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Quantifying Spatial Variability of Snow Water Equivalent, Snow Chemistry, and Snow Water Isotopes: Application to Snowpack Water BalanceGustafson, Joseph Rhodes January 2008 (has links)
This study quantifies spatial and temporal patterns in snow water equivalent (SWE), chemistry, and water isotopes associated with snowpack shading due to aspect and vegetation in the Valles Caldera National Preserve, New Mexico. Depth, density, stratigraphy, temperature, and snow chemistry, isotope, and biogeochemical nutrient samples were collected and analyzed from five snowpit locations on approximate monthly intervals between January-April 2007. SWE showed little variability between sites in January (~10mm) but differences expanded to 84mm (30%) by max accumulation in open sites and 153mm (45%) between all sites. Sulfate varied by 22% (10.6-13.5 microeq/L), Cl- by 35% (17.4-26.9 microeq/L), and d18O by 17% (-16.3 to -13.5), with SWE exhibiting inverse correlations with d18O (r2=0.96), SO42- (r2=0.75), and Cl- (r2=0.60) at max accumulation. Regression relationships suggest variability in SWE and solutes/water isotopes are primarily driven by sublimation. Mass balance techniques estimate sublimation ranges from 1-16% between topographically- and non-shaded open sites.
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Ion Exclusion, pH, and Halogen Activation at the Air-Ice InterfaceWren, Sumi 14 January 2014 (has links)
Although the air-ice interface is atmospherically important, it is difficult to model accurately because exclusion and precipitation of solutes during freezing, deposition of atmospheric species, and heterogeneous/photochemical processes all affect its properties. In this thesis, glancing-angle spectroscopic methods were developed to study ice surfaces. Glancing-angle Raman spectroscopy showed that nitrate is not strongly excluded to the ice surface during freezing, in contradiction with expectations based on equilibrium thermodynamics. Glancing-angle laser-induced fluorescence showed that hydronium ions are not strongly excluded when dilute acidic solutions (HNO3 or HCl) are frozen. These results suggest that solutes are not universally excluded and that care should be taken in modelling surface concentrations on ice.
Deposition of HCl(g) was found to result in different pH responses at the "pure" vs. "salty" ice surfaces. Changes at the "salty" ice surface were consistent with the existence of a brine layer at the air-ice interface while changes at the "pure" ice surface were distinctly different, indicating that it may not be appropriate to model it as a cold, liquid layer. Significantly, results also suggest that the sea ice surface is buffered against pH changes, with important implications for interpreting pH-dependent chemistry.
The conversion of sea-salt derived halides to reactive halogen species can lead to dramatic changes in the oxidative capacity of the overlying atmosphere. At ambient pH and naturally occurring halide concentrations, the dark ozonation of NaBr and NaI solutions was found to proceed more quickly on frozen vs. aqueous substrates, consistent with a freeze-concentration enhancement in halide concentration at the surface. A photochemical mechanism for halogen release from artificial saline snow was evidenced. The presence of ozone and light in the actinic region leads to accelerated production of Br2 and BrCl and the release of Cl2, in a process enhanced by high surface area, acidity and additional gas phase Br2. The results provide strong evidence for snowpack "halogen explosion" chemistry in which gas phase halogens are recycled back into a concentrated brine layer at the snow grain surface.
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Ion Exclusion, pH, and Halogen Activation at the Air-Ice InterfaceWren, Sumi 14 January 2014 (has links)
Although the air-ice interface is atmospherically important, it is difficult to model accurately because exclusion and precipitation of solutes during freezing, deposition of atmospheric species, and heterogeneous/photochemical processes all affect its properties. In this thesis, glancing-angle spectroscopic methods were developed to study ice surfaces. Glancing-angle Raman spectroscopy showed that nitrate is not strongly excluded to the ice surface during freezing, in contradiction with expectations based on equilibrium thermodynamics. Glancing-angle laser-induced fluorescence showed that hydronium ions are not strongly excluded when dilute acidic solutions (HNO3 or HCl) are frozen. These results suggest that solutes are not universally excluded and that care should be taken in modelling surface concentrations on ice.
