlations of the measured CCN concentration with the predicted CCN concentration were strong (R2 > 0.89) for supersaturations of 0.2, 0.3 and 0.6%. The measured concentrations were typically consistent with an aerosol having a soluble fraction between roughly 0.5 and 1.0, suggesting a contribution of sulfate or some other similarly soluble inorganic compound. The predicted CCN were found to vary by +or-3.7% when the soluble fraction was varied by 0.1. Cumulative aerosol concentrations at cutoff dry diameters of 1.1, 0.1 and 0.06 mm were found to be correlated with cloud condensation nuclei concentrations but not with maximum cloud base droplet concentrations. It is also shown that in some cases the predominant mechanisms involved in the formation of precipitation were altered and modified by the aerosol properties. This study suggests that CCN-forced variations in cloud droplet number concentration can change the effective radius profile and the type of precipitation hydrometeors. These differences may have a major impact on the global hydrological cycle and energy budget.

No description available.

Abstract In order to understand the source, transport pathway and sink of settling particulates off northeast Taiwan, time-series sediment traps (PPS-3/3) were deployed on the north slope of Ilan ridge (T18) and in the Okinawa trough (T15 and T16) to collect settling particulates. The trapped particulate samples were determined for apparent mass flux (T18), particle size distribution, and contents of lithogenic portion, metals (Al, Mg, Ca, Fe, Mn, Cu), opal, OC (organic carbon) and IC (inorganic carbon). The results show that mass flux in winter is higher than in summer except for typhoon or rainstorm in summer which may cause high particulate flux. At mooring T11 and T17, only 2 cups had collected particulates but with rapid decrease, and the remaining cups were empty. It is not clear whether Kuroshio plays a role and further investigation is needed. The trapped particulates were mainly clay and silt in the north slope of Ilan ridge and south Okinawa trough, and were sand and silt in the Mien-Hwa canyon. The portion of coarse silt and larger particles (>31 mm) decreases with an increase of distance from the land (from T11 to T18). The grain size distribution of particulate at T18 is similar to that at T15 and T16, but the mass flux in the north slope of Ilan ridge is an order of magnitude higher than in the south Okinawa trough. The size distribution pattern below 600m water depth is very similar at both T15 and T16, but the coarse fraction (> 31 mm) is more at the upper than lower traps, presumably due to lateral transport. The Mn content of the trapped particulates in the south Okinawa trough is twice as hign as that in the north slope of Ilan ridge. High Mn/Al ratio in the trough suggests that Mn is supplied by hydrothermal activities. Lithogenic portions occupy about 84~88.5% at T18, T16 and T15. Relative to other marginal seas biogenic contributions are clearly lower.

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Die Charakterisierung von Nanopartikeln erfordert eine Messung des Dispersitätszustandes bei allen Schritten der Herstellung - von der Synthese bis zum fertigen Produkt. Dafür ist eine leistungsfähige Partikelmesstechnik notwendig, deren Methoden bei der Beschreibung des komplexen Materialverhaltens helfen können. Die Ultraschalldämpfungsspektroskopie ist eine Messmethode, die zur prozessbegleitenden Charakterisierung hochdisperser Pulver und Suspensionen geeignet ist. Mit Vergleichen von Messungen und Modellrechungen wurde festgestellt, dass für die Ultraschalldämpfungs-Modellierung in Dispersionen homogener Partikel ein auf dem Phänomen der elastischen Streuung basierendes Modell praktisch relevant ist. Dies betrifft sowohl die Anwendung zur Messung in Suspensionen als auch in Emulsionen homogener Partikel. Bei einem Vergleich von Modellrechungen und Messungen für ein System poröser Partikel bzw. Aggregate wurde das Modell der Streuung an poroelastischen Kugeln als geeignet zur Beschreibung der Dämpfung disperser Systeme identifiziert. Bei Vorhandensein grober Partikel in Suspensionen nanoskaliger Systeme ist somit eine korrekte Auswertung der Partikelgröße möglich; der bislang übliche Messbereich wurde erweitert. Sekundärer Schwerpunkt der Arbeit ist die Diskussion der numerischen Modellanwendung. Es werden weiterhin Lösungsmöglichkeiten zur Dämpfungsberechnung und zur Berechnung der Größenverteilungen beschrieben. Des Weiteren wurden Anregungen für Entwickler von Ultraschallspektrometern abgeleitet.