Deposition of HCl(g) was found to result in different pH responses at the "pure" vs. "salty" ice surfaces. Changes at the "salty" ice surface were consistent with the existence of a brine layer at the air-ice interface while changes at the "pure" ice surface were distinctly different, indicating that it may not be appropriate to model it as a cold, liquid layer. Significantly, results also suggest that the sea ice surface is buffered against pH changes, with important implications for interpreting pH-dependent chemistry.
The conversion of sea-salt derived halides to reactive halogen species can lead to dramatic changes in the oxidative capacity of the overlying atmosphere. At ambient pH and naturally occurring halide concentrations, the dark ozonation of NaBr and NaI solutions was found to proceed more quickly on frozen vs. aqueous substrates, consistent with a freeze-concentration enhancement in halide concentration at the surface. A photochemical mechanism for halogen release from artificial saline snow was evidenced. The presence of ozone and light in the actinic region leads to accelerated production of Br2 and BrCl and the release of Cl2, in a process enhanced by high surface area, acidity and additional gas phase Br2. The results provide strong evidence for snowpack "halogen explosion" chemistry in which gas phase halogens are recycled back into a concentrated brine layer at the snow grain surface.
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Iodine, Bromine, and Chlorine – Emission Rates and SourcesAngela R. Raso (5930183) 18 December 2018 (has links)
<div>Halogen chemistry in the Arctic boundary layer catalytically destroys O3 and impacts the chemical lifetimes of hydrocarbons, the HOx-NOx cycle, and atmospheric mercury. While many advances have been made in the last several decades in understanding the sources, sinks, and recycling pathways of halogens in the Arctic there are still many unknowns. Previous studies have shown that Br2, BrCl and Cl2 are produced photochemically in the Arctic tundra snowpack, but the magnitude of this production is still poorly understood. Additionally, while there have been suggestions that the tundra snowpack should also produce I2, there have been no previous measurements of I2 in the Arctic. The lack of measurements of the halogen production capacity of Arctic snowpacks has left the community to rely on one-dimensional modeling to estimate the impact of snowpack-derived halogen chemistry on the Arctic atmosphere. Because modeling is inherently dependent on understanding recycling mechanisms, mixing processes, and sinks this leaves the effect of halogens on atmospheric chemistry in the Arctic highly uncertain.</div><div><br></div><div>This work describes efforts to address these uncertainties through measurements made during two field campaigns in Utqiaġvik (formerly Barrow), Alaska in January – February 2014, and February – May 2016. The first measurements of I2 in the Arctic, both in the snowpack interstitial air, and in the air above the snowpack demonstrate that iodine chemistry is active in the Arctic atmosphere, and that I2 is produced photochemically in the tundra snowpack. The effects of active iodine chemistry on both O3 and bromine chemistry is examined through zero- and one dimensional modeling. The first speciated measurements of snowpack phase iodine reveal that much like previous reports of iodine enriched aerosols, the Arctic snowpack is highly enriched in iodine. Vertical profiles of I- in the snowpack suggest that there is a consistent, non-radiation dependent source of iodine to the Arctic environment. It seems likely that this source is transport of iodine-enriched aerosols from the mid-latitudes. However, unlike the Antarctic, and previous</div><div>observations in the mid-latitudes, most Arctic snowpack phase iodine is inorganic, which may contradict transport from the mid-latitudes as a source. One-dimensional modeling was also utilized, in conjunction with the first vertical profile measurements of Br2 and Cl2 between 1 and</div><div>7 m above the snowpack surface to examine the community’s understanding of recycling mechanisms, mixing, sources, and sinks of halogens in the Arctic Atmosphere.</div>
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Contribution à l'élaboration d'un modèle d'évolution physico-chimique de la neige / Development of a snow physico-chemical evolution model : a contributionBock, Josué 02 May 2012 (has links)