<p>This licentiate thesis reports analytical results for the electrostatic response to a test charge moving through dusty plasma. Two particular cases for a slowly moving test charge, namely, grain size distribution and grain charging dynamics are considered. Analytical results for the delayed shielding of a test charge due to dynamical grain charging in dusty plasma are also reported. In the first case, a dusty plasma in thermal equilibrium and with a distribution of grain sizes is considered. A size distribution is assumed which decreases exponentially with the grain mass for large sizes and gives a simple smooth reduction for small sizes. The electrostatic response to a slowly moving test charge, using a second order approximation is found and the effects of collisions are also investigated. It turns out that for this particular size distribution, there is a remarkably simple result that the resulting effective distribution for the electrostatic response is a kappa (generalized Lorentzian) distribution. In the second case, we present an analytical model for the shielding of a slowly moving test charge in a dusty plasma with dynamical grain charging for cases both with and without the collision effects. The response potential is treated as a power series in test charge velocity. Analytical expressions for the response potential are found up to second order in test charge velocity. The first-order dynamical charging term is shown to be the consequence of the delay in the shielding due to the dynamics of the charging process. It is concluded that the dynamical charging of the grains in a dusty plasma enhances the shielding of a test charge. To clarify the physics, a separate study is made where the charging is approximated by using a time delay. The resulting potential shows the delayed shielding effect explicitly. The terms in the potential that depend on the charging dynamics involve a spatial shift given by the test charge velocity and the charging time. This kind of work has relevance both in space and astrophysical plasmas.</p>

Summary: A process is under investigation for the manufacture of dicalcium phosphate by the hydrolosis of concentrated superphosphate containing recycled monocalcium phosphate. The hydrolysis also results in the formation of an aqueous solution of monocalcium phosphate and free phosphoric acid. The phases are separated, followed by washing and drying of the solid dicalcium phosphate. The wash water is used in the hydrolyzer. The solution is returned to the superphosphate production step, where phosphate rock and additional phosphoric acid are added, and where water is evaporated to form the solid superphosphate.Pilot plant results have indicated that filtration rates vary widely under almost identical mixing conditions, presumably due to variations in particle size ranges. It was thought worthwhile, therefore, to study the effects of different mixing variables on the relative particle sizes as indicated by the settling rates of the mixture.

This study has analyzed particel size distribution and needle content in chipped logging residuals (branches and tops) delivered to the district heating plant Ryaverket in city of Borås, Sweden. Two fuel assortments has been analyzed: Chipped logging residuals from pure softwood and from mixed fuel (connifers and broadleaves). The samples has been sieved at Linneaus University laboratory. The study of particle sizes indicates that only 53,2 % of delivered fuel is within the fuels specification (7– 45 mm). The needle content is in this study 12,4 % (dry mass) which is higher than expected. / Sedan oljekriserna på 1970 talet har den svenska energiförsörjningen ändrats i grunden. Idag har stora delar av de tidigare petroleumbaserade bränslena ersatts med olika förnybara biobränslen. Skogsbränsle delas upp i olika bränslesortiment utifrån trädslag samt olika fysikaliska och tekniska egenskaper. Till Borås Energi &amp; Miljö Ab´s värmeverk Ryaverket levereras det årligen ungefär 550000 kubikmeter skogsbränsle fördelat på cirka 30 olika sortiment. Fraktionsfördelningen, det vill säga storleken på bitarna i materialet, samt barrinnehåll är två viktiga kvalitetsfaktorer på bränslet. Denna rapport är en redovisning av en fraktionsanalysstudie på två av bränslesortimenten till Ryaverket. Dels flisad grot av rent barrträ och dels blandsortimentet flisad grot av barr och lövträ. I studien har också gjorts en analys av barrinnehållet i bränslet. Studien har gjorts genom sållning av prover från inkommande bränsleleveranser. Analysen visar att stora delar av det, till värmeverket, inkomna bränslet ligger utanför uppsatta bränslespecifikationer. Av materialet finns 53,2 % inom storleksområdet 7 -45 mm (acceptflis). Delvis bekräftar detta resultat tidigare forskning på området. Barrandelen är hög: 12,4%. Detta är en högre siffra än vad som var förväntat och högre än vad som framkommit i tidigare studier. Slutsatsen är att det troligen krävs omtänkande/nytänkande för att dagens grotbränsle skall fungera optimalt i moderna värmeverk. Skall flisningsutrustningen konstrueras om? Skall ny teknik för online och kontinuerlig mätning av bland annat fraktionsfördelning införas? Vilket är optimalt: att köpa in olika bränslesortiment lassvis och blanda själv på värmeverket? Eller är det mest optimalt att köpa färdigblandat bränsle från leverantör?