Il est aujourd'hui avéré que la composition chimique de l'atmosphère des régions enneigées – et notamment des régions polaires – est sensiblement affectée par les échanges d'espèces chimiques réactives entre l'air et la neige. En effet, le manteau neigeux constitue un véritable réacteur photochimique multiphasique, mais les mécanismes physico-chimiques à l'œuvre en son sein sont encore mal connus. Une compréhension détaillée des processus s'y déroulant est indispensable pour modéliser correctement la composition et la réactivité de l'atmosphère au-dessus des régions enneigées. De plus, la reconstitution de l'évolution post-dépôt des composés chimiques stables de la neige est également un préalable indispensable pour permettre l'interprétation paléoclimatique de leurs profils de concentration enregistrés dans les carottes de glace.Le nitrate (NO3-) présent dans la neige joue un rôle fondamental, car sa photolyse induit notamment l'émission d'oxydes d'azote (NOx = NO + NO2) par le manteau neigeux, qui modifient la capacité oxydante de l'atmosphère via la production d'ozone. L'objet de cette thèse a donc été d'étudier par modélisations les processus physico-chimiques intervenants dans l'évolution de la concentration du nitrate dans la neige.Une première approche, prolongeant des études préexistantes, a visé à identifier un mécanisme réactionnel pour la photochimie du nitrate dans la neige, en postulant notamment l'existence d'une couche quasi-liquide à la surface des grains de neige. Néanmoins, les propriétés exactes de l'interface air – glace sont, à l'heure actuelle, encore mal caractérisées, et il est apparu que cette démarche présentait de trop larges incertitudes pour être poursuivie.Une discussion approfondie a alors été menée afin d'évaluer les tentatives actuelles de modélisation de la chimie de la neige, et dans le but de proposer une nouvelle approche plus réaliste au regard du niveau de connaissance actuel.Ainsi, dans une seconde partie, l'ensemble des processus d'échange physico-chimiques du nitrate entre l'air et la neige ont été étudiés puis modélisés : adsorption à la surface, diffusion en phase solide et co-condensation. Parmi les résultats obtenus, il est apparu que les paramétrisations actuelles de la couverture surfacique en nitrate étaient incapables de reproduire les concentrations mesurées, dans le cas de la neige de surface à Dome C, et révèlent d'importantes surestimations. A contratio, la prise en compte conjointe de la diffusion en phase solide ainsi que d'un processus de co-condensation permet de bien reproduire qualitativement les séries temporelles de plus d'un an, couvrant donc à la fois l'été et l'hiver austral, qui présentent chacun des caractéristiques distinctes en terme de concentration mesurées.Cette étude révèle ainsi l'importance de ces processus physico-chimiques d'échange dans la modélisation de la chimie de la neige, et pose les bases des mécanismes à prendre en compte dans le cadre de développements futurs. / It is increasingly recognized that the atmosphere composition of snow covered regions – especially polar regions – is noticeably affected by air-snow interactions. Indeed, the snowpack is a multiphase reactor, but physico-chemical processes which take place inside are still poorly understood. A detailled understanding of snow-atmosphere interactions is essential for understanding and modeling properly the composition and reactivity of the atmosphere above snow covered regions. Reconstructions of past trends in atmospheric composition using ice cores also require to understand snowpack processes that affected the composition of interstitial air and burried snow after its deposition.Nitrate (NO3-) present in the snowpack plays an important role as it photochemically produces nitrogen oxides (NOx=NO+NO2), which affect the oxidative capacity of the atmosphere through ozone production.This thesis thus aimed at studying physico-chemical processes which take place inside the snowpack and modify nitrate concentration.In a first part, a reaction mechanism to reproduce nitrate photochemistry in snow were developed, based on previous studies. The main hypothesis was that chemical reactions take place in a quasi-liquid layer located on the surface of snow cristals. However, the properties of this ice-air interface are poorly known, and it appeared that this approach had too many uncertainties to be continued.Then, a thorough discussion were carried out to assess current attempts in snow chemistry modeling, and to propose another approach which could prevail given current knowledge on this topic.In a second part, physico-chemical exchange processes between air and snow were studied and modeled. This concerned adsorption, solid phase diffusion and co-condensation. Among the results that arise, it appeared that current parameterizations of nitrate surface coverage are unable to reproduce measured concentrations, in the studied case of Dome C surface snow, and further reveal sizeable overestimations. On the contrary, simultaneous modeling of solid phase diffusion and co-condensation allows a qualitatively good reproduction of measurements, which cover more than a year, thus including both austral summer and winter with their specific features.This study reveals the importance of exchange processes for snow chemistry modeling, and give basis for future work on this topic.
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